This invention belongs to the field of electrochemical
deoxygenation technology, specifically relating to an electrochemical
oxygen atmosphere control system and method. The
system, from bottom to top, includes a porous bottom cover, a first hydrophobic and breathable membrane, an
oxygen-consuming
cathode, a liquid-conducting diaphragm, an
oxygen-evolving
anode, a second hydrophobic and breathable membrane, and a porous top cover. Each component layer forms a zero-gap contact through the clamping force of the outer shell, enabling the device to achieve an ultra-thin thickness. The liquid-conducting diaphragm has a transverse liquid-conducting groove extending to the external
electrolyte chamber, utilizing
capillary action to achieve rapid
electrolyte replenishment and eliminate local hot spots. Through the
coupling design between the hydrophobic and breathable membrane and the
electrode interface, oxygen generated by the oxygen-evolving
anode directly penetrates and overflows in the form of gas molecules, effectively suppressing bubble formation and accumulation in traditional
electrolysis processes, and significantly reducing the
ohmic resistance of the interface and
operating energy consumption. This invention features an extremely thin structure, high reaction efficiency, and no bubble interference, making it suitable for precise oxygen concentration control in spaces such as refrigerators and precision storage environments.