341 results about "Biodegradable polyester" patented technology

The invention relates to the technical field of high polymer material preparation, and discloses a bamboo fiber graft modified full-biodegradable composite membrane material preparation process which comprises the following steps: firstly, performing hot mixing and cooling on dried bamboo fiber powder, anhydrous citric acid, choline chloride, activated zinc oxide and pentaerythritol to prepare a bamboo fiber modified premix; then mixing the biodegradable polyester resin with the premix; adding the mixture into an extruder, injecting epoxidized soybean oil into a barrel through a liquid metering device, and performing melt extrusion granulation under a vacuum exhaust condition; and finally carrying out blow molding to form the film. Through in-situ reaction extrusion of multi-component synergism, surface grafting of bamboo fibers, chain extension of a polyester matrix and interface chemical bonding of the bamboo fibers and the polyester matrix are achieved, interface compatibility is effectively improved, degradation of the material in the processing process is inhibited, and the mechanical property and thermal stability of the composite film material are remarkably improved; the process is efficient and environment-friendly, and the cost is controllable.

The recycled bis(4-hydroxybutyl) terephthalate according to one embodiment has a low amount of residual ethylene glycol derivatives and can therefore be used as a polymerization raw material for high crystallinity engineering polyester products or biodegradable polyesters, offering superior qualities, for example, color.

The invention belongs to the technical field of plastic processing, and particularly relates to a hydrophobic solvent-resistant biodegradable polyester material as well as a preparation method and application thereof in plastic bottles. The preparation method of the hydrophobic solvent-resistant biodegradable polyester material comprises the following steps: reacting polyol glycidyl ether with acrylic acid to prepare polyol glycidyl ether acrylate; the preparation method comprises the following steps: reacting isophthalic dihydrazide with polyol glycidyl ether acrylate to prepare a modifier; pBAT reacts with a modifier and an acrylic acid fluorine monomer to obtain the hydrophobic solvent-resistant biodegradable polyester material. The hydrophobic solvent-resistant biodegradable polyester material adopts PBAT as matrix resin, has biodegradability, has good hydrophobicity and solvent resistance through modification treatment of the modifier and the acrylic acid fluorine monomer, and can be applied to manufacturing of plastic bottles.

The invention relates to a biodegradable composition and a preparation method thereof, belongs to the technical field of degradable materials, and aims to overcome the defects of the traditional biodegradable material in the aspects of tensile strength, edge sealing strength and puncture strength. The composition comprises flexible biodegradable polyester, polylactic acid and inorganic filler, the flexible biodegradable polyester has a specific melting point, melting range and Mz / Mw, the polylactic acid has a certain D-lactic acid unit content so as to achieve high tensile strength, edge sealing strength and puncture strength, and the composition is suitable for preparing full-biodegradable film bags and packaging bags. Comprising food packaging bags, agricultural films and disposable articles, and has excellent biodegradability and mechanical properties.

The invention relates to a multilayer packaging material with high barrier property and application thereof. The multi-layer packaging material at least comprises three layers, namely a layer A, a layer B and a layer C, wherein the layer B is located between the layer A and the layer C; the layer A is prepared from the following raw materials: first biodegradable polyurethane and a cellulose nanocrystal graft which is obtained by performing grafting treatment on cellulose nanocrystal after hydrophobic modification, and the content of the cellulose nanocrystal graft is 1wt%-10wt% of that of the first biodegradable polyurethane; the raw material of the layer B comprises biodegradable polyester containing a glycollic acid structural unit, and the content of the glycollic acid structural unit is not less than 60% mol; the raw material of the layer C comprises second biodegradable polyurethane. The hydrophobic modified cellulose nanocrystals are uniformly dispersed in the layer A, so that the adsorption of water vapor on the layer A is reduced, the permeation of the water vapor is hindered, and the barrier property of the whole material is improved.

The invention encompasses compositions of biodegradable polyester elastomers and biodegradable thermoplastic polyesters with enhanced compatibility using compostable compatibilizing agents. The compositions can be used for melt processing purposes such as extrusion, batch mixing, injection molding, and compression molding. In various embodiments, the compositions encompass polymer blends comprised of at least one biodegradable polyester elastomer, one biodegradable thermoplastic polyester, and one compostable compatibilizing agent. The invention allows for tailored compatibility of the composition through direct compounding of the biodegradable polyester elastomer, the biodegradable thermoplastic polyester, and the compostable compatibilizing agent.

The invention discloses a biodegradable polyester material as well as a preparation method and application thereof, and belongs to the technical field of high polymer materials. The biodegradable polyester material provided by the invention is prepared from the following components in parts by mass: 78 to 97 parts of biodegradable polyester composition, 3 to 22 parts of surface modified calcium carbonate, 0.05 to 0.55 part of chain extender and 0 to 1 part of processing aid, the biodegradable polyester composition comprises PBAT (poly (butylene adipate-co-terephthalate)), PLA (polylactic acid) and PPC (polypropylene carbonate), wherein the mass ratio of the PBAT to the PLA to the PPC is (80-90): (1-10): (1-10); the melt index of the PBAT at 190 DEG C / 2.16 kg is less than or equal to 10 g / 10 min; the molar content of D-lactic acid in the PLA is greater than or equal to 2%; the D50 particle size of the surface modified calcium carbonate is less than or equal to 2.2 microns. The biodegradable polyester material provided by the invention has excellent delayed edge sealing performance and puncture strength.

The invention discloses high-strength and high-toughness carbon dioxide-based biodegradable polyester-polycarbonate and a preparation method thereof. The carbon dioxide-based polyester-polycarbonate composite material is prepared from 90 to 98 percent of carbon dioxide-based polyester-polycarbonate and 2 to 10 percent of a carbon dioxide-based polycarbonate or polyester-polycarbonate hard-soft-hard triblock structure elastomer. The hard segments at the two ends of the elastomer are a polycarbonate chain segment and a polyester chain segment containing rigid groups respectively, so that the elastomer has high glass transition temperature and good compatibility, and the situation that the two phases are incompatible is avoided; soft segments in the two elastomers are polycarbonate chain segments containing long-chain branches, and the soft segments have very low glass transition temperature, so that the effects of buffering stress and toughening are achieved. The special hard-soft-hard three-block structure elastomer is used as a toughening modifier, high-strength and high-toughness carbon dioxide-based biodegradable polyester-polycarbonate can be prepared, and good tensile strength and light transmittance are still kept while the toughness and the processing performance of the material are effectively improved.

The invention relates to the technical field of foaming, and discloses a multi-layer co-extrusion foaming buffer cotton continuous production forming process which comprises the following steps: pretreating raw materials, respectively placing polyolefin resin, biodegradable polyester and foaming agent master batch in a vacuum drying oven, drying at 60 + / -5 DEG C for 2-4 hours, controlling the water content to be less than 0.1 wt%, melting and co-extruding to obtain the multi-layer co-extrusion foaming buffer cotton. When multi-layer co-extrusion synchronous foaming is carried out, by establishing a melt pressure dynamic threshold standard and setting differential pressure control parameters for different functional layers, the stability of interface bonding of all co-extrusion layers is guaranteed, and meanwhile, melt pressure fluctuation in the supercritical fluid injection process is subjected to feedback analysis in real time; according to the method, whether the problem of abnormal fluctuation of melt pressure occurs on a co-extrusion layer interface or not can be detected in real time, the structural integrity of interlayer bonding is guaranteed, the risk of cell collapse is further reduced, and when foaming ratio mismatch is detected, temperature field distribution can be adjusted in real time according to preset gradient foaming parameters.

Disclosed are biodegradable polyesters. Methods for their production and adhesives prepared therefrom. The polyesters comprise a plurality of adducts of two dicarboxylates or anhydrides with a compound having at least two fused ring heterocycles containing a heteroatom and a hydroxyl group pendant from each ring, the adducts are linked by the residues of one or more diols of alkylene diols or polyoxyalkylene diols and a plurality of one or more aliphatic diols containing a pendant carboxylate group. Ester groups are formed by reaction of the hydroxyl groups of the fused ring compounds and the diols with the carboxylate groups of the dicarboxylates and the composition contains pendant carboxylate groups, wherein the composition contains two dicarboxylates, a first dicarboxylate or an anhydride containing between the carboxylate or carboxyl groups a C1-8 hydrocarbylene group and a second dicarboxylate containing between the carboxylate groups a C9-60 hydrocarbylene group.

The invention discloses an isosorbide-based heat-resistant yellowing-resistant biodegradable polyester and a preparation method thereof.The preparation method comprises the following steps that under the condition of an esterification catalyst, dibasic acid and dihydric alcohol are subjected to an esterification reaction, the dibasic acid is composed of terephthalic acid and 1, 1-cyclohexanedicarboxylic acid, and the dihydric alcohol is composed of 1, 1-cyclohexanedicarboxylic acid; the dihydric alcohol is composed of isosorbide and aliphatic dihydric alcohol; after the esterification reaction is finished, adding a polycondensation catalyst, a stabilizer and a toner into an esterification reaction product to carry out polycondensation reaction; after the polycondensation reaction is finished, the polycondensation product is subjected to bracing and grain-sized dicing, and the isosorbide-based heat-resistant and yellowing-resistant biodegradable polyester is obtained. 1, 1-cyclohexanedicarboxylic acid is introduced to replace part of terephthalic acid, aromatic ring structures on polyester chains are reduced, the yellowing resistance of polyester is improved, meanwhile, biomass-sourced isosorbide is added as a heat-resistant modified component, and the isosorbide-based heat-resistant and yellowing-resistant biodegradable polyester is obtained through a direct esterification method.

Disclosed are biodegradable polyesters prepared from bio sourced materials and methods for their production. The polyesters comprise a plurality of adducts of two dicarboxylates or anhydrides with a compound having at least two fused ring heterocycles wherein each heterocycle contains a heteroatom of oxygen or sulfur and at least one hydroxyl group pendant from each ring. wherein the plurality of adducts are linked by a plurality of residues of one or more diols of alkylene diols or polyoxyalkylene diols and a plurality of one or more aliphatic diols containing a pendant carboxylate group wherein ester groups are formed by reaction of the hydroxyl groups of the fused ring compounds and the diols with the carboxylate groups of the dicarboxylates and the composition contains pendant carboxylate groups.

The invention encompasses compositions of biodegradable polyester elastomers and biodegradable thermoplastic polyesters with enhanced compatibility using compostable compatibilizing agents. The compositions can be used for melt processing purposes such as extrusion, batch mixing, injection molding, and compression molding. In various embodiments, the compositions encompass polymer blends comprised of at least one biodegradable polyester elastomer, one biodegradable thermoplastic polyester, and one compostable compatibilizing agent. The invention allows for tailored compatibility of the composition through direct compounding of the biodegradable polyester elastomer, the biodegradable thermoplastic polyester, and the compostable compatibilizing agent.

The invention belongs to the technical field of high polymer materials, and particularly relates to a polylactic acid blended composite material applied to automotive interiors and a preparation method thereof. The raw material of the material is polylactic acid modified ionomer or polylactic acid modified copolymer; a biodegradable polyester or elastomer; a chain extender; an anti-hydrolysis agent; an antioxidant; a nucleating agent; and a lubricant. The preparation method comprises the following steps: carrying out vacuum drying on the polylactic acid ionomer or the polylactic acid modified copolymer and the biodegradable polyester or the elastomer; uniformly mixing the dried polylactic acid ionomer or polylactic acid modified copolymer, biodegradable polyester or elastomer, a chain extender, an antioxidant and a lubricant to obtain a mixture; melting, blending and extruding the mixture; water in the material is pumped out at the tail end of an extruder in a vacuumizing mode, and the polylactic acid blending composite material is obtained after the procedures of water cooling, grain-sized dicing and drying. The material disclosed by the invention has excellent characteristics of high rigidity, high toughness, heat resistance, ultraviolet resistance, antibacterial property and the like, and can be applied to the field of automotive upholstery.

The invention discloses a paper-based molded coffee capsule capable of being naturally composted, a PHA aqueous dispersion in-situ film forming barrier heat-sealing composite layer, a preparation method and application thereof, and belongs to the field of degradable packaging and single-cup extraction capsules. The capsule body is formed by molding paper pulp and is provided with a side wall, a bottom wall and a mouth flange; the biodegradable polyester-based film sealing component is connected to the flange in a sealing manner; and the polyhydroxyalkanoate barrier heat-sealing composite layer covers the inner surface of the body and the sealing surface of the flange. The composite layer is obtained by in-situ film forming of a particle size gradient double-layer aqueous dispersion and comprises a permeation anchoring layer located in paper pulp pores and a continuous compact layer located on the outer side in the thickness direction. The flange is a hot-pressing densified area, and a local thickening heat sealing ring is formed on the sealing face of the flange. Through physical anchoring of the small-particle-size components and surface film forming of the large-particle-size components, the moisture and oxygen blocking and interface bonding performance is achieved, and the brewing sealing performance is guaranteed.

The present invention provides a polyester composition comprising a thermoplastic biodegradable polyester and a PBSN polymer. The polyester composition has good biodegradability, mechanical properties and heat resistance. The invention also provides a molded product containing the polyester composition.

The invention relates to the technical field of printing ink, in particular to modified resin for composite printing ink and a preparation method of the modified resin. 12%-18% of a dynamic covalent bond type fluorosiloxane copolymer; 5%-10% of bio-based degradable polyester resin; 3%-6% of TiO2 (at) SiO2 nanoparticles with a core-shell structure; 0.5%-2% of a pH response color changing material; 2%-5% of temperature-sensitive shape memory microspheres; 0.1%-0.8% of a light-induced isomerization molecular switch; 1%-3% of a biomimetic mineralization enhancer; 0.8%-1.5% of a gradient dispersing aid; 0.8%-2% of a two-dimensional black phosphorus / silver nanowire heterostructure; 1%-3% of a polydopamine modified boron nitride nanosheet; 5%-15% of epoxy functionalized organic silicone oil; 1%-4% of a photoinitiator; 0.5%-2% of an antioxidant / uvioresistant absorbent; 1%-3% of ceramic micro powder; 5%-15% of a high-performance pigment; 0.5%-2% of an infrared reflective additive; 0.1%-0.5% of a molecular sieve drying agent; 0.5%-2% of a self-repairing microcapsule; 2%-4% of hyperbranched polysilsesquioxane; 1%-3% of an efficient ultraviolet screening agent; and the balance of solvent.

The present invention provides a biodegradable polylactic acid-based polyester foamable particles and an injection-molded low-density foamed product and a preparation method. The preparation method of the biodegradable polylactic acid-based polyester foamable particles comprises the following steps: mixing a biodegradable polymer, a biodegradable bead foaming agent and a nucleating agent, and then extruding and granulating to obtain completely biodegradable polylactic acid-based polyester foamable particles. The preparation method of the injection-molded low-density foamed product comprises the following steps: heating and melting the biodegradable polylactic acid-based polyester foamable particles and then injecting them into a mold, maintaining the pressure for a period of time after the injection is completed, and then opening the mold to obtain a polylactic acid-based polyester injection-molded low-density foamed product. The present invention solves the problem that biodegradable polyesters such as ordinary polylactic acid are not easy to foam due to low viscosity. The provided polylactic acid-based polyester injection-molded low-density foamed product is completely biodegradable and has good machinability and basic impact resistance.

The invention relates to the technical field of fibers, and discloses an easily biodegradable polyester-nylon composite fiber and a preparation process thereof.The preparation method comprises the steps that 2-(2-acrylamido ethyl formate) benzoic acid is subjected to graft modification to obtain modified polylactic acid, and the modified polylactic acid, polyethylene glycol terephthalate PET and nylon 66 resin are subjected to blending melt spinning to obtain the polyester-nylon composite fiber. The modified polylactic acid improves the compatibility between the PET and the nylon 66 resin, so that the polyester-nylon composite fiber has higher mechanical properties, and the tensile strength and the elongation at break are obviously improved. The polylactic acid has better biodegradability, and the introduced ester group also has biodegradability, so that the biological decomposition rate of the fiber is improved. The modified polylactic acid contains a large amount of hydrophilic carboxyl and amido bonds, so that the moisture regain of the composite fiber is improved, and the modified polylactic acid can be better applied to hydrophilic moisture absorption fiber textiles.

The invention discloses a curcumin-containing polyurethane hydrogel for promoting healing of scalded wounds. The hydrogel is prepared by a one-step method under the condition of no solvent and no catalyst. The raw materials comprise biodegradable polyester polyol, polyethylene glycol, bio-based diisocyanate, an acidic response chain extender, a zwitterionic chain extender, curcumin, a biodegradable cross-linking agent and a notoginsenoside aqueous solution. The hydrogel disclosed by the invention has the effect of promoting healing of scalded wounds; in a hemostasis stage, the hydrogel can quickly stop bleeding and construct a physical barrier; in the inflammation stage, the quaternary ammonium salt in the hydrogel and the physically loaded curcumin have a synergistic effect to effectively kill bacteria; in wound remodeling and hyperplasia stages, notoginsenoside slowly released by the hydrogel can regulate inflammatory response, improve collagen deposition and promote granulation tissue hyperplasia and neovascularization. The hydrogel has good biocompatibility, controllable degradation performance and multifunctional biological activity, and can be used as an efficient special dressing for scalded wounds.

The application discloses a paper-based moulded coffee capsule capable of natural composting, a PHA aqueous dispersion in-situ film-forming barrier heat-sealing composite layer and a preparation method and application thereof, and belongs to the field of degradable packaging and single-cup extraction capsules. The capsule comprises a capsule body formed by moulded paper pulp, a side wall, a bottom wall and a mouth flange, a biodegradable polyester-based film sealing member sealed to the flange, and a polyhydroxyalkanoate barrier heat-sealing composite layer coated on the inner surface of the body and the sealing surface of the flange. The composite layer is obtained by in-situ film-forming of a particle size gradient double-layer aqueous dispersion, and comprises an infiltration anchoring layer located in the pores of the paper pulp and a continuous dense layer on the outside along the thickness direction. The flange is a heat-pressed densification area, and a locally thickened heat-sealing ring is formed on the sealing surface of the flange. The application realizes the moisture and oxygen barrier and interface bonding performance through physical anchoring of small particle size components and surface film-forming of large particle size components, and guarantees the brewing sealing performance.

The invention relates to a biodegradable composition with low tape casting precipitation as well as a preparation method and application of the biodegradable composition. The biodegradable composition with low tape casting precipitation is prepared from the following components in parts by weight: 69 to 91 parts of polylactic acid, 0 to 16 parts of flexible biodegradable polyester, 0 to 11 parts of filler, 0.1 to 3.1 parts of anti-precipitation agent and 0.1 to 3.1 parts of phosphite ester antioxidant. The anti-precipitation agent and the phosphite antioxidant are added into the biodegradable composition taking polylactic acid as a main body, so that the problem of tape casting precipitation of the biodegradable composition is effectively solved.

For manufacturing household composting products, Based on the total weight of polylactic acid a) and aliphatic-aromatic biodegradable polyester b), 10 to 85% by weight of at least one polylactic acid a), Based on the total weight of polylactic acid a) and aliphatic-aromatic biodegradable polyester b), 15 to 90% by weight of at least one biodegradable aliphatic-aromatic polyester and Use of polymer compositions containing the above.

The present invention provides a microcapsule composition comprising at least one core-shell microcapsule, wherein the at least one core-shell microcapsule comprises a core comprising at least one benefit agent and a shell surrounding the core, wherein the shell comprises a resin formed by the reaction of: 5 - a Michael acceptor which is the reaction product of a biodegradable polyester polyol with an α,β-unsaturated acid chloride; and - a Michael donor comprising at least two nucleophilic moieties selected from the group consisting of a nitrogen nucleophile, a sulfur nucleophile, an oxygen nucleophile, a carbon nucleophile, a phosphorus nucleophile, and mixtures thereof, which are capable to react with the 10 acrylic double bond of the Michael acceptor. The invention also relates to consumer products comprising the microcapsule composition, a method for preparing the microcapsule composition and to the use of the microcapsule composition to enhance the performance of a benefit agent in a consumer product.

Embodiments provide a biodegradable polyester resin composition comprising: a polyester resin comprising a diol, an aromatic dicarboxylic acid, and an aliphatic dicarboxylic acid; and a fiber-based reinforcing material wherein the first turbidity change rate of the fiber-based reinforcing material is less than 15%, thereby achieving improved physical properties.

The invention discloses a composite degradation accelerant, a controllable degradation polyester composite material and a preparation method of the controllable degradation polyester composite material. According to the invention, the halloysite-loaded degradation accelerant is used for coating the degradation bacterium spores to form a core-shell structure, so that the composite degradation accelerant is obtained, the thermal stability of the degradation bacterium spores is improved, and the degradation bacterium spores can be subjected to thermal processing with biodegradable polyester; through the synergistic effect of the composite degradation accelerant and the degrading bacteria, the biodegradation rate of the biodegradable material is regulated and controlled; the composite degradation accelerant and biodegradable polyester are blended and compounded, and the degradation rate is regulated and controlled through the design of the load rate and the raw material ratio, so that the problem of poor controllability of the degradation rate of the existing biodegradable material is solved; the production process is simple, and the existing biodegradable polyester modification production line is adopted, so that large-scale industrial production can be realized.

The invention relates to polylactic acid carbon dots as well as a PLA / PVA (polylactic acid / polyvinyl alcohol)-based full-biodegradable polyester composite material and a preservative film thereof. The polylactic acid carbon dots are prepared by a microwave irradiation method, and the full-biodegradable polyester composite material takes PLA as a main base material, PVA as auxiliary resin, food-grade talcum powder as a filler, the polylactic acid carbon dots as a compatilizer, glycerol and stearic acid as lubricants and B215 as an antioxidant. Performing high-speed mixing and stirring to obtain a modified mixture, extruding and pelletizing the modified mixture to obtain a full-biodegradable polyester composite material, and performing film blowing on the polyester composite material to obtain the full-biodegradable preservative film. The polyester composite material prepared by the invention can be biodegraded under a matured compost condition (the test period is 140 days), the biodegradation rate is 91.79%, the relative biodegradation rate is 97.15%, the products are carbon dioxide and water, and inspection items such as the total migration amount and heavy metals meet standard requirements.

The invention belongs to the technical field of biodegradable plastics, and provides a biodegradable film as well as a preparation method and application thereof. The biodegradable film disclosed by the invention is prepared from the following raw materials in 100 parts by weight: 74 to 99.998 parts of biodegradable polyester; 0.001 to 15 parts of gutta-percha; 0-2 parts of a compatilizer; 0.001 to 2 parts of an anti-blocking agent; 0-2 parts of a coupling agent; 0-2 parts of a dispersant; and 0-8 parts of color master batch. The biodegradable polyester is used as a raw material, and the gutta-percha is used as a functional aid, so that the biodegradable film has excellent ultraviolet aging resistance, mechanical property, barrier property and processability; the film mulching safety period of crops can be obviously prolonged, and the method can adapt to different soil conditions and farming operation. The obtained biodegradable film is green and safe in processing and using processes, can be used in the field of agricultural plastic mulching films, and can also be used in the fields of shopping bags, garbage bags, food packaging, vegetable greenhouse films, injection molding plates, injection molding sheets and the like.

The invention provides a controlled release method of a low-additive-amount coal-based quantum carbon dot composite coated slow-release fertilizer, and relates to the technical field of slow-release fertilizers, the controlled release method comprises the following steps: S1, carrying out surface functional modification on coal-based quantum carbon dots, grafting amino and carboxyl on the surfaces of the coal-based quantum carbon dots, and forming molecular-level crosslinking points capable of being subjected to dual crosslinking with inorganic silicon-oxygen bonds and organic ester bonds; s2, sequentially wrapping a basic controlled release shell layer formed by biodegradable polyester and an intelligent response layer embedded with the coal-based quantum carbon dots by taking fertilizer particles as a core through a layer-by-layer spraying and fluidized bed coating process to form a composite coating structure; the coal-based quantum carbon dots subjected to surface functionalization modification serve as molecular-level crosslinking points under the extremely-low addition amount of 0.1-1 wt%, the molecular-level crosslinking points, inorganic silicon-oxygen bonds and organic ester bonds form a double-crosslinking network, the compactness and stability of a coating layer are remarkably improved, and therefore the raw material cost and processing energy consumption are reduced, and green manufacturing is achieved.

Methods of forming compostable polymeric materials and compostable polymeric materials formed through the methods are provided herein. In an embodiment, a method includes blending a biodegradable polymer chosen from a biodegradable polyester, a biodegradable polysaccharide, or combinations thereof, with a polymer-degrading enzyme and a plasticizer to form an intermediate composition. The intermediate composition is gel extruded to form the compostable polymeric material. In an embodiment, a compostable polymeric material is formed by a method comprising the recited steps.