30 results about "Cuprous ion" patented technology

The invention belongs to the technical field of marine organism prevention materials, and particularly discloses a marine organism prevention high-density polyethylene composite material and a preparation method thereof. The preparation method comprises the following steps: firstly, preparing a Ti < 3 > C < 2 > T < x > MXene (at) Cu2O composite material based on an in-situ growth method; the material is composed of two-dimensional Ti < 3 > C < 2 > T < x > MXene and Cu2O nanoparticles which grow on the surface of the two-dimensional Ti < 3 > C < 2 > T < x > MXene in situ and have bactericidal performance, the nanocomposite has the enhancement effect of the nanoparticles and the two-dimensional material on macromolecules at the same time, and good enhancement and marine organism prevention effects are guaranteed. Besides, PE-g-MAH is added in the formula to serve as a compatibilizer, in an HDPE amorphous region, a large number of hydroxyl groups on the surface of Ti3C2Tx MXene coated Cu2O are connected with acid anhydride groups in the compatibilizer PE-g-MAH through chemical ester bonds, a polyethylene chain of PE-g-MAH is mixed and dissolved with an HDPE matrix, and therefore the mechanical strength of the material can be improved in the amorphous region at the same time. Cu2O growing on the surface of MXene in situ can release cuprous ions after seawater permeates, and marine organisms such as algae spores, bacteria and barnacles and mussels are killed.

The invention provides a laser-induced surface metallized glass fiber reinforced polyether-ether-ketone modified material and a preparation method thereof. The laser-induced surface metallized glass fiber reinforced polyether-ether-ketone modified material is prepared from the following components in percentage by weight: 39%-69.5% of PEEK resin, 20%-40% of low-dielectric flat glass fiber, 5%-10% of low-dielectric filler, 5%-10% of Cu-Ni coordination compound and 0.5%-1% of antioxidant. According to the invention, the Cu-Ni coordination compound is added into the PEEK modified material, then the PEEK modified material is subjected to laser induction treatment with a specific wave band, reducing cuprous ions or nickel ions are obtained on the surface layer of the PEEK modified material, and then the reducing cuprous ions or nickel ions are catalytically reduced into metal atoms through an electroplating process, so that the metal layer is embedded into the PEEK base material, and the binding force between the metal coating and the PEEK base material is improved.

The present application provides an extractant and a method for purifying copper-containing cyanide wastewater, belonging to the technical field of wastewater purification. The extractant uses an imidazole ring as the molecular backbone, and through a quaternization reaction, aliphatic chain functional groups are introduced to adjust the hydrophobic property of the extractant, ensuring that the extractant is insoluble in the inorganic aqueous phase. By derivatizing the amino group to form a thioester group, the terminal mercapto group hydrolyzes under alkaline conditions to form an S- activation site, which can effectively bond with cuprous ions (Ⅰ). At the same time, the S- activation site and the lone pair electrons on the adjacent N atom cooperate with each other to chelate cuprous ions (Ⅰ) to the greatest extent, ensuring that the cuprous ions exist in the form of chelates and will not be further converted into the free state. In addition, the lone pair electrons on the N atom and the carboxyl group can cooperate with each other to achieve targeted chelation of cupric ions (Ⅱ) in the solution. The present application realizes the efficient extraction of copper in the cyanide-containing wastewater, achieving the purpose of purifying the copper-containing cyanide wastewater.

The application provides an antiseptic and antibacterial coating composition, an antiseptic and antibacterial coating and a preparation method and application thereof. The antiseptic and antibacterial coating composition comprises an epoxy resin, a composite filler, a curing agent, a first surfactant and a first solvent; wherein the composite filler comprises a cuprous oxide core and an inorganic porous shell layer arranged on the surface of the cuprous oxide core, and a quaternary ammonium salt is also contained in the pore structure of the inorganic porous shell layer. By coating the inorganic porous shell layer on the surface of the cuprous oxide core, the release rate of cuprous ions from the cuprous oxide can be effectively reduced, and the side reaction between the cuprous oxide and the epoxy resin can be inhibited. By arranging the quaternary ammonium salt in the pore structure of the inorganic porous shell layer, the release rate of the quaternary ammonium salt can be effectively controlled, and the chemical stability of the quaternary ammonium salt can be improved, so that the double-channel slow release of cuprous ions and quaternary ammonium salt is realized, the synergistic effect of cuprous ions and quaternary ammonium salt in antibacterial and antiseptic aspects is improved, and the antibacterial and antiseptic performance of the prepared antiseptic and antibacterial coating is improved.

The present application belongs to the technical field of gas capture, and particularly relates to a method for capturing fluorine-containing greenhouse gas. In a dark environment, an adsorbent is used to adsorb fluorine-containing greenhouse gas. The adsorbent is a polymer containing cuprous ions and iodine ions, and the chemical formula is CuI(L), wherein L is a weak bridging nitrogen-containing ligand. After the adsorption of the adsorbent reaches saturation or the adsorption time reaches a set time, the adsorbent is irradiated, the adsorbent releases the absorbed fluorine-containing greenhouse gas, and the regeneration of the adsorbent is completed. The present application can absorb fluorine-containing greenhouse gas in waste gas at normal temperature and pressure, and can desorb fluorine-containing greenhouse gas by irradiation at normal temperature and pressure to realize the regeneration of the adsorbent. The regeneration energy consumption is low, the implementation is convenient, and the operation cost is reduced.

The present disclosure relates to hydrometallurgical processes for obtaining copper metal from a copper-containing feedstock. The processes include solubilising copper in the feedstock to obtain a solution comprising cuprous ions and reducing the cuprous ions to obtain a copper deposit at a cathode from which the copper deposit is subsequently stripped. The present disclosure further relates to electrolytic cells for obtaining copper metal from a copper-containing feedstock.

The invention provides a preparation method of nano cuprous sulfide and the nano cuprous sulfide, and particularly relates to the technical field of preparation of inorganic nano materials. The preparation method of the nano cuprous sulfide comprises the following steps: adding a sulfur source solution into an acidic complex solution of cuprous ions to obtain an intermediate suspension; then carrying out ultrasonic reaction on the intermediate suspension, continuing to react for 1-2 hours after the system becomes black suspension, then stopping the reaction, and carrying out solid-liquid separation on the system to obtain a precipitate; and finally, washing the precipitate, and carrying out vacuum drying to obtain the nano cuprous sulfide. Wherein a sulfur source in the sulfur source solution comprises a thioamide compound. According to the preparation method, the intermediate suspension serving as a precursor of cuprous sulfide has good stability, formation and conversion of an intermediate are promoted under the ultrasonic action, the particle size of nano cuprous sulfide is effectively controlled, and the nano cuprous sulfide is uniform in distribution, small in size and good in uniformity and dispersity.

The invention discloses a double-cuprous complex and a preparation method and application thereof.The double-cuprous complex is specifically a binuclear cuprous complex which is formed by two cuprous ions, four N atoms of bitzH2 and P atoms on two POP and has two twisted tetrahedral configurations, solid powder of the complex emits blue light, and the double-cuprous complex can be used for preparing blue light. After mechanical grinding, blue fluorescence is converted into green fluorescence, and after a ground solid sample is fumigated by dichloromethane steam, blue light is recovered, so that the compound has a reversible force-induced color-changing property and also has high optical contrast; the characteristics of wide color gamut change range and high color vividness are beneficial to the preparation of high-contrast force sensing materials, and have huge application potential in the fields of force sensors, memories, anti-counterfeiting marks and the like.

The invention discloses an electrolyte for a super-stable aqueous copper-sulfur battery as well as a preparation method and application of the electrolyte. The electrolyte comprises an aqueous solvent, AB type halide salt and cuprous ion halide salt CuB, the cation A of the AB type salt is selected from at least one of Li < + >, Na < + >, K < + >, choline cation and NH4 < + >, and the anion B is Cl <->, Br <-> or I <->; and the anion of the CuB is the same as the anion of the AB type salt. The preparation method comprises the following steps: dissolving AB type salt in a water-based solvent, and then adding CuB for dissolving. According to the electrolyte disclosed by the invention, the electrochemical reaction of the copper-sulfur battery is adjusted from two-step conversion to one-step conversion, so that shuttling of polysulfide is inhibited in mechanism, voltage polarization is reduced, the solubility of Cu < + > is improved, and the interface stability is enhanced. The water-based copper-sulfur battery containing the electrolyte has ultra-long cycle life and high capacity retention ratio, the capacity retention ratio still reaches 88% or above after 400 times of circulation under 1C multiplying power, and the preparation process is simple, adapts to various electrode and diaphragm materials and is suitable for large-scale application.

The application provides a brightener, a preparation method and application thereof. The brightener has a structure as shown in formula 1, wherein R is any one of CH3-(CH2) x -, Ph-(CH2) y - or an azacyclic group, x is 2-5, and y is 0-4. The brightener is connected with a functional group having strong polarity, has good inhibition effect on copper, and has a capturing cuprous ion at the other end of the structure, accelerates copper deposition, has certain leveling performance, can form leveling effect on the surface copper high potential, forms acceleration effect on the low point position in the hole, and can effectively improve the deep plating capacity of the acid copper plating solution, and the deep plating capacity can reach 79-85%.

The present invention relates to an iron-based bone implant and a preparation method thereof for accelerating the dissolution of an acidified passivation film, and belongs to the field of degradable biomedical metals. The iron-based bone implant for accelerating the dissolution of an acidified passivation film is composed of an iron-potassium chloride (3.7wt.%) matrix and copper, wherein the mass percentage of copper is 0.3-1.5wt.%. The iron powder, copper powder, and potassium chloride powder mixture are mechanically mixed and ball-milled and then formed by electric spark sintering. The beneficial effects of the present invention are that the cuprous ions produced by the dissolution of copper and the cuprous chloride generated by the cuprous ions undergo a hydrolysis reaction inside the passivation film, thereby forming an acidic environment to weaken the shielding and blocking effect of the passivation film, while suppressing the generation of a new passivation film. Finally, the reaction medium outside the passivation film can react with the internal iron matrix, thereby accelerating the entire degradation process.

The invention belongs to the field of analytical chemistry and mass spectrometry detection, and discloses a rapid identification method of cannabinoid compounds based on paper spray mass spectrometry, which comprises the following steps: dropwise adding a to-be-detected sample solution on a cuprous ion modified cellulose paper base, and carrying out paper spray mass spectrometry detection to obtain the cannabinoid compounds. By monitoring a protonated molecule ion peak [M + H] < + > and a Cu < + > adduct ion peak [M + 63Cu] < + > / [M + 65Cu] < + > in a mass spectrogram, strictly controlled key isomers CBD and delta9-THC can be distinguished, and the method can be used for accurately identifying whether a complex matrix contains a cannabinoid compound with a 1, 5-diene structure or not and distinguishing the cannabinoid compound from a cannabinoid isomer without the cannabinoid compound with the 1, 5-diene structure. Meanwhile, whether CBC, CBL, delta9-THC or delta8-THC and other cannabinoid compounds are contained or not is prompted when CBD exists. The method does not need to depend on a high-resolution mass spectrum or a secondary mass spectrum, does not need to use noble metal ions and metal organic complexes, can realize rapid, accurate and low-cost identification within tens of seconds only under the condition of a low-resolution mass spectrum and a primary mass spectrum, and has a good prospect in non-clinical diagnosis scenes such as scientific research, supervision and detection and the like.

The invention provides an anti-corrosion and anti-bacterial coating composition, an anti-corrosion and anti-bacterial coating and a preparation method and application of the anti-corrosion and anti-bacterial coating. The anticorrosive and antibacterial coating composition comprises epoxy resin, composite filler, a curing agent, a first surfactant and a first solvent, wherein the composite filler comprises a cuprous oxide inner core and an inorganic porous shell layer arranged on the surface of the cuprous oxide inner core, and quaternary ammonium salt is contained in a pore structure of the inorganic porous shell layer. The surface of the cuprous oxide core is coated with the inorganic porous shell layer, the cuprous ion release rate of cuprous oxide can be effectively reduced, meanwhile, side reaction between cuprous oxide and epoxy resin is inhibited, quaternary ammonium salt is arranged in a pore channel structure of the inorganic porous shell layer, the release rate of the quaternary ammonium salt can be effectively regulated and controlled, and the chemical stability of the quaternary ammonium salt is improved; therefore, double-channel slow release of the cuprous ions and the quaternary ammonium salt is realized, the synergistic effect of the cuprous ions and the quaternary ammonium salt in the antibacterial and anti-corrosion aspects is improved, and the antibacterial and anti-corrosion performance of the prepared anti-corrosion and antibacterial coating is improved.

The present invention relates to a colorless copper-zinc composite antibacterial phosphate glass and a preparation method thereof. The glass is composed of 52%-65% P2O5, 30%-38% ZnO, 0%-15% BaO, 0%-10% CaO, 0%-6% SiO2, 0%-5% Al2O3, 0%-5% B2O3, 0.1%-2.0% Cu2O, totaling 100%. First, the raw materials prepared in proportion are mixed evenly, then heated to 900-1100°C to form a uniform glass liquid, and then cooled to room temperature at a speed of 10-100°C / s to finally obtain a colorless copper-zinc composite phosphate glass. The copper element in the glass mainly exists in the form of cuprous ions, so it is colorless and has good anti-Escherichia coli performance. The preparation method of the present invention is simple and easy, does not require the addition of a reducing agent, and has many advantages such as low cost, non-toxic and harmless, and a wide range of applications.

The invention discloses a method for detecting the binding condition of an ethylene receptor ETR1 and cuprous ions based on a nuclear magnetic resonance technology. The method comprises the following steps: preparing an ethylene receptor key binding domain through genetic engineering; the method comprises the following steps: carrying out isotope labeling on an ethylene receptor key binding domain by using a 15N isotope, preparing BCA2-Cu < + >, titrating cuprous ions into the ethylene receptor key binding domain, detecting the binding of the ethylene receptor key binding domain and the cuprous ions by using a nuclear magnetic resonance technology, and comparing 1H-15N HSQC spectrograms when cuprous ions with different concentrations are added, it is proved that when the ethylene receptor key binding domain is combined with cuprous ions, chemical shift of amino acid in a spectrogram can change irregularly and remarkably, and it is judged that the ethylene receptor binding domain is combined with the cuprous ions. A binding system of the ethylene receptor key binding domain and the cuprous ions is constructed, and the binding condition of the ethylene receptor binding domain and the cuprous ions is verified.

The invention discloses a method and a system for recycling chlorine in hydrogen chloride based on a cuprous chloride-hydrochloric acid system, and relates to the technical field of polyvinyl chloride production. CuCl reacts with saturated hydrochloric acid to generate a [CuCl2] <->, [CuCl3] < 2-> or [CuCl4] < 3-> complex solution, cuprous ions (Cu < + >) in the solution can efficiently capture chlorine molecules (Cl2) in hydrogen chloride (HCl) gas, and a trichloro copper acid (H2 [CuCl3]) or tetrachloro copper acid (H2 [CuCl4]) complex is formed. When the complex is heated, the complex can be decomposed to release chlorine, and meanwhile CuCl is reduced and can be recycled. By adopting the method provided by the invention, the single absorption efficiency can reach 95-98%. According to the method provided by the invention, the problem of explosion accidents caused by hydrogen chloride perchlorination in the PVC production process by a calcium carbide method is thoroughly solved; the chlorine-hydrogen ratio during hydrogen chloride synthesis is improved, and the purity control index of hydrogen chloride is improved, so that the yield of vinyl chloride is improved, and side reactions are reduced; the vinyl chloride tail gas treatment difficulty and cost are reduced; cuCl can be recycled, and the cost is low.

The invention provides a preparation method of cuprous ion reaction liquid and a method for promoting dissolution of zinc ferrite. The preparation method of the cuprous ion reaction liquid comprises the following steps: S1, providing iron oxide, copper powder and a sulfuric acid solution; the iron oxide contains ferric iron, and the copper powder contains zero-valent copper; the sulfuric acid concentration of the sulfuric acid solution is 50-800 g / L; s2, the iron oxide and the copper powder are placed in the sulfuric acid solution, first mixing treatment is conducted at the temperature of 50-95 DEG C, and cuprous ion reaction liquid is obtained; the cuprous ion reaction liquid contains cuprous ions; the molar ratio of the ferric iron to the zero-valent copper is (0.9-4): 1; the duration of the first mixing treatment is not less than 10 minutes. A large number of stable cuprous ions can be generated in the sulfuric acid solution, and dissolution of zinc ferrite can be promoted based on the cuprous ion reaction solution.

The invention provides a preparation method of a long-life strong-luminescence near-infrared II-region fluorescent copper nanocluster, which comprises the following steps: adding an aqueous solution of ligand template molecules into an aqueous solution of copper nitrate to obtain a mixed solution; wherein the ligand template molecule is selected from any one or a mixture of more than two of a small molecule compound, polypeptide or protein; the ligand template molecule contains a functional group with a sulfydryl or disulfide bond structure; cu < 2 + > in the mixed solution is reduced into cuprous ions by using a sodium borohydride aqueous solution, and then the reaction is continued, so that copper atoms grow and gather in ligand template molecules to form the copper nanocluster with the copper atom number of 20-45. The copper nanocluster prepared by the method disclosed by the invention can emit near-infrared II-region fluorescence, has higher fluorescence quantum yield, long fluorescence lifetime and good biological safety, and has various application potentials in the fields of fluorescence detection, biological analysis, imaging and the like.

The present invention discloses an aggregation-induced luminescence fluorescent probe for detecting cuprous ions Cu(I), as well as its preparation method and application. The structure of the aggregation-induced luminescence fluorescent probe is shown in Formula I below; wherein R is selected from one of H, an alkyl group with carbon atoms ranging from C1 to C4, and COOH. The fluorescent probe provided by the present invention uses a chromophore quinoline nitrile derivative as an AIE structural unit and a sulfide-rich bis(2-((2-(ethylsulfide)ethyl)-thio)ethyl)amine as a Cu(I) recognition unit. It has excellent aggregation-induced luminescence properties, exhibits excellent selectivity and high sensitivity response to Cu(I), and can in situ detect the process of Cu(II) being reduced to Cu(I), providing technical support for revealing the role of Cu ions in cell physiology and pathology in the future.

The invention relates to the technical field of polycrystalline silicon production, in particular to a cuprous ion modified adsorbent as well as a preparation method and application thereof. The cuprous ion modified adsorbent comprises an inorganic carrier containing a nitrogen element and Cu < + > loaded on the inorganic carrier. The low-valence Cu < + > ions are used as key active components, the dispersity of Cu < + > species is improved by means of rich pore channels and structural nitrogen sites in the activated carrier, the utilization efficiency of active metal is greatly improved, then the adsorbability of the adsorbent is improved, and the adsorbent has certain regeneration capacity.

The invention relates to the technical field of medicine synthesis, and discloses a synthesis process of a novel tyrosine kinase inhibitor intermediate, which comprises the following steps: 1, adopting a mixed alkali scheme, namely a potassium carbonate and cesium carbonate mixed system, and replacing cesium carbonate with cheap potassium carbonate; and 2, constructing an amino group with a protecting group by adopting a Ullmann coupling strategy catalyzed by cuprous ions. And step 3, carrying out simple Boc removal reaction to obtain the target molecule. According to the method, the use of the energetic raw material nitropyrazole is avoided, the 4-bromopyrazole which is relatively low in price, relatively high in safety and stable in supply is adopted, the limitation difficulty of material purchase and transportation is reduced, the production safety is improved, the production cost is greatly reduced, the palladium catalytic hydrogenation reaction is avoided, the production risk is reduced, and the production cost is reduced. And the production cost is further reduced, so that the industrial production is simpler, more convenient and more feasible.

The invention discloses a method for regulating and controlling dissolved oxygen and potential dechlorination through cooperation of ultrasonic waves and a sulfite solution, and relates to the technical field of solution purification and impurity removal. Comprising the following steps: dissolving sulfite with deionized water to obtain a sulfite solution; respectively heating the sulfite solution and the chlorine-containing solution to be treated; after heating is finished, slowly adding the sulfite solution into the chlorine-containing solution to be treated at a constant speed, stirring and reacting, and simultaneously adopting ultrasonic wave for synergistic reaction; after the reaction is finished, carrying out vacuum filtration to obtain filtrate and filter residues; copper ions in the solution are reduced into cuprous ions by the sulfite ions, and cuprous chloride precipitates are generated by the cuprous ions and chloride ions, so that the removal of chlorine is realized. The dissolved oxygen content and the oxidation-reduction potential of the system are reduced by means of ultrasonic synergistic enhancement, temperature rise and the like, and cuprous chloride is prevented from being dissolved inversely while the reducing capacity of the sulfite solution is enhanced. Ultrasonic waves play multiple roles in the process, including reaction resistance reduction, mass transfer acceleration, reaction temperature maintenance, reaction interface updating and the like.

The invention discloses a method for catalytically converting CO2 (carbon dioxide) by using a cuprous ion-loaded melamine-functionalized super-crosslinked polymer. The method comprises the following steps: firstly, synthesizing a series of melamine-functionalized super-crosslinked polymers HCP-3N-nNH2-Cu; then, according to the types of substituent groups in melamine monomers and the proportion of the monomers to a cross-linking agent, the catalyst with different specific surface areas and CO2 adsorption capacities is prepared. HCP-3N-2NH2-Cu having the maximum specific surface area and CO2 adsorption capacity is preferably used as a catalyst. And then, the HCP-3N-2NH2-Cu is characterized by a plurality of characterization methods, so that the structure and the composition of the HCP-3N-2NH2-Cu are confirmed. The HCP-3N-2NH2-Cu shows an excellent catalytic effect in the two-component reaction of catalytic conversion of CO2 and alkynyl amine. In addition, the recycling performance of HCP-3N-2NH2-Cu is verified, and the result shows that the yield is not obviously reduced after the catalyst is recycled for three times.

The invention relates to a copper-based alloy nano composite material, the copper-based alloy nano composite material comprises a nano carbon material and copper-based alloy nano particles loaded on the nano carbon material, the copper-based alloy nano particles comprise cuprous ions and at least one non-copper metal element, and the cuprous ions and the at least one non-copper metal element are not in contact with each other. The non-copper metal element is any one of VIII group elements or IB group elements. According to the copper-based alloy nano composite material provided by the invention, the copper-based alloy nano particles containing various metal elements are loaded on the nano carbon material, so that the copper-based alloy nano composite material is formed, and a new copper-based alloy nano material is developed.

Embodiments of the present application provide a semiconductor structure and a formation method thereof. The semiconductor structure formation method includes: providing a substrate, a dielectric layer on the substrate, the dielectric layer having a trench; forming a metallic copper layer filling the trench; forming a contact layer on an upper surface of the metallic copper layer, a material of the contact layer containing cuprous ions; and forming a barrier layer on an upper surface of the contact layer, a material of the barrier layer containing a same element as the material of the contact layer. The embodiments of the present application help improve a contact effect between the metallic copper layer and the barrier layer.

This invention discloses a method for reducing DC power consumption by adjusting the anode polarization potential in copper electrolysis. The method involves adding additive A and an anode polarization potential-reducing additive during electrolysis. The concentration of the anode polarization potential-reducing additive is adjusted according to voltage changes in the electrolytic cell during electrolysis to suppress anode passivation and simultaneously accelerate the cuprous ion to copper ion reaction rate, thereby reducing the anode polarization potential and ensuring normal copper electrolysis while reducing DC power consumption. This invention uses organic additives to suppress anode passivation and accelerate the cuprous ion to copper ion reaction rate to reduce the anode polarization potential, thus achieving the goal of reducing DC power consumption. It has advantages such as simple operation, wide adaptability, and significant power consumption reduction effect.

The invention relates to a preparation method and application of a nitrogen-rich carbon material loaded with Cu2O in situ. The preparation method comprises the following steps: dissolving gelatin, glucose and metal copper salt in deionized water, performing high-pressure hydrothermal reduction to obtain a cuprous ion doped gelatin solution, and performing freeze drying to obtain a cuprous ion doped gelatin precursor; and carrying out thermal crosslinking and high-temperature carbonization treatment on the obtained gelatin precursor to obtain the nitrogen-rich carbon material loaded with Cu2O in situ, and carrying out CO2 electroreduction on the material to obtain a C2 product. The nitrogen-doped carbon material is used as a substrate, the advantages of large specific surface area, stable chemical property, good conductivity and the like of the carbon material are exerted, nitrogen atom doping can induce more electrons to enter the carbon substrate, so that more active sites are generated, the stably existing Cu2O (111) can promote CO2 to activate and generate CO * and a C-C coupling process, a C2 product is further generated, and the carbon material has the advantages of high specific surface area, stable chemical property, good conductivity and the like. The catalytic performance is greatly improved.

A cuprous ion-doped borosilicate glass for radiation detection and a preparation method thereof. The method uses a reduction melting method to prepare a Cu + ion-doped borosilicate glass. After the obtained glass sample is irradiated with X-rays of a certain dose, bright long afterglow will be generated under ultraviolet light excitation, and there is an obvious linear relationship between the initial light intensity of the afterglow and the X-ray dose. The glass of the present invention is prepared under a reducing atmosphere, and the mass percentages of each component are as follows: 50-75 mol% of SiO2, 8-13 mol% of Na2O, 6-10 mol% of CaO, 0-2 mol% of Al2O3, and 5-30 mol% of B2O3; the doped luminescent ion is CuO with a concentration of 0.01-0.1 mol%. The present invention for the first time uses X-rays to induce specific defect structures in the glass to achieve long afterglow luminescence of the glass, and there is an obvious linear relationship between the initial light intensity of the afterglow and the X-ray dose, and it is proposed to carry out radiation dose detection based on this.

The invention relates to the technical field of etching solutions, in particular to a low-adsorption-capacity roughening micro-etching solution for cuprous ions as well as a preparation method and application of the low-adsorption-capacity roughening micro-etching solution. The coarsening micro-etching liquid with low cuprous ion adsorption capacity comprises the following raw materials: a composite oxidant containing a heterocyclic structure, cyclohexylamine, organic acid, a halide ion source, a copper ion source, a stabilizer and water. All the components in the raw materials have a synergistic effect, a layer of protective film is formed on the board surface of the base material, and adsorption of cuprous ions is reduced; meanwhile, cuprous ions are oxidized into copper ions under the action of a composite oxidizing agent containing a heterocyclic structure, so that the content of the copper ions in a hydrochloric acid solution in the subsequent pickling step is reduced, and the situation that the coarsening effect is affected by re-etching the coarsened honeycomb-shaped surface appearance due to the fact that the concentration of the copper ions is too high is prevented. In addition, a stabilizer is added into the roughening micro-etching liquid system with low cuprous ion adsorption capacity, the components are not easy to decompose, and the roughening micro-etching liquid system can be in a working state for a long time.

The invention provides a CsCuX3 micron wire and a preparation method thereof, and belongs to the technical field of photoelectric materials. The preparation method comprises the following steps: putting concentrated hydrochloric acid into a beaker, sequentially adding cesium chloride (CsX) and cuprous chloride (CuX) solid reagents, stirring until reactants are fully dissolved to obtain a clear precursor solution, transferring the precursor solution into a reaction kettle, and carrying out heat preservation reaction at 160-200 DEG C for 8-15 hours to prepare the CsCuX3 micron-wire crystal. According to the method, cuprous ions (Cu < + >) are introduced as a copper source, and the CsCuX3 micron wire with the high length-diameter ratio is synthesized in one step under the hydrothermal condition. The micron wire material is in a uniform one-dimensional linear shape, the length is far greater than the diameter, the micron wire material has an excellent length-diameter ratio, the purity is high, the defect is few, the stability is good, and the stable one-dimensional perovskite material is expected to be used in photoelectric devices for a long time.