The present invention relates to an electrochemical element comprising: a negative
electrode comprising at least particles comprising
silicon; and a positive
electrode comprising, as active material: i) at least one compound LixMn1.y.zFeyMzPO4 (I), wherein M is selected from among (B, Mg, AI, Si, Ca, Ti, V, Cr, Co, Ni, Cu, Zn, Y, Zr, Nb, S, K, Pb, V, Mo, W, Hf, Bi, Se and mixtures thereof); with 0.8 ≤ x ≤ 1.2; 0.5 ≤ 1-y-z < 1; 0 < y ≤ 0.5; 0 ≤ z ≤ 0.2; ii) at least one compound Liw(NixMnyCozM't)O; (II), wherein M' is selected from among (AI, B, Mg, Si, Ca, Ti, V, Cr, Fe, Cu, Zn, Y, Zr, Nb, W, Mo, S, Sr, Ce, Ta, Ga, Nd, Pr, La and mixtures thereof); with 0.9 ≤ w ≤ 1.1; 0 < x; 0 ≤ y; 0 ≤ z; 0 ≤ t; wherein: a) the ratio (% Si / A) is such that: 0.7 ≤ (% Si / A) ≤ 4.0, (A) being the product of the content by weight of compound (I) in the positive
active layer, expressed relative to the total weight of compounds (I) and (II), and the
molar content of iron (%Fe) in compound (I), expressed relative to the
molar content of iron and
manganese in compound (I); and (%Si) being the content by weight of
silicon in the active material of the negative
active layer, expressed relative to the total weight of the active material of the negative
active layer; and ≤ b) the ratio (N / P) between the first-charge capacity of the negative
electrode and the first-charge capacity of the positive electrode is such that: 1.1 ≤ (N / P) ≤ 1.7.