419 results about "Ammonium metavanadate" patented technology

The invention provides a method for preparing low-chromium low-potassium vanadium oxide by using a sodium vanadium solution, which comprises the following steps: S1) adjusting the pH value of the sodium vanadium solution to 10.5-11.0, and reacting with a chromium removal agent to obtain initial chromium removal slurry; s2) adjusting the pH value of the initial chromium removal slurry to 9.0-9.5, reacting with a silicon removal agent, and carrying out solid-liquid separation to obtain a filtrate; s3) reacting the filtrate with hydrogen peroxide, adding ammonium salt, precipitating vanadium, and performing solid-liquid separation to obtain ammonium metavanadate and primary vanadium precipitation wastewater; s4) adjusting the pH value of the primary vanadium precipitation wastewater to 6-7, reacting with ferrous sulfate, adding a complexing agent, mixing with the sodium vanadium solution, precipitating, and performing solid-liquid separation to obtain ammonium polyvanadate; and oxidizing and calcining the ammonium metavanadate to obtain the low-chromium low-potassium vanadium oxide. According to the method provided by the invention, the low-chromium and low-potassium vanadium oxide is prepared from the sodium vanadium solution, meanwhile, ammonium salt and vanadium in the primary vanadium precipitation wastewater are recycled, and the comprehensive production cost of the vanadium oxide is reduced.

The invention relates to a crystallization method of ammonium metavanadate crystals. The crystallization method comprises the following steps: cooling an ammonium metavanadate concentrated solution to obtain an ammonium metavanadate supersaturated solution; the cooling treatment process comprises the step of adding a crystallization regulating agent into the ammonium metavanadate concentrated solution; sequentially carrying out aging treatment and solid-liquid separation on the ammonium metavanadate supersaturated solution to obtain an ammonium metavanadate solid phase; by adding a crystallization regulating agent in the cooling treatment process, regulating the growth rate and growth direction of ammonium metavanadate crystals, matching with the steps of aging treatment and the like, the crystallization rate of the crystallization method is improved, preferably, the crystallization rate is up to 89.5% or above, and the high-purity ammonium metavanadate product with large grain size and regular morphology is obtained. Wherein the median particle size preferably reaches up to 86.5 microns or above, the purity reaches up to 99.97% or above, and the requirement for high-quality vanadium products at present is met.

The invention provides a method for preparing vanadium pentoxide from iron-containing ammonium metavanadate, which comprises the following steps: S1) mixing iron-containing ammonium metavanadate with water to obtain ammonium metavanadate slurry; s2) mixing the ammonium metavanadate slurry with a complexing agent, adjusting the pH value to 1.5-2.5, carrying out iron dissolving reaction, and carrying out solid-liquid separation to obtain ammonium polyvanadate; 3, ammonium polyvanadate is calcined, and vanadium pentoxide is obtained.According to the method for preparing vanadium pentoxide from iron-containing ammonium metavanadate, the technical thought of acid dissolution-complexing iron removal is provided, the content of iron in vanadium pentoxide is effectively reduced, the process is simple, and the process cost is low.

The invention relates to the technical field of vanadium pentoxide preparation, and particularly discloses a preparation method of high-purity vanadium pentoxide, which comprises the following steps: S1, vanadium slag pretreatment: carrying out microwave activation on vanadium slag, and then carrying out ball milling and roasting to obtain clinker; the sulfuric acid-oxalic acid composite acid and the clinker are mixed and leached, the pH is adjusted after leaching is completed, and vanadium-containing leachate is obtained through filtering; s3, vanadium enrichment: heating the vanadium-containing leachate, adding a sodium carbonate solution while stirring, adjusting the pH value, preserving heat and curing, and then carrying out hot filtration to obtain vanadium-rich filter residues; s4, vanadium purification: mixing the vanadium-rich filter residues with a sodium hydroxide solution, stirring, introducing compressed air while stirring, and carrying out hot filtration after the reaction is finished, so as to obtain vanadium-rich filtrate; and S5, calcining: carrying out two-stage calcining on the ammonium metavanadate precursor to obtain high-purity V2O5. The preparation method is high in vanadium recovery rate, and the purity of the prepared V2O5 is 99% or above.

The invention belongs to the field of hydrometallurgy, and particularly discloses a high-purity vanadium oxide electrode and a preparation method thereof. The method comprises the following steps: pre-treating the alkaline vanadium leaching solution by using an activated aluminum oxide adsorption column to obtain a pre-treated solution; adding a composite impurity removal agent taking modified lignosulfonate as a main agent into the pretreatment liquid for primary impurity removal to obtain primary impurity-removed filtrate; adding a calcium hydroxide suspension and a flocculating agent into the primary impurity-removed filtrate for secondary impurity removal to obtain secondary impurity-removed filtrate; purifying the secondary impurity-removed filtrate by using an ion exchange column to obtain a purified solution; ammonium salt is added into the purified liquid for vanadium precipitation, and ammonium metavanadate crystals are obtained; calcining the ammonium metavanadate crystal to obtain high-purity vanadium pentoxide; and preparing the high-purity vanadium oxide electrode by using the high-purity vanadium pentoxide. According to the scheme, the high-purity vanadium pentoxide is prepared by taking the alkaline vanadium leaching solution as a raw material through a multi-stage deep impurity removal process, and the high-purity vanadium oxide electrode is prepared by taking the alkaline vanadium leaching solution as the raw material.

The invention relates to the field of chemical industry, and discloses a method for preparing high-purity vanadium oxide by purifying ammonium vanadate, which comprises the following steps: adding a carbonate solution into ammonium vanadate, stirring, and heating to 75-95 DEG C to obtain a vanadium-containing return solution; keeping the temperature of the vanadium-containing return solution, and adding a calcium salt impurity removal agent to obtain a vanadium-containing purified solution and first-stage impurity removal slag; oxalate is added into the vanadium-containing purified liquid, the temperature of the vanadium liquid is kept, and deeply-purified vanadium liquid and second-stage impurity removal slag are obtained; cooling the deeply purified vanadium liquid to 5-35 DEG C, stirring and reacting, and then carrying out solid-liquid separation to obtain ammonium metavanadate and secondary vanadium precipitation supernatant; adding pure water into the ammonium metavanadate product, pulping, stirring, and heating to 80-95 DEG C to obtain a secondary return solution; the pH of the secondary return solution is adjusted to 1.6-2.0, the temperature is raised to 95-98 DEG C, and ammonium polyvanadate and a third-section vanadium precipitation supernatant are obtained; and drying the ammonium polyvanadate, raising the temperature to 500-600 DEG C in an oxidizing atmosphere, and carrying out heat preservation and calcination to obtain a vanadium pentoxide product. The method can be used for preparing a high-purity vanadium pentoxide product.

The invention discloses a stone coal vanadium extraction method, and belongs to the technical field of stone coal vanadium extraction, and the method comprises the following steps: crushing stone coal vanadium ore, and simultaneously carrying out microwave irradiation to obtain an activated sample; immersing the activated sample and an oxidizing agent solution into an acid solution, heating and reacting to obtain a suspension, and carrying out solid-liquid separation to obtain a leachate; then, vanadium in the leachate is adsorbed and enriched through ion exchange resin containing quaternary ammonium groups, and an enriched vanadium solution is obtained through desorption with alkali liquor; then adjusting the pH value of the enriched vanadium liquid, adding an impurity removal agent, uniformly stirring, standing, and carrying out solid-liquid separation to obtain a purified liquid; finally, a precipitator is added into the purified liquid, solid-liquid separation is carried out after the reaction is completed, and the ammonium polyvanadate product is obtained.The method not only can remarkably reduce energy consumption, but also can effectively improve the purity of ammonium polyvanadate.

The invention provides a method for preparing high-purity vanadium pentoxide from carbonation leachate. The method comprises the following steps: S1) carrying out silicon removal on the carbonation leachate, and carrying out solid-liquid separation to obtain silicon-removed slag and silicon-removed liquid; s2) mixing the post-silicon-removal liquid with a complexing agent, and reacting to obtain a post-reaction liquid; s3) carrying out vanadium precipitation on the reacted liquid to obtain ammonium metavanadate and vanadium precipitation wastewater; s4) oxidizing and calcining the ammonium metavanadate to obtain high-purity vanadium pentoxide; the complexing agent is selected from one or more of ethylene diamine tetraacetic acid, disodium ethylene diamine tetraacetate and tetrasodium ethylene diamine tetraacetate. According to the method, the leaching solution obtained through the vanadium slag low-calcium roasting-carbonation leaching vanadium extraction technology serves as the raw material, ions such as iron, calcium and magnesium are controlled to enter the vanadium product through complexing, high-purity vanadium pentoxide with the low impurity content is obtained, the technological process is simple, implementation is easy, the cost is low, and the method is one of the methods for preparing high-purity vanadium pentoxide through the carbonation leaching solution.

The invention belongs to the technical field of wet-process vanadium extraction, and particularly relates to a method for preparing ammonium metavanadate from vanadium slag sodium salt leachate, which comprises the following steps: S1, after vanadium slag sodium salt roasting, leaching and impurity removal are performed to obtain vanadium-containing leachate; s2, a chromium removal agent and a silicon removal agent are added into the vanadium-containing leachate, and after chromium and silicon are removed, solid-liquid separation is conducted to obtain a first solution; s3, adding an oxidizing agent into the first solution for oxidation to obtain a second solution; and S4, carrying out ammonium salt vanadium precipitation on the second solution to obtain ammonium metavanadate, and further preparing the ammonium metavanadate into a vanadium product. The method has the advantages of short flow, less auxiliary material consumption, less energy power, less required equipment and facilities, high vanadium yield and low production cost, and is beneficial to promoting the application of vanadium products in the non-steel field.

The invention relates to the technical field of metal recovery and extraction, and discloses a method for recovering metal in a slurry bed residual oil hydrogenation waste catalyst, which comprises the following steps: (1) taking the slurry bed residual oil hydrogenation waste catalyst as a raw material, and introducing water vapor and oxygen while heating to obtain a waste catalyst; (2) mixing the obtained waste catalyst with an alkaline reagent A and water, heating, leaching and filtering to obtain filtrate I; (3) adding an alkaline reagent B into the filtrate I, and adjusting the pH value to 8.0-11.0 to obtain filtrate II; (4) cooling and standing the filtrate II to separate out an ammonium metavanadate solid and obtain a filtrate III; (5) removing the filtrate III by using anion exchange resin to obtain molybdenum-rich filtrate; and (6) adjusting the pH value of the molybdenum-rich filtrate to be acidic, and performing evaporative crystallization to obtain a molybdic acid solid. After the slurry bed residual oil hydrogenation waste catalyst is subjected to high-temperature treatment in the presence of water vapor and oxygen, metal is leached and recovered by adopting alkali liquor, the process is simple, and the recovery rate is high.

The invention discloses a method for preparing high-purity vanadium pentoxide from high-concentration sodium vanadium solution, which comprises the following steps: adjusting the pH value of the high-concentration sodium vanadium solution with acid, sequentially adding an inorganic ammonium salt and an organic ammonium salt, respectively reacting, carrying out solid-liquid separation to obtain vanadium-containing precipitate, dissolving the vanadium-containing precipitate, adding ammonium sulfate to prepare ammonium metavanadate, and filtering to obtain the high-purity vanadium pentoxide. And reducing ammonium metavanadate to prepare vanadium pentoxide. According to the method, introduction of more impurities due to hydrolysis in the vanadium precipitation process of the high-concentration sodium vanadium solution is effectively prevented. The method is simple in technological process, and does not need the procedures of impurity removal, high temperature and the like.

The invention provides a method for closed-loop preparation of high-purity vanadium pentoxide from ammonium metavanadate, and belongs to the technical field of metallurgy. The method comprises the following steps: carrying out acid-process vanadium precipitation on an ammonium metavanadate raw material to obtain ammonium polyvanadate; carrying out alkaline vanadium precipitation on the ammonium polyvanadate to obtain high-purity ammonium metavanadate; and roasting the high-purity ammonium metavanadate to obtain the vanadium pentoxide. The existing method for producing high-purity vanadium pentoxide from ammonium metavanadate mainly adopts a pure alkali method or an acid method for purification, and has the problems of high purification cost, repeated purification, incapability of closed-loop production, low purity and the like, the acid-alkali combined secondary crystallization method is adopted, closed-loop production is realized, the cost is low, no pollution is caused, vanadium pentoxide with the purity of 99.9% can be obtained, the additional value is increased, and the method is suitable for industrial production. And the requirements of high-end vanadium markets are met.

The invention relates to a waste incineration fly ash harmless recycling method based on low temperature, and belongs to the technical field of fly ash harmless treatment.The fly ash harmless recycling method comprises the steps that fly ash, auxiliary materials and a catalyst are evenly mixed, and a mixture is obtained; the auxiliary material comprises phosphate; the catalyst is obtained by reacting a mixed system containing titanyl sulfate, ammonium metavanadate, sodium acetate and sodium isethionate; the mass ratio of titanyl sulfate to ammonium metavanadate to sodium acetate to sodium isethionate is 100: (0.5-3): (5-10): (3-6); and the mixture is subjected to mechanical alloying treatment, extrusion forming granulation and heat treatment, and a harmless recycling product is obtained. By means of the harmless recycling method for the fly ash, fixation of heavy metal and decomposition of dioxin at the low temperature can be achieved, the harmless recycling treatment process is high in efficiency and low in energy consumption, and the obtained harmless recycling product is lasting in heavy metal stabilizing effect, low in dioxin content and low in heavy metal leaching concentration.

The invention discloses a preparation method of 5N specified-grade high-purity vanadium pentoxide, which comprises the following steps: step S1, taking high-purity ammonium metavanadate as a raw material, mixing the raw material with pure water in proportion, heating for dissolving, and cooling to obtain an ammonium metavanadate solution; s2, enabling the ammonium metavanadate solution to pass through a resin column for adsorption, and collecting column passing liquid; s3, carrying out vacuum concentration on the column passing liquid, cooling and crystallizing the obtained concentrated liquid, and carrying out suction filtration to obtain primary crystals; s4, mixing the primary crystal with pure water in proportion, heating, filtering, cooling filtrate, crystallizing, filtering and washing with water to obtain a secondary crystal; step S5, repeating crystallization operation for 1-3 times to obtain recrystallized ammonium metavanadate; and step S6, putting ammonium metavanadate into a porcelain baking tray, putting the porcelain baking tray into a calcining furnace, vacuumizing, calcining and cooling to obtain a 5N specified-grade high-purity vanadium pentoxide product. The method has the characteristics of simple principle, convenience in operation, high reliability and the like, and the purity of vanadium pentoxide is remarkably improved.

The invention belongs to the technical field of building glass and coating materials thereof, and discloses a one-step chemical synthesis method of W-VO2 (M) nano-particles and application of the W-VO2 (M) nano-particles in thermochromic smart windows.The method comprises the steps that firstly, ammonium metavanadate, hydrazine hydrate and ammonium metatungstate serve as raw materials, tungsten-doped M-phase vanadium dioxide nano-particles are chemically synthesized through a one-step hydrothermal method, and the tungsten-doped M-phase vanadium dioxide nano-particles are prepared; the obtained W-VO2 (M) nanoparticles are high in crystallinity, small in particle size (10-40nm), high in purity and low in phase change temperature; then, by taking a polyvinylpyrrolidone material as a parent material, uniformly distributing the W-VO2 (M) nanoparticles in PVP (Polyvinyl Pyrrolidone) to form a uniformly dispersed thin film; according to the application of the W-VO2 (M) nanoparticles in the thermochromic intelligent window, not only can high visible light transmittance be obtained, but also the solar energy regulation and control capability of the W-VO2 (M) nanoparticles can be improved, and the application of the W-VO2 (M) nanoparticles in the fields of the thermochromic intelligent window and radiation refrigeration is further promoted.

The invention discloses a vanadium-doped lithium manganese iron phosphate positive electrode material as well as a preparation method and application thereof. Secondary hydrothermal treatment is adopted, so that the particle size and the size of the material can be obviously controlled, short nanorod particles of lithium manganese iron phosphate grow into nanoparticles with the length smaller than 100 nm and the width smaller than 20 nm in an oriented mode, the diffusion size of Li < + > in the [010] direction is reduced, the diffusion path of Li < + > is shortened, meanwhile, ammonium metavanadate serves as a vanadium source to carry out Fe / Mn site substitution on the lithium manganese iron phosphate positive electrode material, and the lithium manganese iron phosphate positive electrode material is obtained. The preparation method has the advantages of reducing the dissolution behavior of manganese, increasing lattice defects, improving the lattice constant, carrying out double-layer modification of morphology and structure, ensuring the migration rate of Li < + > in the charge-discharge process, and realizing the improvement of the electrochemical performance of the lithium manganese iron phosphate positive electrode material.

The invention relates to a preparation method of oxygen vacancy-containing bismuth vanadate BiVO4-OVs or metal bismuth-loaded bismuth vanadate xBi0 / BiVO4. The preparation method comprises the following steps: weighing bismuth nitrate pentahydrate and ammonium metavanadate according to a molar ratio of bismuth nitrate pentahydrate to ammonium metavanadate of 1: 1 + x; the preparation method comprises the following steps: respectively dissolving bismuth nitrate pentahydrate and ammonium metavanadate in a solvent, fully mixing the bismuth nitrate pentahydrate and the ammonium metavanadate, adjusting the pH value of the solution, placing a reaction system in an environment of 140-180 DEG C for reaction, washing and drying a product, and roasting under the protection of argon to obtain the product. In addition, the invention also discloses an application of the bismuth vanadate BiVO4-OVs containing oxygen vacancies or the bismuth vanadate xBi0 / BiVO4 loaded with metal bismuth as a catalyst in preparation of benzaldehyde by photocatalytic oxygen oxidation of cinnamyl aldehyde. According to the method, the utilization rate of cinnamyl aldehyde can be increased, efficient oxidation can be achieved in the initial stage of reaction, good benzaldehyde selectivity can be achieved, and the adopted catalyst is efficient and non-toxic and has no influence on the naturalness of benzaldehyde.

The invention provides a potassium-magnesium-silicon ternary co-doped sodium vanadium phosphate positive electrode material and a preparation method thereof, and belongs to the technical field of energy materials. The positive electrode material is formed by doping a Na site with K < + > ions, doping a V site with Mg < 2 + > ions and doping a P site with Si < 4 + > ions, and the chemical formula of the positive electrode material is Na < 3.1 > KxV < 2-x > Mgx (PO4) 2.9 (SiO4) 0.1 / C (x = 0.03, 0.05, 0.07); according to the invention, ammonium metavanadate, sodium acetate and ammonium dihydrogen phosphate are used as raw materials, potassium dihydrogen phosphate, magnesium acetate tetrahydrate and tetraethyl silicate are used as doping sources, citric acid monohydrate is used as a chelating agent, and the potassium-magnesium-silicon ternary co-doped sodium vanadium phosphate electrode material is prepared by a solution gel method, so that the electronic conductivity is improved, the rate capability and the cycle stability are improved, and the preparation method is simple and convenient. The preparation method has a good application prospect in sodium ion battery positive electrode materials.

The invention discloses a method for removing chromium in ammonium polyvanadate through reduction precipitation, according to the method, the effect of efficient chromium removal can be achieved only through simple dissolution and chemical precipitation methods, the chromium content of a product is smaller than 300 ppm, and the requirement for the content of impurity elements is avoided; the method is high in chromium removal efficiency, low in energy loss, high in vanadium recovery rate, clean, environmentally friendly and suitable for industrial production; and the prepared high-purity ammonium metavanadate is relatively high in purity and low in impurity element content, and can meet the requirements on the purity of vanadium products in the aspects of electrolyte and aeronautical manufacturing.

The invention discloses a regeneration method of a marine vanadium-titanium denitration catalyst. The regeneration method comprises the following steps: (1) immersing a deactivated catalyst into a diluent of a special cleaning agent for grease for cleaning; (2) carrying out spray cleaning on the catalyst cleaned in the step (1), wherein a spray cleaning solution is water; (3) carrying out acid chemical cleaning on the catalyst cleaned in the step (2) to remove alkali metal harmful substances such as sodium, potassium and the like attached to the catalyst; (4) washing the catalyst cleaned in the step (3) with water; (5) drying the catalyst cleaned in the step (4); (6) the catalyst dried in the step (5) is soaked in an active solution for active reimplantation, and the active solution mainly comprises ammonium paratungstate and ammonium molybdate and further comprises one of ammonium metavanadate and vanadyl oxalate; and (7) draining the catalyst subjected to activity reimplantation in the step (6), and putting the catalyst into a calcining furnace for activity activation. According to the method disclosed by the invention, more than 98% of pollutants such as grease, ash, alkali metal and sulfate can be removed, and the use temperature after regeneration is reduced by 20-60 DEG C compared with the original use temperature.

The invention belongs to the technical field of trichlorosilane purification, and discloses an adsorbent for adsorbing phosphorus impurities in trichlorosilane and a preparation method and application thereof.The preparation method comprises the steps that activated carbon is immersed in a solution containing ammonium metavanadate and oxalic acid, ultrasonic treatment and drying are conducted, and a vanadium oxide / carbon material mixture is obtained; calcining the vanadium oxide / carbon material mixture, and performing reduction treatment to obtain the oxygen vacancy-rich activated carbon loaded vanadium oxide adsorbent. The activated carbon loaded vanadium oxide adsorbent rich in oxygen vacancies is prepared by using a dipping-calcining-reducing method, and phosphorus impurities are adsorbed and removed by using the interaction of the activated carbon loaded vanadium oxide adsorbent and PCl3. The active carbon loaded vanadium oxide adsorbent rich in oxygen vacancies interacts with PCl3, so that trace PCl3 can be efficiently removed.

The invention provides a method for recovering valuable elements from slurry bed catalyst discharged oil residues, and relates to the technical field of solid waste treatment. The method comprises the following steps: sequentially carrying out medium-temperature oxidizing roasting and high-temperature reduction cracking on slurry bed catalyst discharged oil residues to obtain cracking residues; the cracking residues and an alkaline oxidation leaching agent are mixed for leaching, and nickel-containing leaching residues and molybdenum and vanadium-containing leaching liquid are obtained; the leachate containing molybdenum and vanadium is mixed with ammonium salt for vanadium precipitation, and an ammonium metavanadate product and vanadium precipitation tail liquid are obtained; the vanadium precipitation tail liquid and an acid reagent are mixed for neutralization molybdenum precipitation, and crude molybdic acid is obtained; the crude molybdic acid is sequentially subjected to calcination, alkali dissolution, ion exchange impurity removal and neutralization, and a molybdic acid product is obtained. According to the method, the leaching rates of molybdenum, vanadium and nickel can be greatly increased, comprehensive recovery of valuable elements is achieved, the comprehensive recovery rates of molybdenum, vanadium and nickel in the whole process are all larger than 99%, and the product purity is high and meets the quality requirements of corresponding standards.

The invention discloses a molybdenum-manganese composite metal oxide catalyst for efficiently purifying NO2 as well as a preparation method and application of the molybdenum-manganese composite metal oxide catalyst, and relates to the technical field of catalysts. According to the technical scheme, ammonium metavanadate, oxalic acid, ammonium metatungstate and titanium dioxide are mixed to prepare turbid liquid, the turbid liquid is heated in a water bath, stirred and evaporated until the turbid liquid is solidified, and a vanadium-tungsten-titanium composite oxide precursor is prepared after drying and calcination; the preparation method comprises the following steps: dissolving manganese salt and ammonium molybdate in formamide, carrying out ultrasonic treatment to form a uniform solution, mixing the solution with the vanadium-tungsten-titanium composite oxide precursor powder, carrying out heat preservation and stirring, and finally drying and calcining to prepare the molybdenum-manganese metal diatom vanadium-tungsten-titanium composite oxide catalyst. The molybdenum-manganese composite metal oxide catalyst provided by the invention can realize efficient catalytic reduction of NO2 to form N2 and H2O at a low temperature of 200 DEG C, and the conversion rate of NO2 in a temperature interval of 200-400 DEG C is higher than 85%; and meanwhile, the N2 selectivity is kept close to that of a V2O5-WO3 / TiO2 catalyst.

The invention provides a method for short-process all-component echelon recovery of a waste hydrogenation catalyst, and relates to the field of solid waste treatment. The recovery method of the waste hydrogenation catalyst comprises the following steps: roasting the waste hydrogenation catalyst and sodium carbonate to obtain a roasted product; the roasted product is leached with water, and leaching liquid and leaching residues are obtained; extracting the leaching solution by using an extracting agent to obtain a vanadium-molybdenum-containing organic phase, sequentially carrying out reverse extraction treatment on the vanadium-molybdenum-containing organic phase by using a strong alkaline reverse extraction agent and a weak alkaline reverse extraction agent to obtain a vanadium reverse extraction solution and a molybdenum reverse extraction solution, and carrying out vanadium precipitation treatment on the vanadium reverse extraction solution to obtain ammonium metavanadate; acidizing the molybdenum strip liquor to precipitate molybdenum to obtain ammonium molybdate; carrying out sintering treatment on the leaching residues and alkaline substances, leaching obtained calcine with water to obtain water leaching residues and filtrate, and carrying out aluminum precipitation treatment on the filtrate to obtain aluminum hydroxide, aluminum oxide or pseudo-boehmite; and reducing and smelting the water leaching residues to obtain the ferro-nickel alloy. According to the invention, multi-element comprehensive recovery of all components of vanadium, molybdenum, nickel, aluminum and sulfur can be realized, and high-value utilization of all components of the waste hydrogenation catalyst is realized.

The invention relates to a preparation method of an aluminum alloy corrosion-resistant composite coating, and belongs to the technical field of aluminum alloy treatment. The method comprises the following steps: firstly, mixing sodium phosphate, sodium silicate, sodium fluoride, ammonium metavanadate, sodium molybdate and sodium hydroxide according to a specific proportion to prepare a micro-arc oxidation liquid medicine, and carrying out micro-arc oxidation treatment on a pretreated aluminum alloy to form a black micro-arc oxidation coating; then, potassium permanganate and hydrogen peroxide are used for treating the multi-walled carbon nanotubes, zinc elements are introduced into the carbon nanotubes, the carbon nanotubes and the graphene oxide are combined through ball milling treatment, meanwhile, a silane coupling agent KH560 is added, compatibility is further enhanced, and the composite filler is obtained. And the composite filler is mixed with water-based acrylic resin emulsion, water-based polyurethane emulsion and the like to prepare an electrophoretic coating, and the aluminum alloy subjected to micro-arc oxidation is subjected to electrophoretic deposition treatment to obtain the composite coating. The aluminum alloy corrosion-resistant composite coating prepared through the method has excellent absorbance and good corrosion resistance.

The invention discloses a preparation method of an ethane oxidative dehydrogenation supported catalyst. The catalyst is formed by supporting a transition metal oxide on the surface of an M1 catalyst, the preparation method of the M1 catalyst comprises the following steps: dissolving ammonium heptamolybdate tetrahydrate, ammonium metavanadate, telluric acid and a dispersing agent in deionized water to form a mixed solution; and adding an aqueous solution of niobium oxalate into the mixed solution within 15-50 minutes to form a suspension, aging, carrying out hydrothermal crystallization, drying, roasting, and removing the M2 phase to obtain the M1 catalyst. The pore structure and the specific surface area of the molybdenum-vanadium-tellurium-niobium catalyst can be improved by adding a dispersing agent in the preparation process of the M1 catalyst and limiting the time for adding an aqueous solution of niobium oxalate into a mixed solution, and through mutual cooperation of all steps and parameters, the pore structure and the specific surface area of the molybdenum-vanadium-tellurium-niobium catalyst can be improved; and then the transition metal oxide is loaded on the surface of the M1 catalyst for phase interface coupling, and the transition metal oxide and the M1 catalyst cooperate with each other, so that the catalytic performance of the loaded catalyst can be remarkably improved.

The invention relates to the technical field of aqueous zinc ion battery positive electrode materials, in particular to an ammonium vanadate positive electrode material and a preparation method and application thereof. The invention provides a preparation method of an ammonium vanadate positive electrode material, which comprises the following steps: mixing an ammonium metavanadate solution and gas phase growth carbon fibers, sequentially adding cyclodextrin and anhydrous oxalic acid, and carrying out hydrothermal reaction to obtain the ammonium vanadate positive electrode material. The ammonium vanadate positive electrode material prepared by the method disclosed by the invention has excellent cycling stability and rate capability.

The invention provides a chlorine tungsten anion and cation co-doped sodium vanadium phosphate positive electrode material and a preparation method thereof, and belongs to the technical field of energy materials. The positive electrode material is formed by doping V site with W < 4 + > ions and doping (PO4) 3 site with Cl <-> ions, the chemical formula of the positive electrode material is Na < 3-x > V < 2-x > W < x > (PO4) < 3-y > Cl3y / C, x is equal to 0.05, 0.1 and 0.15, and y is equal to 0.09, 0.12 and 0.15; according to the preparation method, ammonium metavanadate, sodium acetate and ammonium dihydrogen phosphate are taken as raw materials, tungsten disulfide and sodium chloride are taken as doping sources, citric acid monohydrate is taken as a chelating agent, and the chlorine tungsten anion and cation co-doped sodium vanadium phosphate electrode material is prepared by a solution gel method, so that the electronic conductivity is improved, and the rate capability and the cycling stability are improved; the preparation method has a good application prospect in sodium ion battery positive electrode materials.

The invention provides a long-circulation high-rate negative electrode material as well as a preparation method and application thereof, and belongs to the technical field of negative electrode materials. Silicon powder, tin powder and graphene are compounded and subjected to carbon coating, a three-dimensional conductive network is constructed, volume expansion is relieved, and conductivity, cycling stability and rate capability are improved; tungsten oxide serves as an interface stabilizer to form a protective layer, side reaction is inhibited, interface impedance is reduced, and a conductive network is enhanced; metaphosphoric acid is decomposed to generate an inorganic phosphate protective film, and nitrogen-doped carbon generated by urea decomposition is combined, so that the interface stability and conductivity are remarkably improved, and the cycle life is remarkably prolonged; lithium carbide reacts with vinylidene fluoride to generate a lithium fluorocarbon additive, and lithium ions are released in stages to reduce the first lithium loss and stabilize an interface; a vanadium-based metal-organic framework prepared from ammonium metavanadate and terephthalic acid is combined with pre-embedded lithium and graphitized carbon coating, so that a lithium ion transmission path is optimized, and the performance of the lithium ion battery is improved. The synergistic modification measures improve the long cycle stability and high rate performance of the negative electrode material.

The present invention provides a method for producing a molybdenum-vanadium-aluminum-chromium alloy with high uniformity. The composition of the molybdenum-vanadium-aluminum-chromium alloy is as follows: Mo 25% - 28%, V 24% - 27%, Cr 28% - 31%, with the balance being Al, O ≤ 0.05%, C ≤ 0.05%, and the segregation of the main content being < 0.6%. It relates to the field of metallurgical technology. The technological steps are as follows: (1) Prepare an ammonium molybdate-ammonium dichromate-ammonium metavanadate precursor by hydrothermal method using sodium molybdate, sodium metavanadate, sodium dichromate, and ammonium chloride; (2) Perform high-temperature treatment on the precursor to obtain a MoO3 / V2O5 / CrO3 composite material; (3) Mix the MoO3 / V2O5 / CrO3 composite material, refined aluminum powder, and calcium oxide in proportion, load them into a furnace and ignite to undergo a thermite reaction to obtain a molybdenum-vanadium-aluminum-chromium alloy ingot. Compared with the molybdenum-vanadium-aluminum-chromium alloy produced by the traditional thermite method, the uniformity of the present invention is greatly improved, and it can be used for the production of titanium alloys such as TB2, TB9, TB15, and TB16.