1057 results about "Cyanide" patented technology

The invention discloses a preparation method and application of a prussian blue material, and belongs to the field of battery materials.The preparation method of the prussian blue material comprises the following steps that S1, a solution containing ferrocyanide is prepared to serve as a raw material A, a solution containing transition metal salt is prepared to serve as a raw material B, a to-be-doped solution C containing alkali metal ions is prepared, the method comprises the following steps: S1, preparing a to-be-doped solution C containing transition metal ions, S2, adding a base solution into a container, continuously adding the raw material A and the raw material B into the base solution, and stirring and mixing to form a precipitate, and S3, in the precipitation process, continuously adding the to-be-doped solution C into the raw material A and continuously adding the to-be-doped solution D into the raw material B until the precipitation is finished to obtain the Prussian blue material. According to the invention, the moisture resistance, the rate capability and the cycle stability of the Prussian blue material are greatly improved.

Active materials (e.g., alkali-metal metal phosphate (e.g., lithium iron phosphate), alkali-metal metal oxide and / or alkali-metal metal cyanide materials), preparation processes, and apparatuses useful in the manufacture thereof are described. Well-ordered active material particles (e.g., lithium iron phosphate particles) prepared by the processes and manufacturing apparatuses disclosed herein are also described.

The invention belongs to the field of electrochemistry, and particularly relates to a method for electrochemical lithium extraction of a decommissioned lithium battery assisted by a pseudocapacitor cathode, which comprises the following steps: a) providing an anode electrode and a cathode electrode; the anode electrode is an anode electrode made of a recycled retired lithium battery anode material or an retired lithium battery anode plate; the cathode electrode contains a Prussian blue analogue, the Prussian blue analogue is prepared by mixing citrate, transition metal salt and cyanide in water for reaction, and the transition metal salt is one or more of cobalt salt, ferric salt, copper salt and nickel salt; and b) immersing the anode electrode and the cathode electrode into the electrolyte, and electrifying to carry out electrochemical lithium extraction. According to the method, a pseudocapacitance material with a lithium discharging characteristic is adopted as a cathode to replace a common metal pole plate or a carbon material, a pseudocapacitance reaction with a corrected electrode potential is adopted to replace a hydrogen evolution reaction on the cathode of an existing system, and finally, low-energy-consumption and high-selectivity recovery of lithium is realized.

The invention discloses a cyanide-free cadmium-iron alloy plating process for high-strength structural steel. The cyanide-free cadmium-iron alloy plating process comprises the step that a nickel-titanium alloy plating layer, a cyanide-free cadmium-iron alloy plating layer and a hexavalent chromium passivation film are sequentially prepared on a high-strength structural steel substrate from inside to outside. The prepared sample piece is subjected to a hydrogen brittleness test according to HB 5067.1-2005 Part 1 of hydrogen brittleness test of plating process: Mechanical Method, and the test result meets the standard requirement; the surface of a plated part is free of white rust after being subjected to an acetate mist test for 400h according to GB / T 10125-2021 Artificial Atmosphere Corrosion Test Salt Spray Test, and a plating layer of the plated part has excellent corrosion resistance; according to GB / T 5270-2005 < GB / T 5270-2005 < GB / T > 5270-2005 < GB / T > 5270-2005 > < GB / T > 5270-2005 > < GB / T > 5270-2005 > < GB / T > 5270-2005 > < GB /

The invention discloses an alkaline cyanide-free cadmium plating process for an ultrahigh-strength steel part. The alkaline cyanide-free cadmium plating process comprises the steps of oil removal, stress elimination, electrolytic oil removal, flowing water washing, weak corrosion, flowing cold water washing, copper pre-plating, flowing cold water washing, alkaline cyanide-free cadmium plating, flowing water washing, hydrogen removal, aftertreatment, drying and inspection. In order to avoid the situation that the metal surface of the workpiece is passivated in a plating tank, the pretreatment process is adopted, a cyanide-free copper electroplating layer is pre-plated on the surface of the workpiece, the surface of the part is adjusted, the surface activity is improved, and then the binding force of a base body and the plated cadmium is improved; according to the method, a stress eliminating process and a long-time hydrogen removing process after plating are adopted before plating, so that the hydrogen embrittlement risk is reduced, the process steps are simple, and the implementation is high.

The invention provides a cyanide breaking agent and method for treating alkaline cyanide-containing wastewater. The cyanide breaking agent is a combination of an oxidizing agent, a Fe3O4 ZIF-8 core-shell magnetic catalyst and PDMS-hydrophobic silicon dioxide composite liquid. Through a catalytic oxidation-adsorption integrated method, the reaction path is shortened, efficient removal of cyanide is realized, the effluent is far lower than 0.5 mg / L specified by the national standard, a recyclable product is obtained, and the risk of secondary pollution caused by HCN or heavy metal precipitation is reduced; non-photocatalytic nanoscale Fe3O4-ZIF-8 core-shell magnetic catalyst particles are combined with PDMS-hydrophobic silicon dioxide composite liquid to cooperate with an oxidizing agent, the process that cyanide is converted into non-toxic products through integrated two-stage oxidation is promoted, and meanwhile the content of ammonia nitrogen in wastewater is further reduced by combining modified activated carbon.

The invention relates to the technical field of sewage treatment, in particular to a wastewater recycling method which comprises the following steps: cyanide breaking: in an alkaline environment, adding an oxidizing agent to oxidize wastewater; first monitoring: monitoring the oxidation reduction potential and the free cyanide concentration in real time, and adjusting the adding proportion of sodium hypochlorite based on the ORP dynamic range and the cyanide concentration attenuation rate; precipitation: adding hydroxide, and carrying out heavy metal precipitation; second monitoring: acquiring component information in the sewage, and adding sodium hydroxide and sodium sulfide in a gradient compensation manner after triggering judgment; membrane treatment: performing filtration and degradation treatment through a biological membrane; 3, monitoring: dynamically adjusting the aeration intensity and the backwashing period according to the coupling relationship between the pressure difference slope and the sludge concentration; and 4, monitoring: calculating a process capability index, judging whether the process capability index is smaller than a third threshold value, and if so, adjusting the sodium sulfide dosage in the precipitation stage. The method has the effect of reducing resource waste in the wastewater treatment process.

The invention belongs to the technical field of solid pollutant treatment, and particularly relates to a method for removing cyanide in cyanidation tailings through metal activated persulfate oxidation. The problems that different cyanide removal mechanisms are different, the removal efficiency is low, the cost is high, secondary pollution is easily caused and the like exist in treatment of the cyanidation tailings. The tailings are subjected to cyanogen reduction treatment by adopting a stage treatment method. The method comprises the following steps: firstly, crushing the tailings to prepare a charcoal-loaded metal composite material Me / BC; when free cyanide in the tailings is smaller than or equal to 50 mg / kg, Me / BC activated persulfate is used for conducting cyanide reduction treatment on the tailings; when the tailings contain free cyanide gt; when the concentration is 50 mg / kg, free cyanides in the tailings are removed through leaching, and then Me / BC is used for activating persulfate to degrade strong complex state cyanides in the tailings. By adopting the method, the problems that complex cyanide is difficult to remove by a single leaching method and persulfate is large in dosage and high in cost in a single oxidation method can be solved, and the cascade cyanogen removal method is efficient, low in cost and free of secondary pollution.

The cyanide-free copper-zinc alloy plating solution comprises 18-24 g / L of polycuprous thiocyanate, 9-13 g / L of polyzinc thiocyanate, 130-170 g / L of polysodium thiocyanate and 8-12 mL / L of brightener, the pH value of the plating solution is 10-12, the temperature of a plating bath is 35-55 DEG C, the cathode current density is 0.5-1.5 A / dm < 2 >, the cathode movement speed is 3-5 m / min, a copper-zinc alloy plate with the copper mass fraction being 68% is used as an anode, and the anode movement speed is 3-5 m / min. The brightening agent is prepared from 60 to 100 parts of N, N '-di-n-propylethylenediamine, 10 to 20 parts of waterborne polyurethane resin, 80 to 120 parts of polyacrylamide of which the molecular weight is less than 8000 and 770 to 870 parts of deionized water. A steel matrix or zinc alloy matrix copper-zinc alloy and bright nickel plated sample piece is subjected to an acetate fog test for 72 h according to GB / T 10125-2021 Artificial Atmosphere Corrosion Test Salt Spray Test, the surface of the steel matrix or zinc alloy matrix copper-zinc alloy and bright nickel plated sample piece is free of rust, and according to GB / T 5270-2005 Metal Covering Layer Electro-Deposition and Chemical Deposition Layer Adhesive Strength Test Method, the coating binding force is tested by a thermal shock method. And the result meets the standard requirement.

The invention discloses a double-metal cyanide catalyst as well as a preparation method and application thereof, and belongs to the technical field of double-metal cyanide catalysts. The preparation method of the double-metal cyanide catalyst comprises the following steps: S1, mixing a metal salt aqueous solution and a metal cyanide aqueous solution, and reacting to obtain double-metal cyanide slurry; and S2, adding acid into the double-metal cyanide slurry, aging, centrifuging and drying to obtain the double-metal cyanide catalyst, the weight ratio of the double metal cyanide slurry to the acid in the step S2 is 1: (0.001-0.004); the metal cyanide in the metal cyanide aqueous solution comprises cobalt element. When the double metal cyanide catalyst is used for preparing polyether, the chromaticity of the polyether can be reduced.

The invention discloses a cyanide-free cadmium plating bath solution, a preparation method of the cyanide-free cadmium plating bath solution and application of the cyanide-free cadmium plating bath solution in cadmium plating. The cyanide-free cadmium plating bath solution comprises the following components according to the concentration: 50-70 g / L of cadmium chloride, 180-250 mL / L of an etidronic acid aqueous solution, 16-33 g / L of potassium sodium tartrate, 0.01-0.2 g / L of polyethylene glycol, 0.01-0.2 g / L of a brightener and 0.01-0.1 g / L of an additive HY. The method has the advantages that the bath solution is environment-friendly and non-toxic, wastewater treatment is simple, a plating layer is high in deposition speed, fine in crystallization and good in binding force, the problems that cyanide cadmium plating pollutes the environment, EDTA cadmium plating is poor in stability and the like are effectively solved, and the method has good application value and economic and social benefits.

The invention discloses a cellulose-based lithium ion battery diaphragm capable of promoting lithium ion migration as well as a preparation method and application of the cellulose-based lithium ion battery diaphragm. The method comprises the following steps: dissolving a plant fiber raw material into a prepared alkali alcohol urea solvent, and then introducing a fluorine-containing modifier and a cyano-containing modifier to modify the plant fiber raw material; and then coating the surface of a polytetrafluoroethylene film with the obtained modified cellulose solution for preheating and shaping, then dipping in water to finish final shaping of the diaphragm and removal of non-cellulose components, and finally performing hot-pressing and drying to remove moisture, thereby obtaining the cellulose-based lithium ion battery diaphragm capable of promoting lithium ion migration. A fluorine-containing group and a cyano-containing group are simultaneously introduced into a cellulose molecular chain, so that the lithium ion migration promoting effect and the electrochemical performance of the battery diaphragm can be effectively improved.

The invention discloses a method for preparing a mine filling cementitious material by using cyanide tailings, comprising the following steps: weighing dried cyanide tailings, secondary aluminum ash, barium slag and phosphogypsum in proportion, and putting them into a tank mixer for mixing; after uniform mixing, adding sodium hydroxide solution for wetting, and using a tablet press to press the powder into a cubic green body, and placing the green body in an oven for drying without overlapping; putting the dried green body into a high-temperature box-type muffle furnace for calcining; adding phosphogypsum into the calcined clinker phase, crushing the green body, and sending the green body into a ball mill for ball milling treatment to obtain a cementitious material, and using tailings as aggregates, and supplemented with a polycarboxylic acid water reducer, and adding water to prepare a cementitious material for mine filling; the invention uses cyanide tailings as raw materials, and combines industrial solid wastes such as barium slag, secondary aluminum ash and phosphogypsum, and adopts a one-step activation method to prepare a cementitious material, which can simultaneously complete the decyanation and detoxification of the tailings and the activation of the tailings, has a simple process flow, and the prepared filling material has a fast hydration and hardening rate, good fluidity and high mechanical strength.

The utility model discloses a thermal hydrolysis cyanide breaking device, which relates to the technical field of wastewater treatment and comprises a cyanide breaking reactor, a wastewater heat exchanger, a pipeline mixer, a steam mixer, an instrument control valve and the like. After being heated by the wastewater heat exchanger, the wastewater enters a cyanide breaking reactor, and steam enters a steam mixer to heat the wastewater to a specified temperature and then enters the cyanide breaking reactor. The characteristic that the cyanide aqueous solution is easy to hydrolyze is utilized, so that the cyanide aqueous solution is hydrolyzed at the temperature of higher than 140 DEG C to produce sodium formate and ammonia, the toxicity of cyanide is eliminated, high-temperature wastewater discharged from the cyanide breaking reactor enters the wastewater heat exchanger to exchange heat with wastewater to be treated, and heat is recovered; the pressure of the reactor is controlled through a wastewater heat exchanger outlet wastewater outlet pipeline pressure regulating valve. The cyanide wastewater treatment device is reasonable in design, only a small amount of sodium hydroxide is needed for adjusting the pH of wastewater, no chemical agent needs to be added in other procedures, the cyanide wastewater treatment efficiency is improved, and the cost is saved.

The invention discloses a track kiln for preparing high-strength basalt aggregate from cyanidation tailings, and relates to the technical field of solid waste recycling, the track kiln comprises a base, a track and a kiln car, the track is fixedly mounted at the top of the base, and the kiln car is internally provided with a self-propelled structure and can travel along the track; the device further comprises a side frame fixedly connected to the top of the kiln car, hollow shafts are symmetrically and fixedly connected to the inner side of the side frame, and the sides, close to each other, of the two hollow shafts are fixedly connected with center gears. Raw materials are conveyed in the form of arranging the tunnel kiln, the raw materials are contained in the trays in the conveying process, the materials move in a static mode along with the kiln car, no relative rolling exists between particles, large friction does not exist between the raw materials and between the raw materials and the conveying system, and particle shape damage caused by friction is reduced; the problems that irregular-structure raw material particles outside the raw materials are crushed or rubbed flat due to mutual friction of the raw materials, irregular forms cannot be reserved, and the mechanical property of the aggregate is affected are solved.

The invention relates to a flow battery carbon-based electrode and a preparation method and application thereof, and the preparation method comprises the following steps: respectively dissolving cobalt salt and alkali in a polar organic solvent, and uniformly mixing to form a precursor solution; placing a carbon-based material in the precursor solution, and carrying out a hydrothermal reaction to obtain a carbon-based electrode precursor; and performing high-temperature carbonization on the carbon-based electrode precursor in an inert atmosphere, cooling to room temperature after the reaction is completed, and then cleaning and removing impurities from a product to obtain the carbon-based electrode, the polar organic solvent is at least one of formamide, acetonitrile and N, N-dimethylformamide; after cobalt cyanide is deposited on the surface of the carbon-based material, surface etching and nitrogen doping are carried out on the carbon-based material under the high-temperature condition, surface modification of the carbon-based material is achieved, the contact area of the surface of the carbon-based electrode and electrolyte is increased, and the electrochemical performance of the carbon-based electrode is improved.

The invention discloses a catalyst for simultaneously removing cyanide and organic matters in wastewater by a peroxymonosulfate oxidation method as well as a preparation method and application of the catalyst, and belongs to the field of chemistry and chemical engineering, in particular to the technical field of catalyst preparation. According to the preparation method, metal oxides such as molybdenum, cerium, vanadium and the like are introduced as a substrate, precise doping of cobalt and nickel and loading of noble metal nanoparticles are performed, and the structural stability and the anti-sintering capability of the catalyst are enhanced through surface modification while uniform distribution of metal elements is ensured, and efficient performance is kept for a long time under high-temperature complex reaction conditions; the catalyst prepared by the method is applied to simultaneous removal of cyanides (free cyanogens and complex cyanogens) and organic matters in wastewater by a peroxymonosulfate oxidation method, has excellent catalytic activity, can quickly reach the degradation rate of 90% or above for 100pmm cyanides (free cyanogens and complex cyanogens) and 200mg / LCOD organic matters in wastewater, and has excellent degradation effect and reaction rate.

The invention discloses an electrolyte based on a fluorine-containing polynitrile compound and a high-voltage supercapacitor, and belongs to the field of energy storage materials. The electrolyte comprises a fluorine-containing polynitrile compound, an organic solvent and electrolyte salt; the structure of the fluorine polynitrile compound is as follows: Fm-A-(CN) n, wherein A is C1-C10 alkyl, C6-C14 aryl or a heteroatom-containing linking group, m is greater than or equal to 1, and n is greater than or equal to 2. By introducing the Fm-A-(CN) n structure compound and utilizing the synergistic effect of fluorine atoms and cyano groups, a stable interfacial film is formed on the surface of an electrode, so that the working voltage of the electrolyte is increased to 3-3.2 V. The capacitance decay rate of the electrolyte in the range of 60-80 DEG C is lt; the method is suitable for the fields of vehicle-mounted energy storage, power grid frequency modulation and the like.

The embodiment of the invention relates to the photovoltaic field, and provides a cyanide-free electroplating silver-coated copper conductive material, a preparation method thereof and a crystalline silicon solar cell. The silver-coated copper electrode provided by the embodiment of the invention comprises a copper core and a copper-tin alloy electroplated layer coated on the surface of the copper core, the surface of the pre-plating material is coated with the silver electroplating layer; the surface of the silver-coated copper material is coated with the self-repairing layer; wherein the self-repairing layer comprises a resin film and a pH response type microcapsule, the microcapsule is embedded in the resin film, and the microcapsule is filled with an ammonium molybdate corrosion inhibitor. The copper-silver interface bonding force can be improved through the copper-tin alloy electroplated layer, and the silver layer material does not contain cyanogen and is environmentally friendly; the corrosion inhibitor in the pH response type microcapsule in the self-repairing film layer on the surface of the silver layer is released under a specific pH condition to form a protection film on the silver layer again, so that the self-repairing purpose is achieved, and the dynamic protection effect is achieved.

The invention provides a method for detecting related substances of bromo-n-butane, which adopts a gas chromatography detection method, and the chromatographic conditions are as follows: a chromatographic column is a DB-624 quartz capillary column, and the specification is 30m * 0.32 mm * 1.8 [mu] m; the column temperature is 40 DEG C; the stationary phase is 6% of cyanopropyl phenyl-94% of dimethyl polysiloxane; the temperature of a sample injector is 250 DEG C; the sample size is 1 [mu] L; the split ratio is 20: 1; the carrier gas is nitrogen; the flow rate of nitrogen is 2.1 mL / min; a detector is a hydrogen ion spark detector, and the temperature of the detector is 250 DEG C. The invention further provides application of the method. The method can be used for rapidly and accurately detecting the related substances of the n-butyl bromide, realizes effective separation of the n-butyl bromide and impurities thereof, and is of great significance in improving the effective quality of the n-butyl bromide, controlling the content of the impurities brought into the synthesis reaction of the bupivacaine hydrochloride by the starting material and improving the quality stability of the bupivacaine hydrochloride.

According to the harmless filling method and system for the cyanide-containing tailings, cyanide-containing tailing slurry is directly subjected to filter pressing and dehydration, and rapid and efficient solid-liquid separation is achieved under the vacuum effect by adopting a ceramic filter press and utilizing a special microporous ceramic filter plate of the ceramic filter press. Furthermore, cyanide-containing wastewater is recycled and treated, and recycled water is used for washing and / or slurry preparation, so that the cyclic utilization of water resources is realized, the consumption of fresh water is reduced, and the production cost is reduced. By utilizing the belt conveyor with an accurate metering function, accurate control of the adding amount of the tailing filter cake is realized, and the consistency of the raw material proportion and the target value during subsequent stirring is ensured. Moreover, through automatic adjustment of online concentration monitoring and a central control system, real-time water supplementing adjustment can be achieved, it is ensured that the slurry concentration is always close to a set value, and therefore the uniformity and quality of filling materials are improved. In the filling process, the accuracy and the high efficiency of filling operation are ensured through the application of real-time monitoring and automatic control technologies.

The invention relates to an electrolyte and a preparation method thereof, a zinc-iron flow battery, a power utilization device and an energy storage device. The electrolyte comprises the following components: ferrous cyanide salt, alkali, a catalyst and water; the catalyst comprises a compound with the following structural formula: # imgabs0 #, wherein each R is respectively and independently 4-carboxyl phenyl, 4-sulfonyl phenyl, 4-aminophenyl or 4-phosphorous acid; m is iron (III), cobalt (II), manganese (II) or nickel (II). The electrolyte is beneficial to electron and proton transfer and can effectively reduce an electrochemical reaction energy barrier, so that the electrochemical reaction rate and the ionic conductivity are improved, the battery energy efficiency is improved, and the voltage loss is reduced.

The invention relates to the technical field of hazardous waste resource utilization, in particular to a method for recycling overhaul slag and chromium-containing aluminum mud. The overhaul slag contains fluoride, cyanide and carbon, the chromium-containing aluminum mud contains aluminum and hexavalent chromium, and the method comprises the following steps: carrying out redox reaction on inorganic acid, the chromium-containing aluminum mud and the overhaul slag to obtain a decyanation material containing fluoride, carbon, aluminum and chromium; carrying out a precipitation reaction on the decyanation material by using a calcium-containing alkaline oxide to obtain a precipitation material containing chromium, aluminum, carbon and fluorine; carrying out chlorination reaction on the precipitation material by using preheated chlorine to obtain aluminum-containing chlorinated flue gas and chromium-containing chlorinated slag; separating and purifying the aluminum-containing chlorinated flue gas to obtain an aluminum-containing solid phase; and washing the chromium-containing chlorination slag to obtain a trivalent chromium-containing solution. According to the method, the chromium-containing aluminum mud and the overhaul slag are used as raw materials, and the removal effect of toxic elements in the overhaul slag and the chromium-containing aluminum mud and the recovery rate of valuable elements such as aluminum and chromium can be synchronously improved through the oxidation-reduction reaction, the precipitation reaction and the chlorination reaction.

The invention relates to the technical field of catalysts, and provides a catalyst and a preparation method thereof, and an application of the catalyst in carbon dioxide-based degradable plastics, the catalyst is a supported catalyst, and comprises a carrier and an active component; the carrier comprises ternary hydrotalcite, and the active component comprises double metal cyanide and a rare earth yttrium complex; the raw material of the double metal cyanide comprises a cyano coordination compound; the cyano coordination compound comprises potassium hexacyanomanganate and / or potassium hexacyanocobaltate. According to the technical scheme, the problems of low yield and more byproducts when the catalyst is used for catalyzing and preparing the carbon dioxide-based degradable plastic in the related technology are solved.

The invention belongs to the technical field of surface treatment, and particularly relates to a method for predicting the thickness of a cyanide-free electrogalvanizing coating. Comprising the following steps: step 1, preparing a cyanide-free electrogalvanizing solution; 2, cyanide-free electrogalvanizing test parameters are designed, and a test is conducted; 3, the thickness of a cyanide-free electrogalvanizing coating is obtained according to a cyanide-free electrogalvanizing test; step 4, establishing a cyanide-free electrogalvanizing coating thickness model; and 5, performing parameter optimization on the cyanide-free electrogalvanizing coating thickness model, thereby predicting the cyanide-free electrogalvanizing coating thickness according to the parameter-optimized cyanide-free electrogalvanizing coating thickness model.

The invention provides a preparation method of a chlorantraniliprole key intermediate 2-amino-5-cyano-N, 3-dimethyl benzamide, which comprises the following steps: taking cheap and easily available o-methylaniline as a raw material, acylating an aniline substrate through Boc anhydride, carrying out ortho-lithiation on n-butyllithium, introducing carbon dioxide gas, and carrying out acid hydrolysis to obtain 2-amino-3-methyl benzoic acid, thereby obtaining the chlorantraniliprole key intermediate 2-amino-5-cyano-N, 3-dimethyl benzamide. The preparation method comprises the following steps: firstly, preparing an isatoic anhydride intermediate, then carrying out triphosgene ring closing to obtain an isatoic anhydride intermediate, carrying out bromine para-position halogenation, carrying out cuprous cyanide high-temperature Rosenmn-von Braun reaction, and finally carrying out methylamine ring opening to obtain the target product 2-amino-5-cyano-N, 3-dimethylbenzamide, and although the route is long, the yield is high, the continuity is good, few industrial three wastes are generated, and the cost is lower, so that the preparation method has great industrial production value.

The invention provides a cyanide generation and absorption efficiency monitoring method based on double-color indicator gradient change, and belongs to the technical field of cyanide monitoring, the absorption process is visually reflected through the double-color indicator gradient change, the absorption efficiency can be rapidly judged through color change without a complex instrument, the operation is simple and convenient, and the cost is low. And gradient color development and spectral analysis are combined, so that the detection limit can reach a mu g / L level, the trace detection requirement is met, and the absorption condition of the low-concentration cyanide can be accurately monitored. Through real-time change of the color gradient, the concentration distribution and the reaction process of the cyanide in the absorption process can be dynamically reflected, real-time data support is provided for industrial process control and environmental emergency monitoring, expensive detection equipment is not needed, the reagent cost is low, and the method is suitable for large-scale popularization and application.

The invention relates to the technical field of wastewater processing, and discloses a cyanide remover formula for total cyanide wastewater in coal chemical industry, which comprises the following steps: S1, preparation of formula materials: the raw materials to be prepared comprise calcium hypochlorite, hydrogen peroxide, ferrous sulfate, polyferric sulfate and lime, and the dosage of the calcium hypochlorite is adjusted according to the concentration of cyanide in the wastewater; generally, 50-100g of calcium hypochlorite can be added into per cubic meter of wastewater, 100-200ml of hydrogen peroxide can be added into per cubic meter of wastewater, and 50-100g of ferrous sulfate can be added into per cubic meter of wastewater. According to the cyanide remover formula for the total cyanide wastewater in the coal chemical industry, calcium hypochlorite and hydrogen peroxide serve as strong oxidants, cyanide can be directly oxidized into low-toxicity or non-toxic substances, the oxidation capacity far exceeds that of aluminum salt and ferric salt in a comparison case, and the oxidation reaction speed is high; the cyanide can be effectively removed within a short time, and the treatment efficiency is improved.

The invention discloses a treatment and resource recycling method of electroplating cyanide copper wastewater, and belongs to the technical field of electroplating wastewater treatment. The method comprises the following steps: carrying out strong base regulation on the cyanogen copper wastewater, and putting a ferrous sulfate solution into the cyanogen copper wastewater subjected to strong base regulation to carry out binding reaction; adding acid to adjust the cyanide copper wastewater after the binding reaction, and carrying out Prussian blue reaction; adding a coagulation aid agent into the solution after the Prussian blue reaction, and carrying out solid-liquid filtration separation on the solution to obtain ferricyanide mud and preliminarily precipitated cyanogen-removed wastewater; carrying out weak base regulation on the preliminarily precipitated cyanogen-removed wastewater, adding hydrogen peroxide into the preliminarily precipitated cyanogen-removed wastewater subjected to weak base regulation, and carrying out oxidation reaction by using copper in the preliminarily precipitated cyanogen-removed wastewater subjected to weak base regulation as a catalyst so as to remove residual cyanogen-containing pollutants; and after the oxidation reaction is finished, lime is added for flocculent precipitation to obtain copper sludge, so that the copper cyanogen compound is converted into a recyclable resource through a one-time technological process, and the resource utilization rate is increased.

The invention discloses a method for quantitatively testing the content of organic carbon and disseminated particle size in gold ore, and belongs to the technical field of gold ore detection. The method comprises the steps of sample preparation and quantitative testing, wherein palm wax serves as a cementing agent, barite serves as a standard sample, and a to-be-tested sample is prepared through melting, mixing, consolidation, polishing and carbon spraying; the quantitative test is based on an automatic process mineralogy test system, palm wax backgrounds are removed through backgrounds deduction, an energy spectrum library is established to recognize organic carbon and barite particles, the area ratio of the organic carbon and the barite particles is measured, the mass ratio is converted by combining the density ratio, the organic carbon content of raw ore is inversely calculated, and meanwhile, the particle size distribution of the organic carbon is counted. The method solves the problem that the content and granularity of organic carbon cannot be accurately quantified at the same time in the prior art, has the advantages of high test precision, high efficiency, comprehensive parameters and simplicity and convenience in operation, and can provide key data for optimization of a gold ore cyanidation leaching process.