909 results about "Caprolactone" patented technology

The invention provides a high-temperature-resistant and high-salt-resistant nano imbibition agent as well as a preparation method and application thereof. The high-temperature-resistant and high-salt-resistant nano imbibition agent is prepared from amination modified mesoporous silica nanoparticles, nano cellulose, rhamnolipid, an anionic surfactant, citrate modified sodium zirconium phosphate, polyethylene glycol-b-polycaprolactone and a sulfydryl-carboxyl imidazoline derivative, therefore, the composite carrier formed by the aminated mesoporous silica nanoparticles and the nanocellulose has high mechanical strength and uniform dispersity, the oil-water interfacial tension is reduced through the synergistic effect of the rhamnolipid and the anionic surfactant, and the crude oil stripping efficiency is remarkably improved; the citrate modified sodium zirconium phosphate enables the salt resistance of the system to be greatly improved, and in a high-temperature and high-salt oil reservoir environment, the nano imbibition agent can remarkably improve the crude oil recovery rate and reduce the injection pressure and dosage; meanwhile, good adsorption resistance is achieved, and reservoir blockage is prevented; in addition, low-toxicity corrosion inhibition components protect equipment, and the service life of an oil well is prolonged.

The invention discloses an absorbable suture line for surgical suture and a preparation method thereof, and relates to the technical field of medical materials. The absorbable suture line for surgical suture is prepared from the following raw materials in parts by weight: 50 to 65 parts of polylactic acid, 15 to 20 parts of polyglycolic acid, 3 to 5 parts of sodium carboxymethyl cellulose, 3 to 8 parts of a toughening agent, 3 to 6 parts of an antibacterial agent, 0.3 to 0.8 part of a lubricating agent, 1 to 2 parts of sodium hyaluronate and 5 to 10 parts of polyvinyl alcohol. The toughening agent is obtained by reacting hydroxyethyl acrylate with ethylenediamine to generate a four-arm compound and then reacting with 6-caprolactone and DL-lactide. The absorbable suture line for surgical suture prepared by the invention has excellent tensile property and antibacterial property, and can meet the application requirements of clinical medical treatment.

The invention discloses a Janus wound dressing with antibacterial and tissue repair promoting functions and a preparation method of the Janus wound dressing, belongs to the technical field of wound dressings, and aims to realize antibacterial, tissue repair promoting and moist wound healing microenvironment through freeze drying and electrostatic spinning technologies. Polycaprolactone (PCL), bioactive glass (BG) and curcumin Cur are used for preparing a hydrophobic inner layer capable of promoting tissue repair, methacrylated gelatin GelMA is used for preparing a hydrophilic outer layer with moisturizing performance, and the PCL-BG-Cur / GelMA composite wound dressing with antibacterial, moisturizing and repair promoting functions is constructed. Animal experiment results show that the dressing loaded with curcumin Cur and bioactive glass BG has multiple functions of synergistic antibiosis, moisturizing and the like, the result shows that the prepared dressing has the performance of promoting epithelization, collagen deposition, new hair follicle formation and the like, and the dressing has a considerable application prospect in the aspect of rapid wound repair.

The invention relates to the technical field of dental restoration materials, in particular to a bacteriostatic dental restoration composite film and a preparation method thereof. The oral cavity restoration composite film is composed of an upper-layer antibacterial film, a middle-layer polycaprolactone fiber film and a lower-layer bone restoration film. The upper-layer antibacterial film is prepared from the following components in parts by weight: 3 to 4 parts of cinnamon essential oil, 0.5 to 1 part of xanthan gum, 0.5 to 1 part of seed meal protein, 0.1 to 0.15 part of tannic acid, 5 to 7 parts of silk fibroin, 1 to 1.5 parts of polylactic acid, 0.6 to 1 part of chitosan, 1 to 1.5 parts of polyvinyl alcohol and 1.5 to 2.5 parts of glycerol; the lower-layer bone repair membrane is prepared from the following raw materials in parts by weight: 2 to 3 parts of nano-hydroxyapatite, 3 to 5 parts of citric acid, 6 to 9 parts of lactic acid, 3 to 4 parts of tyrosine, 1 to 2 parts of glycollic acid, 2 to 3 parts of casein, 0.2 to 0.3 part of hyperoside and 1 to 2 parts of gelatin.

The invention discloses a biodegradable polylactic acid composite material and a preparation method thereof, and relates to the technical field of polylactic acid materials. The method comprises the steps that firstly, chitosan activated through hydrochloric acid is subjected to graft modification through a KH550 silane coupling agent, meanwhile, nano-zinc oxide is subjected to surface modification through stearic acid, the chitosan and the nano-zinc oxide are mixed, spray drying is conducted, and antibacterial composite powder is prepared; the preparation method comprises the following steps: performing hydrochloric acid activation and KH570 silane coupling agent modification on nano silicon dioxide, performing hydroxypropylation modification on alkali lignin, and performing reflux crosslinking reaction on the modified alkali lignin, KH570 modified nano silicon dioxide, polycaprolactone, methyl methacrylate and azodiisobutyronitrile to prepare a heat-resistant reinforcer; uniformly mixing polylactic acid, poly (butylene succinate), the antibacterial composite powder, the heat-resistant reinforcer, tributyl citrate, polyethylene glycol and talcum powder, and extruding and granulating by using a twin-screw extruder to obtain the heat-resistant antibacterial material. The composite material prepared by the invention has excellent antibacterial property, heat resistance and biodegradability.

The invention discloses a quick-curing polyurethane seamless expansion joint material for roads and a preparation method, and belongs to the technical field of road engineering materials. The material is prepared from polyether polyol, polycaprolactone glycol, a bisphenol A epoxy-polyether block isocyanate terminated prepolymer, a methyl phenyl silicon-boron hybrid hydroxyl chain extender, diphenylmethane diisocyanate, calcium carbonate, wollastonite, a hindered amine anti-aging agent and dioctyl phthalate. Wherein the bisphenol A epoxy-polyether block isocyanate terminated prepolymer is prepared by the following steps: reacting bisphenol A with epoxy chloropropane to generate epoxy resin, reacting with polytetramethylene ether glycol, and introducing isophorone diisocyanate; the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation and ethylene glycol reaction on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester; and the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester. The material has the advantages of quick curing property, weather resistance and high-temperature stability, and is suitable for road seamless expansion joint scenes.

The invention discloses a high-dispersion graphene conductive adhesive solution for a battery and a preparation method of the high-dispersion graphene conductive adhesive solution, and belongs to the technical field of conductive adhesive solutions. The high-dispersion graphene conductive adhesive solution for the battery prepared by the invention is prepared from the following raw material components in parts by mass: 6 to 8 parts of high-dispersion graphene, 4.5 to 13.5 parts of an adhesive and 60 to 90 parts of a solvent, the preparation method comprises the following steps: ultrasonically dispersing graphene in a mixed solution of hexadecyl triyl ammonium bromide and deionized water, sequentially adding hexadecyl triyl ammonium bromide, sodium molybdate dehydrate, bismuth nitrate pentahydrate and cerium nitrate hexahydrate, uniformly stirring and dispersing, performing hydrothermal reaction, washing, drying, grinding and sieving to obtain the high-dispersion graphene. The adhesive is prepared from an amphiphilic polyethylene glycol-polycaprolactone block copolymer and amphiphilic polyacrylate.

The present invention discloses a class of nitrogen heterocycle-substituted hexa-dentate aminophenoxy rare earth complexes (I), a preparation method thereof, and an application thereof in the highly active catalytic ring-opening polymerization of lactones. The preparation method comprises the following steps: reacting a neutral ligand with a metal raw material compound in an organic medium, then adding an alcohol for reaction, and obtaining the target compound through filtration, concentration, and recrystallization. The nitrogen heterocycle-substituted hexa-dentate aminophenoxy rare earth complex of the present invention is a highly efficient catalyst for the ring-opening polymerization of lactones, and can be used for catalyzing the polymerization reaction of lactones such as lactide, and catalyzing the one-pot copolymerization of lactide and ε-caprolactone to obtain a multi-block copolymer. The nitrogen heterocycle-substituted hexa-dentate aminophenoxy rare earth complex of the present invention has good tolerance to impurities, has very high catalytic activity, and can obtain high molecular weight polyester materials. A has a structure shown in formula (II), (III), (IV) or (V); B has a structure shown in formula (VI) or (VII).

The invention discloses a degradable resin material, an optical property regulator, an optically-adjustable environment-friendly mulching film and a processing method of the optically-adjustable environment-friendly mulching film, and belongs to the field of degradable environment-friendly materials. The invention provides a degradable polyester resin material with a novel structure, namely polycaprolactone-co-lactide. The degradable polyester resin material is formed by performing ring-opening copolymerization on epsilon-caprolactone and lactide under the catalytic action of a symmetric binuclear Schiff base complex; the ratio of the average chain segment length of caprolactone to the average chain segment length of lactide in the resin material is (2-2.2): (2-2.2), which is close to that of an alternating copolymer. The compound can be used as an optical property regulator, and preparation of an environment-friendly mulching film with adjustable optical properties such as ultraviolet light absorbance, infrared light transmittance and haze can be realized under the condition that no dye or other coloring additives are used.

The invention relates to the technical field of polymer compositions, and particularly discloses a degradable bio-based food packaging material and a preparation method thereof.The degradable bio-based food packaging material is prepared from polylactic acid, ITA esterified bacterial cellulose, CSL-ITA esterified bacterial cellulose, polycaprolactone glycol, acetyl tributyl citrate, a photoinitiator and tocopherol; the preparation method comprises the following steps: esterifying bacterial cellulose hydrogel with itaconic anhydride, grafting with sodium copper chlorophyllin, dehydrating with gradient ethanol, and drying with supercritical CO2 to obtain modified powder; according to the preparation method, the interfacial compatibility of the bacterial cellulose and the polylactic acid is enhanced through ITA esterification, the illumination antibacterial function is given by utilizing CSL grafting, the polycaprolactone glycol and the acetyl tributyl citrate are synergistically used for toughening and improving the brittleness, the photoinitiator is added, the photoinitiator is added for mixing, and ultraviolet crosslinking curing is performed after film forming. The tocopherol protects the stability of the antibacterial structure of the CSL, the water resistance is improved through photo-crosslinking, and the material is degradable and meets the food packaging requirement.

The invention provides a full-degradable polymer composite material for tableware and a preparation method of the full-degradable polymer composite material, and belongs to the technical field of polymer materials. According to the invention, amylose corn starch, hydrophobic modified corn starch, cassava acetylated distarch phosphate, a polylactic acid-poly (butylene succinate) interpenetrating network structure material, a copolymer of 3-hydroxybutyrate and 3-hydroxyvalerate, polycaprolactone, stearic acid modified micron titanium dioxide, chitosan quaternary ammonium salt and a composite plasticizer are adopted according to a specific ratio; the fully-degradable polymer composite material is obtained by compounding the composite heat stabilizer and stearic acid, has controllable and good biodegradability and good mechanical properties, enhances heat stability, improves processability, makes all the components easier to mix uniformly, facilitates molding processing of the material, and improves production efficiency and product quality.

The invention relates to the technical field of polymer composite materials, in particular to a polycaprolactone-based composite material as well as a preparation method and application thereof. The preparation method comprises the following steps: carrying out surface grafting treatment on nano cellulose to obtain modified nano cellulose; mixing the modified nanocellulose, polycaprolactone and a solvent to obtain slurry; carrying out melt blending and granulation on the slurry to obtain composite granules; and carrying out melt blending and granulation on the composite granules, a metal soap stabilizer and a natural resin derivative to obtain the polycaprolactone-based composite material. The polycaprolactone-based composite material prepared by a novel composite process of nano cellulose graft modification-solvent replacement synergetic melt co-extrusion has the core advantages of high mechanical strength, excellent light transmittance, long-acting weather resistance and the like, is good in processing adaptability and simple and convenient to operate, can realize continuous large-scale production, and remarkably reduces energy consumption and raw material cost.

The invention relates to a preparation method of polycaprolactone, which comprises the following steps: mixing epsilon-caprolactone, a polymerization initiator and a temperature response type solvent to obtain a mixture; polymerizing the mixture under the catalytic action of a catalyst to obtain a primary polymer; and separating out the primary polymer to obtain a final polymerization product. According to the preparation method of the polycaprolactone, the temperature response type solvent has the characteristic of temperature response and shows good solubility to a polymerization product at the conventional polymerization temperature of the epsilon-caprolactone, the system viscosity is greatly reduced in the polymerization stage, mass and heat transfer and continuous and uniform chain growth in the polymerization process are facilitated, and the yield of the polycaprolactone is improved. And when the temperature of the system is reduced to a specific temperature or below, the polymerization product is crystallized and separated out, and narrow-distribution polycaprolactone can be obtained by simple separation, so that the problems of thermal degradation of the product and monomer residue in the traditional high-temperature devolatilization are effectively solved.

The invention discloses an anti-fibrosis drug coating degradable woven stent for treating urethrostenosis, the stent is a hollow cylinder formed by spirally weaving wires, the wires are made of biodegradable polymer materials, the surface of the stent is coated with a drug coating, anti-fibrosis drugs are selected as the drugs, and the anti-fibrosis drug coating is made of biodegradable polymer materials. The drug coating is prepared by using an ultrasonic atomization spraying method; the biodegradable polymer material comprises one or a compound of more than one of poly L-lactic acid, poly D, L-lactic acid, poly (L-lactic acid / D, L-lactic acid), poly (glycolide / lactide), poly (glycolide-lactide), poly (L-lactic acid / caprolactone), poly (glycolide / caprolactone), poly (D, L-lactic acid / caprolactone), polydioxanone and the like. The stent body is made into a self-expanding stent by adopting a weaving method; the biodegradable ureteral stent with the drug coating has good biocompatibility, degradability and mechanical property, and has a wide market application prospect.

The invention discloses a preparation method of a polymer vesicle capable of crossing a blood brain barrier, and belongs to the field of high polymer materials and medical engineering. The preparation method of the polymer vesicle capable of crossing the blood brain barrier comprises the following steps: synthesizing an amphiphilic block copolymer by utilizing ring-opening polymerization reaction of polycaprolactone and anhydride in an amino acid ring, then assembling the polymer into the polymer vesicle, and modifying a monoclonal antibody of a transferrin receptor on a polypeptide chain. The polymer vesicle prepared by the invention is simple and convenient in preparation process, short in period, good in stability, good in biocompatibility and good in biodegradability, can be used as an excellent carrier of chemotherapeutic drugs, and can effectively realize drug delivery of targeting brain tumor cells across a blood brain barrier. Compared with a commercial drug delivery carrier, the polymer vesicle has the advantage that the permeability of the drug in a bionic blood brain barrier and the targeted uptake rate of brain tumor cells are remarkably improved.

The invention discloses a method for directionally depolymerizing polycaprolactone into a caprolactone monomer, and belongs to the technical field of directional depolymerization of caprolactone. According to the invention, efficient closed-loop depolymerization of polycaprolactone is realized, and generation of dimers is reduced. According to the polycaprolactone depolymerization method provided by the invention, the polycaprolactone can be directionally depolymerized into the caprolactone monomer without a high vacuum degree condition, the depolymerization condition is relatively mild, the process is efficient, and a new way is developed for chemical recovery of waste plastics while the environmental and economic benefits of recycling of the polycaprolactone are improved. The obtained depolymerization product is relatively high in purity, relatively high in conversion rate and low in dimer generation amount, and the depolymerization product can be directly and efficiently recycled.

The present invention belongs to the technical field of oils for hydraulic supports and provides a biodegradable natural plant-extracted emulsified oil for hydraulic supports and a preparation method thereof. First, through multi-step chemical modification of palm oil, including epoxidation, boronation, phosphating, and block polymerization, the epoxidation reaction introduces epoxy groups, increasing the reactivity of the oil; the boronation and phosphating reactions further enhance the polarity of the oil and its ability to form a lubricating film; and through block polymerization with caprolactone, the stability and wear resistance of the lubricating film are enhanced. Second, through carboxymethylation of chitosan, the carboxyl groups in the carboxymethyl chitosan react with oxides on the metal surface to form a chemical passivation protective film; and the sulfonic acid groups in the sodium lignosulfonate bind to the metal surface through electrostatic adsorption, further forming a protective layer. The synergistic effect of the two forms a multi-layer dense protective film on the metal surface, significantly improving the anti-corrosion performance of the emulsified oil.

The invention relates to the technical field of sewage treatment, in particular to a preparation method of a degradable bactericide for an oil field. According to the invention, a hydroxypropyl guanidine gum-polycaprolactone-ethylenediamine fragment copolymer is taken as a carrier, a methylisothiazolinone quaternary ammonium salt (Q-MIT) bactericide is loaded, and the degradable bactericide for the oil field is obtained by cooperating with a dodecyl ethyl sulfide (TC-SE) bactericide and combining with sodium polyaspartate. A carrier forms a hydrogen bond with a polar group on the surface of a biological membrane through a hydroxypropyl guanidine gum main chain to realize targeted anchoring, a polycaprolactone branched chain encapsulates Q-MIT through a hydrophobic effect, primary amino groups of ethylenediamine are introduced to form a pH sensitive Schiff base bond with Q-MIT, and the primary amino groups and adipic dihydrazide form a thermal response hydrazide bond to construct a dual dynamic covalent bond, so that controlled release of Q-MIT is realized, and the biomembrane is prepared. And moreover, the components of the whole system are connected through degradable chemical bonds, so that the environmental protection property and sustainability of oil field operation are guaranteed.

The present invention relates to the technical field of cyclohexanone catalytic oxidation, and specifically to a titanium silicalite molecular sieve and a preparation method thereof, a method for preparing cyclohexanone oxime, and a method for preparing caprolactone. The method comprises: (1) uniformly mixing a silicon source, an alkaline template, a titanium source, and water to obtain a titanium silicalite sol; and (2) adding a silanization agent to the titanium silicalite sol, and hydrothermally crystallizing and calcining the obtained mixture. The present invention treats the titanium silicalite sol precursor with a specific silanization agent to prepare a titanium silicalite molecular sieve. When used in the catalytic oxidation of cyclohexanone and the ammoximation reaction of cyclohexanone, the titanium silicalite molecular sieve has high catalytic activity, and the conversion rate of cyclohexanone can be increased to above 91%.

A collagen membrane with an effect of inducing ordered remodeling of tissues, a preparation method therefor, and use thereof, relating to the technical field of surgical supply materials. The preparation method for the collagen membrane comprises the following steps: subjecting a fiber membrane to a heat pressing treatment to obtain the collagen membrane with the effect of inducing ordered remodeling of tissues. The fiber membrane is formed by cross-stacked fibers with a diameter of 0.5-15 μm. The fibers comprise collagen and poly(L-lactide-co-caprolactone). The mass ratio of the collagen to the poly(L-lactide-co-caprolactone) is 1:(1.5-2.5). By combining the collagen, which has good biocompatibility and an effect of promoting tissue repair, with PLCL, which is biodegradable and features excellent mechanical properties and good cell adhesion, the collagen membrane not only has an extracellular matrix-like structure, but also exhibits good structural stability, facilitating the regulation of cell behaviors and tissue regeneration, and effectively promoting the growth, adhesion, and proliferation of host cells, thereby inducing ordered remodeling of tissues.

The invention provides a preparation method of an acoustic / photosensitizer-manganese dioxide nanoparticle and a product thereof. According to the method, firstly, a potassium permanganate reduction method is adopted to precisely synthesize the high-purity MnO2 nano-substrate, and according to the method, the size uniformity and dispersion stability of nano-particles can be precisely controlled by regulating and controlling the pH value and temperature of a reaction system and the concentration of a reducing agent. On the basis, amphiphilic high-molecular polyethylene glycol-polycaprolactone (PEG-PCL) is modified on the surface of the MnO2 nanometre. The whole preparation process is green and mild, and complex equipment is not needed; the reaction conditions are mild, nanoparticles are uniform, and the acoustic / photosensitizer can be combined and applied to an imaging technology to realize real-time monitoring.

The invention belongs to the technical field of pesticide preparations, and relates to a preparation method and application of prothioconazole sustained-release microspheres. The preparation method comprises the following steps: adding an active compound, an emulsifier, isocyanate and polycaprolactone polyol into cyclohexanone, and uniformly mixing to obtain an oil phase; adding a dispersing agent into water and uniformly mixing to obtain a water phase; and adding dibutyltin dilaurate into the oil phase, reacting, mixing with the water phase, shearing, and stirring to obtain the prothioconazole sustained-release microsphere suspending agent. The prothioconazole sustained-release microsphere prepared by the process still keeps higher bactericidal activity on the premise of good leaf surface stability, so that reduction of the pesticide application frequency, improvement of the pesticide utilization rate and long-acting prevention and control of prothioconazole in the field are expected to be realized, and the prothioconazole sustained-release microsphere conforms to the national double reduction policy and is suitable for large-scale popularization and application.

The invention discloses a modified polylactic acid high-temperature-resistant degradable composite material and a preparation method thereof, and relates to the technical field of degradable materials. The modified polylactic acid high-temperature-resistant degradable composite material at least comprises the following raw materials in parts by mass: 70-80 parts of polylactic acid; 15 to 25 parts by mass of a lignin-polylactic acid-polycaprolactone block copolymer; 5 to 10 parts by mass of poly (butylene adipate-co-terephthalate); 2-5 parts by mass of stearic acid modified nano silicon dioxide; 0.3 to 0.8 part by mass of an anti-hydrolysis agent; and 0.2 to 0.5 part by mass of an antioxidant. According to the prepared modified polylactic acid high-temperature-resistant degradable composite material, the mechanical property and the high temperature resistance of the polylactic acid composite material are improved, the degradation rate can be regulated and controlled through the proportion of all the components, and the use requirements of different scenes are met.

The present invention belongs to the technical field of petrochemical catalysis, and relates to a preparation method for improving the stability of a Cu-Beta zeolite catalyst for preparing caprolactam from caprolactone, and the use thereof. In the present invention, a cavity-modified dealuminated Beta zeolite is used as a carrier, and copper is loaded in pore channels of the zeolite carrier by means of an improved ammonia distillation method. The cavity modification refers to subjecting the dealuminated Beta zeolite carrier to a desiliconization technique controlled by the use of a weak organic base so as to enlarge silanol nests generated by dealumination of the dealuminated Beta zeolite carrier, thereby better accommodating and stabilizing the nano and sub-nano copper particles. The core of the improved ammonia distillation method involves impregnating a zeolite carrier with an equal volume of a copper-ammonia complex solution, such that the copper-ammonia complex mainly undergoes, during ammonia distillation, a reaction of depositing copper hydroxide in zeolite pore channels, thereby improving the sintering resistance. The Cu-Beta catalyst prepared using the method provided by the present invention exhibits high activity, selectivity and stability when applied to the reaction of caprolactam prepared from caprolactone via gas-solid phase hydroamination.

The invention discloses a preparation method and application of shape memory short fiber stiffened hydrogel, and the preparation method comprises the following steps: obtaining a copolymer PLCL nanofiber membrane of poly-L-lactic acid and caprolactone through electrostatic spinning, carrying out stretching shaping and cutting at a certain temperature, dispersing in a low-temperature homogenizer to form shape memory short fibers SMSFs, and carrying out shape memory short fiber reinforcement on the shape memory short fibers SMSFs to obtain the shape memory short fiber hydrogel. The SMSFs are added into the double-network hydrogel, and the shape memory short fiber stiffened hydrogel is obtained by exciting the shape memory effect of the SMSFs. The invention relates to an application of a shape memory short fiber, which is used for preparing shape memory short fiber stiffened hydrogel for promoting osteogenic differentiation and inhibiting osteoclast generation. According to the shape memory short fiber stiffened hydrogel and the application method thereof, the stiffening effect of the shape memory short fiber stiffened hydrogel has the direct regulation and control effect on stem cell osteogenic differentiation and indirectly has the ability of inhibiting osteoclast formation, and a new way is provided for preparing a bone regeneration scaffold for osteoporotic bone defect repair.

The invention relates to the technical field of paint, and discloses high-gloss spray paint for motorcycles and a spraying process of the high-gloss spray paint. The high-gloss spray paint is prepared from the following raw materials in parts by mass: 8 to 12 parts of polyethylene glycol-polycaprolactone-acrylate, 15 to 20 parts of sulfydryl acrylate, 20 to 30 parts of acrylic resin, 6 to 10 parts of additive, 8 to 15 parts of metallic pigment, 20 to 30 parts of amino resin, 1 to 2 parts of flatting agent, 15 to 30 parts of solvent, 1 to 2 parts of solvent oil and 0.02 to 0.05 part of photoinitiator. The additive is prepared from silane modified tert-butyl methyl benzoate, double-bond modified tert-butyl methyl benzoate and an assistant cross-linking agent according to the mass ratio of (1 to 2) to (5 to 6) to 1; the preparation method of the assistant crosslinker comprises the following steps: adding 5-amino-2, 4-di-tert-butyl methyl benzoate and triphenylmethane triisocyanate into tetrahydrofuran, uniformly mixing, stirring to react for 6-8 hours at 70-90 DEG C, and removing the solvent to obtain the assistant crosslinker.

The invention discloses a preparation method of modified thermostable polycaprolactone, and belongs to the technical field of high polymer materials. The method comprises the following steps: selecting branched monomers such as 3-methyl-epsilon-caprolactone, inhibiting molecular chain slippage through a side group steric effect, and improving chain rigidity; a super-crosslinking metalloporphyrin porous material catalyst is adopted; (3) introducing a light / heat reversible group to an end group; and (4) optimizing process conditions and narrowing molecular weight distribution. Experiments show that the modified PCL obtained by the method is high in thermal decomposition temperature, small in melt flow rate change rate, low in yellowing index and high in tensile strength, and the comprehensive performance of the modified PCL is far better than that of the modified PCL obtained by a traditional method. The material is suitable for the fields of medical instruments, intelligent packaging and the like, and has the characteristics of high thermal stability, rapid shape recovery and controllable degradation.

The application discloses a degradable cotton soft towel and a preparation method thereof, relates to the technical field of fiber composite materials, and belongs to the patent classification D01F8 / 02. The preparation method comprises the following steps: performing alkali treatment and enzymolysis on Egyptian long-staple cotton fibers to obtain pretreated cotton fibers, and preheating, stretching and setting poly-caprolactone fibers to obtain pretreated poly-caprolactone fibers; mixing and opening the two kinds of fibers, and then air-laying to form a fiber web; constructing a super water-absorbing network by impregnating a main network solution carboxymethyl chitin and oxidized cellulose nanofilament and an auxiliary network dispersion liquid calcium alginate gel microspheres and a hyaluronic acid crosslinking body; forming micron protrusions through hexagonal nickel template hot pressing, and obtaining a base by electrostatic spraying modification of nano silicon dioxide; and obtaining the cotton soft towel through vacuum drying, slitting and sterilization after spraying of an essence liquid. The cotton soft towel has excellent water absorption performance through the synergistic effect of multistage pores, a super water-absorbing network and micro-nano surface modification, and the poly-caprolactone fibers and the cotton fibers used in the cotton soft towel are mixed, and both have good biodegradability.

The invention discloses a preparation method of photo-thermal driven liquid metal microsphere-polymer shape memory fibers, which comprises the following steps: compounding liquid metal microspheres LMP with waterborne polyurethane WPU to form coating slurry with photo-thermal response capability, uniformly coating the surface of thermoplastic polyurethane / polycaprolactone TPU / PCL shape memory fibers prepared by a wet spinning process with the coating slurry, and carrying out photo-thermal driving on the surface of the TPU / PCL shape memory fibers to obtain the photo-thermal driven liquid metal microsphere-polymer shape memory fibers. And the TPU-PCL / LMP-WPU composite fiber with the photo-thermal response capability is obtained. The method has the advantages that illumination or near-infrared laser is applied to serve as an activation source, non-contact heating is achieved, and fiber deformation can be driven within a short time to complete anti-fake recognition.

The invention provides a biodegradable polyurethane binding material and a preparation method thereof. The biodegradable polyurethane binding material comprises the following raw materials in parts by weight: 50-150 parts of a prepolymer; 40 to 66 parts of tackifying resin; 10 to 30 parts of isocyanate; 7-10 parts of a chain extender; 0.2 to 5 parts of a catalyst; and 0.28 to 0.95 part of an antioxidant. Wherein the prepolymer is prepared by mixing polyethylene glycol, isophorone diisocyanate, polycaprolactone glycol, dimethylolpropionic acid, 1, 4-butanediol, triethylamine and sodium 2-[(2-aminoethyl) amino] ethanesulfonate, and the prepolymer is prepared by mixing polyethylene glycol, isophorone diisocyanate, polycaprolactone glycol, dimethylolpropionic acid, 1, 4-butanediol, triethylamine and sodium 2-[(2-aminoethyl) amino] ethanesulfonate. The weight ratio of the 1, 4-butanediol to the triethylamine to the 2-[(2-aminoethyl) amino] sodium ethanesulfonate is 9: 4: 8: 1: 1: 1; compared with the prior art, the polyurethane adhesive material has the advantages that components with specific contents are adopted, good interaction is realized, and the prepared polyurethane adhesive material can be completely degraded through microorganisms in the natural environment after being cured and is environment-friendly.