The invention relates to an in-situ regeneration method of a butylene oxy-
dehydrogenation catalyst, which mainly solves the problems that the in-situ regeneration effect of the butylene oxy-
dehydrogenation catalyst is poor, so that the life of the catalyst is shortened, the conversion rate and yield of reaction are reduced, and the change of the catalyst results in long stopping time of a device and influences the output of the device in the prior art. The method comprises the following steps of: a) stopping feeding of
oxygen-containing gas and then a butylene
raw material, purging the catalyst with 300-500 DEG C
superheated water vapor for 0.2-56h, b) gradually reducing the amount of the
water vapor till the
airspeed of the
water vapor is 500-2000h<-1>,
filling in air till the
molar ratio of the air to the
water vapor is 0.05-0.2, controlling the regeneration temperature at 360-450 DEG C, conducting regeneration of the oxy-
dehydrogenation catalyst, and c) reducing the amount of the vapor, allowing the temperature rise of a
bed to be reduced gradually till the temperature at an inlet and an outlet of the catalyst
bed keeps constant, and accomplishing the technical scheme of
catalyst regeneration. The method solves the problems better, and can be used for industrial production of preparing butadiene through butylene oxy-dehydrogenation.