The invention relates to a determination method of
zinc in
gold alloy, and belongs to a determination method of amount of
zinc in
gold alloy. The method comprises the following steps:
aqua regia is used for dissolving a sample material, hydrazine
hydrate is used for deposition and separation gold, filtering is carried out, and filter residues are used for recycling gold;
sodium hydroxide and a
hydrogen peroxide solution are added into a filtrate for deposition and separation of
nickel and
copper, filtering is carried out, and an
acetic acid-
sodium acetate
buffer solution is added into the filtrate;
xylenol orange is used as an indicator, EDTA is used for
titration till the color of the solution changes into luminous yellow from
wine red, and the
titration volume is used for calculating the content of
zinc;
hydrochloric acid is added into the filter residue for dissolving,
volumetric flask is prepared, the amount of zinc is determined by an atomic absorption
spectrometer at the
wavelength of 213.8nm, and sum of the zinc contents which are determined by the two determination methods is the content of the zinc in the
alloy. The method can be used for accurately determining the content of zinc in the
gold alloy, and is suitable for analysis on a large scale, at the same time the method fills the blank of determination methods of zinc in gold
alloy.