The invention relates to a conductive composition containing poly(3,4-ethylenedioxythiophene)/lignosulfonic acid and a preparation method thereof. The method comprises the following steps of: chemically oxidizing and polymerizing 100 parts by weight of monomer (3,4-ethylenedioxythiophene) and 170-300 parts by weight of an oxidant in 100-1,000 parts by weight of an aqueous solution in which lignosulfonic acid is taken as a carrier; and adding 200-500 parts by weight of a non-aqueous solvent, 10-100 parts by weight of a polyhydroxy aromatic compound and 50-200 parts by weight of a bonding agent to obtain the conductive composition containing poly(3,4-ethylenedioxythiophene)/lignosulfonic acid. A product prepared with the method meets the requirements of low production cost, transparency, high conducting performance, high adhesion and high hardness in an efficient antistatic agent, and has the characteristics of high dispersion stability, heat stability, temperature stability and water washing resistance. The conductive composition has economic and environmental protection effects as well as a good industrial prospect.