298 results about "Nanorod" patented technology

The invention belongs to the technical field of conductive polymer materials, and particularly relates to a three-dimensional polypyrrole conductive material and a preparation method and application thereof. The preparation method of the three-dimensional polypyrrole conductive material comprises the following steps: (1) preparing a metal copper quantum dot and graphene oxide mixed dispersion liquid; (2) adding an oxidizing agent to obtain a reaction solution; (3) adding a pyrrole monomer, and carrying out a polymerization reaction to obtain a graphene oxide / polypyrrole composite dispersion liquid; and (4) adding a reducing agent to reduce the graphene oxide to obtain the three-dimensional polypyrrole conductive material. After the metal copper quantum dots are loaded on the graphene oxide sheet layer, the graphene oxide sheet layer becomes a structure-oriented core in subsequent polymerization, and finally the stable three-dimensional conductive composite material with graphene as a framework and polypyrrole nanosheets as connection points is formed. Compared with a traditional three-dimensional material formed by overlapping and integrating a two-dimensional graphene sheet layer and a conductive nanowire / nanorod, the three-dimensional material with the structure can form an efficient conductive path more easily under the condition of low filler content.

The invention discloses an intelligent purification coating with a bionic pulmonary membrane type respiratory metabolism function. The intelligent purification coating comprises a sensing and adsorption layer, a driving and transportation layer and a catalysis and metabolism unit, the sensing and adsorption layer is composed of a chemical heterojunction network formed by two-dimensional transition metal carbonitride MXene and a zeolite imidazate framework structure material through an in-situ coordination reaction of metal ions and hydroxyl groups on the surface of MXene; the driving and transporting layer takes a cross-linked liquid crystal elastomer network as an intelligent response matrix, and high-length-diameter-ratio magnetic ferroferric oxide nanorods of which the surfaces are modified by a silane coupling agent are uniformly dispersed and embedded into the matrix; and the catalysis and metabolism layer is anchored on a preset key mass transfer path in the driving and transporting layer in a discrete metabolism island form. According to the coating, various volatile organic compounds (VOCs) and enzyme-light synergistic deep mineralization can be realized under mild conditions, and the energy metabolism function of mitochondria can be accurately simulated.

The invention belongs to the technical field of hydrolysis hydrogen production, and particularly relates to a preparation method of a CoPx-CeO2 loaded platinum catalyst with a core-shell structure and application of the CoPx-CeO2 loaded platinum catalyst in seawater electrolysis hydrogen production. A Co (CO3) 0.5 (OH) nanorod precursor is prepared on foamed nickel through a hydrothermal method and then calcined to obtain CoPx, a CeO2 film is electrically deposited to obtain a CoPx-CeO2 composite carrier, and platinum is impregnated and loaded to obtain the CoPx-CeO2-Pt catalyst. The catalyst shows excellent hydrogen evolution catalytic activity in seawater, and the CoPx-CeO2 composite carrier prevents Pt nano-particles from being agglomerated through interaction of metal carriers, so that the atom utilization rate of Pt is increased. Meanwhile, the CeO2 film actively enriches OH <-> in an alkaline electrolyte to construct a local high-alkalinity microenvironment on the surface of the catalyst, Cl <-> in seawater is prevented from getting close to an active site corroding the catalyst through electrostatic repulsion, and the stability and durability of the catalyst are improved.

The invention discloses an electromagnetic wave absorbing material CoFe2O4 / ZnO-RGO with a ternary heterostructure as well as a preparation method and application of the electromagnetic wave absorbing material CoFe2O4 / ZnO-RGO, and belongs to the technical field of electromagnetic wave absorption. According to the material, a novel heterostructure with a multi-scale interface and a three-dimensional conductive network is constructed by compounding magnetic loss type CoFe2O4, dielectric loss type ZnO nanorods and resistance loss type RGO. Wherein the ZnO nanorod not only serves as a dielectric loss body, but also effectively enhances the structural anisotropy and the interface polarization effect of the material, and cooperates with the magnetic loss of CoFe2O4 and the resistance loss of RGO to jointly optimize impedance matching and improve the electromagnetic attenuation capability, so that the material shows excellent wave-absorbing performance under various thickness and even ultrathin conditions. The material source is wide, the cost is low, the preparation process is green, simple and convenient, the material is suitable for large-scale production, and an effective material solution is provided for electromagnetic wave absorption application in the national defense and civil fields.

This invention discloses an energy storage type TiO2 / CN X The photoanode of WO3 composite material and its preparation method include the following steps: preparing WO3 nanorods by hydrothermal method; adding WO3 nanorods and anionic surfactant to water, sonicating, adding pyrrole, stirring, and then adding an initiator solution dropwise under ice bath conditions, stirring, and obtaining WO3 / PPy composite after reaction; adding WO3 / PPy composite and anionic surfactant to an alcohol solution, sonicating and stirring, adding tetrabutyl titanate, glacial acetic acid and acetone, and then adding an aqueous alcohol solution dropwise, transferring to a hydrothermal reactor for reaction, obtaining precursor TiO2 / PPy / WO3 composite after hydrothermal reaction; loading the precursor TiO2 / PPy / WO3 composite onto a conductive substrate. TiO2 / CN X / WO3's excellent sustained photocathode protection performance can be attributed to the highly conductive CN X In synergy with WO3, a narrow-bandgap semiconductor with energy storage properties, TiO2 nanoparticles with stable photoelectrochemical properties serve as the main material, ensuring the stability of the photoelectric performance of ternary materials.

The invention provides a nitride epitaxial wafer, a preparation method of the nitride epitaxial wafer and a Micro-LED. The nitride epitaxial wafer comprises a heterogeneous substrate, a composite column structure, a nitride buffer layer, an n-type nitride layer, a light-emitting layer and a p-type nitride layer. The composite column structures are distributed on the surface of one side of the heterogeneous substrate at intervals, and each composite column structure comprises a plurality of composite Si nano columns and a composite nano layer wrapping the surfaces of the composite Si nano columns; the composite Si nano column comprises a first composite Si nano column and a second composite Si nano column; the height of the first composite Si nanorod is different from that of the second composite Si nanorod; the nitride buffer layer covers the composite column structure, and the surface of one side, far away from the substrate, of the nitride buffer layer is a horizontal plane; the light-emitting layer comprises at least one light-emitting unit, and each light-emitting unit comprises an In-containing quantum well layer and a nitride quantum barrier layer which are arranged in a stacked mode. According to the invention, the brightness, electric leakage and ESD antistatic release performance of the nitride epitaxial wafer can be improved.

The invention belongs to the technical field of electrode materials, and particularly relates to a MnCo2O4 / ZnCo2O4 nano composite material as well as a preparation method and application thereof. The preparation method comprises the following steps: taking soluble manganese salt and soluble cobalt salt as raw materials, taking foamed nickel as a carrier, carrying out hydrothermal reaction in an alkaline environment to obtain MnCo-LDH / NF, then immersing the MnCo-LDH / NF in a precursor solution composed of the soluble cobalt salt, soluble zinc salt and 2-methylimidazole, carrying out coordination reaction to obtain MnCo-LDH ZIF-67 / ZIF-8, and finally carrying out heat treatment to obtain the MnCo2O4 / ZnCo2O4 nano composite material. In the MnCo2O4 / ZnCo2O4 nano composite material obtained by the method disclosed by the invention, MnCo2O4 with a nanorod structure and ZnCo2O4 with a dodecahedron structure form a heterojunction, so that the defect of poor conductivity of MnCo2O4 is overcome.

The invention discloses a titanium dioxide nanorod / dissimilar metal MOFs heterojunction material and a preparation method and application thereof, and belongs to the technical field of photoelectrochemistry seawater hydrogen production. Soluble nickel salt, soluble cadmium salt or soluble cobalt salt and ammonium molybdate are adopted as metal sources, spherical dissimilar metal MOFs grow on the surface of a TiO2 nanorod in situ, and the TiO2 nanorod / dissimilar metal MOFs heterojunction material is prepared. According to the present invention, the oxygen deficiency-regulated dissimilar metal MOFs material (i.e., the titanium dioxide nanorod / dissimilar metal MOFs heterojunction material) is obtained through subsequent acid etching and annealing treatment, the material is subjected to in-situ reconstruction during the OER process to spontaneously form the active hydroxide (NiOOH) of anion protection (MoO4 < 2->), and the excellent stability is represented; only small Faraday efficiency loss (1.2-2.3%) occurs in a high chloride ion environment (3.5 wt%-7wt% of NaCl), and an extensible path is provided for industrial-scale solar hydrogen production by using seawater.

The application discloses an IMU light path structure based on multiple super surfaces, and the light beam generated by a laser 1 is divided into three mutually perpendicular light beams after the action of a beam splitting super surface 3, and then is converted into circularly polarized light and linearly polarized light by a polarization conversion beam splitting super surface 4, and is used for pumping and detection of a nuclear magnetic resonance gyroscope 5 respectively. The beam splitting super surface 3 is composed of polarization-insensitive cylindrical nanorods, and the incident light is split and corresponding deflection is generated by combining the generalized Snell law. The polarization conversion beam splitting super surface 4 is composed of polarization-sensitive rectangular nanorods and polarization-insensitive cylindrical nanorods, the rectangular nanorods are used for converting linearly polarized light into circularly polarized light, and the cylindrical nanorods maintain the linear polarization characteristics and realize light beam splitting and direction adjustment. The application adopts a single laser configuration, realizes efficient light field regulation and control based on super surfaces, avoids the problem that a traditional IMU light path system depends on multiple lasers, reduces the system volume, complexity and energy consumption, improves the stability and integration, and is suitable for high-precision inertial navigation applications.

The present application relates to the technical field of thin film photocatalyst preparation, in particular to a kind of heterojunction thin film photocatalyst and its preparation method and application, the present application is constructed by purple phosphorus nanosheet (VPNS) and ZnO nanorod array on flexible substrate ITO-PEN A kind of VPNS / ZnO nanorod array heterojunction thin film photocatalyst, and it shows excellent catalytic performance in photocatalytic degradation organic pollutants and carries out sewage treatment, can realize the demand of photocatalysis and carries out sewage treatment.The VPNS / ZnO heterojunction thin film photocatalyst provided in the present application on flexible substrate ITO-PEN has the advantages of simple preparation method, high efficiency and good stability, high degradation efficiency, easy recovery and the like.

This invention provides a self-supporting one-dimensional nanorod array composite material, its preparation method, and its application, belonging to the field of clean energy harvesting technology. The preparation method provided by this invention includes the following steps: mixing soluble nickel salt, soluble molybdate, and water, and carrying out a hydrothermal reaction to obtain a NiMo precursor; heat-treating the NiMo precursor and a modifier under a protective atmosphere to obtain the self-supporting one-dimensional nanorod array composite material. Experimental results show that the composite material prepared by the method provided by this invention has excellent electrocatalytic water splitting activity and operational stability, and photo-assisted synthesis further enhances the electrocatalytic water splitting activity of the composite material, making it applicable to solar-driven electrocatalytic water splitting.

The application discloses a kind of implant and its preparation method and application, the implant includes material body, metal oxide layer and mixed crystal layer, the mixed crystal layer is located the surface of the metal oxide layer;The metal oxide layer includes metal oxide nanorod array;The metal oxide is selected from zinc oxide, silver oxide or its combination;The mixed crystal layer includes CaP crystal and metal oxide crystal.The implant of the application is sterilized by the bacteriostatic metal ion generated by physical puncture and degradation of metal oxide nanorod, has good antibacterial effect to gram-positive bacteria and gram-negative bacteria, prevents infection;It can also relieve post-implantation inflammatory response, reduce immune response under post-implantation infection, shorten wound healing time.In addition, due to the coating effect of mixed crystal layer on metal oxide layer, the bacteriostatic metal ion is slowly released, the release time is long, and long-lasting antibacterial effect can be achieved, and post-implantation inflammatory response can be reduced.

The invention belongs to the technical field of zinc ion batteries, and particularly relates to a zinc metal negative electrode and a zinc ion battery. The zinc metal negative electrode comprises a zinc metal substrate and a coating covering the surface of the zinc metal substrate, the coating comprises a conductive metal oxide; the coating is formed on the zinc metal substrate in a manner independent of an organic polymer binder. According to the scheme, the use of an insulating organic polymer adhesive is avoided, so that the conductivity of the coating is improved, and the structural controllability of the coating is improved. The high-conductivity indium tin oxide (ITO) nanorod is prepared through cooperation of microwave solvothermal synthesis and high-temperature calcination, and a protective layer which is free of a binder and controllable in structure is constructed on the surface of the zinc foil through the electrophoretic deposition technology.

The application belongs to the technical field of lithium ion battery electrode materials, and specifically discloses a one-dimensional lithium manganate nanorod with controllable diameter and a preparation method and application thereof. The application disperses manganese sulfate, potassium permanganate, a structure directing agent and a surfactant into a solvent, carries out a hydrothermal reaction, and obtains black precipitate; then the black precipitate is sintered to obtain manganese dioxide nanorods; the manganese dioxide nanorods are mixed with lithium hydroxide, and two-stage sintering is carried out to obtain one-dimensional lithium manganate nanorods. The one-dimensional lithium manganate nanorods are uniform in thickness and have very small surface energy, when used as a positive electrode material, can effectively shorten the transmission path of lithium ions, are not prone to agglomeration and have good flexibility, can maintain the integrity of the structure during long-time service under a large current, and are beneficial to improving the rate and cycle performance of the electrode. In addition, by adjusting the concentration of potassium permanganate and the hydrothermal reaction temperature, the diameter of the manganese dioxide can be accurately adjusted, and the controllable preparation of the one-dimensional lithium manganate can be realized.

The invention belongs to the technical field of catalysts, and discloses a nanorod-like Keggin type heteropolyacid catalyst and a preparation method and application thereof, the nanorod-like Keggin type heteropolyacid catalyst has a double rod-like structure, and the double rod-like structure is a rod-like structure with the length of 50-150 nm and a rod-like structure with the length of 3-10 [mu] m. The heteropolyacid catalyst has the characteristics of large specific surface area, double rodlike structure and the like, and the reaction performance of the catalyst for preparing methacrylic acid by oxidizing methylacrolein can be optimized.

The invention discloses a sulfur-free FR-4 copper-clad plate and a preparation method thereof, and belongs to the technical field of copper-clad plates. The copper-clad plate is prepared from sulfur-free epoxy resin, a sulfur-free curing agent, a sulfur-free flame retardant, organic silicon hybrid macromolecules, tetrafunctional epoxy resin, linear phenolic resin, microencapsulated ammonium polyphosphate, melamine cyanurate, surface grafting modified boehmite nanorods and filler. Through the design of a sulfur-free system, the sulfur content of the product is lower than 50 ppm, and the problems of contact resistance increase, unstable signal transmission and the like caused by sulfide migration of a traditional FR-4 copper-clad plate in a high-temperature and high-humidity environment are thoroughly solved. Meanwhile, the organic silicon hybrid macromolecules and the high-functionality epoxy resin have a synergistic effect, so that the balance of high glass transition temperature and high toughness is realized. The copper-clad plate has excellent dielectric property, flame retardant property and long-term reliability, and meets the development requirements of high reliability and high performance of electronic products.

The invention discloses a preparation method and application of an H-Fe3O4 (at) C nanorod electrode material with a core-shell structure. Dissolving iron nitrate nonahydrate, urea, ammonium fluoride and other drugs in ultrapure water, immersing the carbon fiber cloth in the precursor solution, and carrying out a hydrothermal reaction; after the reaction is completed, cooling to room temperature, washing and sintering to obtain a Fe3O4 nanorod taking the carbon fiber cloth as the substrate; putting the Fe3O4 nanorod serving as a working electrode into a deposition solution of potassium chloride and a pyrrole monomer, and carrying out a constant-pressure deposition reaction; after deposition is completed, washing and sintering are carried out, and the Fe3O4 (at) C core-shell nanorod is obtained. And finally, carrying out rapid Joule heat treatment to further graphitize the carbon layer, cooling, and taking out to obtain the H-Fe3O4 (at) C nanorod. The H-Fe3O4 (at) C nanorod is used as a negative electrode to assemble the asymmetric supercapacitor, the capacitance retention rate of the supercapacitor is 93.7% after 25000 cycles of charge and discharge, the capacitance retention rate is far higher than that of most current pseudocapacitance supercapacitors, and the self-discharge rate of the capacitor is inhibited while good electrochemical stability is achieved.

The invention belongs to the field of composite material preparation, and relates to a preparation method of a flexible vegetation-imitating green leaf camouflage material, which comprises the following steps: doping chrome green Cr2O3 particles in a polydimethylsiloxane (PDMS) matrix to form a bottom film with the appearance color similar to that of green vegetation, and then coating a layer of film doped with Au or Ag and other metal nanoparticles on the bottom film to obtain the flexible vegetation-imitating green leaf camouflage material. Therefore, the wave modulation method based on surface plasmon enhanced absorption is realized, the material can imitate the reflectivity of green vegetation in a near-infrared band, PDMS is taken as a matrix and doped with chrome green particles, so that the color of the film is similar to that of a green plant macroscopically, Ag nanorods doped in the upper PDMS coating can enable the chrome green coating to imitate a red edge effect, and the reflectivity of the green vegetation can be simulated in a near-infrared band. Vegetation is simulated in a near-infrared band. The two layers of films are compounded, so that the camouflage material and the vegetation green leaves have the same color and spectrum, and the preparation method and the material have very wide application prospects.

The invention relates to a flow polarization process for improving the polarization efficiency of a ceramic / polymer-based piezoelectric composite material, and belongs to the technical field of flexible piezoelectric composite materials. Piezoelectric nanorods selected by the composite material are consistent in electric dipole orientation under a mesoscale (can be prepared by a molten salt method, a hydrothermal method or an electrostatic spinning method), a thermosetting polymer is used as a matrix (such as polydimethylsiloxane, thermosetting epoxy resin and the like), and polarity orientation of piezoelectric filler in the polymer matrix is regulated and controlled by means of electrophoresis, so that the piezoelectric composite material is obtained. The orientation of the electric dipoles of the material is consistent under the macroscopic scale, the material is firstly polarized and then molded, and the polarization efficiency of the material is remarkably improved.

The invention belongs to the field of photocatalysis, and particularly discloses a perovskite composite photocatalyst for photocatalytic ethanol dehydrogenation and application. The composite photocatalyst takes a CdS nanorod as a carrier, a Cs2AgBiBr6 double perovskite active component formed by CsBr, AgBr and BiBr3 precursors is loaded on the surface of the CdS nanorod through a vacuum in-situ growth method, and a Pt, Rh or Ni metal cocatalyst can be further loaded. The method comprises the following steps: dispersing a CdS nanorod and a perovskite precursor in a mixed organic solvent, carrying out vacuum freezing-air exhaust circulation treatment, and removing the solvent under a heating condition to prepare the composite photocatalyst. When the photocatalyst is used for an ethanol photocatalytic dehydrogenation reaction under an anaerobic condition, hydrogen, acetaldehyde and acetal can be efficiently generated under the irradiation of visible light. According to the method, the photo-generated charge separation efficiency and the reaction stability are remarkably improved, and a new way is provided for ethanol high-valued conversion.

This invention discloses a CuS nanostructure material, its preparation method, and its applications. The CuS nanostructure material uses Cu-MOF octahedrons as a precursor, which are hydrothermally sulfided to obtain an octahedral hierarchical structure assembled from CuS nanorods. The CuS nanorods have a size of 50-100 nm, and the edge length of the precursor Cu-MOF octahedrons is 0.8-1 μm. This invention utilizes a one-step hydrothermal method to prepare a CuS nanostructure material through Cu-MOF sulfidation, resulting in a zinc-ion battery anode material with high conversion efficiency and excellent electrochemical performance.

This invention relates to the field of electrocatalytic materials technology, specifically to a ternary metal Prussian blue analogue-based partial conversion sulfur phosphating electrocatalyst, its preparation method, and its application. A CoMoO4 nanorod array is grown on a nickel foam surface via a hydrothermal method, further generating an in-situ FeCoNi-PBA precursor to form a hollow, embedded cubic structure. Hydrothermal sulfidation yields hollow, porous NiCo2S4 nanorods; subsequent low-temperature gas-phase phosphating achieves partial conversion of NiCo2S4, generating a NiCoP shell in-situ on the surface, forming a core-shell heterogeneous interface with the core, resulting in a NiCoP / NiCo2S4 / NF electrocatalyst. Compared to traditional bifunctional electrocatalyst preparation methods, this invention utilizes a two-step "sulfidation followed by phosphating" method to construct a stable heterogeneous interface in-situ on a conductive substrate, enabling the resulting catalyst to exhibit both good hydrogen evolution and oxygen evolution activity and long-term stability under high current in alkaline water electrolysis.

The application discloses a preparation method of a black electrically controlled light valve film based on nano SiC particles, and comprises the following steps: taking silica powder, graphite powder and NaCl-KCl with a mass ratio of 1:(2-5):(4-8) as raw materials to prepare rod-like SiC, wherein the molar ratio of NaCl to KCl is 1:(0.5-2); using a dopamine hydrochloride solution to modify the rod-like SiC to prepare black rod-like SiC@ dopamine powder; using oleic acid to modify the rod-like SiC@ dopamine to prepare modified black nano rod-like SiC powder; dispersing the modified black nano rod-like SiC powder in a dispersing agent, adding a stabilizer to prepare a black dispersion liquid; providing silica gel, uniformly mixing the black dispersion liquid with the silica gel to prepare a coating material; coating the coating material on the ITO surface of one ITO-PET conductive film and performing drying treatment to form a coating layer, oppositely arranging the ITO surface of the other ITO-PET conductive film to the coating layer and performing pressing treatment to prepare a black electrically controlled light valve film. The application can be electrically controlled to switch between colorless transparent and black transparent states, and meets the sunshade requirements of a vehicle regulation.

The present application relates to the technical field of photocatalytic and photoelectrocatalytic material preparation, in particular to a hematite film with a surface-loaded ligand-free nanocrystal inlaid titania passivation layer and a preparation method and application thereof. The hematite film with a nanorod structure and a surface-loaded titania passivation layer, and the ligand-free nanocrystal inlaid in the titania passivation layer, and the mass fraction of the ligand-free nanocrystal in the titania passivation layer is 0.085-0.43%, the ligand-free nanocrystal is inlaid on the titania passivation layer to improve the carrier bulk transport problem of the titania passivation layer, and then the hematite / electrolyte interface is activated to obtain a high-performance hematite photoanode material.

The invention relates to a graphene-coated molybdenum dioxide nanorod composite material as well as a preparation method and application thereof. The composite material is of a core-shell structure and takes a molybdenum dioxide nanorod as a core and a graphene layer as a shell; the graphene layer is formed by high-temperature carbonization of polyaniline, and the thickness of the graphene layer is 10-80 nm. The preparation method comprises the following steps: dissolving a molybdenum source in a nitric acid aqueous solution for hydrothermal reaction to prepare a molybdenum trioxide nanorod precursor; dispersing the molybdenum trioxide nanorod precursor in an acidic solution, sequentially adding aniline and ammonium persulfate under a stirring condition, and reacting to obtain a polyaniline / molybdenum trioxide composite precursor; and drying the composite precursor, and carrying out high-temperature calcination to obtain the graphene-coated molybdenum dioxide nanorod composite material. Compared with the prior art, the composite material has the high conductivity of graphene and the chemical activity of molybdenum dioxide, and shows excellent removal efficiency and cycling stability on lead ions in the capacitive deionization process.

The application discloses a kind of delta-MnO2-GO catalyst and its preparation method and application in room temperature formaldehyde degradation, it is related to inorganic catalyst technical field.The preparation method of delta-MnO2-GO catalyst of the application can significantly limit the growth of manganese dioxide nanosheet by doping with low amount of GO, to manufacture abundant mass transfer transmission channel, delta-MnO2-GO catalyst presents unique two-dimensional crown structure, two-dimensional coral-like hierarchical pore structure delta-MnO2 nanorod is uniformly dispersed on the GO of plane structure, greatly promote the exposure of catalytic site and the mass transfer of reactant, produce a large number of surface active oxygen ROS and hydroxyl radical-OH, greatly maintain the excellent catalytic activity and stability to HCHO degradation, stably realize nearly 100% HCHO elimination at room temperature.

The invention provides a preparation method of a polymer nanorod with a controllable and adjustable length-diameter ratio. The invention further provides a preparation method of the anti-tumor nano-drug, the anti-tumor nano-drug is prepared by the preparation method of the polymer nano-rod with the controllable and adjustable length-diameter ratio, and the paclitaxel nano-drug is prepared by the method. The three-step method adopted by the invention is based on a traditional emulsification method, special instruments and equipment are not needed, large-scale production is easy to realize, and the batch yield is relatively high; the preparation conditions are mild, and the drug activity can be effectively protected; the method is low in energy consumption, economical and efficient. According to the method, the length-diameter ratio of the nanorod can be controllably adjusted on the basis of not changing the raw material composition of the nanorod, the consistency of other parameters in the subsequent biological behavior research is favorably kept, the influence of mixed factors is reduced, and the reliability and repeatability of the research can be improved. Besides, when the length-diameter ratio of the nano-carrier is adjusted, only the process of heating fracture in the last step needs to be changed, so that the cost can be greatly saved, customized production is facilitated, or preclinical simple preparation is realized.

The invention belongs to the technical field of photocatalytic materials and preparation thereof, and discloses a ZnIn2S4 / CoO / ATP ternary composite photocatalyst based on attapulgite (ATP) as well as preparation and application of the ZnIn2S4 / CoO / ATP ternary composite photocatalyst. The ZnIn2S4 / CoO / ATP ternary composite photocatalyst comprises a CoO / ATP composite material and a composite material consisting of ZnIn2S4 nanosheets grown on the surface of the CoO / ATP composite material, and the mass ratio of ZnIn2S4 to CoO / ATP is 3: 7. The CoO nanoparticles and the ZnIn2S4 nanosheets are loaded on the surface of the ATP nanorod in situ, the composite photocatalyst with a hierarchical structure is constructed, the material has the advantages of being stable in chemical property, high in catalytic efficiency, easy to recycle and the like and can be used for solar energy conversion and photocatalytic hydrogen production, and meanwhile application and development of silicate minerals in the field of photocatalytic hydrogen production are promoted.

This invention belongs to the technical field of solar cells and discloses a three-dimensional two-dimensional core-shell self-encapsulated inverted perovskite solar cell and its preparation method. The method involves preparing an inverted planar heterojunction perovskite solar cell using NiO nanocrystals with a particle size of 3-5 nm and SnO2 nanorods with a particle size of 2-4 nm and an aspect ratio of 3-5, respectively, forming a hole transport layer (15-25 nm) and an electron transport layer (15-30 nm). A pyridylamine derivative hydrohalate is attached as a ligand to the surface of the NiO nanocrystals and SnO2 nanorods and added to the PbI2 layer. During the two-step preparation of the three-dimensional perovskite light-absorbing layer (500-800 nm) of formamidine triiodide(II)ate (FAPbI3), two-dimensional perovskites are simultaneously generated at the FAPbI3 / hole transport layer interface, the FAPbI3 / electron transport layer interface, and the grain boundaries within the FAPbI3 layer, thus forming a three-dimensional two-dimensional core-shell self-encapsulated perovskite light-absorbing layer. Finally, an aluminum-doped zinc oxide (AZO) top electrode was sputtered onto the electron transport layer to obtain a three-dimensional two-dimensional core-shell self-encapsulated inverted perovskite solar cell.

The invention provides a red-light nitride epitaxial wafer, a preparation method thereof and a Micro-LED. The red-light nitride epitaxial wafer comprises a sapphire substrate, an insertion structure, an n-type nitride pattern structure layer, a light-emitting layer and a p-type metal nitride layer, the insertion structure penetrates through the n-type nitride pattern structure layer, the light-emitting layer and part of the p-type metal nitride layer and comprises a composite Si nano-column and a composite regulation and control layer, and the composite Si nano-column comprises a Si nano-column and a semi-ellipsoid structure; the composite regulation and control layer comprises a protection layer and a buffer layer, the protection layer is arranged on the outer wall of the Si nano-column, and the buffer layer is arranged on the area between the adjacent composite Si nano-columns; and an n-type nitride pattern structure layer, a light-emitting layer and a p-type metal nitride layer are laminated on the buffer layer between the adjacent composite Si nano columns. The In component merging and uniformity can be improved, the light-emitting efficiency and brightness of the Micro-LED are improved, the half-peak width of the light-emitting wavelength is reduced, and the color purity of display application is improved.