The invention discloses a
lithium ion battery
thermal runaway early warning method and a multi-frequency real-time impedance test
system, and belongs to the field of
lithium ion battery safety. The method comprises the following steps: screening a frequency range sensitive to temperature change and insensitive to charge state change through an electrochemical impedance
spectroscopy experiment, selecting a characteristic frequency by adopting an RReliefF
algorithm, carrying out real-time monitoring on an impedance module value under the characteristic frequency, and judging a safety state and carrying out first-stage, second-stage and third-stage early warning based on a preset strategy; according to the multi-frequency real-time impedance test
system provided by the invention, through multi-frequency synchronous excitation, synchronous acquisition and
fast Fourier transform analysis, a multi-characteristic frequency impedance measurement period is compressed to be within 0.3 second, and
thermal runaway transient impedance change can be captured. The
lithium ion battery
thermal runaway early warning method can achieve
lithium ion battery thermal runaway full-stage grading early warning, is high in early warning accuracy and
time resolution, is stable and effective in a 0-100% full SOC range and in batteries of different chemical systems, and provides reliable
technical support for
lithium ion battery thermal runaway safety protection.