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203results about How to "Improve colloidal stability" patented technology

Implementation method of reversible addition fragmentation chain emulsion polymerization

The invention discloses an implementation method of reversible addition fragmentation chain emulsion polymerization. 20-40 parts by weight of water, 0.1-2 parts by weight of bipolar macromolecule reversible addition fragmentation chain reagent, 1-20 parts by weight of monomer and 0.005-0.2 part by weight of micromolecule reversible addition fragmentation chain reagent are added into a reactor, stirring to be uniform is carried out, stirring is carried out, nitrogen is led in, heating is carried out until the temperature is increased to be 50-80 DEG C, 0.004-0.08 part by weight of water soluble initiator is added, initiated polymerization is carried out for 10-60min, 0-2 parts by weight of alkaline aqueous solution is added, and polymerization is continued for 0.5-5h. The invention utilizes bipolar macromolecule reversible addition fragmentation chain reagent with special structure as emulsifier and chain transfer agent, micromolecule reversible addition fragmentation chain is combined with emulsion polymerization, alkali is replenished, so as to improve the stability of emulsion; besides, process is simple, energy consumption is low, reaction time is short, conversion rate is high, no traditional emulsifier is adopted, molecular weight is consistent with design value, and molecular weight distribution is less than 2.0, thus having good industrialization prospect.
Owner:ZHEJIANG UNIV

Method for preparing reversible addition-fragmentation chain transfer emulsion polymerization

ActiveCN101591403AShort reaction inhibition periodFast responseEmulsionChemistry
The invention discloses a method for preparing reversible addition-fragmentation chain transfer emulsion polymerization. The method comprises the following steps: adding 0.1 to 2.5 portions of amphiphilic macromolecular reversible addition-fragmentation chain transfer reagent, 20 to 40 portions of water and 1 to 20 portions of monomer by weight into a reactor, and stirring and mixing the mixture; introducing nitrogen into the reactor; heating the reactor to a temperature of between 50 and 80 DEG C; and adding 0.005 to 0.05 portion of water-soluble initiator by weight into the reactor to initiate polymerization for 0.5 to 6 hours. The method has the advantages of simple flow equipment, low energy consumption, easy removal of water system reaction heat, short reaction inhibition period, high reaction speed, high final percent conversion and good emulsion stability, and the amphiphilic macromolecular reversible addition-fragmentation chain transfer reagent can be used as a chain transfer reagent and an emulsifier without adding conventional emulsifier in addition, has actual molecular weight in accordance with a molecular weight design value and distribution of the molecular weight less than 1.4, can be synthesized into a segmented copolymer through semicontinuously adding the monomer, and has good industrial prospect.
Owner:ZHEJIANG UNIV

Preparation method of ferric oxide nanoparticle supported sodium alginate nanogel

The invention relates to a preparation method of ferric oxide nanoparticle supported sodium alginate nanogel. The preparation method comprises steps as follows: (1), PEI (polyethylenimine) coated Fe3O4 nano-particles (Fe3O4-PEI) are synthesized with a hydrothermal method; (2), an aqueous solution of sodium alginate is firstly activated by EDC (carbodiimide) and has a double emulsion reaction to form a W / O / W polymer emulsion; (3), Fe3O4-PEI in the step (1) is taken as a crosslinking agent and added into the polymer emulsion in the step (2) to have a crosslinking reaction, and the ferric oxide nanoparticle supported sodium alginate nanogel is obtained after an organic solvent and a surface active agent are removed. The method is very simple, and operation and separation are easy; meanwhile, sources of raw materials are extensive; the prepared sodium alginate nanogel has a smaller grain diameter, is uniformly distributed, high in relaxation rate and low in cost, has a remarkable radiography effect, simultaneously has excellent water solubility, gel stability, biocompatibility and blood compatibility, doesn't have a harmful effect on a living body, and has potential application value in the magnetic resonance imaging diagnosis field.
Owner:DONGHUA UNIV

Lubricating grease composition for automobile glass lifter and preparation method of lubricating grease composition

ActiveCN102876434AOutstanding water resistanceOutstanding shear performanceLubricant compositionAntioxidantEvaporation
The invention provides a lubricating grease composition for an automobile glass lifter and a preparation method of the lubricating grease composition. The lubricating grease for the automobile glass lifter comprises the following ingredients in percentage by weight: 87 to 91.5 percent of basic oil, 7.5 to 12 percent of thickening agents, 0.5 percent of antioxidants, 0.03 percent of anti-rust agents and 0.5 percent of structure improving agents. The unique mixed thickening agent type is adopted, so the water-resistance and shearing performance of the lubricating grease are excellent, good low-temperature and viscosity-temperature performance is given to the lubricating agent through the proper basic oil type and mixture ratio, and the wide temperature use requirement being minus 40 DEG C to 70 DEG C of the automobile glass lifter accessories can be perfectly met. The prepared lubricating grease has the characteristics that the water resistance and the oxidation resistance are excellent, the oil rate is low, the evaporation loss is small, the shearing stability is high, the high-low temperature performance and the anti-corrosion protection effect are good, and the like, the use requirements of the automobile glass lifter can be perfectly met, and the use temperature range of the lubricating grease is minus 40 DEG C to 130 DEG C.
Owner:CHINA PETROLEUM & CHEM CORP

Block copolymer containing block with glass transition temperature higher than 100 DEG C and method for preparing block copolymer

The invention discloses a block copolymer containing a block with the glass transition temperature higher than 100 DEG C and a method for preparing the block copolymer. In the method, the block copolymer latex is prepared by taking n-butyl acrylate as a soft segment and the random copolymer of styrene and gamma-methyl-alpha-methylene-gamma-butyrolactone as a hard segment, adopting an emulsion polymerization system and applying a reversible addition-fragmentation chain transfer free radical polymerization technology. The method adopts simple processes and equipment, and the processes are environmental-friendly and energy-saving; an amphipathic macromolecule reversible addition-fragmentation chain transfer reagent is adopted, has the dual functions of both a chain transfer reagent and an emulsifier, not only is the good monomer polymerization control realized, but also the traditional emulsifier is prevented from being used; the reaction has no inhibition period, the reaction speed is high and the final conversion rate is high; the colloidal particles are stably increased during the process; and the glass transition temperature of the hard segment of the product can reach 155 DEG C, and the block copolymer has a good application prospect in the field of high-heat-resistance thermoplastic elastomers.
Owner:ZHEJIANG UNIV
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