The invention relates to the technical field of
fuel cells, and provides a
solid oxide fuel
cell and a preparation method thereof, and the preparation method comprises the following steps: providing a half-
cell precursor comprising an
electrolyte layer and a NiO-based
ceramic layer; placing the half-
cell precursor in an acid solution for reaction treatment, selectively
etching to remove at least part of NiO phase in the NiO-based
ceramic layer, and cleaning to form a porous
ceramic layer; injecting
nickel slurry into pores of the porous ceramic layer, and performing
drying and first
calcination treatment to form a porous Ni-based
metal ceramic composite anode layer; and preparing a porous
cathode layer on the surface of the other side of the
electrolyte layer to form the
solid oxide fuel cell. According to the method, the NiO phase of the NiO-based ceramic layer is removed by using the
pickling solution, and the
nickel slurry is injected to construct the porous Ni-based
metal ceramic composite anode, so that the problems that the pore structure is random and difficult to control when the porous
anode is prepared by pore-forming of a traditional pore-forming agent and reduction of NiO by introducing
hydrogen, and the active area of the anode is reduced due to migration, agglomeration and coarsening of Ni particles are solved.