The invention discloses a preparation method of
oxygen-deficient
tungsten oxide WO2.72 nanospheres with
photodegradation adsorption performance, which comprises the following steps: firstly, providing cations by using
urea, embedding the cations into
tungsten oxide to form a non-stoichiometric compound
ammonium tungsten bronze (NH4) 0.33 WO3, capturing and separating out cations NH4 < + > in holes by using OH <-> radicals provided by deionized water in a
mixed solution, and promoting the valence state of W to be reduced from W < 6 + > to W < 5 + >, thereby obtaining the
oxygen-deficient
tungsten oxide WO2.72 nanospheres with
photodegradation adsorption performance. Meanwhile, in the synthesis process, the
alcohol serves as a
solvent, on one hand, a reaction medium needed for synthesizing the WO2.72 is provided, on the other hand, through interaction of the
alcohol, the
urea and the deionized water, growth and morphology of the product are controlled, the final product WO2.72 is synthesized, the WO2.72 synthesized in the mode not only solves the agglomeration problem of WO2.72 synthesized in the prior art, but also improves the yield of the WO2.72. And moreover, by accurately controlling the synthesis conditions, accurate regulation and control on the morphology and the size of the product are realized, and the adsorption and
photodegradation properties of the product are improved.