383 results about "Lithium acetate" patented technology

The invention discloses a process of coprecipitation-combustion synthesis of nickel cobalt manganese lithium carbonate. (1) Utilizing acetate or nitrate of nickel, cobalt, and manganese as transition metal source and ammonia as complexing agent and utilizing H2C2O4, (NH4)3C2O4, (NH4)2CO3 or NH4HCO3 as precipitator, compound carbonate contained Ni-Co-Mn or oxalate precursors is synthesized by coprecipitation method. (2) Directly drying the compound carbonate containing Ni-Co-Mn or the suspension liquid of the oxalate and adding lithium nitrate or lithium acetate or a small quantity of water or ethanol to adjust into rheological phase. (3) Laying the materials in rheological phase in an electric stove to perform burning synthesis reaction, wherein the electric stove heats the materials in rheological phase at temperature of 400-600DEG C and then keeps constant temperature. (4) Temper drawing the reaction product with temperature of 600-1200DEG C, and anode active materials of lithium ion battery LiNixCoyMn1-x-yO2 is obtained. The invention has the advantages of simple technique, easy operation, saving water and energy and environment-friendliness, further, the synthetic material is provided with the shape of sphere or near-sphere, high specific capacity and fine cycle performance.

The present invention is microwave synthesis process of high density spherical lithium ferric phosphate as the positive electrode material of lithium ion cell, and belongs to the field of energy source material preparing technology. Spherical lithium ferric phosphate is prepared through mixing ferrous sulfate and solid phosphorus in the required Fe/P ratio; adding in certain speed into deionized water; adding alkali matter to regulate pH value to form the precursor ammonium ferrous phosphate; drying the precursor, mixing with lithium acetate in the same ratio, adding proper amount of conducting agent, and high temperature treatment at 600-800 deg.c for 3-30 hr in the protecting atmosphere. Thus prepared spherical lithium ferric phosphate has average grain size of 5-10 microns, tap density 2.0-2.3 g/cu cm, and room temperature initial specific discharge capacity of 140-160 mA/g. The process is simple, low in cost, high in yield and suitable for industrial production.

The invention discloses a lithium-enriched ternary anode material of a power lithium-ion battery and a preparation method of the lithium-enriched ternary anode material. The molecule formula of the lithium-enriched ternary anode material of the power lithium-ion battery is Li1.2Ni0.13Co0.13Mn0.54O2. The preparation method comprises the following steps of: dissolving lithium acetate, cobaltous acetate, nickel acetate and manganese acetate in deionized water according to the molar ratio of Li: Co: Ni: Mn: O being 1.2: 0.13: 0.13: 0.54: 2 to obtain a solution 1; adding citric acid according to the ratio of the molar weight of the citric acid to the total molar weight of Ni, Co and Mn being 1:1 to obtain a solution 2; dropwise adding the solution 2 into the solution 1, and then adjusting the pH value to 9, continuously stirring the solution at the temperature of 80 DEG C until purple gel is formed, and then sequentially drying, ball milling, calcining segment by segment and grinding to obtain the lithium-enriched ternary anode material of the power lithium-ion battery with large discharging specific capacity and good cycling performance.

The present invention belongs to the technical field of new energy and material, and particularly relates to a preparation method of a Li4Ti5O12-TiO2 composite electrode material. The utility model aims to settle a technical problem of providing a cathode material which has the following advantages: simple preparation method and capability of charging/discharging at a high magnification. Lithium acetate and tetrabutyl titanate are respectively used as a lithium source and a titanium source. Ammonia water is used as a pH value conditioning agent. Amorphous Li4Ti5O12-TiO2 precursor is prepared through the heat of solvent, and Li4Ti5O12-TiO2 composite powder with good crystal form is prepared after heat treatment. The sample which is synthesized according to the invention has the following advantages: small particle, uniform dispersion, regular shape, stable structure. good high-magnification charging/discharging characteristic, high cycling performance, and wide development prospect as cathode material of lithium ion battery. The preparation method of the Li4Ti5O12-TiO2 composite electrode material has the following main advantages: simple synthesis equipment and technique; easy control for phase composition, particle size and particle shape; flexible operation; reduced synthesis temperature; shortened heat treatment time; and reduced energy consumption.

The invention relates to a silicon-carbon cathode material with artificial SEI layers, high specific volumetric capacity and cycle performance and application of the silicon-carbon cathode material. The silicon-carbon cathode material is of an intermediate-phase graphite structure which is secondarily granulated, outer shell layers of the intermediate-phase graphite structure are amorphous carbon coating layers, inner shell layers of the intermediate-phase graphite structure are dense LiF membranes, and nanometer silicon is uniformly dispersed to form cores of the intermediate-phase graphite structure. A method for preparing the silicon-carbon cathode material includes steps of 1, crushing and shaping intermediate-phase graphite balls with large particle diameters to obtain intermediate-phase graphite micro-powder with median particle diameters of approximately 7 micrometers; 2, carrying out ball-milling dispersion on the nanometer silicon and the micro-powder obtained at the step 1; 3, uniformly mixing lithium acetate solution and materials obtained at the step 2 with one another; 4, carrying out dropwise addition reaction on NH4F solution and materials obtained at the step 3; 5, carrying out spray-drying on materials obtained at the step 4; 6, mixing PVDF (polyvinylidene fluoride) and materials obtained at the step 5 with one another to obtain mixtures and granulating and coating the mixtures; 7, immobilizing and carbonizing materials obtained at the step 6; 8, sieving materials obtained at the step 7. The silicon-carbon cathode material and the application have the advantages that the silicon-carbon composite cathode material is stable in cycle performance, high in specific volumetric capacity and easy to industrially produce; a lithium ion battery with a cathode which is processed from the silicon-carbon cathode material is high in specific volumetric capacity and excellent in cycle performance.

The invention discloses a method for preparing lithium titanate powder. The method comprises the following steps of: weighing an excessive amount of lithium salt (lithium nitrate or lithium acetate and the like) with the concentration 0-5 percent according to the metering ratio of a chemical formula Li4Ti5O12, preparing the lithium salt into a solution, and adding an appropriate amount of coordination agent and incendiary agent (such as citric acid or EDTA (Ethylene Diamine Tetraacetic Acid) or oxalic acid ) into the Li<+> solution to obtain a uniform mixed solution A; weighing metatitanic acid (H2TiO3) according to the metering ratio of a chemical formula Li4Ti5O12, adding an appropriate amount of hydrogen peroxide (oxyful, H2O2) and an excessive amount of ammonia water (NH3*H2O), and adding a certain amount of coordination agent and incendiary agent (such as citric acid or oxalic acid or EDTA and the like) after the metatitanic acid is fully dissolved to obtain a uniform mixed solution B; mixing the prepared solution A with the solution B, heating and concentrating into jelly (or drying into powder at a temperature between 50 DEG C and 200 DEG C); and putting the powder obtained by drying (or the directly prepared jelly) into a muffle furnace for calcining at a temperature between 500 DEG C and 900 DEG C for 1-10 hours to obtain Li4Ti5O12 powder. The method has the advantages of simple technical process, low cost of raw materials, easiness for control of stoichiometric ratio and excellent electrochemical performance of a product, and is suitable for mass production; and the particle diameter of the powder is between 50 nanometers and 500 nanometers.

The invention relates to a preparation method for a manganese phosphate lithium nanosheet. According to the preparation method, glycol and water are used as a solvent, and polyethylene glycol is introduced, so that the formation of crystal nucleus and the growth of crystal are influenced, and as a result, the thermosynthesis of the solvent of the manganese phosphate lithium nanosheet can be achieved. The preparation method comprises the following steps of: dissolving ascorbic acid in the water/glycol solvent; then dissolving into phosphoric acid and manganese acetate in sequence; dropwise adding the water/glycol solution of manganese acetate to the previous solution containing phosphoric acid, lithium acetate and ascorbic acid; then introducing proper polyethylene glycol; fully mixing to obtain a precursor for water/solvent thermal reaction; transferring the precursor into a reaction kettle system to be sealed; thermally processing at 160 to 240 DEC G; and carrying out thermal reaction to the solvent to obtain the manganese phosphate lithium nanosheet. By adopting the preparation method, products are stable in quality, high in purity and high in dispersion of particles; the lithium ions can be dispersed well; the electrochemical performance of a lithium ion battery can be improved; and the preparation method is simple in technical process, easy to control, free of pollution, low in cost, and easy for mass production.

A method for preparing positive electrode multielement active material containing lithium / manganese composite oxide includes directly using lithium hydroxide coprecipitation to prepare M ( OH )2 , mixing it with lithium salt in grinding , forming plate by pressing , prebaking , cooled ball grinding , forming plate by pressing and backing . In the method , applied nickel salt is nickel acetate or nickel nitrate , applied cobalt salt is cobalt acetate or cobalt nitrate, applied manganese salt is manganese nitrate or manganese acetate and applied lithium salt is lithium carbonate or lithium acetate .

The invention discloses a method for preparing a spinel type lithium titanate nanowire array, in particular a method for preparing the spinel type lithium titanate nanowire array by using an aluminum oxide template. The method comprises the following steps of: preparing a porous aluminum oxide template; deoiling and annealing an aluminum plate, and performing electrochemical polishing, secondary anodic oxidation and hole expansion; synthesizing a lithium titanate sol precursor; adding butyl titanate, a complexing agent, ethylene glycol and lithium acetate dihydrate into absolute ethanol according to a proportion in turn and continuously stirring; preparing the lithium titanate nanowire array; dipping the porous aluminum oxide template into the lithium titanate sol precursor under vacuum; performing high-temperature roasting; and finally dissolving the template off with NaOH solution. Spinel type lithium titanate nanowires prepared by the method have the diameters of between 50 and 100nm; and the array has the advantages of uniform aperture size, large specific surface area, high degree of order, regular distribution, adjustable composition, controllable structure and the like.

The invention provides a modified nickel cobalt manganese ternary composite electrode material coated on an oxide surface and a preparation method thereof. A coating layer of the composite electrode material is prepared from two or three metal oxides MxOy, wherein M is niobium, zirconium or yttrium; the thickness of the coating layer is 0.5-50nm and the weight percent in the composite electrode material is 1%-10%; the prepared nickel cobalt manganese composite electrode material has an alpha-NaFeO2 layered structure. Nickel acetate, cobalt acetate, manganese acetate and lithium acetate are taken as raw materials, the metal oxides are served as surface coating matters and the high-temperature sintering and in-situ coating combined technology is adopted for preparing the high-performance composite electrode material. The coating layer of the composite electrode material can prevent the metal ions in active materials from dissolving, can resist against the corrosion of HF to active materials and can reduce the surface impedance and promote the cycling stability. The preparation process is simple, the operation is easy, the production period is short, the equipment requirement is low and industrial development and popularization and application are benefited.

The method for preparing lithium-manganese oxide by using low-beat solid phase reaction includes the following steps: according to stoichiometric ratio mixing lithium acetate, manganese acetate and solid phase organic acid or alcohol or sugar or amino acid; grinding at room temp., drying the obtained mixture at 75-85 deg.C and calcining at 350-850 deg.c for 12-18 hr. so as to obtain the invented final product Li1+xMn2O4 or Li1+xMnO2, in which x=-0.1í½+0.2. According to different stoichiometric ratio the spinelle type LiMn2O4 or laminate LiMnO2 can be obtained.

The invention discloses a synthesis method for a lithium iron phosphate/carbon composite material. The synthesis method is characterized by comprising the following steps of: (1) uniformly mixing lithium phosphate, iron powder, iron phosphate, another lithium source and a carbonous conductive agent precursor, wherein the another lithium source is one or the combination of any of the following components: lithium carbonate, lithium oxalate, lithium acetate, lithium hydroxide and lithium nitrate, and the carbonous conductive agent precursor is one or the combination of any of the following components: glucose, sucrose, citric acid, starch, polyvinyl alcohol, stearic acid and lauric acid; (2) putting the raw material mixture obtained in the step (1) into a ball-milling container and performing full ball milling; and (3) putting the mixture subjected to the ball milling into nitrogen gas and baking the mixture at 600-800 DEG C to prepare the lithium iron phosphate/carbon composite material. The synthesis method is simple in process, and the synthesized lithium iron phosphate/carbon composite material is high in specific capacity and excellent in high-current and cycle performance.

The invention discloses a method for coating through an all-solid-state lithium-ion electrolyte material Li<7>La<3>Zr<2>O<12>. The method comprises the following steps: (1) dissolving lithium acetate and lanthanum acetate into water; (2) dissolving zirconium n-butoxide into an ethanol-acetate solution; and (3) adding the solution obtained in the step (1) to the solution obtained in the step (2) under a stirring condition, adding a positive active material, carrying out ultrasonic treatment for 30-60 minutes, ageing for 10-12 hours, drying the obtained gel at 80-100 DEG C for 1-2 hours, heating the gel to 600-650 DEG C for burning for 3-5 hours, and naturally cooling the product to obtain the Li<7>La<3>Zr<2>O<12>-coated positive active material. Compared with an existing method, the method provided in the invention can make the burning temperature obviously lowered; and burning loss of a lithium element at a high temperature is avoided.

The invention discloses a normal-temperature stable high-efficiency environment-friendly sealing agent for aluminum and an aluminum alloy. The formula of the sealing agent comprises, by weight, 3%-15%of sodium acetate, 0%-2% of lithium acetate, 0.2%-5% of sodium benzoate, 0%-2% of urea, 5%-30% of a stabilizer, 0.5%-10% of a dispersing agent, 0%-15% of a complexing agent, 0.5%-10% of a pH buffer agent, 0%-10% of a corrosion inhibitor and the balance deionized water. According to the normal-temperature sealing agent, the solution system is stable; a hole sealing film is compact; the hole sealing agent is small in consumption and long in service life; the surface of a workpiece subjected to hole sealing is smooth and bright, is free of color change, does not generate powder, is capable of effectively preventing fingerprints and can achieve oil stain resistance; the problems that the surface of an aluminum product subjected to hole sealing by a hole sealing agent used in the existing industrial production is not enough in brightness, is relatively dark in color, and is high in hydrophilic performance and prone to generate water stains after being cleaned and dried are solved, and theproblem that a lot of products generate white ash is also solved; and the strength, the hardness and the corrosion resistance of the workpiece are improved.

The invention discloses an electrolyte for inhibiting the growth of lithium dendrites and a lithium battery. The electrolyte comprises an additive, a lithium salt and an organic solvent. The additiveincludes at least one in the group consisting of lithium hexafluorophosphate, lithium perchlorate, lithium bis(trifluoromethane) sulfonate, lithium trifluoromethanesulfonate, lithium fluoroborate, trilithium hexafluoroaluminate, lithium hexafluoroarsenate, lithium fluoride, lithium chloride, lithium bromide, lithium nitrate, lithium polysulfide, lithium nitride, lithium phosphide, lithium oxalateborate, lithium oxide, lithium sulfite, lithium sulfate, lithium acetate, lithium hydroxide and lithium oxalate, and the lithium salt is different from the additive. According to the lithium battery containing an additive, a layer of solid electrolyte membrane can be formed on a surface of the lithium metal negative electrode during charge and discharge, and the polymerization of the electrolyte can be induced to form an oligomer which covers a surface of a lithium negative electrode and a surface of a positive electrode material matched with the lithium negative electrode. The protective layer can effectively inhibit the growth of the lithium dendrites, and therefore, the safety performance of the battery is improved.

The invention discloses a method for preparing a lithium titanate carbon composite material, and the method comprises the following steps of: dispersing graphite powder in concentrated sulfuric acid, adding KMnO4 and H2O2 while stirring to obtain a nano graphite oxide material, and preparing an aqueous solution of graphene oxide, thereby obtaining porous graphene material; preparing the porous graphene material into porous graphene solution, and evenly mixing a lithium carbonate/lithium acetate mixture, titanium dioxide and deionized water together through ball milling to obtain slurry; next, mixing the slurry with the porous graphene solution under the stirring condition, thereby obtaining porous graphene and lithium titanate precursor powder; and sintering the precursor powder, thereby obtaining the lithium titanate carbon composite material. The lithium titanate carbon composite cathode material prepared by the method provided by the invention employs the composite material of lithium titanate and porous graphene, and has high multiplying power and ultra-stable cycle performance, and further has high energy density; and therefore, the cathode material is high in specific capacity, good in cycle performance and long in service life if being applied to the lithium ion battery.

The invention discloses a silicon-based negative electrode material for a lithium ion battery. The silicon-based negative electrode material comprises an amorphous silica matrix, a plurality of nanometer silicon nucleuses, a carbon coating and a LiF coating, wherein the plurality of nanometer silicon nucleuses are embedded into the amorphous silica matrix; the carbon coating coats the amorphous silica matrix; and the LiF coating coats the carbon coating. The invention also provides a preparation method for the silicon-based negative electrode material. The preparation method comprises the following steps: adding nanometer silicon powder into an alkaline solution, adding a carbon source, evaporating the solution to dryness and then carrying out drying so as to obtain an intermediate material; and sintering the intermediate material under the protection of inert gas, then uniformly dispersing the intermediate material in a lithium acetate solution, adding an ammonium fluoride solution, carrying out a hydrothermal reaction and then carrying out washing, filtering and drying. The preparation method provided by the invention is simple in process and easy for large-scale production; andthe prepared negative electrode material is small in volume expansion, high in electron conductivity, low in internal resistance and good in electrochemical performance.