586 results about "Soft segment" patented technology

The invention relates to the technical field of macromolecules, and discloses a preparation method of modified polyurethane toughened epoxy resin, which comprises the following steps: by taking 4-(Boc-amino) phenylboronic acid, diethanol amine, 1, 3-bis (3-glycidyl ether oxypropyl) tetramethyldisiloxane and the like as raw materials, carrying out a series of chemical reactions to obtain a borate siloxane chain extender; the method comprises the following steps: adding a polyurethane prepolymer into the epoxy resin, participating in chain extension of polyurethane, and modifying the epoxy resin by using the polyurethane prepolymer to obtain the modified polyurethane toughened epoxy resin. A'soft segment 'and an Si-O structure in the modified polyurethane can also improve the flexibility of a curing network, effectively change the fracture mechanism of the resin, absorb a large amount of energy when the resin is fractured, and contribute to improving the toughness of the epoxy resin; on the basis of ensuring the strength of the epoxy resin, the toughness and flame retardant property of the epoxy resin are improved, and the epoxy resin can be applied to the fields of composite materials, coatings, adhesives and the like with higher toughness and flame retardant requirements, and has wide applicability.

The invention provides a comb-shaped polymer binder, a pole piece and a battery, the comb-shaped polymer binder comprises an acrylate main chain, a flexible soft segment, a polar hard segment and a functional chain segment, the flexible soft segment, the polar hard segment and the functional chain segment are respectively grafted on the acrylate main chain, the flexible soft segment comprises an ether chain segment and / or an ester chain segment, the polar hard segment comprises a polar group and / or a first heteroaromatic ring group, and the functional chain segment comprises a functional group and a second heteroaromatic ring group. The functional chain segment comprises an aromatic ring group containing a pi-conjugated structure and / or a second heteroaromatic ring group containing a pi-conjugated structure. The comb-shaped binder adopts a structural design of'hard section anchoring + soft section buffering + functional side chain ', is helpful for enabling the binder to have high peel strength, stress buffering and electron conduction capabilities at the same time, is compatible with an existing wet coating-rolling process, is helpful for improving the peel strength and prolonging the cycle life of an electrode plate when being used for preparing the electrode plate, and is beneficial for improving the service life of the electrode plate. And the rate capability of the battery is improved.

The invention relates to the technical field of polyurethane coatings, in particular to a hydrophobic flame-retardant polyurethane coating and a preparation method thereof. The preparation method comprises the following steps: firstly, taking 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and methallyl alcohol as raw materials, and reacting to obtain hydroxyl grafted phosphaphenanthrene; taking 1, 1, 3, 3-tetramethyldisiloxane and methallyl alcohol as raw materials, and reacting according to a molar ratio of 1: 2 to obtain dihydroxy siloxane; then cyanuric chloride, hydroxyl grafted phosphaphenanthrene and dihydroxyl siloxane react according to the molar ratio of 1: 1: (1.5-1.8), and the dihydroxyl-terminated silicon-containing flame retardant is obtained. The preparation method comprises the following steps: mixing a dihydroxyl-terminated silicon-containing flame retardant with polytetrahydrofuran ether glycol to serve as a soft segment, and reacting with isocyanate to obtain a hydrophobic flame-retardant polyurethane emulsion; mixing the hydrophobic flame-retardant polyurethane emulsion, an anti-aging agent, an ultraviolet light absorber, a defoaming agent, kaolin, nano silicon dioxide and talcum powder to obtain the hydrophobic flame-retardant polyurethane coating.

The invention belongs to the field of electrochemical energy, and relates to polyurethane with self-repairing capability, a solid electrolyte, a composite electrode and a preparation method, a soft segment part of the self-repairing polyurethane-based solid electrolyte has good segment motion capability, and compared with polyethylene glycol, the crystallinity is greatly reduced; and the ionic conductivity and the lithium ion transference number are greatly improved. The dynamic disulfide bond and the hydrogen bond of the hard segment part jointly form a dynamic reversible macromolecular network, so that the mechanical strength is considered, and the tensile property, the self-healing property and the repeatable processing property are good. The self-repairing polyurethane-based solid electrolyte has relatively high ionic conductivity and lithium ion transference number, and can be cured on an electrode in situ to eliminate the interface contact problem of the electrolyte and the electrode, and the positive electrode and the negative electrode of the battery are healed into a whole through the self-healing capability of polyurethane, so that the performance of the battery is greatly improved, and the service life of the battery is prolonged. And the material has a good application prospect in all-solid-state lithium batteries.

The invention relates to the technical field of inorganic non-metallic materials, in particular to a quaternized cholic acid polyurethane modified polyvinyl chloride material, a preparation method and application. The quaternized cholic acid polyurethane polymer is based on a polyurethane elastomer developed by using cholic acid molecules with a rigid skeleton as a hard segment unit and flexible oligomeric ethylene glycol as a soft segment unit, hydroxyl on cholic acid polyurethane is quaternized to prepare cation modified cholic acid polyurethane, and the cation modified cholic acid polyurethane simulates amphiphilic characteristics of natural peptides. The quaternized cholic acid polyurethane is introduced into a polyvinyl chloride (PVC) matrix as an antibacterial agent, so that the growth of microorganisms such as bacteria and molds can be effectively inhibited, the antibacterial property is achieved, bacteria breeding on the inner surface of a pipeline is avoided, and the composite material is endowed with better biocompatibility and antibacterial property; meanwhile, the quaternized cholic acid polyurethane can effectively improve the strength and toughness of the PVC material; wide application prospects are realized.

The invention discloses a self-repairing nylon elastomer material as well as a preparation method and application thereof. The preparation method comprises the following steps: S1, polymerizing a nylon monomer in the presence of an amine end-capping reagent to prepare a double-amino-terminated nylon hard segment; s2, adding the double-amino-terminated nylon hard segment, the double-carboxyl-terminated polyether and / or polyester soft segment and a disulfide bond-containing chain extender into a reactor, adjusting the proportion of the raw materials, and polymerizing under an optional auxiliary A to obtain a double-amino-terminated pre-polymerized nylon elastomer; and S3, adding the double-amino-terminated pre-polymerized nylon elastomer and a dialdehyde chain extender into the reactor, and carrying out a reaction in the presence of an optional auxiliary agent B to obtain the self-repairing nylon elastomer material. According to the self-repairing nylon elastomer material provided by the invention, the nylon elastomer can be self-repaired in various environments through the synergistic effect of various dynamic covalent bonds, and the polymerization efficiency is remarkably improved.

The invention discloses a vegetable oil-based room-temperature water-induced self-healing polyurethane elastomer and a preparation method thereof. The elastomer is prepared by taking polytetramethylene ether glycol and tung oil glycol as soft segments, isophorone diisocyanate as a hard segment, dimethylolpropionic acid as a hydrophilic chain extender and 3-aminophenylboronic acid as an end-capping reagent. Polytetramethylene ether glycol and tung oil glycol are used as soft segments, isophorone diisocyanate is used as a hard segment, dimethylolpropionic acid is used as a hydrophilic chain extender, 3-aminophenylboronic acid is used for blocking, then triethylamine is used for neutralization, and a waterborne polyurethane material with high-density crosslinking sites is synthesized. The material has good mechanical properties and fracture toughness, the tensile strength of the polyurethane film can reach 6.94 MPa, the elongation at break can reach 790.1%, and the film has good rebound resilience.

The invention discloses polytetrahydrofuran ether amine polyurea with high elongation at break as well as a preparation method and application thereof, and belongs to the technical field of macromolecules. The raw materials comprise a component (A) and a component (B), wherein the component (A) is diisocyanate with a symmetrical linear molecular structure; the component (B) is polytetrahydrofuran ether amine with a symmetrical linear structure, and the molar ratio of the NCO functional group of the diisocyanate to the NH2 functional group of the polytetrahydrofuran ether amine is 1.07-1.00; the molecular structure of the polytetrahydrofuran ether amine polyurea with high elongation at break is a microphase separation structure composed of a hard segment and a soft segment, and the weight percentage of the hard segment relative to the soft segment is greater than 20%. The elongation at break of the polytetrahydrofuran ether amine polyurea product with high elongation at break is 1500% or above, and the polytetrahydrofuran ether amine polyurea product can meet the requirements of expansion joints of ballastless tracks of high-speed railways, expansion joints of highways and airport runways, electronic element potting and the like on the elongation at break of high-elasticity materials.

The invention discloses a large-current-carrying-capacity flexible power cable, which belongs to the technical field of cable preparation, is used for solving the technical problem that the flame retardant property and the mechanical property of the power cable need to be further improved in the prior art, and specifically comprises a cable core, a wrapping layer, an insulating layer and a sheath layer which are sequentially arranged from inside to outside. The preparation method comprises the following steps: preparing alkoxy silane containing a benzocyclobutene group, preparing flame-retardant particles by using a sol-gel method, preparing modified polyurethane by using modified polysiloxane and 2, 5-furandimethanol as soft segments, naphthalene diisocyanate as a hard segment and trimethylolpropane as a chain extender, and preparing the flame-retardant flame-retardant polyurethane. The linear low-density polyethylene, the MAH-g-PE, the modified polyurethane, the flame-retardant particles and the auxiliary additive are melted and extruded outside the wire core to form the insulating layer, so that the power cable is obtained, the flame-retardant property of the power cable is effectively improved, and the mechanical property and the current-carrying stability of the power cable are also improved.

The invention belongs to the technical field of polyurethane materials, and particularly relates to high-strength polyurethane based on carbon dioxide polycondensation and a preparation method of the high-strength polyurethane. The high-strength polyurethane is prepared from the following raw materials in parts by mole: 100 parts of diisocyanate; 0.05 to 0.5 part of a catalyst; the sum of the parts of the polycarbonate diol and the chain extender is 100, and the part of the chain extender is 25-50. The polyurethane soft segment provided by the invention is directly polycondensed based on carbon dioxide instead of using a carbonic ester monomer, so that the utilization rate of carbon dioxide is greatly increased, and the sustainable development of the polyurethane material industry is facilitated. Meanwhile, a chain extender used in polyurethane contains adjustable high-density hydrogen bonds, so that the elastomer material has excellent mechanical properties, high strength and high toughness, and the tensile strength can reach 80 MPa or above; the chain extender is derived from sustainable resources, and the structure can be flexibly regulated and controlled. The polyurethane preparation method provided by the invention is simple to operate, is suitable for large-scale continuous line production, and has good implementation value and market prospect.

The invention discloses a solvent-free vanillin-hydroxyethyl acrylate double-system closed waterborne polyurethane emulsion adhesive as well as a preparation method and a use method thereof, and belongs to the field of waterborne polyurethane emulsion adhesives. The invention is mainly prepared from the following components in parts by weight: 40 to 50 parts of soft segment monomer, 50 to 60 parts of hard segment monomer, 20 to 40 parts of sealing agent, 0.02 to 0.15 part of catalyst, 0.4 to 0.6 part of emulsifier, 0.2 to 0.6 part of initiator, 4 to 12 parts of neutralizer, 5 to 15 parts of functional monomer and 340 to 360 parts of deionized water. According to the double-system closed waterborne polyurethane emulsion adhesive disclosed by the invention, rapid crosslinking curing of the adhesive can be realized through thermocuring, the highest hardness of an adhesive layer can reach about 26 MPa, the adhesive strength is high, and the mechanical property is relatively good.

The invention discloses a low-staining low-viscosity waterborne polyurethane macromolecular coloring agent and a preparation method of the low-staining low-viscosity waterborne polyurethane macromolecular coloring agent. Comprising the following components in parts by weight: 15 to 30 parts of aliphatic diisocyanate, 15 to 30 parts of micromolecular dye, 10 to 30 parts of polypropylene glycol and / or dihydroxy silicone oil, 25 to 50 parts of polyethylene glycol, 1 to 3 parts of micromolecular dihydroxy compound chain extender, 0.05 to 0.3 part of catalyst, 90 to 140 parts of acetone and 50 to 300 parts of water. By designing the hydrophilicity and proportion of the soft and hard segments of the polyurethane coloring agent, the waterborne polyurethane macromolecular coloring agent color paste which is low in staining, easy to clean, less than 1000mpas in product viscosity, more than 5% in color concentration and more than 5% in dye equivalent and good in compatibility is finally obtained, and the waterborne polyurethane macromolecular coloring agent color paste can meet the requirements of liquid product coloring agents such as clothing care and household cleaning agents. The cleaning agent can also be used for liquid cleaning agent products for body care and catering.

The invention provides modified liquid epoxy resin, a liquid molding compound and a preparation method and application thereof, the modified liquid epoxy resin has a hard segment-soft segment-hard segment structure, the hard segment is composed of liquid epoxy resin, and the soft segment is composed of a flexible chain segment organic matter with an active group at the tail end. The liquid molding compound comprises the following components in percentage by mass: (A) 10-20% of the modified liquid epoxy resin; (B) 5-15% of a curing agent; (C) 70-90% of a filler; and (D) 0.1 to 1.5 percent of curing accelerator. The modified liquid epoxy resin provided by the invention can effectively reduce the crosslinking density, is beneficial to molecular movement, finally achieves the effects of reducing stress and shrinkage characteristics, can improve the toughness of a liquid plastic package material when being applied to the liquid plastic package material, reduces the internal stress and thermal expansion coefficient of the epoxy plastic package material, and has more excellent processability and process reliability.

The invention discloses a pressure-resistant and anti-permeation deep sea intrinsic antifouling poly-fatty ammonia glycol as well as a preparation method and application of the pressure-resistant and anti-permeation deep sea intrinsic antifouling poly-fatty ammonia glycol. The deep-sea intrinsic antifouling poly-fatty amino vinegar comprises polymer soft segments, antibacterial hard segments and polyiso-oxoacid chain segments, wherein the polymer soft segments, the antibacterial hard segments and the polyiso-oxoacid chain segments are alternately distributed; wherein the antibacterial hard segment comprises a barking group two-fat unit. The antibacterial hard segment in the deep-sea intrinsic antifouling poly-fatty ammonia endows the poly-fatty ammonia glucoside with a fouling organism contact killing function, and the barking ring and the poly-fatty ammonia glucoside synergistically endow the deep-sea intrinsic antifouling poly-fatty ammonia glucoside with high pressure resistance and high permeability; meanwhile, the deep-sea intrinsic antifouling poly-fatty ammonia glucoside is suitable for surface antifouling of thousand-deep-sea environment equipment, can resist deep washing high pressure and seawater permeation, and can effectively prevent adhesion of deep washing bacteria and fouling organisms.

The invention provides unsaturated waterborne polyurethane, a polyurethane composite material as well as a preparation method and application of the unsaturated waterborne polyurethane and the polyurethane composite material. According to the preparation method, isocyanate is introduced into a soft segment through a block process, an unsaturated chain extender is added, unsaturated double bonds are introduced, and waterborne polyurethane with excellent performance is prepared. Meanwhile, cellulose nanofibers are added into the unsaturated waterborne polyurethane, so that the interfacial compatibility and mechanical properties of the unsaturated waterborne polyurethane are improved. The unsaturated waterborne polyurethane provided by the invention has excellent film-forming property, stability and mechanical property.

The invention belongs to the technical field of acrylic plates, and particularly relates to a continuous casting high-hardness acrylic plate and a preparation method thereof.The preparation method comprises the steps that siloxane modified methacrylic acid, methyl methacrylate and n-butyl methacrylate are mixed, an azo initiator is added into the mixture, and then stirring and mixing are conducted to obtain pre-polymerized slurry; the preparation method comprises the following steps: mixing hydroxyl-terminated ether polysiloxane, isophorone diisocyanate and a catalyst dibutyltin dilaurate, reacting to obtain a macromolecular prepolymer, and then adding an end-capping reagent and a photoinitiator into the macromolecular prepolymer to obtain coating slurry; and injecting the pre-polymerized slurry between two annular steel belts which operate synchronously, coating the two annular steel belts with the coating slurry, and carrying out ultraviolet curing to obtain the high-hardness acrylic plate. Through ultraviolet curing, a high-hardness layer is formed outside the acrylic plate, polyurethane is modified by hydroxyl-terminated ether polysiloxane, the rigidity of a soft chain segment is improved by a polysiloxane chain segment, and the hardness of polyurethane is improved.

The invention relates to the technical field of secondary batteries, and discloses a secondary battery, a negative active layer in a negative plate comprises a negative active material and a negative adhesive, the negative active material comprises a silicon-based material, the negative adhesive comprises a polymer, and the raw material of the polymer comprises a hard segment monomer and a soft segment monomer; the electrolyte comprises carbonic ester substances and lithium salt; on the basis of the total mass of the raw materials of the polymer, the mass content of the soft segment monomer is r%; on the basis of the total mass of the electrolyte, the mass content of the carbonic ester substance is t%; t / r is greater than or equal to 0.234 and less than or equal to 1.770. According to the secondary battery provided by the invention, the chemical structure of the adhesive is optimized and the composition of the electrolyte solution is adjusted, so that the excellent electrochemical performance of the battery is ensured, the swelling effect of the electrolyte on the adhesive is reduced, the cycle life of the battery is prolonged, and the safety of the battery is improved.

The invention discloses high-strength and high-toughness carbon dioxide-based biodegradable polyester-polycarbonate and a preparation method thereof. The carbon dioxide-based polyester-polycarbonate composite material is prepared from 90 to 98 percent of carbon dioxide-based polyester-polycarbonate and 2 to 10 percent of a carbon dioxide-based polycarbonate or polyester-polycarbonate hard-soft-hard triblock structure elastomer. The hard segments at the two ends of the elastomer are a polycarbonate chain segment and a polyester chain segment containing rigid groups respectively, so that the elastomer has high glass transition temperature and good compatibility, and the situation that the two phases are incompatible is avoided; soft segments in the two elastomers are polycarbonate chain segments containing long-chain branches, and the soft segments have very low glass transition temperature, so that the effects of buffering stress and toughening are achieved. The special hard-soft-hard three-block structure elastomer is used as a toughening modifier, high-strength and high-toughness carbon dioxide-based biodegradable polyester-polycarbonate can be prepared, and good tensile strength and light transmittance are still kept while the toughness and the processing performance of the material are effectively improved.

The invention belongs to the technical field of 3D printing photocuring, and particularly relates to photocuring organic silicon modified polyurethane acrylate resin as well as preparation and application thereof. According to the invention, isophorone diisocyanate is used as a hard segment, polypropylene glycol-1000, dimethylolpropionic acid and dihydroxy-terminated silicone oil are used as soft segments, and the light-cured organic silicon modified polyurethane acrylic resin is synthesized with pentaerythritol triacrylate. By controlling the hydroxyl content in the double-terminal hydroxyl silicone oil and the proportion of the double-terminal hydroxyl silicone oil in a soft segment, the prepared organic silicon modified polyurethane acrylic resin has better flowability and light transmittance and higher double bond content; the organic silicon modified polyurethane acrylic resin, the acryloyl morpholine and the photoinitiator are cured according to a specific proportion, and the obtained elastomer has good mechanical properties and thermal stability and has high printing precision. The synthesized organic silicon modified polyurethane acrylate resin has the potential of replacing a traditional polyurethane acrylate material.

The invention discloses a polyamide elastomer as well as a preparation method and application thereof, and belongs to the technical field of high polymer materials. By reasonably controlling the covalent connection rate of the soft and hard sections of the polyamide elastomer and the types of the soft sections and the hard sections of the polyamide elastomer, the obtained polyamide elastomer is high in relative viscosity and excellent in mechanical property, rebound resilience, fatigue resistance and the like, and is suitable for preparing sports equipment, hoses, medical instruments and sealing materials.

The invention provides an adhesive with high adhesion strength for a low-surface-energy material as well as a preparation method and application of the adhesive, and relates to the field of materials. The adhesive comprises a fluorinated hard segment and a long polymer chain soft segment with a plasticizing effect, the fluorinated hard segment monomer corresponding to the fluorinated hard segment comprises a fluorinated methacrylate monomer; the soft segment monomer corresponding to the long polymer chain soft segment with the plasticizing effect comprises a polyether methacrylate monomer. The preparation method of the adhesive comprises the following steps: mixing the fluorinated hard segment monomer, the soft segment monomer and an initiator to obtain a precursor liquid; and carrying out polymerization reaction on the degassed precursor liquid, and then carrying out vacuum drying to obtain the adhesive. The adhesive provided by the invention has excellent bonding strength, does not need to carry out surface pretreatment on materials, reduces the production cost, and provides a new idea for the development of bonding of low-surface-energy materials.

The invention discloses a silane functionalized graphene oxide / waterborne polyurethane hydrophobic coating and preparation, and belongs to the technical field of paints.The silane functionalized graphene oxide / waterborne polyurethane hydrophobic coating is prepared by the steps that natural graphite powder serves as a raw material, and graphene oxide is prepared through a Hummer method; n-(beta-aminoethyl)-gamma-aminopropyl trimethoxy silane is grafted to the surface of the graphene oxide through a chemical reduction method, and GO-AATS composite filler is obtained; then, castor oil is used as a soft segment, isophorone diisocyanate is used as a hard segment, and a series of GO-AATS-WPU emulsions are prepared. According to the silane functionalized graphene oxide / waterborne polyurethane hydrophobic coating and preparation, chemical bonds are formed between graphene oxide and waterborne polyurethane, and the interfacial compatibility of graphene oxide and waterborne polyurethane is improved, so that the mechanical property, water resistance, corrosion resistance and thermal stability of the waterborne polyurethane coating are improved.

The invention discloses a sulfonate grafted polyether-polyester-polyamide block copolymer and a synthesis method thereof, and belongs to the field of materials. The invention provides a block copolymer elastomer material taking polycaprolactam as a hard segment and polyether and polyester as soft segments, and specific sulfonic acid groups are introduced to meet specific applications. According to the invention, caprolactam, 6-aminocaproic acid, aliphatic dibasic acid, aliphatic diamine, polyether glycol, sulfonate grafted polyester polyol BY-3305 and the like are used as raw materials, and macromolecular sulfonate grafted polyester polyol BY-3305 is used as a sulfonate grafting agent, so that the reaction efficiency is higher than that of a small molecular monomer containing a sulfonic acid group, and fewer reaction byproducts are generated; the polymerization reaction can be smoothly carried out. The sulfonate grafted polyether-polyester-polyamide block copolymer elastomer is obtained through one-step melt polymerization, and has the advantages of being simple and convenient in synthesis method, low in production cost, high in strength, adjustable in performance and the like.

The invention provides a polyurethane urea elastomer, a preparation method and application thereof, and an ionic conductive elastomer, and belongs to the field of polymer materials. A soft-segment substance, isocyanate and a catalyst are subjected to a prepolymerization reaction to obtain a prepolymer, the prepolymer, a chain extender and an organic solvent are subjected to a chain extension reaction to obtain the PUU elastomer, the soft-segment substance contains hydroxyl, and the chain extender contains phenyl and a bishydrazide substituent. According to the invention, PUU is synthesized by a chain extender simultaneously containing phenyl and a bishydrazide substituent, the phenyl in the PUU can be assembled in situ based on pi-pi interaction to form an aggregate, and the aggregate and multiple hydrogen bonds between amido urea bonds on two sides of the aggregate jointly form a double-lock hard domain which has high binding energy and is cross-linked based on non-covalent interaction in the PUU. The unique structure of PUU improves the mechanical properties, including strength, elasticity and tear resistance, of the material on one hand, and endows the material with a function of repairing mechanical damage on the other hand.

The invention discloses a supramolecular polyurethane prepolymer, supramolecular polyurethane prepolymer ink, a supramolecular polyurethane elastomer as well as a preparation method and application of the supramolecular polyurethane prepolymer. The structural formula of the supramolecular polyurethane prepolymer is as follows: # imgabs0 #; wherein m is 5-35, n is 6-28, and R is 2-acetyl benzene, phenyl or biphenyl. The supramolecular polyurethane prepolymer has multiple strong hydrogen bonds formed by allophanate bonds and carbamate bonds, microphase separation of soft and hard segments of polyurethane is promoted, the tightness of chain segment spatial conformation is increased by utilizing a planar structure of boron atoms, hydrogen bonds between the carbamate bonds are enhanced, and the microphase separation of soft and hard segments of polyurethane is promoted. The tensile strength, the thermal stability and the toughness of a 3D printed product are improved by virtue of multi-reinforcement coupling due to the dynamic characteristics of the boric acid ester bond, and the 3D printed product has excellent bearing capacity.

The invention discloses an oxide-enhanced, high-strength and high-temperature-resistant diaphragm and a preparation method thereof, and belongs to the technical field of battery diaphragms. The diaphragm is of a three-layer co-extrusion structure, a surface layer is composed of a block olefin polymer and a styrene elastomer, the block olefin polymer comprises soft chain segment polyethylene and hard chain segment polyolefin containing rigid groups, the styrene elastomer is a block copolymer with an (S) m-(P / B) n-(S) m microphase separation structure, and the thickness of the styrene elastomer is 1-10 micrometers. And the middle layer consists of high-density polyethylene and hydrophobically modified oxide. The preparation method comprises the following steps: synthesis of the block olefin polymer, three-layer co-extrusion sheet casting, two-way stretching, extraction drying, secondary transverse stretching and heat setting. Through molecular structure design and multiphase compounding, the mechanical strength, the membrane rupture temperature and the thermal stability of the diaphragm are synergistically improved, meanwhile, good electrolyte wettability and processing consistency are kept, the problems that a traditional wet-process diaphragm is poor in temperature resistance and insufficient in strength are effectively solved, and the safety of a lithium battery is remarkably improved.

The invention discloses a preparation method of a long-acting antistatic polymer master batch for skin-core spinning polyester, and relates to the technical field of high polymer material preparation. The hard segment comprises the following components: 100 parts of aromatic polyester, the aromatic polyester is generated through a reaction of 100 parts of an aromatic monomer and 80-120 parts of aliphatic dihydric alcohol, the aromatic monomer is dimethyl terephthalate, and the aliphatic dihydric alcohol is 1, 4-butanediol. Through cooperation of the hard segment structure, the soft segment structure, the polyaniline, the protonic acid, the ionic liquid, the fluorine-containing polymer and the sulfonate, the problems that the antistatic performance of the polyester master batch depends on environment humidity, the subsequent process is easy to lose efficacy, and the compatibility with a polyester matrix is poor are solved; the master batch can maintain a stable antistatic effect in a low-temperature and low-humidity environment, the performance of the master batch is not attenuated after subsequent procedures such as elasticizing and printing and dyeing, meanwhile, short filaments and broken filaments are avoided in the spinning process, and the continuity of polyester fiber production and the quality of finished products are improved.

The invention provides a polyamide elastomer and a preparation method thereof. The method comprises the following steps: (1) under the action of a first catalyst, carrying out condensation polymerization on a poly-diol compound and a binary acid monomer in a solvent to obtain an end-capping reagent; (2) under the action of a second catalyst, an end-capping reagent and a comonomer are subjected to a contact reaction, and a polyamide block is obtained; and (3) in the presence of a stabilizer and under the action of a third catalyst, carrying out contact reaction on the soft segment and the polyamide block to obtain the polyamide elastomer, wherein the polydihydric alcohol compound is polyalkylene ether glycol with the number-average molecular weight of 150-2000, and the stoichiometric ratio of the polydihydric alcohol compound to the binary acid monomer is 1: (2.0-2.4); the comonomer is C4-C12 lactam and / or C4-C12 amino carboxylic acid; and the soft segment is a hydroxyl-terminated diol polymer. According to the invention, the performance loss of the hard-segment-dominated material is not caused on the basis of improving the soft-segment-dominated material mechanical property of the product, and the polyamide elastomer product with excellent comprehensive performance is obtained.

The invention discloses a low-temperature-resistant adhesive as well as a preparation method and application thereof. The low-temperature-resistant adhesive is prepared from the following components in parts by mass: 39 to 43 parts of cashew nut oil modified phenolic resin, 28 to 31 parts of epoxy resin CYD128, 27 to 29 parts of hydrogenated butadiene-acrylonitrile rubber, 0.2 to 0.4 part of metal organic salt accelerant and 1 to 2 parts of curing agent. The cashew nut oil modified phenolic resin is prepared from cashew nut oil, phenol, formaldehyde, sodium hydroxide and phosphoric acid. The cashew nut oil with flexible long chain segments is adopted to synthesize the modified phenolic resin, the proportion of the soft chain segments in the epoxy resin is remarkably increased, the brittleness of a cured product at low temperature is effectively improved, the hydrogenated butadiene-acrylonitrile rubber is introduced, good combination of strength and ductility is achieved, and the adhesive is not prone to degumming and failure at low temperature.

The invention provides a high-strength and high-thermal-plastic-temperature polysiloxane polyurea thermoplastic elastomer containing dynamic acetal amine bonds and a preparation method of the high-strength and high-thermal-plastic-temperature polysiloxane polyurea thermoplastic elastomer. According to the invention, the diisocyanate and macromolecular polydimethylsiloxane copolymer is used as a soft segment, the diisocyanate and 1, 3-bis (3-aminopropyl) tetramethyldisiloxane copolymer is used as a hard segment, and the polyhydroxy compound containing dynamic acetal amine bonds is used as a cross-linking agent, so that the prepared elastomer has good mechanical properties and high thermal plasticizing temperature, and can be used for preparing the polyurethane elastomer. Repeated processing can be realized; the preparation process is simple and feasible, and the product has stable performance and good reproducibility and is suitable for popularization and application.