238 results about "Zinc sulfide" patented technology

The invention discloses preparation and application of an organic-inorganic interface layer modified zinc negative electrode. The preparation method comprises the following steps: firstly, dispersing organic polymer polylactic acid and zinc sulfide powder into tetrahydrofuran, then coating the surface of zinc foil with the dispersed solution, and drying a solvent at 70 DEG C, so as to prepare the zinc negative electrode modified by an organic-inorganic interface layer. According to the interface layer, zinc ion deposition is regulated and controlled, and the problem of zinc dendrite growth is solved. In addition, the polylactic acid-zinc sulfide composite coating can effectively improve the redox kinetics of zinc ions and improve the coulombic efficiency of the zinc negative electrode. Due to the good ionic conductivity, the interface modification layer can improve diffusion of zinc ions, and the polarization influence caused by the concentration gradient of the zinc ions is relieved. Therefore, the prepared polylactic acid-zinc sulfide composite interface layer modified zinc negative electrode symmetric battery has more excellent cycling stability, the half battery has more stable coulombic efficiency, and the assembled total battery has more prominent capacity retention rate.

The invention discloses a far-infrared high-transmittance composite material, a preparation method thereof and an optical device, and the far-infrared high-transmittance composite material comprises the following components in parts by weight: 70-99 parts of a polymer matrix; 1-30 parts of an anti-reflection auxiliary agent; the polymer matrix is a sulfur-containing polymer prepared by polymerization reaction of a polymeric monomer and sulfur, and the proportion of carbon-carbon unsaturated bonds is less than 3%; the polymeric monomer is selected from at least one of a vinyl monomer, a propenyl monomer, an acrylic acid monomer, a methacrylic acid monomer, an epoxide monomer, a thiopropyl ring monomer, an alkynyl monomer, a butadiene monomer, an isoprene monomer and a norbornene monomer; the anti-reflection auxiliary agent comprises at least one of nano zinc sulfide, nano zinc selenide, nano calcium fluoride, nano magnesium fluoride and nano magnesium oxide. The composite material and the optical device thereof have high far infrared transmittance and good mechanical properties and processability, and can meet the requirements of various far infrared optical fields.

The invention relates to a dual-waveband medium-long wave infrared optical filter based on a germanium / zinc sulfide asymmetric film system and a preparation method of the dual-waveband medium-long wave infrared optical filter. The dual-waveband medium-long wave infrared optical filter comprises a front film system, a substrate and a back film system, the front film system and the back film system are formed by alternately overlapping germanium layers and zinc sulfide film layers; the average transmittance of the infrared optical filter in the wave band of 3800 nm to 4800 nm and the wave band of 8000 nm to 10000 nm is not lower than 91%. According to the two-waveband medium-long wave infrared optical filter disclosed by the invention, 3800 to 4800 nm amp is realized; according to the infrared filtering window, the light energy of medium waves and long waves of 8000-10000 nm is improved, the luminous flux of other wavebands is well inhibited, the technical problem of the infrared filtering window in some special infrared spectrum detection systems is solved, and a new scheme is provided for infrared application.

The invention relates to a wide-temperature-range stable dual-band infrared optical filter for an extreme environment and a preparation method thereof. The wide-temperature-range stable dual-band infrared optical filter comprises a front film system, a substrate and a back film system, the front film system and the back film system are formed by alternately overlapping germanium layers and zinc sulfide film layers; the drift distance of the central wavelength of the passband of the infrared optical filter is less than 0.05% within the temperature range of-120 DEG C to + 85 DEG C. According to the invention, the internal stress of the film layer is obviously reduced through the optimized film system design, so that the excellent stability of the optical performance in an extreme temperature environment is realized, the technical problem that some special infrared spectrum detection systems work in a wide temperature range is solved, and a reliable solution is provided for high-end aerospace infrared application.

The invention discloses an electrolyte for improving the cycling stability of a zinc-sulfur battery and application of the electrolyte in a photoelectric storage integrated battery. The electrolyte comprises a solvent, an additive and zinc salt, the additive is iodide, and the iodide comprises iodine negative ions and positive ions or polar functional groups. The functional additive is added into the electrolyte, positive ions inhibit dendritic crystals and side reactions of zinc, and iodine negative ions accelerate reversible change between sulfur and zinc sulfide, so that the cycling stability of the zinc-sulfur battery is improved. A zinc-sulfur battery with high specific capacity and long cycle life is integrated with a solar battery, so that the photoelectric storage integrated battery with high overall conversion efficiency, high specific capacity and long cycle life is prepared.

A hydrocarbon gas detection system including a longwave infrared camera, a spectral filter, and a computation unit. The spectral filter is disposed in the light path of the camera sensor. The spectral filter is made of a material selected from the group consisting of calcium fluoride, zinc sulfide, magnesium fluoride, and silicon. The computation unit is arranged to process image data of the longwave infrared camera for the hydrocarbon gas detection.

The invention discloses a hexagonal bismuth phosphate modified indium zinc sulfide (ZIS / HBIP) composite catalyst and a preparation method thereof. The catalyst is applied to photocatalytic synthesis of HO. The indium zinc sulfide (ZIS) nano flower balls in the catalyst are prepared by a hydrothermal method, and then hexagonal bismuth phosphate (HBIP) is loaded on the surface of the ZIS by a room temperature precipitation method to obtain a series of ZIS / HBIP composite catalysts. ZIS and HBIP can effectively improve photo-induced electron-hole separation and transmission, improve the selectivity of direct two-electron oxygen reduction reaction (2eORR) and inhibit HO decomposition. Experimental results show that when the theoretical dosage of HBIP is 0.01 mmol, the prepared ZIS / HBIP 0.01 has the optimal photocatalytic activity, the HO yield within 1 h can reach about 955 [mu] mol.g.h, and efficient synthesis of HO in pure water is achieved.

The invention relates to a dual-band anti-reflection zinc selenide metallized light window and a preparation method thereof, the dual-band anti-reflection zinc selenide metallized light window comprises a front film system, a zinc selenide substrate, a back film system and edge metallized films, the zinc selenide substrate is located between the front film system and the back film system, and the edge metallized films are located at two ends of the zinc selenide substrate; the front film system and the back film system are formed by alternately overlapping zinc sulfide layers and ytterbium fluoride film layers; the edge metallized film is formed by overlapping a chromium film layer, a copper film layer, a nickel film layer and a gold film layer. According to the invention, the two sides of the zinc selenide substrate are respectively provided with an anti-reflection film system structure, so that the light energy of two wave bands of 3500-5000nm and 8000-12000nm is improved; the zinc sulfide and ytterbium fluoride film layer is adopted, so that the stress is lower, and the dual-band anti-reflection optimization effect is better; by improving the edge metallized film stacking structure, the problem that the soft optical material and the metallized film are not firmly combined is solved, and a new scheme is provided for infrared detector welding.

The invention discloses a low-distortion athermalization correctable short-wave infrared optical system and a lens, and belongs to the technical field of optics. According to the system, an optical lens is additionally arranged at the rear end to serve as a correction lens to achieve image correction in an external field environment; passive athermalization under wide-temperature and vacuum conditions is realized through focal power distribution and material matching of each optical lens; all the lenses are set to be spherical surfaces, so that the influence of aspheric surface processing errors on system index precision, processing cost and system installation and adjustment is avoided; the system adopts a positive-negative-positive-negative-negative five-lens focal power configuration. The positive-negative-positive-negative lenses are located at the front end, and the last negative lens is located at the rear end. The five lens materials are zinc sulfide, a chalcogenide material, single crystal barium fluoride, single crystal calcium fluoride and a chalcogenide material in sequence; the correction lens is located at the rear end of the last negative lens. The short-wave infrared optical system can solve the problems that an existing short-wave infrared optical system is large in imaging distortion, or athermalization is not achieved, or image correction under the external field application condition cannot be achieved.

A method for forming a coating on a substrate formed from zinc sulfide (ZnS) is provided. A ZnS film is grown on the substrate with a radio frequency sputtering process and metal dopants are sputtered on the substrate with a high-power impulse magnetron sputtering process. The metal dopants can be molybdenum or tungsten and simultaneously sputtered while growing the ZnS film. The sputtering ionizes the coating where the coating has a sheet resistance that is less than 50 ohm / square and the metal dopants form n-type dopants in the ZnS film. The metal dopants can be formed at a concentration that varies with a thickness of the ZnS film. At a first thickness, the concentration is at a first concentration and at a second thickness greater than the first thickness, the concentration is at a second concentration less than the first concentration.

The invention discloses a preparation method and application of a CuCo2S4 nanotube cluster / Zn3In2S6 nanosheet composite photocatalyst in the field of photocatalytic materials, the catalyst takes a cobalt sulfide copper nanotube cluster as a substrate, an indium zinc sulfide nanosheet layer is loaded on the surface, and a unique composite structure is formed. The preparation method comprises the following steps: preparing a CuCo nanotube cluster precursor through a hydrothermal method, and further preparing the CuCo2S4 nanotube cluster / Zn3In2S6 nanosheet composite photocatalyst through vulcanization and an oil bath method. The preparation method is simple, raw materials are easy to obtain, conditions are mild, control is easy, and the method is suitable for large-scale production. The prepared catalyst has high specific surface area and good dispersibility, also shows high carrier separation efficiency and strong light absorption performance, and can significantly improve the efficiency of photocatalytic decomposition of water to produce hydrogen and the efficiency of heavy metal removal under visible light.

The invention relates to a copper sulfate-free copper-zinc sulfide ore flotation separation method, and relates to the technical field of mineral flotation separation. The method comprises the following steps: obtaining copper-zinc sulfide ore pulp; by taking ethionine ester as a collecting agent and lime as an inhibitor, carrying out copper-zinc bulk flotation on the copper-zinc sulfide ore pulp to obtain copper-zinc bulk concentrate and discardable tailings; zinc sulfate serves as an inhibitor, the copper-zinc bulk concentrate is subjected to regrinding treatment, and copper-zinc bulk concentrate pulp is obtained; copper flotation is conducted on the copper-zinc bulk concentrate pulp, and copper concentrate and copper tailing pulp are obtained; with ethionine ester as a collecting agent, the copper tailing ore pulp is subjected to sphalerite activation under the condition of aeration stirring, and activated sphalerite ore pulp is obtained; and carrying out flotation on the activated sphalerite by using lime as an inhibitor to obtain zinc concentrate. The scheme provided by the invention has the advantages that heavy metal pollution is avoided, the mineral separation cost is reduced, and the process adaptability is high.

The invention belongs to the technical field of photovoltaic packaging materials, and provides a light anti-reflection packaging adhesive film and a preparation method and application thereof. The light anti-reflection packaging adhesive film is prepared from 100 parts of matrix resin, 1 to 15 parts of light anti-reflection master batch, 0.4 to 1.5 parts of cross-linking agent, 0.8 to 3.0 parts of assistant cross-linking agent and 0.3 to 1.0 part of silane coupling agent, the light anti-reflection master batch comprises 100 parts of matrix resin, 0.5-10 parts of an anti-reflection nano material and 0.5-10 parts of a surfactant; the matrix resin is at least one of EVA (ethylene vinyl acetate) resin, POE (polyolefin elastomer) resin and PVB (polyvinyl butyral) resin; the anti-reflection nanometer material is a porous nanometer material, the porosity is 20-70%, the aperture is 2-35 nm, and the anti-reflection nanometer material is selected from one or more of porous nanometer silicon dioxide, porous silicon dioxide loaded zinc oxide, zinc sulfide, zinc oxide, titanium dioxide, zirconium oxide, aluminum oxide and organic silicon resin microspheres. According to the light anti-reflection packaging adhesive film, the light transmittance and the assembly efficiency can be further improved.

The invention relates to a large-size wide-spectrum infrared color separation film with controllable surface precision and a manufacturing method thereof, the color separation film takes a silicon plain film as a substrate, a color separation film is designed on a light incident surface of the silicon substrate, germanium and zinc sulfide are used as high and low refractive index materials of a reflecting film stack, ytterbium fluoride is added in a matching layer, the film thickness ratio is regulated and controlled, and a thin film deposition process is optimized. The surface type change caused by the film layer is reduced; a thickness compensation film layer is added when the antireflection film is designed on the light transmission surface of the silicon substrate, so that the stress of the antireflection film and the stress of the color separation film are mutually counteracted, and the surface type is controlled. Appropriate substrate temperature, deposition rate and local film layer ion auxiliary deposition are adopted in the preparation of the color separation film, and the environmental reliability is good. The prepared large-size color separation sheet is controllable in surface type, the surface type precision RMS of the color separation surface is 0.028 lambda, the surface type precision RMS of the anti-reflection surface is 0.042 lambda, the large-size color separation sheet can highly reflect a broadband of 2-3.95 microns and highly transmit a broadband of 4.2-5.1 microns, and the large-size color separation sheet can be used for spectrum color separation of a large-view-field infrared optical system.

This invention discloses an S-type heterojunction photocatalyst composed of sulfur-defect-containing indium zinc sulfide and tungsten oxide, its preparation method, and its application. Specifically, this invention involves preparing WO3 nanosheets via a hydrothermal method, then loading them onto the surface of Zn3In2S6 using a solvothermal method, followed by introducing sulfur defects through phototreatment to obtain the S-type heterojunction photocatalyst WO3 / V. S -Zn3In2S6. The S-type heterojunction photocatalyst WO3 / V obtained in this invention. S -Zn3In2S6 exhibits excellent activity, enhanced CH4 selectivity, and good stability in the photocatalytic CO2 reduction reaction. Its preparation method is simple and easy, and it has good application prospects in the photocatalytic CO2 reduction reaction.

Magnetic particles with a highly reflective protective membrane (300), comprising: a magnetic core (100), a shell (200) formed on the outer surface of the magnetic core (100), having a multi-layer structure and comprising a first shell (210) made of a dielectric material, and a second shell (220) made of metallic material, formed on the outer surface of the first shell (210) and being a multi-layer membrane in which two or more layers (221, 222, 223) of mutually different metallic materials are stacked on top of each other, and a highly reflective protective membrane (300) which is in contact with the second shell (220) and is formed on the outer surface of the shell (200), wherein the highly reflective protective membrane (300) comprises a multi-layer structure comprising a low refractive index membrane (310) formed on the outer surface of the shell (200) and having an optical thickness between 0.15 to 0.35 of the wavelength, and a high refractive index membrane (320) formed on the outer surface of the low refractive index membrane (310) and having an optical thickness between 0.15 to 0.35 of the wavelength, the dielectric material is one or more materials selected from a group comprising titanium dioxide, aluminum oxide, calcium carbonate, zirconium oxide, magnesium fluoride, zinc oxide and zinc sulfide, the metallic material is one or more materials selected from a group comprising copper, nickel, gold, platinum, silver, aluminum and chromium, the low refractive index membrane (310) consists of one or more materials selected from a group comprising silicon dioxide, magnesium fluoride, polystyrene, polymethyl methacrylate, polystyrene-co-butadiene, vanadium pentoxide, cadmium oxide, polyisobutylene and polyethylene, and the high refractive index membrane (320) consists of one or more materials selected from a group comprising titanium dioxide, aluminum oxide, zinc oxide, zirconium oxide and chromium oxide.

The invention discloses a flotation system for lead-zinc sulfide ore containing pyrrhotite, a technological method of the flotation system and a water treatment method, and belongs to the field of flotation and water treatment. Rough concentrate of the lead-sulfur mixed flotation tank is connected with the lead-sulfur concentration subsystem, tailings are connected with the lead-sulfur scavenging subsystem, lead-sulfur mixed flotation concentrate is connected with the thickener, overflow is connected with the buffer water pool, and underflow is connected with the lead-sulfur separation flotation tank. Lead rough concentrate is connected with the lead concentration subsystem, lead concentrate is connected with the filter press, and filtrate is connected with the buffer water pool. Roughing tailings are connected with a lead scavenging subsystem, sulfur concentrate is connected with a filter press, and filtrate is connected with a buffer water tank. Lead-sulfur mixed flotation tailings are connected with a zinc flotation roughing tank, zinc rough concentrate is connected with a zinc concentration subsystem, zinc concentrate is connected with a zinc concentrate filter press, and filtrate is connected with a buffer water pool. Roughing tailings are connected with the zinc scavenging subsystem and the sedimentation tank, and supernate is connected with the buffer water tank. The buffer pool is connected with ore grinding equipment. The problem that the pyrrhotite is difficult to inhibit after being activated in the zinc blende activation process is solved, the grade and the recovery rate of the zinc concentrate are improved, and the water treatment process is simplified.

The application discloses application of a combined inhibitor in associated gold-silver-lead-zinc sulfide ore flotation separation, wherein the combined inhibitor is a combination of zinc sulfate and methionine, and the mass ratio of the two combined is 2:1; the combined inhibitor is used to realize associated gold-silver-low-copper-lead-zinc polymetallic sulfide ore flotation separation in a low-alkali environment, has a good separation effect, high concentrate grade, effectively reduces the zinc content of lead concentrate, improves the gold and silver recovery rate in the lead concentrate, and has important significance for improving the quality and efficiency of associated gold-silver-low-copper-lead-zinc polymetallic sulfide ore flotation separation. In addition, the methionine in the combined inhibitor is a small-molecule organic substance, is non-toxic and non-polluting, and is easy to degrade, thereby avoiding the problems of traditional inhibitors, such as toxicity, environmental unfriendliness and human body unfriendliness. The combined inhibitor has small dosage, stable effect, and good process application prospect.

The application discloses a beneficiation method for complexly-embedded high-sulfur-content lead-zinc sulfide ore, which comprises one-stage rough separation, three-stage cleaning and three-stage scavenging; a zinc flotation operation comprises one-stage rough separation, three-stage cleaning and three-stage scavenging; a sulfur flotation operation comprises one-stage rough separation, one-stage cleaning and one-stage scavenging; a sulfur concentrate dezincing operation comprises one-stage rough separation, one-stage cleaning and one-stage scavenging, calcium oxide is added in the one-stage cleaning process, a zinc collecting agent is added in the one-stage scavenging process, and tailings after the one-stage cleaning and concentrate after the one-stage scavenging are returned to the one-stage rough separation of the sulfur concentrate dezincing operation. The column machine is combined to improve the recovery rate of useful minerals, the flotation column is used for scavenging to improve the recovery rate of fine particles, the sulfur concentrate is subjected to the dezincing operation, and the dezincing product is returned to the zinc rough separation operation, so that the recovery rate of zinc minerals is improved, and through the column machine combined with the middling regrinding mode, the recovery rates of lead and zinc in the complexly-embedded high-sulfur-content lead-zinc sulfide ore are improved.

The present invention discloses a method for removing impurities from waste acid and fully recycling the waste acid. The method comprises the following steps: introducing hydrogen sulfide into the waste acid for a sulfidation reaction, removing arsenic sulfide and mercuric sulfide precipitates formed during the reaction; continuing to introduce hydrogen sulfide for a step-by-step sulfidation reaction, adding an iron-containing substance to adjust the reaction pH and ORP, and recovering the copper, lead, and zinc sulfide slag precipitates formed during the reaction in a step-by-step manner; adding an iron-containing substance for a neutralization reaction, controlling the pH and ORP, promoting the reaction between iron ions and arsenate, and removing the ferric arsenate precipitate formed during the reaction; adding an adsorbent for an adsorption reaction, and removing fluorine-containing and thallium-containing components by adsorption; introducing an oxidant for an oxidative hydrolysis reaction, controlling the degree of hydrolysis, and preparing polyferric sulfate. The present invention utilizes the iron-containing substance to remove impurities from waste acid, thereby achieving deep impurity removal and full resource utilization of waste acid.

The invention belongs to the technical field of cementing technologies and adhesives, and discloses a low-stress cementing sealing structure of a spherical zinc sulfide window, which is used for realizing butt joint of an aluminum alloy outer cover (2) and the spherical zinc sulfide window (1), and cementing sealing of the lower part of the outer wall of the spherical zinc sulfide window (1) and the upper part of the inner wall of the aluminum alloy outer cover (2). After the sealing assembly is used for sealing the zinc sulfide window, the overall leakage rate of the window (the sealing assembly is placed in a metal sealing container, a standard leakage opening is formed in the container, and the leakage rate is tested at the leakage opening through a helium mass spectrometer) is reduced to 10 <-8 > Pam < 3 > / s from 10 <-7 > Pam < 3 > / s sealed through traditional silicon rubber, the order of magnitude is reduced, and the sealing qualification rate is increased to 98% or above from 80%; compared with traditional epoxy resin sealing, the risk that the window deforms and even cracks is greatly avoided.

The invention belongs to the technical field of inorganic materials, and discloses a preparation process of a zinc sulfide sintered body, which comprises the following steps: taking 90% by mass of zinc sulfide powder, 0.1% by mass of epoxy resin and 9.9% by mass of deionized water, and mixing for 80-100 minutes at the rotating speed of 300-400 r / min and the temperature of 40-50 DEG C; maintaining the pressure of 20-25 MPa for 5-7 minutes to prepare a first green body, crushing the first green body to 325-330 meshes, and presintering the first green body at 980-1000 DEG C for 10-11 hours; and after pre-sintering, adding the same amount of epoxy resin and deionized water for secondary mixing, repeatedly briquetting to prepare a second green body, drying at 380-400 DEG C for 12-12.5 hours, performing secondary sintering at 980-1000 DEG C for 10-11 hours, cooling, and sealing and storing. According to the process, the energy consumption can be reduced, the sintering time is shortened, the production efficiency is improved, the zinc sulfide sintered body which is uniform in structure, stable in performance and free of impurities is prepared, and the process is suitable for the fields of anti-counterfeiting films, infrared optical elements and the like.

The application belongs to the field of photocatalytic water decomposition, and relates to a hollow indium zinc sulfide composite catalyst material loaded with double cocatalysts and a preparation method and application thereof. The material is a composite material of double metal chalcogenide indium zinc sulfide and MnO2 and Ti3C2, the MnO2 has a hollow spherical structure, the indium zinc sulfide has a two-dimensional sheet structure, the indium zinc sulfide is coated on the outer surface of the MnO2 to form a composite spherical structure, and the Ti3C2 is attached to the surface of the composite spherical structure. The catalyst material not only has a higher specific surface area to provide more surface active sites, but also can enhance the refraction and reflection of light, thereby improving the utilization efficiency of light. The MnO2 and the Ti3C2 can be used as hole-type and electron-type cocatalysts respectively, and the unique carrier transport path thereof promotes the separation and transfer of photo-generated carriers, thereby enhancing the photocatalytic hydrogen production and benzyl alcohol oxidation performance of the material.

The invention provides a photoelectric detector and a preparation method, and relates to the technical field of photoelectric detectors. The photoelectric detector comprises a silicon substrate, a functional layer, an electrode layer and an insulating layer, wherein the silicon substrate comprises an n-type silicon layer and a p-type silicon layer which are sequentially stacked from bottom to top. The functional layer is located above the silicon substrate and comprises a molybdenum disulfide layer and a zinc sulfide layer which are sequentially stacked from bottom to top. According to the technical scheme, the zinc sulfide layer is introduced on the molybdenum disulfide layer to form a MoS2-ZnS heterostructure, a wide forbidden band of ZnS complements a response blind area of MoS2 to ultraviolet light, and MoS2 covers visible and near-infrared light, so that a UV-NIR full spectrum is realized. A Type-I heterojunction is formed between MoS2-ZnS heterostructures, a built-in electric field effectively inhibits recombination of photon-generated carriers, the electron mobility is high, and the responsivity and the detection degree are improved. The MoS2-ZnS heterostructure based on the silicon substrate is easy to integrate with a CMOS (Complementary Metal Oxide Semiconductor), so that miniaturization and high integration of the device are realized.

A hot-pressing sintering method for an optical zinc sulfide rectifier includes the following steps: zinc sulfide powder pretreatment; loading: mixing the pretreated zinc sulfide powder with a sintering additive with a melting point lower than zinc sulfide and loading it into a mold with a thermal expansion coefficient smaller than that of polycrystalline zinc sulfide, placing it in a hot press furnace, closing the furnace, the weight of the mixed powder loaded into the mold exceeding the raw material weight required for the ideal product of the mold, the mold being pre-coated with a release agent; starting up, when the absolute pressure drops below 500 Pa, starting the heating, while continuing to evacuate to no more than 5 Pa; the first stage heating at 5-10℃ / min to the second stage heating at 300-400℃ / min. 00℃ and hold for 1-4 hours; S4, the vacuum pressure at the second stage target temperature of 300-400℃ should not exceed 5Pa; 10 minutes before the end of the second stage, pre-pressurize in a cold state to 40-60% of the process pressure; in the third stage, continue to raise the temperature to 900-1000℃ at 5-10℃ / min, hold for 30-60 minutes after reaching the temperature, raise the process pressure to 20-40MPa in 30 minutes, and finally hold for 60-120 minutes; after the holding and pressure holding are completed, release the pressure, turn off the heating, let it cool naturally, cool with the furnace to room temperature, and then remove from the furnace.

The present invention relates to a combined inhibitor for lead-zinc oxide ore in lead-zinc sulfide tailings and its application, belonging to the technical field of lead-zinc oxide ore beneficiation. The combined inhibitor comprises sodium fluorosilicate, sodium sulfide, and sodium humate, wherein the mass ratio of the sodium fluorosilicate, sodium sulfide, and sodium humate is 2:5:1. The present invention also includes applying the combined inhibitor to a reverse flotation recovery process for lead-zinc oxide ore in lead-zinc sulfide tailings. The combined inhibitor and reverse flotation process employed in the present invention achieve simultaneous recovery of lead oxide and zinc oxide while ensuring flotation recovery efficiency, and have the advantages of a simple process and low equipment investment.

Artificial flowers and bunches of flowers that have self-glowing properties include a flower portion and optionally one or more stems and leaves. At least the flower portion includes a self-glowing material, which includes phosphorescent compounds, such as strontium aluminate or zinc sulfide, optionally doped with rare earth elements to enhance glow intensity and duration. The luminescent material may be embedded within the base structure or applied as a surface coating or both, and is bound using a suitable medium such as acrylic or epoxy resin. Optional integration of conventional lighting elements, such as LEDs, is also contemplated

The invention relates to a nano composite microsphere lubricating material and a preparation method thereof, the material is a nano composite microsphere with a three-layer composite core-shell structure, the core is a zinc sulfide nanosphere, the middle layer is a molybdenum disulfide lubricating layer, and the shell is a polyurethane coating layer; the outer diameter of the nano composite microsphere is 90-150nm, the diameter of the zinc sulfide nano sphere is 20-40nm, the thickness of the middle layer is 25-35nm, and the thickness of the shell is 10-20nm. When the material is added into lubricating grease as a solid lubricating material, nanoscale balls can roll between friction pairs, sliding friction is partially converted into rolling friction, and the friction coefficient is effectively reduced; meanwhile, the released molybdenum disulfide and zinc sulfide are spread on the metal surface together to form a layer of firm composite solid lubricating film with low shear strength, so that the extreme pressure anti-wear property is improved; in addition, the polyurethane shell can block oxygen and delay oxidation of the lubricating grease while improving the dispersity.

The application relates to the technical field of semiconductor nanomaterials, and discloses an environment-friendly zinc sulfide nanoparticle as well as a preparation method and application of the zinc sulfide nanoparticle. The preparation method comprises the following steps: (1) activating Aspergillus oryzae spores, performing liquid fermentation, filtering the liquid fermentation product, washing, collecting solid substances, and obtaining biomass; (2) culturing the biomass in the step (1) in a ZnSO4.7H2O aqueous solution to obtain an Aspergillus oryzae liquid solution containing zinc sulfide nanoparticles; (3) drying the liquid solution obtained in the step (2) to obtain Aspergillus oryzae precipitate containing zinc sulfide nanoparticles; and (4) heating the precipitate in the step (3) at 400-450 DEG C for 4-6 h to obtain zinc sulfide nanoparticles. The application endows the zinc sulfide nanoparticles with excellent biocompatibility, expands the application of the zinc sulfide nanoparticles in the fields of biomedicine, chemical sensors, solar cells and light-emitting diodes, and provides a reference for the environment-friendly and batch production of the zinc sulfide nanoparticles.

The present invention discloses a combined gravity-flotation beneficiation method for carbon-containing lead-zinc sulfide ores. The method comprises the following steps: grinding the raw ore, sequentially adding a carbon collector and a frother, and then removing amorphous carbon therefrom through a table flotation process; performing roughing, scavenging, and concentrating on the table flotation concentrate; flotation to obtain a lead concentrate and lead-selected tailings; and then performing roughing, scavenging, and concentrating on the lead-selected tailings; and flotation to obtain a zinc concentrate. The process of the present invention is simple, easy to industrially produce, and convenient for cost reduction. It has good adaptability to lead-zinc sulfide ores containing amorphous carbon, effectively avoiding the adverse effects of amorphous carbon on lead-zinc flotation, and achieving superior lead-zinc flotation performance.