This invention relates to the preparations of
noble metal catalysts, i.e.,
platinum and
platinum alloys, on suitable supports with nanonetwork structures and high catalytic efficiencies. A compact structure of a
monolayer or a few
layers is formed by self-
assembly of
organic polymer, e.g.,
polystyrene (PS), nanospheres or inorganic, i.e.,
silicon dioxide (SiO2), nanospheres on a
support surface. In the void spaces of such a compact arrangement, catalyst is formed by filling with catalyst
metal ion-containing
aqueous solution and reduced by
chemical reduction, or formed by vacuum
sputtering. When using
organic polymer nanospheres as the starting or structure-directing material, the
polymer particles are removed by burning at a high temperature and the catalyst having a nanonetwork structure is obtained. In the case of using
silicon dioxide nanospheres as the starting material,
silicon dioxide particles are dissolved with
hydrofluoric acid solution and evaporated away leading to formation of a similar nanonetwork structure made of catalyst. The catalysts prepared by these methods possess characteristics of robust in structure, uniform in
hole size and high in catalytic surface area. Their main applications include uses as catalysts in direct
methanol and
proton exchange membrane
fuel cells, as well as in chemical reactors, fuel reformers, catalytic
converters, etc.