The invention discloses a
lithium manganate conductive material and a preparation method thereof, and the
lithium manganate conductive material comprises a
lithium manganate inner net layer which is a nano
network layer formed by connecting lithium manganate
crystal grains; the
graphene and / or
carbon nanotube conductive carbon outer net layer is deposited on the surface of the inner net layer. The lithium manganate
crystal grains are uniform and fine, and the
crystal grains are of a continuous net-shaped arrangement structure. Dissolving and mixing the
polymer nanofiber,
manganese salt, lithium salt and M-doped salt to form gel,
drying, and carrying out two-stage programmed heating
calcination in an
oxygen-containing
atmosphere to obtain a lithium manganate nano inner net layer; ultrasonically dispersing the lithium manganate nano inner net layer in water, adding acidified carbon nanotubes and / or
graphene oxide dispersion liquid, and depositing the acidified carbon nanotubes and / or
graphene oxide dispersion liquid on the surface of the inner net layer to form a conductive carbon outer net layer. The obtained lithium manganate conductive material has a continuous large-area two-dimensional
network structure, shows
high conductivity, high specific capacity and excellent
cycling stability, and can be widely applied to the fields of lithium
ion batteries, electrochemical lithium extraction, lithium
ion adsorption and the like.