1818results about "Hydrogen separation using solid contact" patented technology

To provide a system, a method, and an application for carbon recovery system for compact type vessel based on connection between methanol reforming and high-efficiency membrane separation.SOLUTION: Propulsive power is supplied to a vessel by using a methanol aqueous solution as a raw material through steps such as reforming, separation of a reformate product, and hydrogen combustion, hydrogen fuel is manufactured through methanol steam reforming, anxiety about safety of high pressure hydrogen storage in a prior art is eliminated, efficient carbon recovery is carried out by storing separated carbon dioxide by compression and liquefying, heat is supplied for methanol steam reforming and preheating of the fuel by using excess heat of discharged flue gas, and comprehensive use of energy is achieved. Use of hydrogen energy is realized by a vessel without requiring storage and transportation of hydrogen, and a shipping industry contributes to green, low carbon, and sustainable development.SELECTED DRAWING: Figure 1

The invention belongs to the field of hydrogen energy, and particularly relates to a hydrogen purification system with a self-repairing function and a purification method. The product hydrogen is used as the regeneration gas, and when the adsorption effect of the adsorbent is reduced, the product gas in the long pipe vehicle can be directly returned to the PSA system for regeneration operation, so that the problem of system replacement caused by regeneration by using nitrogen is effectively avoided, the problem of replacement after regeneration is avoided, and the production time is shortened.

The invention relates to the technical field of gas purification, in particular to a novel start-up method for a PSA (Pressure Swing Adsorption) hydrogen extraction device, which comprises the following steps: on the basis of the working environment of the PSA hydrogen extraction device, checking before start-up is carried out, nitrogen replacement is carried out, the oxygen content of a hydrogen extraction system is controlled within a preset range, and the pressure of the hydrogen extraction system is reduced to normal pressure; the difference between the current environment data and the standard environment data is analyzed, the valve opening degree and the adsorption pressure are adjusted, the equipment operation parameters are optimized to meet the current environment conditions, and an environment parameter adjusting instruction is obtained. By collecting and analyzing the current environmental data, dynamically adjusting the adsorption pressure and the valve opening and connecting the gas quality monitor to collect and analyze the hydrogen purity in real time, the concentration change of impure substances can be found in time, the adsorption time is optimized according to the data, and it is ensured that the hydrogen purity continuously reaches the high standard; and through continuous monitoring and quality verification of the hydrogen purity of the product, the consistency and reliability of the hydrogen product are guaranteed.

The invention relates to the technical field of hydrogen production equipment, in particular to a hydrogen preparation and purification device and method. According to the hydrogen preparation and purification device, by arranging the deaerator, the pre-drying tower, the first drying tower, the second drying tower, the condenser, the flow regulator, the regeneration gas heater, the regeneration gas condenser and the multiple control valves, heating adsorption and condensation adsorption of hydrogen are achieved, hydrogen consumption is effectively reduced, and the good purification effect of hydrogen is guaranteed; as the hydrogen obtained by water electrolysis is pure and has low impurity content, the process route of removing impurity oxygen by adopting the hydrogen under the catalytic action of the palladium catalyst and then carrying out temperature swing adsorption dehydration by adopting the activated aluminum oxide and molecular sieve composite bed layer is reasonable, the process flow is simple, the energy consumption is low, and for small and medium-sized purification devices, system integration and skid-mounting are easy, and the cost is low. And the method can be widely applied to various industrial fields.

A process to purify helium from a feed gas stream containing a mixture of at least nitrogen, methane and helium including introducing the feed gas stream into a first helium membrane separation unit, thereby producing a first helium membrane permeate and a first helium membrane residue; introducing at least part of the first residue into a first nitrogen membrane separation unit thereby producing a first nitrogen membrane permeate stream; introducing a stream derived from the first helium membrane permeate into a hydrogen PSA unit thereby producing a helium rich product stream. Wherein a stream derived from the first nitrogen membrane permeate stream exits the system as a fuel gas product stream. Wherein the feed gas stream has a higher heating value, and wherein the first nitrogen membrane permeate stream has a higher heating value at least 5% higher than the higher heating value of the feed gas.

The invention relates to the technical field of PSA (Pressure Swing Adsorption) hydrogen extraction, in particular to a hydrogen purification process based on a PSA device, which comprises the following steps: raw material gas is firstly decompressed and enters the PSA device, a product hydrogen after impurity removal is sent to the outside, desorbed gas of the PSA device is pressurized by a desorbed gas compressor and is sent to a first-section shift converter, the raw material gas enters an adsorption tower in an adsorption state, and the desorbed gas enters a second-section shift converter; under the action of a special adsorbent, CO, N2, CH4O, CH4, AR and other components in the raw material gas are adsorbed, and high-purity H2 flows out of the tower top, is subjected to pressure stabilization metering through a regulating valve and then is sent out. According to the hydrogen purification process based on the PSA device, residual impurities can be deeply removed by using two-stage pressure swing adsorption, additionally arranging a two-stage adsorption tower and performing post-treatment detection on hydrogen, the impurity content required by high-purity hydrogen needs to be controlled at a ppm level, the purity of the hydrogen can stably rise to 99.99% or even higher through two-stage PSA, and the purity of the hydrogen is greatly improved. The use standard of ultra-high-purity hydrogen in the production of semiconductors and photovoltaic cells is met, and the process stability and the yield of products are guaranteed.

An integrated energy system comprising a power plant including at least one nuclear reactor and electrical power generation system, the at least one nuclear reactor being configured to generate steam, and the electrical power generation system being configured to generate electricity, a desalination system configured to receive at least a portion of the electricity and steam to produce brine, an electrolysis process configured to process the brine into Sodium Hydroxide (NaOH), a Sodium Formate (HCOONa) production process configured to receive the Sodium Hydroxide (NaOH) to produce Sodium Formate (HCOONa), a Hydrogen (H2) extraction reactor configured to receive the Sodium Formate (HCOONa) and produce Hydrogen (H2), and a fuel cell configured to receive the Hydrogen (H2).

The invention discloses a VPSA hydrogen production device control method and system, and relates to the technical field of hydrogen production machines.The method comprises the steps that methyl alcohol is fed into a cracking device and cracked through a catalyst to generate hydrogen-rich gas, the hydrogen-rich gas is fed into a VPSA decarburization device, and the decarburized hydrogen-rich gas is output; introducing into an adsorption bed I to obtain high-purity hydrogen, performing pulse back flushing on an adsorption bed II by using the high-purity hydrogen, and starting a microwave generator and a vacuum pump to perform desorption; after the adsorption bed II completes desorption, switching the direction of the adsorption bed, and performing the same desorption operation on the adsorption bed I to complete regeneration of the adsorption bed I; acquiring equipment operation data in real time by using a sensor, and dynamically adjusting set data; the adsorption bed I and the adsorption bed II alternately operate, and the operation mode is adjusted in real time. By introducing a comprehensive real-time monitoring and dynamic adjusting mechanism and accurately controlling the alternate operation state of the adsorption bed I and the adsorption bed II, efficient regeneration of the adsorption beds and continuous and stable high-purity hydrogen output are realized.

The invention relates to a method and a system for synthesizing N-methylaniline and co-producing N, N-dimethylaniline by a gas phase method, and belongs to the technical field of chemical engineering. The system comprises a raw material gasification unit, a reaction unit, a separation and rectification unit and a hydrogen recovery unit which are connected through pipelines. The method comprises the following steps of: firstly, mainly synthesizing N-methylaniline from raw materials aniline and part of methanol in a first-methylaniline reactor, then partially or completely feeding first-methylaniline reaction gas into a second-methylaniline reactor, adding methanol steam, and further reacting to generate N, N-dimethylaniline. And after the product gas is subjected to heat exchange energy recovery, a liquid phase and a gas phase respectively enter the separation and rectification unit and the hydrogen recovery unit. The purification of N-methylaniline and N, N-dimethylaniline and the recovery of byproduct hydrogen are realized. The yield of N, N-dimethylaniline (in terms of aniline) can be adjusted in a range of 5-30% by adjusting reaction conditions and a feeding ratio.

The invention, which relates to the technical field of energy management and control, discloses an energy management and control system for wind-solar complementary hydrogen production, comprising an information acquisition module, a demand analysis module, a wind-solar power generation monitoring module, a complementary energy supply module, a stability index analysis module and an influence module. The system has the advantages that the demand analysis module can accurately calculate and distribute the required basic energy based on the starting demand of the hydrogen production equipment, and the wind and light power generation monitoring module can rapidly and preliminarily analyze the energy supply proportion adjustment time according to a preset mechanism, and can timely adjust the time when needed, so that the energy supply efficiency is improved. By means of the complementary energy supply module, wind energy and light energy can work cooperatively, stable electric power is provided for hydrogen production equipment at the optimal proportion according to the actual power generation capacity and the energy storage level of the wind energy and the light energy, the advantage of wind and light complementation is brought into full play, and when any one of wind energy supply equipment and light energy supply equipment goes wrong, the energy supply efficiency is improved. And the hydrogen production equipment can still keep the most basic operation.

The invention discloses a process for preparing ultra-pure hydrogen by recovering and purifying hydrogen. The process comprises the following steps: nitrogen replacement: carrying out three times of pressurization-decompression circulation on an adsorption tower and a pipeline; pretreatment of raw materials: hydrogen-containing tail gas is treated by a buffer tank, a compressor, a desulfurization tower and a horizontal adsorption tower and then enters a PSA (Pressure Swing Adsorption) system; pSA purification: a 6-2-3 / P process is adopted, two towers in six adsorption towers perform adsorption at the same time, and hydrogen larger than or equal to 99.99% is produced; regeneration of the adsorbent is completed through three-stage pressure equalizing and reducing, clockwise / anticlockwise pressure reducing, product hydrogen flushing and three-stage pressure equalizing and boosting; refining by a membrane separation unit: carrying out membrane separation on PSA hydrogen to produce ultrapure hydrogen of which the purity is greater than or equal to 99.999%, and returning trapped gas to a compressor; and condensate water recovery: carrying out steam stripping and deoxygenization on the process condensate liquid, and then taking the process condensate liquid as boiler feed water. The process integrates PSA and membrane separation technologies, realizes efficient and energy-saving ultrapure hydrogen preparation, and is suitable for the fields of green hydrogen energy storage, electronic industry, high-end chemical industry and the like.

The present disclosure relates to a hydrogen purification system and method and a water electrolysis hydrogen production system. The hydrogen purification system includes three dryers, and the three dryers share a regeneration circulation module, which significantly reduces the number of heaters and coolers. Therefore, the manufacturing cost of the system is low. At the same time, a first gas-to-gas heat exchanger is provided in the regeneration circulation system, so that the low-temperature regenerated hydrogen before regeneration and the high-temperature regenerated tail gas after regeneration can exchange heat. On the one hand, this can make full use of the waste heat of the high-temperature regenerated tail gas, and on the other hand, it can significantly reduce the power consumption of subsequent heaters and regeneration coolers. Therefore, the energy consumption of the system is low.

The invention relates to the technical field of gas separation and purification, in particular to a method and system for recycling hydrogen in mixed gas through pressure swing adsorption. The method comprises the following steps: performing multi-layer adsorption impurity removal on mixed gas containing 20-25% of silane, 10-15% of disilane and 60-70% of hydrogen, and cooling to 22-28 DEG C; the mixed gas subjected to primary impurity removal enters a pressure swing adsorption device, and an adsorbent in the adsorption device is modified activated carbon. The system comprises a mixed gas cylinder, a pretreatment unit, a pressure swing adsorption unit and a hydrogen collection unit which are connected in sequence. By adopting the pressure swing adsorption method, the hydrogen recovery rate is remarkably increased and can reach 93%, the purity can reach 99.2% or above, and the strict requirement of high-end industrial production for high-purity hydrogen can be met.

The invention relates to the technical field of energy, in particular to a solar coupling hydrocarbon fuel reforming low-carbon oil displacement system which comprises a solar collecting lens, a gasification cavity, a reaction cavity, a solar heat collector, a condensation cavity, a hydrogen separation assembly and a catalyst. The solar collecting lens is arranged on one side of the solar heat collector; the gasification cavity and the reaction cavity are arranged in the solar heat collector; a hydrogen separation assembly and a catalyst are arranged in the reaction cavity, the gasification cavity is used for gasifying input excessive liquid water and hydrocarbon fuel to obtain gaseous hydrocarbon fuel and excessive water vapor, the gaseous hydrocarbon fuel and the excessive water vapor are subjected to a water vapor reforming reaction under the action of the catalyst, and generated hydrogen is discharged through the hydrogen separation assembly; the remaining carbon dioxide and water vapor are conveyed into a gas injection well to conduct oil displacement on an oil field; the condensation cavity is connected with the mining well. The efficient and environment-friendly device based on hydrocarbon fuel wet reforming directly heats and displaces oil by recovering hydrogen and residual reaction products, so that the energy utilization rate is increased, and carbon dioxide is recovered.

The present disclosure provides systems and methods for hydrogen production as well as apparatuses useful in such systems and methods, including steam generation systems and methods. Hydrogen is produced by reforming of a hydrocarbon in a plurality of reformers to achieve improved reforming efficiency. A CO2 convective reformer (CCR) and an oxygen secondary reformer (OSR) are used in series to convert hydrocarbon and steam to synthesis gas with substantially complete carbon capture. Steam generation is provided along separate pathways to provide separate steam streams of different composition.

The invention relates to the technical field of comprehensive treatment of industrial solid wastes, and particularly discloses a comprehensive utilization method of secondary aluminum ash, which specifically comprises the following steps: deoxidizing the secondary aluminum ash; carrying out hydrolysis treatment on the deoxidized secondary aluminum ash, and carrying out solid-liquid separation to obtain mixed gas, a hydrolysis slurry solid phase and high-salt-alkali ammonia nitrogen hydrolysate; separating and purifying the mixed gas to obtain hydrogen; carrying out at least two times of acid washing treatment and at least one time of alkali washing treatment on the hydrolyzed slurry solid phase to obtain a solid phase product for the concrete admixture; and carrying out ammonia-nitrogen separation on the high-salt-alkali ammonia-nitrogen hydrolysate, and carrying out gradient acidification treatment to obtain aluminum hydroxide and inorganic salt crystals. By implementing the method, high-added-value overall utilization of the secondary aluminum ash can be realized.

The invention discloses a pyrolysis device and method with instantaneous high temperature rise and directional regulation and control, and the method comprises the following steps: putting a pyrolysis substance into a pyrolysis reaction vessel, introducing inert gas into a superheated steam inlet, and emptying air in the pyrolysis device; superheated steam is introduced into the superheated steam inlet, and a pressure regulating valve is regulated to enable the pressure in the tubular furnace to reach the required pressure; and collecting and treating the pyrolysis product at the pyrolysis product outlet. According to the method, the boiling point of the added water vapor is regulated and controlled by controlling the pressure of a reaction section according to a Clausius-Claelong equation, sufficient heat is provided for pyrolysis substances at a high-gasification latent heat speed of the water vapor, short-time efficient pyrolysis is realized, and production of by-products in the process is reduced compared with slow heating.

The invention provides a sulfur-tolerant shift pre-transformation protective agent as well as a preparation method and application thereof, and relates to the technical field of sulfur-tolerant shift. The magnesium aluminate spinel, the nickel aluminate spinel and the activated carbon are used as composite carriers, the cobalt is used as a main conversion active component, the detoxification carriers have good adsorption and removal effects on arsenic compounds and small-particle impurities, the arsenic capacity is large and is not influenced by the content of hydrogen sulfide, the conversion activity of the protective agent is moderate, the temperature rise of a bed layer is controllable, and the conditions of large temperature rise and overtemperature are avoided; the influence of a water-carrying working condition on the catalyst is greatly avoided, and the catalyst is suitable for a pre-shift furnace and a detoxification tank in a sulfur-tolerant shift process.

The invention belongs to the technical field of hydrogen production, and particularly relates to a double-tank metal hydride hydrogen purification device which comprises a first tank body, a second tank body, a primary exhaust pipe, a gas communicating pipe, a first liquid passing bathroom, a second liquid passing bathroom, a circulating liquid bath chamber and a liquid communicating pipe. A first perforated pipe and a first metal hydride are arranged in the first tank body; and a second perforated pipe and a second metal hydride are arranged in the second tank body. The primary exhaust pipe is communicated with the first perforated pipe, and the gas communication pipe is communicated with the primary exhaust pipe and the second perforated pipe. And the first tank body and the second tank body are coated with the first liquid passing bathroom and the second liquid passing bathroom respectively. And the first liquid passing bathroom, the circulating liquid bath chamber, the second liquid passing bathroom and the liquid communicating pipe are communicated in sequence to form a liquid pipeline. Through the design of the circulating liquid bath chamber and the liquid communicating pipe, the hydrogen absorption and heat release process and the hydrogen desorption and heat absorption process are mutually compensated, the heat utilization efficiency is improved, the external heating and cooling requirements are reduced, and the energy consumption in the hydrogen purification process is reduced.

The utility model relates to the technical field of hydrogen drying devices, in particular to a low-pressure, low-dew-point and low-pressure-drop hydrogen drying device which comprises an adsorption tower which comprises a tower A and a tower B, after water is cooled and separated through a regeneration cooler and a regeneration gas-water separator, the hydrogen enters an adsorption tower A through V1 to absorb water and dry to meet the requirement, the hydrogen is discharged out of the tower and passes through V7 to reach a gas using point, a small part of about 20% of gas is divided from dry gas at an outlet and is electrically heated to 180 DEG C, and the gas is sent to a tower B through V6 to regenerate and activate an adsorbent; hydrogen absorbing moisture is discharged from the tower and enters a gas inlet cooler and a gas inlet gas-water separator through a V4, the temperature of the cooled and dehydrated hydrogen is greatly increased after the cooled and dehydrated hydrogen is pressurized by a booster pump, the cooled and dehydrated hydrogen is converged with hydrogen at an inlet and then passes through a regeneration cooler and a regeneration gas-water separator, the cooled and dehydrated hydrogen returns to the adsorption tower A to adsorb moisture, and first-step pressurized reflux drying is completed; and similarly, hydrogen is adsorbed from the tower B, is subjected to split-flow heating regeneration, passes through the tower A, is pressurized and then flows back to the tower B again.

An adsorption system having at least one adsorber retaining a bed of adsorbent material can be configured to provide enhanced purification of fees having relatively low concentrations of hydrogen or helium. Embodiments can utilize an activated carbon layer between at least one upstream layer and at least one downstream layer. The activate carbon layer can include activated carbon can have a pre-selected surface area (SA), bulk density, total open pore volume (TOPV), and / or ratio of TOPV to surface area (TOPV / SA).

A process for producing a hydrogen product where a carbon-containing input, by reforming and water gas shift, is converted into a synthesis gas largely consisting of hydrogen and carbon dioxide, from which a hydrogen fraction and a carbon dioxide fraction are separated, wherein the hydrogen fraction has the composition required for the hydrogen product and the carbon dioxide fraction has a purity which allows delivery thereof as a product or disposal thereof through sequestration. The characterizing feature here is that the synthesis gas consisting largely of hydrogen and carbon dioxide, by means of a first pressure swing adsorber, is fractionated into a carbon dioxide-depleted first PSA high-pressure fraction and a carbon dioxide-enriched first PSA low-pressure fraction, from which, after compression, the carbon dioxide fraction is obtained by cryogenic gas fractionation.

It has been discovered that mixed-alcohol production can utilize the waste tail gas stream from the pressure-swing adsorption section of an industrial hydrogen plant. Some variations provide a process for producing mixed alcohols, comprising: obtaining a tail-gas stream from a methane-to-syngas unit (e.g., a steam methane reforming reactor); compressing the tail-gas stream; separating the tail-gas stream into at least a syngas stream, a CO2-rich stream, and a CH4-rich stream; introducing the syngas stream into a mixed-alcohol reactor operated at effective alcohol synthesis conditions in the presence of an alcohol-synthesis catalyst, thereby generating mixed alcohols; and purifying the mixed alcohols to generate a mixed-alcohol product. Other variations provide a process for producing clean syngas, comprising: obtaining a tail-gas stream from a methane-to-syngas unit; compressing the tail-gas stream; separating the tail-gas stream into at least a syngas stream, a CO2-rich stream, and a CH4-rich stream; and recovering a clean syngas product.

The invention belongs to the technical field of hydrogen purification equipment, and discloses pressure swing adsorption hydrogen purification equipment which comprises an adsorption tower, a gas inlet pipe is fixedly connected to one end of the adsorption tower, a first cavity and a second cavity are formed in the adsorption tower, a partition plate is installed between the first cavity and the second cavity, and the partition plate is rotationally connected with the adsorption tower through a rotating assembly. Adsorbent layers are mounted at the top end and the bottom end of the partition plate, and the two adsorbent layers are arranged in the first cavity and the second cavity correspondingly; the rotating assembly comprises first rotating shafts fixedly mounted on the two sides of the partition plate, one end of one first rotating shaft is fixedly connected with a gear, a mounting plate is arranged on one side of the gear, and during work, the partition plate is driven by the driving assembly to turn over by 180 degrees, so that the positions of the two adsorbent layers in the first cavity and the second cavity are exchanged; and not only can the complexity of operation during replacement of the adsorbent layer be reduced, but also shutdown treatment is not needed, so that continuous and stable operation of the device is ensured.

The invention relates to an external field intelligent regulation and control photocatalytic hydrogen production integrated device and system. The device comprises a Fresnel lens; the double-layer vacuum glass tube comprises an outer-layer glass tube, an inner-layer glass tube and a vacuum layer located between the outer-layer glass tube and the inner-layer glass tube, and the inner-layer glass tube is connected with an external water source and the separation module; the Helmholtz coil comprises two conductor coils, and the two conductor coils are symmetrically arranged at the two ends of the outer-layer glass tube in a sleeving mode and are communicated with an external power source; the photocatalyst is arranged in the inner-layer glass tube and is positioned at a strip-shaped light band of the sunlight focused by the Fresnel lens; the separation module comprises a hydrogen separation membrane and a gas outlet and is used for efficiently separating gas generated by reaction; the Fresnel lens is connected with the double-layer vacuum glass tube through the fixing support and located on the upper side of the double-layer vacuum glass tube. The Helmholtz coil is used for generating a magnetic field to improve the photo-generated charge separation efficiency in the photocatalytic reaction process, so that the hydrogen production efficiency is improved. The efficiency of photocatalytic reaction hydrogen production can be improved through precise regulation and control of an external field.

The invention provides a hydrogen water irrigation coupled carbon dioxide gas fertilizer application system and method, in the system and method, formic acid is used as a raw material to decompose and prepare hydrogen and carbon dioxide, and the decomposed hydrogen and irrigation water are mixed through an aeration head to form hydrogen water for farmland irrigation; the decomposed carbon dioxide is compressed into high-pressure carbon dioxide to be stored in a gas steel cylinder, and the high-pressure carbon dioxide is interlocked with a carbon dioxide gas detector in the greenhouse, so that the concentration of the carbon dioxide in the greenhouse can be supplemented and adjusted in real time, the coupling application of hydrogen water irrigation and carbon dioxide gas fertilizer is realized, and the growth of crops is promoted. The system and the method can reduce the use of chemical fertilizers, reduce environmental pollution and improve the soil structure, and conform to the green agriculture development concept.

Processes and apparatus for low-CO2 emissions methanol production using a high efficiency (>90%) reformer fired with a low-carbon fuel (C:H<0.03) to produce syngas. CO2 is removed from the syngas, and the CO2-lean syngas is fed to a methanol synthesis loop. A purge stream from the methanol synthesis loop is processed to recover a hydrogen-rich stream and a tail gas stream. The hydrogen-rich stream is supplied as fuel to fire the reformer, along with a portion (<10%) of the tail gas, to produce a CO2-lean flue gas (<3 vol %, dry basis). The flue gas is optionally cooled below a dew point to form condensate, which can be collected and removed. The methanol production can have a carbon efficiency of 97% or more, and a CO2 emissions reduction (compared to natural gas firing) of 88% or more.

A hydrogen gas supply apparatus according to one aspect of the present invention includes a compressor configured to compress hydrogen gas and supply the hydrogen gas compressed to a pressure accumulator which accumulates the hydrogen gas, an adsorption column disposed between the discharge port of the compressor and the pressure accumulator, and configured to include an adsorbent for adsorbing impurities in the hydrogen gas discharged from the compressor, and a plurality of valves disposed at the gas inlet / outlet port side of the adsorption column, being at a discharge port side of the compressor, and configured to be able to seal the adsorption column, wherein the space in the adsorption column is sealed using the plurality of valves such that the inside of the adsorption column is maintained to have a high pressure by the hydrogen gas compressed in the case where the compressor is stopped.

The invention relates to the technical field of hydrogen production, in particular to equipment for preparing hydrogen from biomass, a method for preparing hydrogen from biomass and application. The equipment comprises a biomass pretreatment system and a chemical-looping hydrogen production system, wherein the biomass pretreatment system comprises a drying unit, a crushing unit and a granulating unit; the chemical-looping hydrogen production system comprises a biomass hydrogen production reduction reactor, a hydrogen purification device and a dust remover; the dust remover is connected with a regeneration storage tank and an air oxidation reactor; the air oxidation reactor is connected with the biomass hydrogen production reduction reactor; the granulating unit is connected with the biomass hydrogen production reduction reactor; a first heat exchanger is arranged between a synthesis gas outlet of the biomass hydrogen production reduction reactor and the hydrogen purification device, and a water vapor outlet of the first heat exchanger is connected with the biomass hydrogen production reduction reactor; and an oxygen-poor waste gas outlet of the air oxidation reactor is connected with the drying unit. The equipment is simple in structure, waste heat is fully utilized, energy consumption is reduced, hydrogen purity and yield are improved, and carbon dioxide is captured.

The invention relates to the technical field of polycrystalline silicon production, in particular to a metal modified adsorbent as well as a preparation method and application thereof in circulating hydrogen purification. The metal modified adsorbent is obtained by introducing a copper-containing active component, an auxiliary metal component, an oxidation auxiliary component and an ionic liquid on an adsorption carrier, and the number of metal aggregates with the size being 20 nm or above on the metal modified adsorbent is 2.3 * 10 < 6 > / mm < 2 > or below. The composite material has rich surface active sites, metal species on the surface are high in stability and not prone to loss, and the composite material has excellent adsorption performance and long service life, can have extremely high adsorption-oxidation efficiency on phosphorus hydride especially when being applied to the circulating hydrogen purification process in polycrystalline silicon production, and is easy to operate and low in energy consumption.