This invention discloses a method for preparing a composite polyanionic
sodium-
ion battery
cathode material, relating to the field of
sodium-
ion battery
cathode material technology, including the following steps: S1, preparing in-situ doped
ferrous sulfate; S2, preparing a
graphene-based dispersion; S3, preparing a modified
ferrous sulfate solution; S4, preparing an NFPP precursor; S5, preparing an NFPP
cathode material. This invention uses stainless steel
pickling waste liquid as
raw material, first reducing it by adding
elemental iron, then dispersing it in a
graphene-based dispersion containing
tannic acid to obtain carbon-coated modified
ferrous sulfate; preparing the NFPP precursor by co-
precipitation; and finally
sintering to obtain a composite polyanionic
sodium-
ion battery
cathode material with high compaction density and better electrochemical performance, thus improving the problems of poor
conductivity, low compaction, low capacity, low rate capability, and high cost of existing NFPP cathode materials.