859 results about "Lactone" patented technology

The invention provides a sulfonated modified COF-based hydrogel based on a TPAD skeleton, and a preparation method and application thereof, and belongs to the field of water treatment. The preparation method comprises the following steps: S1, synthesizing a TPAD-NHBoc amino monomer by using reagents such as 1, 4, 5, 8-tetrachloroanthraquinone and the like; s2, sequentially adding a TPAD-NHBoc amino monomer, a Dha aldehyde monomer, dioxane and trifluoroacetic acid into a glass tube according to a certain proportion, carrying out ultrasonic treatment, stirring, putting into a reaction kettle, and reacting at 115-125 DEG C for 96-120 hours; s3, after the reaction is finished and cooling is performed, carefully taking out the blocky gel from the glass tube, respectively immersing the blocky gel into dioxane and DMF, and repeatedly replacing the solvent for washing; s4, washing the gel, soaking the washed gel in a DMF solution containing 1, 3-propane sultone, and carrying out a reaction at 75-85 DEG C for 16-20 h to obtain sulfonated modified gel; s5, the obtained sulfonated modified COF-based gel is soaked in DMF, acetone, methanol and water for multiple times of soaking and washing, and the hydrogel is obtained. The sulfonated modified hydrogel based on the TPAD skeleton has excellent solar photo-thermal water evaporation performance.

The invention discloses a phycomycete symbiotic system and application of the phycomycete symbiotic system in treatment of aquaculture tail water, and belongs to the technical field of tail water treatment. The phycomycete symbiotic system comprises chlorella, scenedesmus and activated sludge, and the initial inoculation dry weight ratio of the chlorella to the scenedesmus to the activated sludge is 1: 1: 6. And exogenously adding octanoyl-L-homoserine lactone or tetradecanoyl-L-homoserine lactone into the phycomycetes symbiotic system, so as to construct the phycomycetes symbiotic system with enhanced functions. On the basis of a mixed algae-bacteria symbiotic system with an optimized ratio, directional enhancement of functions is realized by virtue of quorum sensing signal molecules, the stability and resistance gene interception capability of the quorum sensing signal molecules under the stress of antibiotics are verified, and finally efficient purification of the aquaculture tail water is realized. According to the invention, the blank of the prior art in the aspects of advanced regulation and control of a phycomycete synergistic mechanism and synergistic treatment of emerging pollutants is filled up.

The invention relates to the technical field of sewage treatment, in particular to a preparation method of a degradable bactericide for an oil field. According to the invention, a hydroxypropyl guanidine gum-polycaprolactone-ethylenediamine fragment copolymer is taken as a carrier, a methylisothiazolinone quaternary ammonium salt (Q-MIT) bactericide is loaded, and the degradable bactericide for the oil field is obtained by cooperating with a dodecyl ethyl sulfide (TC-SE) bactericide and combining with sodium polyaspartate. A carrier forms a hydrogen bond with a polar group on the surface of a biological membrane through a hydroxypropyl guanidine gum main chain to realize targeted anchoring, a polycaprolactone branched chain encapsulates Q-MIT through a hydrophobic effect, primary amino groups of ethylenediamine are introduced to form a pH sensitive Schiff base bond with Q-MIT, and the primary amino groups and adipic dihydrazide form a thermal response hydrazide bond to construct a dual dynamic covalent bond, so that controlled release of Q-MIT is realized, and the biomembrane is prepared. And moreover, the components of the whole system are connected through degradable chemical bonds, so that the environmental protection property and sustainability of oil field operation are guaranteed.

The invention relates to the technical field of repair compositions, and discloses a repair composition based on mussel mucin and application of the repair composition in skin barrier repair. The invention discloses a mussel mucoprotein-zinc composite microcapsule repair agent, which is prepared from the following components in parts by weight: mussel mucoprotein-zinc composite microcapsules, modified carboxymethyl chitosan, isolactone palmitate, a pH response type ceramide slow release system, dimeticone, cetostearyl alcohol, a calcium ion activating agent, an auxiliary repair factor, beheneth-25, caprylic / capric triglyceride, glyceryl monostearate, glyceryl distearate, pentanediol and citric acid. The preparation method comprises the following steps: adding ethanol, phenoxyethanol / ethylhexylglycerin, trehalose, beta-glucan and purified water; according to the whole technical scheme, through functional complementation and process optimization of all the components, synergistic interaction is achieved, the transpedermis water loss amount can be rapidly reduced, the water content of the skin cuticle is increased, the damaged skin barrier structure can be repaired from the source, and the resistance and stability of the skin are remarkably improved.

The invention provides a composite antifouling system coating as well as a use method and application thereof. The coating sequentially comprises a bottom layer, a copper-containing middle layer and a surface layer in the direction from near to far away from a base material, wherein the copper-containing middle layer comprises 20-30 parts of self-polishing acrylic silicon resin, 5-10 parts of lime rosin, 8-12 parts of zinc oxide, 30-50 parts of cuprous oxide, 2-3 parts of a compound antifouling agent, 0.5-1 part of a thixotropic agent and a first diluent. The surface layer is prepared from 30 to 35 parts of caprolactone and lactic acid grafted linear polyester, 5 to 10 parts of highly hydrolyzed N-(hydroxymethyl) acrylamide (NMA) modified acrylic resin, 15 to 20 parts of copper-free organic antifouling agent, 5 to 12 parts of polytetrafluoroethylene micro powder, 2 to 3 parts of dispersing agent and second diluent. The high-hydrolysis copper-free surface layer forms an isolation barrier, so that the copper-containing middle layer is prevented from being in direct contact with air, and the problem that the antifouling efficiency is reduced due to the fact that water is not discharged for a long time after coating is solved; the stable hydrolysis rate of the surface layer resin can ensure the continuous release of the organic antifouling agent, and the copper-containing intermediate layer can provide deep antifouling guarantee and synergistically realize long-acting antifouling.

The present invention relates to the technical field of organic synthesis, and specifically relates to a method for constructing the chirality of a pyran ring in Orforglipron by means of enzymatic catalysis, the method comprising the following steps: step S1, by using SM1 and SM2 as starting materials, carrying out a reaction under the action of a palladium catalyst and a ligand to obtain INT-1; step S2, under the catalysis of Pd / C, subjecting INT-1 to double bond hydrogenation reduction to obtain INT-2; step S3, in the presence of a solvent, a buffer salt system and enzymatic catalysis, subjecting INT-2 to hydrolysis and resolution to obtain a chirally pure intermediate INT-3; step S4, subjecting INT-3 to a Grignard reaction for cyclization, so as to synthesize a lactone intermediate INT-4; and step S5, subjecting INT-4 to reduction by means of Dibal-H, quenching same, performing extraction with dichloromethane, drying same with anhydrous sodium sulfate, and then performing reduction by means of triethylsilane to obtain a compound of general formula A. In the present invention, the chirality is constructed by means of enzymatic catalysis without the need of SFC resolution for separating isomeric impurities during the construction of the chirality, thereby reducing losses and improving yield, obtaining the target product at high yield and high chiral selectivity, and further saving expenses and reducing costs.

This invention discloses a method for preparing polyether / polyester-polyether random copolymers by electrochemical polymerization. Under energized conditions, the lactone and epoxide monomers undergo simultaneous ring-opening copolymerization. By adjusting the amount of monomers and the reaction time, the composition and proportion of polyester and polyether in the resulting copolymer can be effectively controlled. No catalyst or initiator is used in the polymerization reaction, and the reaction is stable at room temperature. The polyether / polyester-polyether random copolymers prepared by this method have a molecular weight of 10 kg / mol–45 kg / mol and a molecular weight distribution index of 1.10–1.30. The electrochemical polymerization method for preparing polyester-polyether random copolymers provided by this invention is green, pollution-free, and easy to operate, showing promising application prospects.

The present invention relates to a bismuth-containing catalyst of formula (R1)2-(R2)-(Bi)3+ (I), wherein (R1)2- is a dianion of formula (II*), wherein A is unsubstituted or at least monosubstituted linear C3-30-alkylene, wherein at least two not adjacent CH2 groups of C3-30-alkylene are replaced by a heteroatom independently selected from the group consisting of O, S, 5 NH, N-C1-30-alkyl, N-C6-14-aryl and N-C7-30-aralkyl, wherein alkyl and aryl fragments of N-C1-30-alkyl, N-C6-14-aryl, N-C7-30-aralkyl may at least be monosubstituted by hydroxyl, halogen, -CF3, NH2, -NH-C1-6-alkyl, -NH- phenyl, -N(C1-6-alkyl)2, -N(phenyl)2, -SH, -S-C1-6-alkyl, -S-phenyl, -O-C1-6-alkyl or -O-phenyl, to process for the preparation of the bismuth containing catalyst, to a process for the preparation of a compound, oligomer or polymer comprising at least one urethane group using the bismuth-containing catalyst, to a composition comprising (i) at least one monoalcohol (B1) or polyol (B2), (ii) at least one polyisocyanate (A) and (iii) the bismuth-containing catalyst, to a coating or adhesive layer formed from the composition on a substrate, to a foam formed from the composition, and to the use of the bismuth-containing catalyst in for preparing compounds, oligomers or polymers comprising a urethane group, as esterification and transesterification catalyst and as catalyst for ring-opening polymerizations of lactones and epoxides.

The application discloses a Yarrowia lipolytica strain with high yield of gamma-decalactone and / or delta-decalactone and application thereof, and belongs to the technical field of biotechnology. The name of the strain is Yarrowia lipolytica Y-1, and the preservation number is GDMCC No: 67810. The strain Y-1 can be directly used for biological transformation to cooperatively and efficiently prepare gamma-decalactone and delta-decalactone with castor oil acid as a substrate. The strain has three outstanding advantages: ① yield advantage; ② tolerance advantage; and ③ application advantage. The biological transformation method has the advantages of mild reaction condition, low cost, product meeting natural perfume standards, environmental friendliness and the like.

This invention discloses a method for preparing poly(glycolic acid-caprolactone) copolymers, belonging to the field of polymer synthesis technology. The method includes: prepolymerizing ε-caprolactone with a catalyst and initiator at 40–60°C below the melting point of glycolide under an inert atmosphere; adding glycolide and heating to 160–220°C for the main polymerization reaction; after the reaction, dissolving, precipitating, washing, and drying to obtain the poly(glycolic acid-caprolactone) copolymer. This invention utilizes the physical difference in melting points between glycolide and ε-caprolactone, preferentially prepolymerizing ε-caprolactone at a temperature below the melting point of glycolide, resulting in a higher conversion rate of ε-caprolactone than glycolide in the initial stage of the main polymerization, effectively controlling the copolymerization reaction pathway. Using this method, copolymers with a weight-average molecular weight of not less than 100,000 Da and an intrinsic viscosity of 1.8–3.5 dL / g can be obtained within a wide range of glycolide molar content from 15% to 85%, and the degradation behavior is stable and controllable. This method is simple and requires no special equipment or chain extender, making it suitable for the large-scale preparation of medical materials such as absorbable sutures and tissue repair scaffolds.

The invention discloses an enantiomer crystallization resolution method of delta-dodecalactone, which comprises the following steps: hydrolyzing delta-dodecalactone under an alkaline condition for ring opening, acidifying to obtain 5-hydroxylauric acid, adding a dehydroabietylamine solution, dissolving in an alcohol solvent or a solvent system consisting of the alcohol solvent and other solvents, fully reacting, cooling, slowly crystallizing, filtering, washing, and drying to obtain the delta-dodecalactone enantiomer. Filtering, adding ethyl acetate and hydrochloric acid into a filter cake for dissolving, carrying out liquid-liquid extraction and washing an organic phase, and carrying out rotary evaporation concentration on the organic phase to obtain optically enriched delta-dodecalactone; the method is simple to operate and does not depend on expensive special equipment, and the sample loading amount is greatly increased; due to the introduction of dehydroabietylamine, the 5-hydroxylauric acid and the dehydroabietylamine form diastereoisomer salt, and chiral separation is carried out in the crystallization process; the reaction safety is high, and the requirements of green chemistry are met.

This invention relates to the field of enzyme engineering technology, and in particular to a highly efficient lactone hydrolase mutant for degrading zearalenone and its applications. This lactone hydrolase mutant uses the lactone hydrolase gene from Monosporascus sp. GIB2 as a template, and performs a site-directed mutation at amino acid position 134 to obtain L134A, L134V, L134I, and L134M mutants. Under optimal conditions of pH 9.0 and 60℃, these single-point mutants can efficiently degrade zearalenone (ZEN) within 3 minutes. The enzyme activity for degrading zearalenone is significantly improved compared to the original enzyme, with degradation activities increasing by 1.22 (L134A), 1.25 (L134V), 1.17 (L134I), and 1.14 (L134M), respectively, demonstrating significant applications and economic value in the feed industry.

The application provides a preparation method of a polyurethane foaming material. The preparation method comprises the following steps: firstly, pre-polymerization of polytetrahydrofuran ether glycol and hexamethylene diisocyanate; then, mixing, extruding, and granulating of polyhexalactone dihydric alcohol and a catalyst to obtain polyurethane granules. The granules are dried and injection molded into a small embryo to be foamed. The small embryo is immersed in supercritical carbon dioxide, nitrogen is introduced for auxiliary foaming, and gradient pressure relief control is implemented in the foaming process. After foaming, curing treatment is performed to obtain the polyurethane foaming material. The preparation method is beneficial to improving the cell uniformity of the polyurethane foaming material and improving the performance stability of the material after rebound, compression, and aging.

The invention discloses an ultraviolet-controlled photo-reversible dynamic crosslinking high polymer material with reversible antibacterial, shape deformation and toughening functions, and a preparation method thereof, belonging to the technical field of high polymer materials. Comprising the following steps: step 1) dissolving coumarin-3-formic acid, three-arm PCL (polycaprolactone), dicyclohexylcarbodiimide and 4-dimethylaminopyridine in dry dichloromethane in an inert atmosphere to obtain a reaction mixture; the invention relates to a preparation method of a coumarin-terminated three-arm polycaprolactone cross-linked polymer material.The preparation method comprises the following steps of (1) preparing coumarin-terminated three-arm polycaprolactone, (2) heating a reaction mixture obtained in the step (1) for set time, and filtering and separating an obtained product to obtain coumarin-terminated three-arm polycaprolactone, and (3) cross-linking and curing for set time through 365 nm ultraviolet to obtain a target product cross-linked polymer material.The function is highly integrated and dynamically adjustable, and the limitation that a traditional material is single in function is broken through.

The present disclosure provides a P450 cytochrome enzyme for andrographolide synthesis and its application, belonging to the field of bioengineering. The present disclosure uses Saccharomyces cerevisiae CEN.PK2-1D as a host, and implements knockout of ROX1 and GAL80 genes on the genome, and integrative expression of GGPP synthase encoding gene and CPS diterpene synthase encoding gene at ROX1 site; and implements free expression of ApCPR and CYP71A8 and CYP71D10 both with truncated signal peptides, successfully constructing recombinant S. cerevisiae, and achieving de novo synthesis of 3,15,19-Trihydroxy-8(17),13-ent-labdadiene-16-oic acid. Compared with the blank, a response value of a product peak reaches 1.9*106, and this strategy provides necessary reference for analyzing biosynthetic pathway of andrographolide and using metabolic engineering to synthesize andrographolide and related derivatives thereof.

The invention provides yellow glue resistant to corrosion of a plasticizer and a preparation method of the yellow glue. The yellow glue is prepared from a polyurethane prepolymer, a chloroprene rubber sheet, methyl methacrylate, benzoyl peroxide, an anti-aging agent, butanone, cyclohexane, dimethyl carbonate and tackifying resin. The polyurethane prepolymer is prepared from the following components in parts by weight: 10 to 14 parts of 1, 4-butanediol adipic acid polyester polyol, 4 to 8 parts of polycaprolactone polyol, 1 to 3 parts of diphenylmethane diisocyanate, 0.05 to 0.15 part of 1, 6-hexanediol, 1 to 2 parts of hydroxyethyl methacrylate, 0.01 to 0.03 part of organic bismuth catalyst and 75 to 80 parts of butanone. The polyurethane prepolymer with specific crystallization performance is synthesized through cooperation of polycaprolactone polyol and polyester polyol, and the yellow glue is endowed with excellent plasticizer corrosion resistance and low-temperature activation capacity. Active groups in the polyurethane prepolymer are subjected to graft copolymerization with the chloroprene rubber adhesive and MMA, and a plasticizer-resistant polyurethane chain segment is introduced into a molecular chain of the chloroprene rubber adhesive, so that a hard segment-soft segment alternating block structure is formed, and corrosion resistance and viscoelasticity are both considered.

The invention provides thermochromic microcapsules, thermochromic silica gel, a preparation method of the thermochromic silica gel and a physiotherapy pad. The thermochromic microcapsule comprises a core material and a wall material coating the outer surface of the core material, and the core material comprises stearic acid, crystal violet lactone and bisphenol fluorene. The wall material is formed by in-situ polymerization of an amino resin prepolymer on the surface of the core material. The bisphenol fluorene has a fluorene ring, and the fluorene ring is of a large-size and flat structure, so that the rigidity of bisphenol fluorene molecules is high. When the amido resin prepolymer is subjected to in-situ polymerization on the surface of the core material to form the wall material, part of bisphenol fluorene molecules can be embedded into a cross-linked network of the amido resin, and the rigid bisphenol fluorene molecules can well limit movement and rotation of amido resin polymer molecular chains; besides, in the polymerization process, bisphenol fluorene molecules can serve as cross-linking points to react with the amino resin prepolymer, different polymer chains are effectively connected, the cross-linking density of the wall material is improved, and the bisphenol fluorene molecules can effectively improve the mechanical strength and hardness of the wall material.

The invention relates to the technical field of cleaning tablets, and provides a multi-effect cleaning tablet for a kitchen waste processor and a preparation method of the multi-effect cleaning tablet. The multi-effect cleaning tablet comprises a foaming cleaning layer, an oxidation sterilization layer and a deep decomposition layer, the foaming cleaning layer is arranged on one side of the oxidation sterilization layer, the deep decomposition layer is arranged on the opposite side of the oxidation sterilization layer, and the foaming cleaning layer comprises sodium bicarbonate, gluconic acid-delta-lactone, alkyl glycoside, limonene and a chelating agent; the oxidation sterilization layer comprises sodium percarbonate, potassium hydrogen peroxysulfate, potassium carbonate, sodium citrate and a stabilizer; the deep decomposition layer comprises biological enzyme. Gluconic acid-delta-lactone is adopted in the foaming cleaning layer of the multi-effect cleaning tablet to generate gluconic acid, so that the system is prevented from instantly and violently turning over, a middle-layer peroxidation system is favorably released at a proper time, invalid decomposition is reduced, strong acid or violent pH fluctuation is prevented from permeating into an inner layer, the enzyme inactivation risk is reduced, the foaming process is mild, and the foaming effect is good. And the integral integrity of the tablet can be maintained.

The application discloses an electrolyte, a preparation method thereof, and a lithium ion battery. The electrolyte comprises a lithium salt, a nonaqueous organic solvent, and a first additive and a second additive. The first additive is selected from one or more of borate esters with ether chain structures, and the second additive is selected from one or more of sulfonic acid lactones. The application introduces the borate esters with ether chain structures and the sulfonic acid lactones as the additives in the electrolyte, so that an excellent composite CEI film is produced on the surface of a positive electrode, and the electrical performance of the lithium ion battery is improved.

The present disclosure discloses a composition for hair growth comprising Larix europea wood extract, Camellia sinesis leaf extract, Pisum sativum sprout extract, Curcuma longa (Turmeric) callus conditioned media, Hamamelis virginiana (Witch Hazel), Rosmarinus officinalis Leaf Oil, Glycerin, Glycine, Zinc Chloride, Sodium Metabisulfite, Gluconolactone, Sodium Benzoate, Calcium Gluconate, Tetrasodium ethylenediaminetetraacetic acid (EDTA), Saccharide Isomerate, Hyaluronic Acid, Hydrolyzed Hyaluronic Acid, Propanediol, Biotinoyl Tripeptide- 1, Alpha Glucosyl Hesperidin, Caffeine, Hydrolyzed Pea Protein, Polyalkylene Glycol Mono Butyl Ether, Acrylates / C 10-30 Alkyl Acrylate Crosspolymer, Panthenol, Niacinamide, Arginine, PEG-40 Hydrogenated Castor Oil, Ethylhexylglycerin, Phenoxyethanol, and water is added to the composition until the desired volume is achieved. A method for preparing the composition for hair growth is also provided.

The application belongs to the technical field of biological medicine, and particularly relates to a lactobacillus paracasei and application thereof. The lactobacillus paracasei ZY101 is preserved in the China General Microbiological Culture Collection Center, has a preservation number of CGMCC No. 32360, a preservation date of October 25, 2024, and an address of No. 3, Beichen West Road, Chaoyang District, Beijing. Compared with a commercial bacillus acidophilus, the apricot vinegar prepared by using the lactobacillus paracasei ZY101 has new substances including linalool, alpha-farnesene, 2-phenylacetic acid ethyl ester and geranylgeraniol, and further promotes the aroma of the apricot vinegar. Compared with the commercial bacillus acidophilus, the existing substances are obviously improved, and specifically include ethyl acetate, isoamyl acetate, ethyl octanoate, ethyl hexanoate, acetoin, methyl palmitate, gamma-deca-lactone, ethyl dodecanoate, delta-deca-lactone, trans-nerolidol and dihydro-beta-ionone.

The invention relates to a halogen-free heavy oil removal surfactant and a preparation method thereof, and belongs to the technical field of surfactants. The heavy oil removal surfactant is prepared from fatty alcohol-polyoxyethylene ether, hydrophilic alkyl quaternary ammonium salt, a glycosyl nonionic surfactant and an alcohol compound, the glycosyl nonionic surfactant is prepared by sequentially carrying out hydrophobic amidation and hydrophobic epoxy addition on lactobionic acid lactone; the heavy oil removal surfactant is good in oil removal effect, safe, free of halogen and small in corrosivity, and the use performance is improved through compound use of the fatty alcohol-polyoxyethylene ether, the hydrophilic alkyl quaternary ammonium salt and the glycosyl nonionic surfactant.

The invention discloses a process method for co-production of caprolactone and 2, 4-dimethyl benzoic acid. According to the method, cyclohexanone is taken as a raw material, oxygen is introduced as an oxidant, 2, 4-dimethyl benzaldehyde is added as a pro-oxidant, and caprolactone and 2, 4-dimethyl benzoic acid are generated through oxidation reaction. According to the technological method, oxygen and 2, 4-dimethyl benzaldehyde are used as a co-oxidation system, in the presence of the carbon framework material loaded Ti-based catalyst, cyclohexanone can be subjected to oxidation reaction under mild conditions to generate caprolactone, the reaction is safe and efficient, the selectivity of the product caprolactone and the co-product 2, 4-dimethyl benzoic acid is high, the raw material conversion rate is high, and the method is suitable for industrial production. The product yield can be obviously improved, and the economic applicability is good.

The invention discloses a composition for relieving, repairing and promoting skin regeneration as well as a preparation method and application of the composition. The composition is prepared from the following raw materials in parts by weight: 0.1 to 5 parts of mandelic acid, 0.5 to 10 parts of a cynanchum atratum extract, 1 to 8 parts of a xylitol compound, 0.5 to 15 parts of regenerated silicon, 1 to 10 parts of a starfish regeneration repair factor, 0.3 to 1.5 parts of trimethylolpropane tri (3-mercaptopropionic acid) ester, 0.05 to 0.5 part of calcium chloride, 0.1 to 1 part of an additive, 0.2 to 2 parts of chitosan-polycaprolactone, 0.2 to 1 part of a pH regulator and 5 to 15 parts of a solvent. 0.3 to 0.8 part of an antioxidant and 3 to 10 parts of a humectant; the additive is hyaluronic acid or formylated hyaluronic acid. Through a multi-channel synergistic effect, the effects of relieving, repairing and promoting skin regeneration are improved.

The invention belongs to the technical field of high polymer materials, and discloses a polyester-based chemically recyclable crosslinked elastomer and a preparation method thereof. According to the chemically recyclable cross-linked elastomer, an aliphatic lactone monomer and a furyl substituted lactone monomer are subjected to a copolymerization reaction under the action of a catalyst to form a copolyester prepolymer, and the prepolymer further reacts with a cross-linking agent containing complementary dynamic bonds through a furyl side group of the prepolymer to form a reversible cross-linked network. The cross-linked network can simultaneously realize controllable dissociation of dynamic covalent bonds and selective degradation of a polyester main chain under thermal or chemical stimulation, so that an original monomer is efficiently recovered. The cross-linked elastomer provided by the invention has the advantages of excellent mechanical properties, good heat resistance, capability of closed-loop chemical circulation and the like.

This invention discloses a denitrification biological carrier, its preparation method, and its application. The raw materials for preparing the denitrification biological carrier include an iron agent, modified activated carbon, polycaprolactone, sodium dodecyl sulfate, and a hydrogel binder. The modified activated carbon is 3-chloro-2-hydroxypropyltrimethylammonium chloride-modified activated carbon. The iron agent not only removes dissolved oxygen from water but also reduces total nitrogen in wastewater. The modified activated carbon improves its adsorption affinity for nitrogen-containing compounds. Polycaprolactone serves as a slow-release carbon source for denitrification, exhibiting high carbon source utilization. Sodium dodecyl sulfate, through its foaming properties, together with the modified activated carbon, iron agent, and polycaprolactone, forms a high-mechanical-strength, rough, and porous biological carrier structure, providing excellent attachment conditions for heterotrophic denitrifying bacteria. Therefore, applying the denitrification biological carrier of this invention to wastewater treatment systems can achieve good nitrogen removal efficiency and economic benefits.

The present invention discloses a method for producing perillaldehyde and / or perillyl lactone, comprising: contacting a first component with a second component to produce perillaldehyde and / or perillyl lactone; wherein the first component is selected from components containing lysine-2-diol, and the second component is selected from enzymes or microorganisms or their cell lysates or enzyme extracts capable of converting lysine-2-diol into perillaldehyde and / or perillyl lactone.

The invention belongs to the field of microbial fermentation and the technical field of daily chemicals, and particularly relates to deacetylated sophorolipid as well as a preparation method and application thereof. By using cheap culture medium components and screening out saccharomycetes with high yield of lactone type sophorolipid, the problem that the production cost of the sophorolipid is too high is effectively solved, and the application of the sophorolipid in various fields is promoted; through the step of carrying out enzymolysis on a fermentation substrate in advance, the problems of long single fermentation period, low thallus utilization rate, high energy consumption and high cost of traditional saccharomycetes are solved. A multi-round fermentation circulation system is designed, and bacteria liquid is settled and recycled and then inoculated and fermented, so that thalli are efficiently and repeatedly utilized, the unit yield is increased, the fermentation period is shortened, and the production cost is effectively controlled. The structure is adjusted through a resin modification technology, a final product mainly comprises acetylated sophorolipid, and compared with acetylated sophorolipid and deacetylated sophorolipid, the sophorolipid has better foam stability and sensitive skin repairing effect and is suitable for the application fields of cosmetics, washing care and the like.

This invention provides a method for preparing chiral epoxy compounds, chiral β-lactones, and polyhydroxyalkanoates. The method involves three steps: chiral resolution of the epoxy compound, carbonylation of the chiral epoxy compound to prepare a chiral β-lactone, and ring-opening polymerization of the β-lactone. Using this method, polyhydroxyalkanoates with good tensile strength and toughness, as well as a wide processing window, can be prepared. This invention has advantages such as simple steps, low raw material costs, and no need to introduce a second monomer, making it easy to scale up production.