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38 results about "Polarization impedance" patented technology

Method for sorting consistency of lithium titanate single batteries

The invention relates to a method for sorting the consistency of lithium titanate single batteries. According to the method, both static performance parameters such as capacity, voltage and internal resistance and dynamic parameters such as polarization impedance, large-current charging-discharging capacity and self-discharging capacity are considered. The method comprises the following steps that1, primary sorting is carried out according to parameters such as discharge capacity, open-circuit voltage and alternating-current internal resistance; 2, secondary sorting is carried out after the single batteries undergo high-temperature standing for a period of time; and 3, third-time sorting is carried out on the single batteries subjected to secondary sorting by detecting high-rate pulse discharge conditions, and finally the lithium titanate single batteries with high consistency are obtained. According to the method, the problem that the consistency of single batteries in an existing lithium titanate battery system is difficult to sort is solved; the performance of the battery packs which are formed by the lithium titanate single batteries sorted through the method can be better than that of battery packs which are grouped through a common grouping method; and meanwhile, compared with an existing conventional sorting method, the sorting method is simple to operate, free of redundant equipment investment, short in testing time, and facilitates industrial popularization and application.
Owner:天津普兰能源科技有限公司 +1

Impedance measurement system and method for secondary batteries

The invention discloses an impedance measurement system and method for secondary batteries and belongs to a battery measurement technology. The system comprises a battery module, a charging and discharging module, an alternating current frequency scanning module and a signal collecting and processing module. A 203c point of a 203 three-position switch of the charging and discharging circuit is connected with the negative electrode of the battery module 1, and by selecting a switch arm connected with the 203c point, the negative electrode of the battery module 1 is connected with a 202 electronic load and the positive electrode of the battery module 1 through a 203a point to form a discharging circuit. The impedance measurement system and method for the secondary batteries are applied to tests on impedance of the secondary batteries in the working state and can be used for measuring all the single secondary batteries contained in a secondary battery pack in parallel through multiple channels. The Ohm internal resistance, the electrochemical polarization impedance and the concentration polarization impedance of each secondary battery are tested out, the impedance of each secondary battery is analyzed, and the impedance measurement system and method are used for analyzing the charging and discharging performance of the batteries. The service life of the batteries is estimated, and the batteries can run more safely, stably and reliably.
Owner:TSINGHUA UNIV +1

Miniaturized broadband dual-polarized magnetoelectric dipole millimeter wave edge-emitting antenna and array thereof

The invention discloses a miniaturized broadband dual-polarized magnetoelectric dipole millimeter wave edge-emitting antenna and an array thereof. The edge-emitting antenna comprises a top metal layer(1), a first dielectric layer (2), a second metal layer (3), a second dielectric layer (4), a third dielectric layer (5), a third metal layer (6), a fourth dielectric layer (7), a fifth dielectric layer (8) and a bottom metal layer (9) which are sequentially arranged from top to bottom. A size of a transverse electric dipole is reduced through a longitudinal bending structure, miniaturization isfurther achieved, meanwhile, a dual-polarized antenna array composed of the antenna is also provided, and a millimeter wave antenna and an array structure which are wide in impedance bandwidth, low incomplexity feed structure, low in feed profile and easy to directly integrate in two polarization directions are achieved. In the invention, more than 50% of dual-polarization impedance bandwidth canbe obtained, an in-band gain fluctuation is also lower than 3dB, and a stable directional diagram is provided.
Owner:RES INST OF MILLIMETER WAVE & TERAHERTZ TECH

Methods and apparatus for controlling catalytic processes, including catalyst regeneration and soot elimination

The present invention provides methods and apparatus for controlling catalytic processes, including catalyst regeneration and soot elimination. An alternating current is applied to a catalyst layer and a polarization impedance of the catalyst layer is monitored. The polarization impedance may be controlled by varying the asymmetrical alternating current. At least one of water, oxygen, steam and heat may be provided to the catalyst layer to enhance an oxidation reaction for soot elimination and / or to regenerate the catalyst.
Owner:PAPPAS PETER D

Control system for catalytic processes

The present invention provides methods and systems for controlling a catalytic process. The control system includes: an electroconductive support having a layer of a catalyst thereon; a first electrode in contact with said electroconductive support; a second electrode in contact with said catalyst layer; a current control unit for applying a current to said first and second electrodes and for controlling and varying the amount of current applied; an impedance measurement unit for continuously, monitoring and measuring the polarization impedance across an interface between the catalyst layer and the electroconductive support; a processing-unit for comparing the measured polarization impedance with a reference value. The amount of current applied to the catalyst layer and the electroconductive support via the first and second electrodes is varied to change the polarization impedance when the measured polarization impedance differs from the reference value.
Owner:PAPPAS PETER D

Preparation method of textile electrode material and textile electrode material

The invention discloses a preparation method of a textile electrode material and the textile electrode material. The preparation method comprises the steps that firstly, pretreated fabric is soaked ina dopamine hydrochloride solution, and polydopamine coated fabric is obtained; then, the polydopamine coated fabric is soaked in a silver-ammonia solution, a glucose solution is added after a certainperiod of time, and a silver-plated fabric is obtained; the silver-plated fabric is subjected to chlorination treatment in a sodium chloride solution through an electrochemical method, and a silver-silver chloride composite coating fabric is formed; finally, the silver-silver chloride composite coating fabric is modified in a conductive polymer monomer solution through an electrochemical method,and the silver-silver chloride-conductive polymer composite coating fabric is obtained. The surface specific resistance of the textile electrode material is 0.01-5 omega, the polarization impedance ina 0.9% sodium chloride solution is 10-1000 omega, the skin interface impedance is 1K omega-100M omega at 1Hz, and the phase angle variation within the frequency range of 0.5-50Hz is 0-30 degrees.
Owner:MINJIANG UNIV

Preparation method of solid oxide fuel cell cathode by utilizing electrical spinning method

The invention relates to a preparation method of a solid oxide fuel cell cathode by utilizing an electrical spinning method, belonging to the technological field of function materials. The preparation method is characterized in that cathode material metal cations containing the stoichiometric ratio and the precursor solution or colloidal sol of the appropriate amount of polymerizer is subjected to electrical spinning on a substrate; then the spinning precursor sample is dried and sintered to prepare the solid oxide fuel cell cathode materials with a porous structure and controllable microstructure and thickness. The SOFC (Solid Oxide Fuel Cell) cathode prepared by utilizing the electrical spinning method has the advantages of large specific surface area, high porosity, adjustable aperture and good structure homogeneity; the oxygen transmission characteristic and the catalytic activity of the cathode can be enhanced; the polarization impedance is reduced; the performance in intermediate and low temperature solid oxide fuel cells is excellent; the simple, convenient and low-cost preparation of the solid oxide fuel cell cathode is realized by omitting a powder synthesis step and reducing a high-temperature sintering step; and the method comprises the preparation of perovskite structure oxide, class perovskite structure oxide and composite cathode materials.
Owner:DALIAN UNIV OF TECH

Ca-doping medium-low-temperature solid oxide fuel battery cathode material

The invention provides a Ca-doping medium-low-temperature solid oxide fuel battery cathode material, which has the composition general formula of yPrBa1-xCaxCoCuO5+delta-(1-y)M, wherein x is 0.001 to 1.0; delta is 0 to 1.0; y is 10 weight percent to 100 weight percent; M is one or the combination of more than one of Gd0.1Ce0.9O1.95, Gd0.2Ce0.8O1.9, Sm0.1Ce0.9O1.95, Sm0.2Ce0.9O1.9, Y0.16Zr0.92O2.08 and Sc0.2Ce0.01Zr0.89O2.1. The cathode material provided by the invention has the advantages that the Ca is doped into a site A of Pr BaCuCoO5+delta so as to improve the material electric conductivity and the electric chemical performance; meanwhile, the heat expansion coefficient of the material is reduced; the SOFC cathode material with excellent performance can be obtained, so that the cathode material has high oxygen catalytic reduction activity and electric conductivity in the medium-low temperature range; the polarization impedance at 700 DEG C is only 0.014 ohm cm<2>; the maximum output power of the corresponding single battery is as high as 1331 mW cm<-2> at 800 DEG C.
Owner:JIANGSU UNIV

One-dimensional SYCO cathode material and preparation method and method to prepare composite cathode by using the cathode material

The present invention discloses a one-dimensional SYCO cathode material and a preparation method and a method to prepare composite cathode by using the cathode material, and refers to a fuel cell cathode, a preparation method and the application thereof. The invention solves the problem of big interface polarized impedance of cathode material. The chemical formula of the one-dimensional nanometer fibrous SYCO cathode material is Sr1-xYxCoO3-Delta, and the SYCO cathode material is obtained through static spinning. The preparation of the composite cathode comprises the steps of a. preparing fibrous SYCO cathode slurry; b. coating the cathode slurry on an electrolyte and sintering to obtain an SYCO cathode skeleton; c. dipping the cathode skeleton in an electrolyte forerunner liquid and calcining to attach the electrolyte onto the cathode skeleton; and d. repeating step c to increase the electrolyte attached on the cathode skeleton gradually, and calcining to obtain composite cathode. The AC impedance of composite cathode obtained in the invention is up to 0.310 omega cm 2. The invention is mainly applied in solid oxide fuel cells.
Owner:HARBIN INST OF TECH

Measurement method of electrical conductivity of solution stimulated by sine wave superimposed signals of two frequencies

The invention discloses a measurement method of the electrical conductivity of a solution stimulated by sine wave superimposed signals of two frequencies. Two sine wave superimposed signals are used to stimulate an electrode. Electrode response current is filtered through two channels. One channel carries out low pass filtering to precipitate a sine wave signal of a low frequency component. The other channel carries out high pass filtering (or band pass filtering) to precipitate a sine wave signal of a high frequency component. Amplitude and phase detection are respectively carried out on the sine wave signal of the low frequency component and the sine wave signal of the high frequency component, wherein the signals are precipitated by two channels. By combining the parameters of the stimulating signals and detected amplitude and phase of the response current with an electrical conductivity cell equivalent physical model, a joint equation is listed and is solved to acquire Rx, wherein the resistance Rx of the solution to be measured, the electrode distribution capacitance Cp, the electrode polarization impedance, the double electrical layer capacitance Cx of the electrode are unknowns of the joint equation. Electrode constants are combined to calculate the electrical conductivity of the solution. According to the technical scheme, the effects of the electrode distribution capacitance, the electrode polarization impedance and the double electrical layer capacitance of the electrode on measurement can be removed.
Owner:FUJIAN NORMAL UNIV

A-bit surplus solid oxide fuel cell cathode material as well as preparation method and application thereof

The invention relates to an A-bit Pr-surplus solid oxide fuel cell cathode material and a preparation method thereof. The composition molecular formula of the cathode material is Pr1+xBaCo2O6-delta, wherein x represents Pr-surplus amount, x is greater than or equal to 0 and less than or equal to 0.1, and delta represents the content of oxygen vacancy; the invention belongs to the technical field of solid oxide fuel cell cathode materials. The electrochemical performance of PrBaCo2O6-delta is improved by means of A-bit Pr surplus in the perovskite material PrBaCo2O6-delta. The electrical conductivity, oxygen diffusion capacity and oxygen exchange capacity of the A-bit Pr-surplus Pr1+xBaCo2O6-delta material are improved to a certain extent, the polarization resistance at the temperature of 600 DEG C is only 0.046 omega cm <2>, and the maximum power output of a corresponding single cell at the temperature of 650 DEG C reaches up to 1503mW.cm<-2>. The A-bit Pr-surplus solid oxide fuel cellcathode material can obviously reduce the polarization resistance of a PrBaCo2O6-delta cathode, thus contributing to the industrial application of medium and low temperature solid oxide fuel cells.
Owner:上海翌晶氢能科技有限公司

Separator for non-aqueous secondary battery

The invention relates to the field of a lithium-ion battery and specifically relates to a separator for a non-aqueous secondary battery. The separator for the non-aqueous secondary battery provided by the invention comprises a separator base material and a coating attached on the surface of the base material. The surface layer of the coating comprises an adhering area and an electrolyte diffusion area. According to the separator for the non-aqueous secondary battery provided by the invention, the adhering strength of the separator and an electrode can be improved, moreover, after a battery technology production process is carried out, and a pore structure can stilled be kept, thereby facilitating diffusion and conduction of electrolyte and reducing polarization impedance.
Owner:DONGGUAN AMPEREX TECH

Vanadium boron co-doped negative electrode material for fuel cell and preparation method thereof

The invention relates to a vanadium boron co-doped negative electrode material for a fuel cell and a preparation method thereof, belongs to the technical field of negative electrode materials of fuelcells, and aims at providing a preparation method of the vanadium boron co-doped negative electrode material for the fuel cell. The method is characterized in that high valent vanadium and boron are used to dope a B site of an ABO3 type perovskite; dangling bonds of part of high valent vanadium atoms and boron atoms are actively combined, so that the activating energy of crystal lattices is improved, and meanwhile, the spontaneous polarization of a membrane material is reduced; the structure stability is improved while the internal polarization resistance is reduced; part of dangling bonds areused as oxygen ion adsorbing points, so that the transition barrier of oxygen ions are bent, and as a result, the transition capacity of the oxygen ions in the crystal lattices can be improved. The perovskite structural negative electrode material prepared by the method is high in ion transition capacity and stability under intermediate temperature and can be used in a solid fuel cell.
Owner:CHENDU NEW KELI CHEM SCI CO LTD

Methods and apparatus for controlling catalytic processes, including the deposition of carbon based particles

Methods and apparatus for controlling a catalytic layer deposition process are provided. A feed stream comprising a carbon source is provided to a catalyst layer. An asymmetrical alternating current is applied to the catalyst layer. A polarization impedance of the catalyst layer is monitored. The polarization impedance can be controlled by varying the asymmetrical alternating current. The controlling of the polarization impedance provides control over the structure and amount of carbon particles deposited on the catalyst layer. The carbon particles may be in the form of nanotubes, fullerenes, and / or nanoparticles.
Owner:CATELECTRIC

Dual-electrode combined member and stimulation system

PendingCN106994207APrevent in-depthHighly directional controllableEpicardial electrodesHeart stimulatorsDual coreHeart.interventricular septum
The invention relates to the field of medical instruments, discloses a dual-electrode combined member and a stimulation system, and aims at stimulating deep tissues, controllably stimulating two tissues and reducing tissue reaction and polarization impedance. The dual-electrode combined member comprises a screw type electrode or a spindle type electrode and a spiral electrode. The dual-electrode combined member, a stimulation generator and lead bodies form the stimulation system. The stimulation generator comprises a dual pulse output circuit (simply named "dual-core" heart pacemaker when it is used for the heart), and a new simulation mode through which electric pulses of opposite directions are alternately emitted is provided. The dual-electrode combined member and the stimulation system are preferably used for the ventricular septum to perform cardiac resynchronization therapy; and two brand-new cardiac synchronization modes are put forward: one mode is that left and right ventricular electrical stimulation pulses are emitted to control double ventricular electro-mechanical activity; and the other mode is that the cardiac muscle between the cathode and the anode in the ventricular septum is stimulated so that excitation is enabled to be spread to both ventricles from the ventricular septum.
Owner:刘志忠 +1

Power supply device and charging control method

The invention provides a power supply device and a charging control method. The power supply device includes: a transformer; a first conversion circuit, which is located on the primary side of the transformer and used for converting alternating current provided by a power grid into voltage in a pulse form; a second conversion circuit, which is located on the secondary side of the transformer and used for generating output current of the power supply device; a feedback circuit, which is used for generating a feedback signal of the output current; and a switch control unit, which is used for controlling the pulse-form voltage according to the power grid synchronizing signal and the feedback signal so that the waveform of the output current is consistent with the waveform of the power grid synchronization signal, wherein the power grid synchronization signal is a signal in a pulse form, the frequency of the power grid synchronization signal is n times or 1 / n times of the frequency of thealternating current, and n is a positive integer not less than 1. The output current of the power supply device is set as the current in a pulse form, so that the polarization impedance of the batterycan be reduced, the charging time of the constant-current charging stage is prolonged, and the charging efficiency of the battery can be improved.
Owner:GUANGDONG OPPO MOBILE TELECOMM CORP LTD

Thermal battery positive electrode material with high performance and preparation method thereof

The invention discloses a thermal battery positive electrode material with high performance and a preparation method thereof, and belongs to the technical field of thermal batteries. Through the steps of turbid liquid preparation, drying, calcination and the like, in-situ generation of at least one particle of nano-structure MgO, MgF2, Al2O3, AlF3, ZrO2 and SiO2 on the surface of a thermal battery positive electrode active material is realized under specific process conditions, and the wettability of a molten salt electrolyte on the thermal battery positive electrode active material is improved, so that the electrochemical reaction active area between the molten salt and the electrolyte is increased, the ion-electron exchange transfer process in the discharge process is accelerated, and the polarization impedance is reduced, so that when the high-performance positive electrode material is applied to a thermal battery product, the performance of the battery is obviously improved, and the wide application prospects are realized.
Owner:INST OF ELECTRONICS ENG CHINA ACAD OF ENG PHYSICS

Battery cluster inconsistency on-line monitoring method based on polarization impedance voltage rises

The invention discloses an energy storage power station battery cluster inconsistency online evaluation method based on polarization impedance voltage rises. The method comprises the steps: screening battery pack boxes based on two parameter indexes which are available capacity and DC internal resistance, and selecting characterization monomers; acquiring voltage rises [delta]Up and [delta]up, caused by polarization impedance, of the battery clusters and the characterization monomers in real time; acquiring a linear fitting relation f(n*[delta]up, [delta]Up), and performing derivation on the linear fitting relation to obtain a change rate k(n*[delta]up, [delta]Up), with n being the number of battery pack boxes. If the k(n*[delta]up, [delta]Up) is in an increasing trend along with the proceeding of the circulation, it shows that the inconsistency of the battery clusters is intensified. The method is low in implementation cost and easy in practical application, and online evaluation of the inconsistency of the battery clusters is effectively carried out.
Owner:CHANGSHA UNIVERSITY OF SCIENCE AND TECHNOLOGY

Modified solid oxide fuel cell electrode, in-situ solvothermal preparation method thereof and solid oxide fuel cell

The invention provides a modified solid oxide fuel cell electrode. The modified solid oxide fuel cell electrode comprises a solid oxide fuel cell electrode and modified phase nanoparticles compounded on the solid oxide fuel cell electrode, the material of the modified phase nanoparticles comprises one or more of a single metal oxide, a doped metal oxide and a perovskite type catalytic material. According to the invention, a solvothermal method is adopted for modification, in-situ growth of modified phase nanoparticles is carried out on the surface of the solid oxide fuel cell, and a modified electrode with a specific microstructure and structure is obtained. The polarization impedance of the modified electrode is obviously reduced, the output power of the cell is obviously improved, and the preparation method is simple in process, easy to operate, good in morphology controllability, low in reaction temperature and low in energy consumption, and is a preparation method of the in-situ modified solid oxide fuel cell electrode with relatively high feasibility.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI +1

Lithium ion power battery cell matching method

The invention discloses a lithium ion power battery cell grouping method, and the method comprises the following steps: charging and discharging cells, acquiring charging and discharging polarization voltage, and calculating a polarization resistance ratio; grading the battery cells according to the polarization resistance ratio r of the battery cells; removing the abnormal points of the inventory, the alternating-current internal resistance and the self-discharge parameters of the graded battery cells; and automatically grouping the cells of the same level through series-parallel connection. According to the method, the polarization impedance in the actual charging and discharging process of the battery cell is considered and is added to matching, compared with a method of grouping by capacity, the overall capacity exertion of the battery cell pack is remarkably improved, the capacity conversion rate is improved to 93%-95% from the original 85%-92%, module heat production is reduced, and internal friction is reduced. The operation is simple and feasible.
Owner:WUHU ETC BATTERY LTD

Stable solid oxide fuel cell cathode material realized by A-site regulation and preparation and application thereof

The invention belongs to the technical field of solid oxide fuel cells, and discloses a stable solid oxide fuel cell cathode material realized by A-site regulation and preparation and application thereof. The cathode material is characterized in that the composition general formula of the cathode material is AA 'B2O6-delta, the specific molecular formula of the cathode material is Ba < 1-x > Gd < 0.8 > Pr < 0.2 + x > Co2O6-delta, delta is larger than or equal to 0 and smaller than or equal to 1, and delta is the oxygen vacancy content; x satisfies 0 < = x < = 0.4. The invention also discloses a preparation method of the cathode material. The anionic material disclosed by the invention has relatively high electronic conductivity, relatively low polarization impedance, relatively low activation energy, relatively high power density and good stability. The cathode material is used for the fuel cell.
Owner:SOUTH CHINA UNIV OF TECH

Preparation method of nanofiber composite cathode for intermediate temperature solid oxide fuel cell

InactiveCN104659378BComponent distribution is evenThe active area of ​​the electrochemical reaction increasesMaterial nanotechnologyCell electrodesElectrochemical responseFiber
The invention relates to a preparation method of a nanofiber composite negative electrode of an intermediate-temperature solid oxide fuel cell, belonging to the technical field of energy materials. The preparation method comprises the following steps: firstly preparing a mixed spinning solution containing perovskite structured oxide components and oxygen ion conductor electrolyte components, spinning the mixed solution by virtue of an electrospinning technique to prepare composite fiber, drying and carrying out high-temperature sintering, so as to obtain nanofiber structured composite negative electrode. The diameter of the composite negative electrode fiber is 100-600 nanometers; nanofiber is formed by virtue of agglomeration of perovskite oxide components and electrolyte component nano-particles, wherein the mass percent of the perovskite oxide components is 45%-65%. Components in the nanofiber negative electrode are uniformly distributed, so that the transmission of ions and electrons is benefited; the activation area of electrochemical reaction and the interface of three-phase reaction are large, so that the oxygen reduction catalytic activity of the negative electrode is improved, and the polarization impedance of the negative electrode is reduced; furthermore, the preparation process is simple, the operation is easy, and the cost is low.
Owner:DALIAN UNIV OF TECH

Impedance measurement system and impedance measurement method of a secondary battery

The invention discloses an impedance measurement system and method for secondary batteries and belongs to a battery measurement technology. The system comprises a battery module, a charging and discharging module, an alternating current frequency scanning module and a signal collecting and processing module. A 203c point of a 203 three-position switch of the charging and discharging circuit is connected with the negative electrode of the battery module 1, and by selecting a switch arm connected with the 203c point, the negative electrode of the battery module 1 is connected with a 202 electronic load and the positive electrode of the battery module 1 through a 203a point to form a discharging circuit. The impedance measurement system and method for the secondary batteries are applied to tests on impedance of the secondary batteries in the working state and can be used for measuring all the single secondary batteries contained in a secondary battery pack in parallel through multiple channels. The Ohm internal resistance, the electrochemical polarization impedance and the concentration polarization impedance of each secondary battery are tested out, the impedance of each secondary battery is analyzed, and the impedance measurement system and method are used for analyzing the charging and discharging performance of the batteries. The service life of the batteries is estimated, and the batteries can run more safely, stably and reliably.
Owner:TSINGHUA UNIV +1

Electrochemical device and electronic device comprising same

The invention relates to an electrochemical device and an electronic device comprising the same. The electrochemical device comprises an electrolyte, a positive electrode and a negative electrode. Thenegative electrode comprises a negative electrode active material layer, the negative electrode active material layer includes a negative electrode active material, and the electrolyte includes fluoroethylene carbonate, wherein the electrochemical device satisfies the following relational expressions: 0.5 < Rct / Rcp < 1.5, both Rct and Rcp are less than 35 milliohms, and 0.005 <= A / B <= 0.1; Rct represents the charge transfer impedance in a 50% state of charge at 25 DEG C, and Rcp represents the concentration polarization impedance in a 50% state of charge at 25 DEG C; the mass of the fluoroethylene carbonate corresponding to 1g of the negative electrode active material is Ag, and the specific surface area of the negative electrode active material is B m <2> / g. The invention aims to improve the quick charging performance of the electrochemical device while maintaining the cycle performance of the electrochemical device.
Owner:NINGDE AMPEREX TECH

Method for Measuring the Conductivity of a Solution Excited by Two Frequency Sine Wave Superposition Signals

The invention discloses a measurement method of the electrical conductivity of a solution stimulated by sine wave superimposed signals of two frequencies. Two sine wave superimposed signals are used to stimulate an electrode. Electrode response current is filtered through two channels. One channel carries out low pass filtering to precipitate a sine wave signal of a low frequency component. The other channel carries out high pass filtering (or band pass filtering) to precipitate a sine wave signal of a high frequency component. Amplitude and phase detection are respectively carried out on the sine wave signal of the low frequency component and the sine wave signal of the high frequency component, wherein the signals are precipitated by two channels. By combining the parameters of the stimulating signals and detected amplitude and phase of the response current with an electrical conductivity cell equivalent physical model, a joint equation is listed and is solved to acquire Rx, wherein the resistance Rx of the solution to be measured, the electrode distribution capacitance Cp, the electrode polarization impedance, the double electrical layer capacitance Cx of the electrode are unknowns of the joint equation. Electrode constants are combined to calculate the electrical conductivity of the solution. According to the technical scheme, the effects of the electrode distribution capacitance, the electrode polarization impedance and the double electrical layer capacitance of the electrode on measurement can be removed.
Owner:FUJIAN NORMAL UNIV

Lithium battery electrochemical polarization impedance detection method

PendingCN112327186AAccurate detectionWide impedance measurement rangeElectrical testingElectrolytic agentElectrical battery
The invention relates to the technical field of impedance detection, and discloses a lithium battery electrochemical polarization impedance detection method. The method comprises the following steps that: S1, before electrochemical impedance detection treatment is carried out on a lithium battery, the lithium battery is made to stand in a ventilated and dry environment, so that an electrolyte canbe in a balanced state, the deviation of the electrochemical polarization impedance of the battery caused by the imbalance of the electrolyte is avoided; S2, the current flowing through the lithium battery also flows through a resistor Rr, the potential of the L point is kept to be 0V, and an I-V conversion amplifier enables the current on the Rr and the current on the lithium battery to be balanced; and S3, the high-end voltage and the voltage of the Rr are measured, so that the impedance value of the lithium battery can be calculated. According to the lithium battery electrochemical polarization impedance detection method can detect the electrochemical polarization impedance value of the lithium battery more accurately and has a wider impedance measurement range. It can be ensured that awider detection condition is provided, so that the detection method has simple performance.
Owner:安可捷检测(常州)有限公司
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