704 results about "Soft segment" patented technology

The invention relates to the technical field of polyurethane production, in particular to a polyurethane super-hydrophobic foam composite material for packaging and a preparation method thereof. The polyurethane super-hydrophobic foam composite material for packaging is prepared by reacting a component A and a component B according to a mass ratio of 100: (31.7-46.5), wherein the component A comprises polyether polyol X with high molecular weight and high activity, polymer polyol, a chain extender, a cross-linking agent, an organic metal catalyst, a tertiary amine catalyst, a foam stabilizer, a foaming agent, a flame retardant, inorganic filler and the like, and the component B is isocyanate modified by polyether polyol Y with high functionality. An ester bond, a rigid benzene ring group and a Si-O-Si chain segment are introduced into a polyether polyol molecular chain segment to improve the internal soft segment structure and chemical crosslinking density of the polyurethane foam, and the prepared super-hydrophobic polyurethane foam not only has excellent hydrophobicity and high temperature resistance, but also is low in density and good in mechanical property.

The invention relates to the technical field of macromolecules, and discloses a preparation method of modified polyurethane toughened epoxy resin, which comprises the following steps: by taking 4-(Boc-amino) phenylboronic acid, diethanol amine, 1, 3-bis (3-glycidyl ether oxypropyl) tetramethyldisiloxane and the like as raw materials, carrying out a series of chemical reactions to obtain a borate siloxane chain extender; the method comprises the following steps: adding a polyurethane prepolymer into the epoxy resin, participating in chain extension of polyurethane, and modifying the epoxy resin by using the polyurethane prepolymer to obtain the modified polyurethane toughened epoxy resin. A'soft segment 'and an Si-O structure in the modified polyurethane can also improve the flexibility of a curing network, effectively change the fracture mechanism of the resin, absorb a large amount of energy when the resin is fractured, and contribute to improving the toughness of the epoxy resin; on the basis of ensuring the strength of the epoxy resin, the toughness and flame retardant property of the epoxy resin are improved, and the epoxy resin can be applied to the fields of composite materials, coatings, adhesives and the like with higher toughness and flame retardant requirements, and has wide applicability.

The invention relates to a thermoplastic polyimide resin with a block structure and a preparation method thereof, and a polyimide adhesive film and polyimide composite copper foil composed of the thermoplastic polyimide resin with the block structure. The polyimide adhesive film is formed by coating thermoplastic polyimide resin and thermosetting polyimide resin on a polyimide base film and mixing the thermoplastic polyimide resin and the thermosetting polyimide resin. Wherein the thermoplastic resin is composed of a hard segment containing a benzimidazole or amide unit and a soft segment containing a flexible ether bond. The polyimide adhesive film composite copper foil is prepared through rolling, mold pressing and other processing modes. The thermoplastic polyimide resin is of a soluble structure and does not need precursor processing, so that the formation of bubbles is effectively inhibited, and an IPN interpenetrating network structure is formed between the cured thermoplastic resin and thermosetting resin, so that the copper foil has excellent mechanical property, adhesive property and dimensional stability after being compounded; therefore, the method can be applied to the fields of semiconductor packaging, flexible copper-clad plates and the like.

The invention discloses a preparation method of a non-additive nitrogen-phosphorus-cerium synergistic flame-retardant polyurethane elastomer, and the polyurethane elastomer is prepared by taking isocyanate as a hard segment and poly (1, 4-butanediol adipate) as a soft segment, and compounding the hard segment and the soft segment with 2-amino-4-hydroxy-6-methylpyrimidine, a phosphorus reactive flame retardant and cerium oxide. The preparation method is simple, the process is easy to control, and the prepared polyurethane elastomer has good tensile strength; besides, the limit oxygen index of the polyurethane elastomer reaches 27.4, the polyurethane elastomer meets commercial standards of flame-retardant materials and UL-94 V-0 flame-retardant grade requirements, the ultraviolet band light transmittance is 0%, ultraviolet rays can be completely isolated, and the polyurethane elastomer has a good anti-oxidation function and can be applied to the industries of wires, cables, pipe profiles, films, general molding and the like.

The invention relates to the field of matt films, in particular to a scratch-resistant BOPP (biaxially-oriented polypropylene) matt film and a preparation method thereof. The scratch-resistant BOPP matt film comprises an upper surface matt layer, a middle core layer and a lower surface layer which are sequentially arranged, the upper surface matting layer comprises a matting master batch; the matting master batch comprises 28 to 50 weight percent of co-polypropylene, 8 to 14 weight percent of ethylene-octylene block copolymer, 6 to 10 weight percent of micro-crosslinked polypropylene and 30 to 50 weight percent of high-density polyethylene; the ethylene-octylene segmented copolymer comprises a hard segment with low octylene content and high crystallinity, and an amorphous soft segment with high octylene content; the middle core layer comprises homo-polypropylene; the lower surface layer comprises a smooth surface layer or an extinction layer. By utilizing the synergistic effect of the ethylene-octylene block copolymer and the micro-crosslinked polypropylene, the compressive deformation performance, the impact strength, the tensile strength and the yield strength of the co-polypropylene are improved, the indentation of a film surface in a scraping pressure applying stage and the scratches and damages generated in a sliding stage are reduced, the scratch resistance of the upper surface matting layer is improved, and the matting effect is ensured.

The invention relates to a biodegradable high-strength medical soft tissue adhesive as well as a preparation method and application thereof. The medical soft tissue adhesive comprises a soft segment, a hard segment and a hard segment chain extender, the soft segment is a polyethylene glycol polymer; the hard segment is isocyanate; the hard segment chain extender comprises a hard segment electrically neutral chain extender and a hard segment ionized chain extender; the molar ratio of the polyethylene glycol polymer to the isocyanate to the hard segment electrically neutral chain extender to the hard segment ionized chain extender is (1-7): (50-95): (14-20): (2-6). The preparation method comprises the following steps: mixing the polyethylene glycol polymer, the hard segment chain extender and the isocyanate, heating and reacting to obtain a mixed reaction system; cooling after the reaction is completed, adding a rheology modifier, a foaming catalyst and a stabilizer into the mixed reaction system, and uniformly mixing to obtain the biodegradable high-strength medical soft tissue adhesive which is suitable for functional composite materials.

The invention provides a comb-shaped polymer binder, a pole piece and a battery, the comb-shaped polymer binder comprises an acrylate main chain, a flexible soft segment, a polar hard segment and a functional chain segment, the flexible soft segment, the polar hard segment and the functional chain segment are respectively grafted on the acrylate main chain, the flexible soft segment comprises an ether chain segment and / or an ester chain segment, the polar hard segment comprises a polar group and / or a first heteroaromatic ring group, and the functional chain segment comprises a functional group and a second heteroaromatic ring group. The functional chain segment comprises an aromatic ring group containing a pi-conjugated structure and / or a second heteroaromatic ring group containing a pi-conjugated structure. The comb-shaped binder adopts a structural design of'hard section anchoring + soft section buffering + functional side chain ', is helpful for enabling the binder to have high peel strength, stress buffering and electron conduction capabilities at the same time, is compatible with an existing wet coating-rolling process, is helpful for improving the peel strength and prolonging the cycle life of an electrode plate when being used for preparing the electrode plate, and is beneficial for improving the service life of the electrode plate. And the rate capability of the battery is improved.

The invention relates to the technical field of polyurethane coatings, in particular to a hydrophobic flame-retardant polyurethane coating and a preparation method thereof. The preparation method comprises the following steps: firstly, taking 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and methallyl alcohol as raw materials, and reacting to obtain hydroxyl grafted phosphaphenanthrene; taking 1, 1, 3, 3-tetramethyldisiloxane and methallyl alcohol as raw materials, and reacting according to a molar ratio of 1: 2 to obtain dihydroxy siloxane; then cyanuric chloride, hydroxyl grafted phosphaphenanthrene and dihydroxyl siloxane react according to the molar ratio of 1: 1: (1.5-1.8), and the dihydroxyl-terminated silicon-containing flame retardant is obtained. The preparation method comprises the following steps: mixing a dihydroxyl-terminated silicon-containing flame retardant with polytetrahydrofuran ether glycol to serve as a soft segment, and reacting with isocyanate to obtain a hydrophobic flame-retardant polyurethane emulsion; mixing the hydrophobic flame-retardant polyurethane emulsion, an anti-aging agent, an ultraviolet light absorber, a defoaming agent, kaolin, nano silicon dioxide and talcum powder to obtain the hydrophobic flame-retardant polyurethane coating.

The invention belongs to the field of electrochemical energy, and relates to polyurethane with self-repairing capability, a solid electrolyte, a composite electrode and a preparation method, a soft segment part of the self-repairing polyurethane-based solid electrolyte has good segment motion capability, and compared with polyethylene glycol, the crystallinity is greatly reduced; and the ionic conductivity and the lithium ion transference number are greatly improved. The dynamic disulfide bond and the hydrogen bond of the hard segment part jointly form a dynamic reversible macromolecular network, so that the mechanical strength is considered, and the tensile property, the self-healing property and the repeatable processing property are good. The self-repairing polyurethane-based solid electrolyte has relatively high ionic conductivity and lithium ion transference number, and can be cured on an electrode in situ to eliminate the interface contact problem of the electrolyte and the electrode, and the positive electrode and the negative electrode of the battery are healed into a whole through the self-healing capability of polyurethane, so that the performance of the battery is greatly improved, and the service life of the battery is prolonged. And the material has a good application prospect in all-solid-state lithium batteries.

The invention relates to the technical field of inorganic non-metallic materials, in particular to a quaternized cholic acid polyurethane modified polyvinyl chloride material, a preparation method and application. The quaternized cholic acid polyurethane polymer is based on a polyurethane elastomer developed by using cholic acid molecules with a rigid skeleton as a hard segment unit and flexible oligomeric ethylene glycol as a soft segment unit, hydroxyl on cholic acid polyurethane is quaternized to prepare cation modified cholic acid polyurethane, and the cation modified cholic acid polyurethane simulates amphiphilic characteristics of natural peptides. The quaternized cholic acid polyurethane is introduced into a polyvinyl chloride (PVC) matrix as an antibacterial agent, so that the growth of microorganisms such as bacteria and molds can be effectively inhibited, the antibacterial property is achieved, bacteria breeding on the inner surface of a pipeline is avoided, and the composite material is endowed with better biocompatibility and antibacterial property; meanwhile, the quaternized cholic acid polyurethane can effectively improve the strength and toughness of the PVC material; wide application prospects are realized.

The invention relates to a polyamide elastomer and a foam material thereof, the polyamide elastomer comprises a hard segment and a soft segment, the hard segment comprises a polyamide block, and the soft segment comprises a polyether block and / or a polyester block; wherein the molar ratio of the hard segment to the soft segment is (2-3): (2-3); the number-average molecular weight of the hard segment is 1000-3000, and the mass ratio of the hard segment to the soft segment is (1-3): 1; the polyamide elastomer is prepared by reacting a hard-segment raw material with a soft-segment raw material, and the hydroxyl value of the soft-segment raw material is 30-600mgKOH / g. The polyamide elastomer disclosed by the embodiment of the invention has the characteristics of narrow molecular weight distribution, high melt mass flow rate and excellent mechanical property and wear resistance; and when being used for preparing a foaming material, the composite material can improve the stability in the foaming processing process and the performance of the foaming material, such as the closed-cell rate.

The invention discloses a self-repairing nylon elastomer material as well as a preparation method and application thereof. The preparation method comprises the following steps: S1, polymerizing a nylon monomer in the presence of an amine end-capping reagent to prepare a double-amino-terminated nylon hard segment; s2, adding the double-amino-terminated nylon hard segment, the double-carboxyl-terminated polyether and / or polyester soft segment and a disulfide bond-containing chain extender into a reactor, adjusting the proportion of the raw materials, and polymerizing under an optional auxiliary A to obtain a double-amino-terminated pre-polymerized nylon elastomer; and S3, adding the double-amino-terminated pre-polymerized nylon elastomer and a dialdehyde chain extender into the reactor, and carrying out a reaction in the presence of an optional auxiliary agent B to obtain the self-repairing nylon elastomer material. According to the self-repairing nylon elastomer material provided by the invention, the nylon elastomer can be self-repaired in various environments through the synergistic effect of various dynamic covalent bonds, and the polymerization efficiency is remarkably improved.

The invention discloses a vegetable oil-based room-temperature water-induced self-healing polyurethane elastomer and a preparation method thereof. The elastomer is prepared by taking polytetramethylene ether glycol and tung oil glycol as soft segments, isophorone diisocyanate as a hard segment, dimethylolpropionic acid as a hydrophilic chain extender and 3-aminophenylboronic acid as an end-capping reagent. Polytetramethylene ether glycol and tung oil glycol are used as soft segments, isophorone diisocyanate is used as a hard segment, dimethylolpropionic acid is used as a hydrophilic chain extender, 3-aminophenylboronic acid is used for blocking, then triethylamine is used for neutralization, and a waterborne polyurethane material with high-density crosslinking sites is synthesized. The material has good mechanical properties and fracture toughness, the tensile strength of the polyurethane film can reach 6.94 MPa, the elongation at break can reach 790.1%, and the film has good rebound resilience.

The invention discloses polytetrahydrofuran ether amine polyurea with high elongation at break as well as a preparation method and application thereof, and belongs to the technical field of macromolecules. The raw materials comprise a component (A) and a component (B), wherein the component (A) is diisocyanate with a symmetrical linear molecular structure; the component (B) is polytetrahydrofuran ether amine with a symmetrical linear structure, and the molar ratio of the NCO functional group of the diisocyanate to the NH2 functional group of the polytetrahydrofuran ether amine is 1.07-1.00; the molecular structure of the polytetrahydrofuran ether amine polyurea with high elongation at break is a microphase separation structure composed of a hard segment and a soft segment, and the weight percentage of the hard segment relative to the soft segment is greater than 20%. The elongation at break of the polytetrahydrofuran ether amine polyurea product with high elongation at break is 1500% or above, and the polytetrahydrofuran ether amine polyurea product can meet the requirements of expansion joints of ballastless tracks of high-speed railways, expansion joints of highways and airport runways, electronic element potting and the like on the elongation at break of high-elasticity materials.

The invention discloses a large-current-carrying-capacity flexible power cable, which belongs to the technical field of cable preparation, is used for solving the technical problem that the flame retardant property and the mechanical property of the power cable need to be further improved in the prior art, and specifically comprises a cable core, a wrapping layer, an insulating layer and a sheath layer which are sequentially arranged from inside to outside. The preparation method comprises the following steps: preparing alkoxy silane containing a benzocyclobutene group, preparing flame-retardant particles by using a sol-gel method, preparing modified polyurethane by using modified polysiloxane and 2, 5-furandimethanol as soft segments, naphthalene diisocyanate as a hard segment and trimethylolpropane as a chain extender, and preparing the flame-retardant flame-retardant polyurethane. The linear low-density polyethylene, the MAH-g-PE, the modified polyurethane, the flame-retardant particles and the auxiliary additive are melted and extruded outside the wire core to form the insulating layer, so that the power cable is obtained, the flame-retardant property of the power cable is effectively improved, and the mechanical property and the current-carrying stability of the power cable are also improved.

The invention belongs to the technical field of polymer materials, and provides a waterborne polyurethane dispersoid as well as a preparation method and application thereof, the waterborne polyurethane dispersoid is prepared from the following raw materials: polyisocyanate, polybutadiene polyol, a hydrophilic chain extender, an optional micromolecule chain extender and a neutralizer; polybutadiene polyol with a specific structure and molecular weight is adopted as a soft segment, and through component design and mutual compounding, the waterborne polyurethane dispersion has lower polarity and surface energy, has good adaptability with a low-surface-energy substance / low-surface-energy filler, can form excellent dispersion and coating effects on the low-surface-energy substance, and can be used for preparing the waterborne polyurethane dispersion. The slurry performance is improved; meanwhile, the waterborne polyurethane dispersion has excellent solvent resistance, low temperature resistance, hydrolysis resistance and mechanical properties, and has wide application prospects in the fields of battery slurry dispersants, photovoltaic backboard adhesives, conformal coating and the like.

The invention belongs to the technical field of polyurethane materials, and particularly relates to high-strength polyurethane based on carbon dioxide polycondensation and a preparation method of the high-strength polyurethane. The high-strength polyurethane is prepared from the following raw materials in parts by mole: 100 parts of diisocyanate; 0.05 to 0.5 part of a catalyst; the sum of the parts of the polycarbonate diol and the chain extender is 100, and the part of the chain extender is 25-50. The polyurethane soft segment provided by the invention is directly polycondensed based on carbon dioxide instead of using a carbonic ester monomer, so that the utilization rate of carbon dioxide is greatly increased, and the sustainable development of the polyurethane material industry is facilitated. Meanwhile, a chain extender used in polyurethane contains adjustable high-density hydrogen bonds, so that the elastomer material has excellent mechanical properties, high strength and high toughness, and the tensile strength can reach 80 MPa or above; the chain extender is derived from sustainable resources, and the structure can be flexibly regulated and controlled. The polyurethane preparation method provided by the invention is simple to operate, is suitable for large-scale continuous line production, and has good implementation value and market prospect.

The invention belongs to the technical field of sponge products, and particularly relates to polyurethane sponge with a composite structure and a preparation method of the polyurethane sponge. Polyethylene glycol is used as a soft segment, isophorone diisocyanate is used as a hard segment, chitosan is added to serve as a raw material, polymerization and foaming are conducted, polyurethane foam is obtained, and in order to improve the antibacterial activity of the polyurethane foam, glycidyl trimethyl ammonium chloride is used for conducting quaternization modification on the chitosan, so that the antibacterial activity of the polyurethane foam is improved. Quaternary ammonium ions exist and can be adsorbed to the surfaces of thalli, the permeability of cell membranes is changed, the cell structure is destroyed, and therefore the antibacterial activity of the material is effectively improved, meanwhile, pearl powder is further added in the preparation process, the pearl powder is modified through citric acid and trisodium citrate, and the antibacterial activity of the material is improved. The problem of non-uniform dispersion caused by direct addition of the pearl powder is effectively solved.

The invention discloses a solvent-free vanillin-hydroxyethyl acrylate double-system closed waterborne polyurethane emulsion adhesive as well as a preparation method and a use method thereof, and belongs to the field of waterborne polyurethane emulsion adhesives. The invention is mainly prepared from the following components in parts by weight: 40 to 50 parts of soft segment monomer, 50 to 60 parts of hard segment monomer, 20 to 40 parts of sealing agent, 0.02 to 0.15 part of catalyst, 0.4 to 0.6 part of emulsifier, 0.2 to 0.6 part of initiator, 4 to 12 parts of neutralizer, 5 to 15 parts of functional monomer and 340 to 360 parts of deionized water. According to the double-system closed waterborne polyurethane emulsion adhesive disclosed by the invention, rapid crosslinking curing of the adhesive can be realized through thermocuring, the highest hardness of an adhesive layer can reach about 26 MPa, the adhesive strength is high, and the mechanical property is relatively good.

The invention discloses a low-staining low-viscosity waterborne polyurethane macromolecular coloring agent and a preparation method of the low-staining low-viscosity waterborne polyurethane macromolecular coloring agent. Comprising the following components in parts by weight: 15 to 30 parts of aliphatic diisocyanate, 15 to 30 parts of micromolecular dye, 10 to 30 parts of polypropylene glycol and / or dihydroxy silicone oil, 25 to 50 parts of polyethylene glycol, 1 to 3 parts of micromolecular dihydroxy compound chain extender, 0.05 to 0.3 part of catalyst, 90 to 140 parts of acetone and 50 to 300 parts of water. By designing the hydrophilicity and proportion of the soft and hard segments of the polyurethane coloring agent, the waterborne polyurethane macromolecular coloring agent color paste which is low in staining, easy to clean, less than 1000mpas in product viscosity, more than 5% in color concentration and more than 5% in dye equivalent and good in compatibility is finally obtained, and the waterborne polyurethane macromolecular coloring agent color paste can meet the requirements of liquid product coloring agents such as clothing care and household cleaning agents. The cleaning agent can also be used for liquid cleaning agent products for body care and catering.

The invention relates to the technical field of rubber, and discloses low-temperature-resistant rare earth butadiene rubber and a preparation method thereof. Phosphorus-containing quaternary ammonium salt modified polyurethane, polyethoxylene ether modified phenolic resin, rare earth butadiene rubber and sulfur are added into an internal mixer to be mixed and then vulcanized, and the low-temperature-resistant rare earth butadiene rubber is obtained. In the phosphorus-containing quaternary ammonium salt modified polyurethane, silicon-oxygen bonds enable the rubber to maintain stability at low temperature, so that the low-temperature-resistant effect of the rubber is improved; polyurethane and a rubber molecular chain form an interpenetrating polymer network, so that the mechanical property of the rubber is improved; due to the soft segment chain of polyurethane, the rubber has better toughness at low temperature, and the low temperature resistance of the rubber is improved; an ether bond in polyoxyethylene ether has flexibility and stability, so that the rubber is not easy to crystallize or cure at low temperature; phosphorus, silicon and sulfur elements are used together to generate a synergistic flame-retardant effect, so that the flame retardance of the rubber is improved; the phenolic resin plays a reinforcing role in the rubber, so that the mechanical property of the rubber is improved.

The invention provides modified liquid epoxy resin, a liquid molding compound and a preparation method and application thereof, the modified liquid epoxy resin has a hard segment-soft segment-hard segment structure, the hard segment is composed of liquid epoxy resin, and the soft segment is composed of a flexible chain segment organic matter with an active group at the tail end. The liquid molding compound comprises the following components in percentage by mass: (A) 10-20% of the modified liquid epoxy resin; (B) 5-15% of a curing agent; (C) 70-90% of a filler; and (D) 0.1 to 1.5 percent of curing accelerator. The modified liquid epoxy resin provided by the invention can effectively reduce the crosslinking density, is beneficial to molecular movement, finally achieves the effects of reducing stress and shrinkage characteristics, can improve the toughness of a liquid plastic package material when being applied to the liquid plastic package material, reduces the internal stress and thermal expansion coefficient of the epoxy plastic package material, and has more excellent processability and process reliability.

The invention discloses a pressure-resistant and anti-permeation deep sea intrinsic antifouling poly-fatty ammonia glycol as well as a preparation method and application of the pressure-resistant and anti-permeation deep sea intrinsic antifouling poly-fatty ammonia glycol. The deep-sea intrinsic antifouling poly-fatty amino vinegar comprises polymer soft segments, antibacterial hard segments and polyiso-oxoacid chain segments, wherein the polymer soft segments, the antibacterial hard segments and the polyiso-oxoacid chain segments are alternately distributed; wherein the antibacterial hard segment comprises a barking group two-fat unit. The antibacterial hard segment in the deep-sea intrinsic antifouling poly-fatty ammonia endows the poly-fatty ammonia glucoside with a fouling organism contact killing function, and the barking ring and the poly-fatty ammonia glucoside synergistically endow the deep-sea intrinsic antifouling poly-fatty ammonia glucoside with high pressure resistance and high permeability; meanwhile, the deep-sea intrinsic antifouling poly-fatty ammonia glucoside is suitable for surface antifouling of thousand-deep-sea environment equipment, can resist deep washing high pressure and seawater permeation, and can effectively prevent adhesion of deep washing bacteria and fouling organisms.

The invention provides unsaturated waterborne polyurethane, a polyurethane composite material as well as a preparation method and application of the unsaturated waterborne polyurethane and the polyurethane composite material. According to the preparation method, isocyanate is introduced into a soft segment through a block process, an unsaturated chain extender is added, unsaturated double bonds are introduced, and waterborne polyurethane with excellent performance is prepared. Meanwhile, cellulose nanofibers are added into the unsaturated waterborne polyurethane, so that the interfacial compatibility and mechanical properties of the unsaturated waterborne polyurethane are improved. The unsaturated waterborne polyurethane provided by the invention has excellent film-forming property, stability and mechanical property.

The invention belongs to the technical field of acrylic plates, and particularly relates to a continuous casting high-hardness acrylic plate and a preparation method thereof.The preparation method comprises the steps that siloxane modified methacrylic acid, methyl methacrylate and n-butyl methacrylate are mixed, an azo initiator is added into the mixture, and then stirring and mixing are conducted to obtain pre-polymerized slurry; the preparation method comprises the following steps: mixing hydroxyl-terminated ether polysiloxane, isophorone diisocyanate and a catalyst dibutyltin dilaurate, reacting to obtain a macromolecular prepolymer, and then adding an end-capping reagent and a photoinitiator into the macromolecular prepolymer to obtain coating slurry; and injecting the pre-polymerized slurry between two annular steel belts which operate synchronously, coating the two annular steel belts with the coating slurry, and carrying out ultraviolet curing to obtain the high-hardness acrylic plate. Through ultraviolet curing, a high-hardness layer is formed outside the acrylic plate, polyurethane is modified by hydroxyl-terminated ether polysiloxane, the rigidity of a soft chain segment is improved by a polysiloxane chain segment, and the hardness of polyurethane is improved.

The invention relates to the technical field of secondary batteries, and discloses a secondary battery, a negative active layer in a negative plate comprises a negative active material and a negative adhesive, the negative active material comprises a silicon-based material, the negative adhesive comprises a polymer, and the raw material of the polymer comprises a hard segment monomer and a soft segment monomer; the electrolyte comprises carbonic ester substances and lithium salt; on the basis of the total mass of the raw materials of the polymer, the mass content of the soft segment monomer is r%; on the basis of the total mass of the electrolyte, the mass content of the carbonic ester substance is t%; t / r is greater than or equal to 0.234 and less than or equal to 1.770. According to the secondary battery provided by the invention, the chemical structure of the adhesive is optimized and the composition of the electrolyte solution is adjusted, so that the excellent electrochemical performance of the battery is ensured, the swelling effect of the electrolyte on the adhesive is reduced, the cycle life of the battery is prolonged, and the safety of the battery is improved.

The invention discloses high-strength and high-toughness carbon dioxide-based biodegradable polyester-polycarbonate and a preparation method thereof. The carbon dioxide-based polyester-polycarbonate composite material is prepared from 90 to 98 percent of carbon dioxide-based polyester-polycarbonate and 2 to 10 percent of a carbon dioxide-based polycarbonate or polyester-polycarbonate hard-soft-hard triblock structure elastomer. The hard segments at the two ends of the elastomer are a polycarbonate chain segment and a polyester chain segment containing rigid groups respectively, so that the elastomer has high glass transition temperature and good compatibility, and the situation that the two phases are incompatible is avoided; soft segments in the two elastomers are polycarbonate chain segments containing long-chain branches, and the soft segments have very low glass transition temperature, so that the effects of buffering stress and toughening are achieved. The special hard-soft-hard three-block structure elastomer is used as a toughening modifier, high-strength and high-toughness carbon dioxide-based biodegradable polyester-polycarbonate can be prepared, and good tensile strength and light transmittance are still kept while the toughness and the processing performance of the material are effectively improved.

The invention belongs to the field of food packaging, and particularly relates to an efficient long-carbon-chain polyamide elastomer modified atmosphere preservative film as well as a preparation method and application thereof. The high-efficiency long-carbon-chain polyamide elastomer modified atmosphere preservative film is prepared from a raw material comprising a long-carbon-chain polyamide elastomer material, and the long-carbon-chain polyamide elastomer material is a segmented copolymer formed by alternately using long-carbon-chain polyamide as a hard segment and polyether as a soft segment. The preparation method of the long-carbon-chain polyamide elastomer modified atmosphere preservative film can adopt one of extrusion blow molding or two-way stretching. The film preparation method provided by the invention does not need a solvent, and the preparation process is simple and environment-friendly. The modified atmosphere preservative film disclosed by the invention has good modified atmosphere performance, controllable and adjustable CO2 permeability, CO2 / O2 separability and water vapor permeability, also has an ethylene gas removal function and good mechanical properties and thermal stability, and can meet the fresh-keeping requirements of fruits and vegetables with different respiratory action intensities.

The invention belongs to the technical field of 3D printing photocuring, and particularly relates to photocuring organic silicon modified polyurethane acrylate resin as well as preparation and application thereof. According to the invention, isophorone diisocyanate is used as a hard segment, polypropylene glycol-1000, dimethylolpropionic acid and dihydroxy-terminated silicone oil are used as soft segments, and the light-cured organic silicon modified polyurethane acrylic resin is synthesized with pentaerythritol triacrylate. By controlling the hydroxyl content in the double-terminal hydroxyl silicone oil and the proportion of the double-terminal hydroxyl silicone oil in a soft segment, the prepared organic silicon modified polyurethane acrylic resin has better flowability and light transmittance and higher double bond content; the organic silicon modified polyurethane acrylic resin, the acryloyl morpholine and the photoinitiator are cured according to a specific proportion, and the obtained elastomer has good mechanical properties and thermal stability and has high printing precision. The synthesized organic silicon modified polyurethane acrylate resin has the potential of replacing a traditional polyurethane acrylate material.

The invention relates to the field of high polymer materials, and discloses a visible light repairing type waterborne polyurethane emulsion and a preparation method thereof.The preparation method comprises the following steps that polytetrahydrofuran, isophorone diisocyanate, 2, 2-dimethylolpropionic acid and butyltin dilaurate are taken and placed in a reactor, pre-polymerization chain extension is conducted at the temperature of 60-90 DEG C, and a polyurethane prepolymer is obtained; the preparation method comprises the following steps: firstly, adding ASB-PEG2000-ASB, carrying out chain extension at 40-60 DEG C, then adding butanediol and carbohydrazide, continuously carrying out chain extension, then adding glucose, carrying out crosslinking at 40-60 DEG C, finally cooling to 25-50 DEG C, adding triethylamine, carrying out stirring to form a salt, adding deionized water, carrying out stirring dispersion, and carrying out emulsification so as to prepare the visible light repairing type waterborne polyurethane emulsion. The water-based polyurethane emulsion has the advantages that the water-based polyurethane emulsion has wide absorption in the visible light wave band, the self-repairing efficiency is high, the water-based polyurethane emulsion and polytetrahydrofuran are simultaneously used as soft segments to be introduced into water-based polyurethane, and the prepared water-based polyurethane emulsion has high mechanical performance and a visible light induced self-repairing function.