30 results about "Ac impedance spectra" patented technology

The invention belongs to the technical field of electrochemistry, and in particular relates to a preparation method of a sulfide ore working electrode used for measuring electrochemical signals under pressure leaching process conditions of sulfide ore, a sulfide ore working electrode, and the application of the working electrode to sulfide ore working electrodes. Methods for the study of pressure leaching processes. It solves the problems of lack of devices and methods for measuring dynamic high temperature and high pressure electrochemical signals and the lack of representativeness of using natural bulk electrodes in the prior art. The sulfide ore working electrode is made of carbon powder and mineral powder mixed in a certain proportion and added with a binder (PVDF). Through the open circuit potential test, polarization curve test and AC impedance spectrum test technology, the electrochemical mechanism of chalcopyrite leaching at different temperatures is tested; with the help of AC impedance technology, the number of sub-processes in the leaching process can be distinguished, and the equivalent circuit simulation The kinetic parameters of each sub-process were obtained by methods such as the following methods, and the formation and growth mechanism of the passivation film on the chalcopyrite surface were determined.

The invention provides a fuel cell diagnosis method and diagnosis system, including: injecting synchronous multi-frequency current excitation into the fuel cell; collecting the time domain current excitation signal and voltage feedback signal of the fuel cell, and calculating the AC current at different frequency points Impedance spectrum data; construct the AC impedance spectrum model of the fuel cell, and convert the nonlinear model equation of the AC impedance spectrum model into a linear model equation; fit the AC impedance spectrum data and the linear model equation according to the principle of least squares, and obtain the AC The parameter values ​​of the impedance spectrum model; the eigenvectors of the fuel cell are obtained according to the parameter values; the fault classification algorithm is used to classify the eigenvectors, and the working status of the fuel cell is diagnosed according to the classification results, thereby greatly reducing the calculation by fitting the linear model equation The complexity and amount of calculation, and also avoid the problem that the nonlinear least squares method is easy to fall into local optimum and low precision.