The invention discloses a three-
electrode battery. The three-
electrode battery comprises an outer shell, a positive
electrode, a negative electrode, diaphragms,
electrolyte, a
reference electrode and a
nickel electrode lug; the
reference electrode is arranged between the positive electrode and the negative electrode; the diaphragms are arranged respectively between the positive electrode and the
reference electrode and between the reference electrode and the negative electrode; the whole three-electrode battery is packaged in the outer shell; and the outer shell is filled with the
electrolyte. One end of the reference electrode is a naked
copper wire which is completely arranged between the positive electrode and the negative electrode, and the three electrodes are subjected to
lithium plating before an
AC impedance test; the other end of the reference electrode is a varnished wire; one portion of the varnished wire is immerged in the
electrolyte, and the other portion of the varnished wire is located outside the positive electrode and the negative electrode and extends to the outer side of the outer shell to be connected with the
nickel electrode lug; and the
nickel electrode lug is fixed with the outer shell. The invention also discloses a preparation method of the three-electrode battery. The three-electrode battery has the advantages that the
signal interference resistance is strong, the manufacturing cost is low, transmission of the
lithium ions between the positive electrode and the negative electrode is guaranteed, in-situ monitoring for the
electric potential of the positive electrode, the
electric potential of the negative electrode and the impedance of the
lithium ion battery in a use process is carried out, the detection accuracy is improved obviously, and the detection efficiency is improved.