6408 results about "Gas separation" patented technology

Provided is a gas separation type showerhead for effective energy supply. The gas separation type showerhead includes: a gas supply module to which a first gas and a second gas are separately supplied; a gas separation module in which the supplied first and second gases are separately dispersed; and a gas injection module which is a multi-hollow cathode having a plurality of holes and in which the first and second gases separately dispersed are ionized in the holes to be commonly dispersed.

An electrical current generating system is disclosed that includes a fuel cell operating at a temperature of at least about 250° C. (for example, a molten carbonate fuel cell or a solid oxide fuel cell), a hydrogen gas separation system or oxygen gas delivery system that includes a compressor or pump, and a drive system for the compressor or pump that includes means for recovering energy from at least one of the hydrogen gas separation system, oxygen gas delivery system, or heat of the fuel cell. The drive system could be a gas turbine system. The hydrogen gas separation system or the oxygen gas delivery system may include a pressure swing adsorption module.

Provided herein is a conditioning apparatus that includes a geometrical configuration having an inlet flow deceleration conduit and a cyclonic tube to effectuate both liquid-gas separation and droplet coalescence. The apparatus is typically positioned at the inlet of a separator vessel used for removing water and gas from extracted crude oil containing entrained water and gas. The apparatus promotes droplet coalescence and gas separation for mixed fluids flowing into an existing water and oil separation device.

The invention discloses a method for preparing a precursor for chemical vapor deposition of metallic rhenium and belongs to the technical field of material preparation. According to the method, ReCl5 is made to react in an oxidizing atmosphere, efficient solid-liquid-gas separation is conducted on reactants and products with a sand core filter bulb so that reactants, reaction products and waste gas can be effectively separated, the reaction products ReOCl4 and ReO3Cl are gathered in a collection vessel heated by an oil bath pan at the same time, oxygen introduction is stopped after reaction ends, circulation of inert gases is maintained, a tube furnace is cooled, the oil bath pan is heated at the same time to enable ReO3Cl to volatilize to enter a rectification unit to be collected, ReOCl4 is purified, and then the high-purity precursor ReOCl4 for chemical vapor deposition of metallic rhenium is obtained. By the adoption of the method, reaction efficiency is high, ReOCl4 and ReO3Cl are separated through rectification, and the purity of the product ReOCl4 is improved.

Shaped microporous articles are produced from polyvinylidene fluoride (PVDF) and nucleating agents using thermally induced phase separation (TIPS) processes. The shaped microporous article is oriented in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0. The shaped article may also comprise a diluent, glyceryl triacetate. The shaped microporous article may also have the micropores filled with a sufficient quantity of ion conducting electrolyte to allow the membrane to function as an ion conductive membrane. The method of making a microporous article comprises the steps of melt blending polyvinylidene fluoride, nucleating agent and glyceryl triacetate; forming a shaped article of the mixture; cooling the shaped article to cause crystallization of the polyvinylidene fluoride and phase separation of the polyvinylidene fluoride and glyceryl triacetate; and stretching the shaped article in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0.

Various systems, method and apparatuses are disclosed that include a pressure swing adsorption apparatus coupled to a fuel cell, wherein the fuel cell receives at least a portion of a product gas from the pressure swing adsorption and powers the pressure swing adsorption apparatus. Also disclosed is a portable gas separator that include a housing that houses a rotary pressure swing adsorption apparatus.

Metal-organic framework (MOF)-polymer mixed matrix membranes (MOF-MMMs) have been prepared by dispersing high surface area MOFs (e.g. IRMOF-1) into a polymer matrix (e.g. Matrimid 5218). The MOFs allow the polymer to infiltrate the pores of the MOFs, which improves the interfacial and mechanical properties of the polymer and in turn affects permeability. Pure gas permeation tests show the incorporation of 20 wt-% of IRMOF-1 in Matrimid 5218 polyimide matrix results in 280% improvement in CO2 permeability without a loss of CO2 / CH4 selectivity compared to those of the pure Matrimid 5218 membrane. This type of MOF-MMMs has significantly improved gas separation performance with dramatically high CO2 permeability (>35 barrer) and higher than 29 CO2 / CH4 selectivity at 50° C. under 100 psig pressure, which are attractive candidates for practical gas separation applications such as CO2 removal from natural gas.

An adsorbent material fabricated into a reinforcement-free, self-supported coherent thin sheet and configured for use as a parallel passage contactor element in adsorption / separation applications with gases and liquids is disclosed. The adsorbent sheet material is obtained by enmeshing fine adsorbent particulates in a polymer binder. Particulates include but are not limited to carbon particles, inorganic oxides particles, or ceramic particles, or synthetic polymer resin particles. The adsorbent sheet advantageously contains a large volume percentage of active adsorbent particles. The parallel passage contactor device fabricated from the adsorbent sheet material is characterized by minimal mass transfer resistance and better separation efficiency expressed as height equivalent to a theoretical plate, while it maintains most of the adsorptive properties of the starting particulates, and can be used in gas separation applications with short adsorption cycles, such as rapid pressure swing adsorption, rotary concentrators, rapid electric swing adsorption.

A preparation method of completely peeled oxidation graphene / rubber nanometer composite material adopts combination of emulsion compounding and flocculation processes or combination of emulsion compounding and spraying drying processes. The preparation method retains the phase state structure of the oxidation grapheme / rubber composite emulation in the liquid state and obtains the phase-state structure which is highly dispersed, highly peeled and dispersed in nanometer scale dispersion. Simultaneously, substances capable of acting with generating ionic bond effect or chemical bond effect with an oxidation graphene surface functional group are added into the oxidation graphene / hydrosol to serve as an interface agent, thereby improving interface combination effect of oxidation graphene and rubber. Vulcanized rubber prepared by the composite material of the preparation method through follow-up mixing and vulcanizing has mechanical property such as high tensile strength, stretching stress and tearing strength and is capable of greatly improving abrasion resistance and gas separation performance of the vulcanized rubber. The preparation method is simple, easy, low in cost, apt to industrialization and wide in suitable aspect, saves energy and has better economical and social benefits.

The Portable Renewable Energy System for Enhanced Oil Recovery (“PRESEOR”) is a truck mobile system that reforms biomass into CO2 and hydrogen, following which the gases are separated, with the CO2 sequestered underground for enhanced oil recovery (EOR) and the hydrogen used to generate several megawatts of carbon-free electricity. In contrast to large central power plants that are generally not well-located to support EOR, the small PRESEOR can go directly to the oilfields where it is needed, and do so in a timely manner. The PRESEOR sequesters more biomass-derived carbon than is released by the burning of the oil it yields, thereby producing not only carbon-free electricity but carbon-free oil. Using PRESEOR, over 80 billion barrels of U.S. oil would be made recoverable, without the need to drill new wells in pristine areas.

An inert gas generating system for generating inert gas on a vehicle having a fuel tank and a fuel tank vent. The system includes an inlet for receiving a flow of gas having a nitrogen component and an oxygen component from a gas source, a heat exchanger downstream from the inlet and in fluid communication with the inlet for cooling gas received from the inlet, and a gas separation module downstream from the heat exchanger and in fluid communication with the heat exchanger for separating gas received from the heat exchanger into a nitrogen-enriched gas flow and an oxygen-enriched gas flow. The gas separation module is adapted to deliver nitrogen-enriched gas from the nitrogen-enriched gas flow to the fuel tank without delivering the nitrogen-enriched gas through the fuel tank vent. The gas separation module is also adapted to deliver nitrogen-enriched gas from the nitrogen-enriched gas flow to the fuel tank vent.

PCT No. PCT / JP97 / 00572 Sec. 371 Date Jan. 8, 1998 Sec. 102(e) Date Jan. 8, 1998 PCT Filed Feb. 27, 1997 PCT Pub. No. WO97 / 31990 PCT Pub. Date Sep. 4, 1997This invention provides a method for reclaiming oil from waste plastic in such a way that thermosetting resins and solid foreign matter in the plastic will not pose a problem. This method greatly reduces the burden of presorting the garbage or industrial waste. To achieve this objective when oil is to be reclaimed from a waste plastic containing chlorine compounds, such as vinyl chloride, the plastic must first be stripped of chlorine. Prior to pyrolysis, while being conveyed forward in a continuous stream, the plastic is mixed with heated sand and / or an additive agent to raise its temperature to 250-350 DEG C. This creates a product which is comprised of a mixture of sand and substantially dechlorinated plastic. The product is mixed with heated sand to heat it directly to a temperature of 350-500 DEG C. It is maintained at this temperature until pyrolysis occurs. In order to obtain high-quality oil with a low boiling point, a first gas / liquid separation process separates the product obtained from the aforesaid pyrolysis into liquid high-boiling point oil, gaseous low-boiling point oil and low molecular-weight gases, and recirculates the liquid high-boiling point oil to the pyrolysis process, and a second gas / liquid separation process separates the gaseous low-boiling point oil and low molecular-weight gases into liquid low-boiling point oil and low molecular-weight gases. The first and second gas / liquid separation process are connected in sequence.

Apparatus, methods, and systems for extracting oil or natural gas from a well using a portable coal reformer. In one example, the method may include reforming coal by reaction with water to generate driver gas (comprising carbon dioxide and hydrogen gas), and injecting the driver gas into the well. The driver gas reduces the viscosity and pressurizes the oil to help extract the oil from the oil well. The coal reforming operation may include combusting coal or other combustible material with ambient oxygen to release energy, and heating coal and water with the energy released to a temperature above that required for the coal reforming reaction to proceed, thereby reforming coal and water into driver gas. The driver gas may be purified by filtering out particles and sulfur before injecting into the well. A portion of the hydrogen gas may be separated from the driver gas and used to generate electrical power.

This invention relates to a novel process for sustainable CO2-free production of hydrogen and carbon by thermocatalytic decomposition (or dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and / or water. The process is applicable to any hydrocarbon fuel, including sulfurous fuels. Combination of a catalytic reactor with a gas separation unit allows to produce high purity hydrogen (at least, 99.0 v %) completely free of carbon oxides. In a preferred embodiment, sustainable continuous production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation can be achieved via surface gasification of carbon catalysts by hot combustion gases during catalyst heating. The process can conveniently be integrated with any type of fuel cell.

A gas separation process uses a structured particulate bed of adsorbent coated shapes / particles laid down in the bed in an ordered manner to simulate a monolith by providing longitudinally extensive gas passages by which the gas mixture to be separated can access the adsorbent material along the length of the particles. The particles can be laid down either directly in the bed or in locally structured packages / bundles which themselves are similarly oriented such that the bed particles behave similarly to a monolith but without at least some disadvantages. The adsorbent particles can be formed with a solid, non-porous core with the adsorbent formed as a thin, adherent coating on the exposed exterior surface. Particles may be formed as cylinders / hollow shapes to provide ready access to the adsorbent. The separation may be operated as a kinetic or equilibrium controlled process.

This invention relates to a novel process for sustainable CO2-free production of hydrogen and carbon by thermocatalytic decomposition (or dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and / or water. The process is applicable to any hydrocarbon fuel, including sulfurous fuels. Combination of a catalytic reactor with a gas separation unit allows to produce high purity hydrogen (at least, 99.0 v %) completely free of carbon oxides. In a preferred embodiment, sustainable continuous production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation can be achieved via surface gasification of carbon catalysts by hot combustion gases during catalyst heating. The process can conveniently be integrated with any type of fuel cell.

A process for treating mixtures of organic components, including azeotropic mixtures. The process includes a gas- or liquid-phase membrane separation step in conjunction with a dephlegmation step to treat at least a portion of the permeate vapor from the pervaporation step. The process yields a membrane residue stream, a stream enriched in the more volatile component as the overhead stream from the dephlegmator and a condensate stream enriched in the less volatile component as a bottoms stream from the dephlegmator. Any of these may be the principal product of the process.

The invention discloses a super-hydrophilic and underwater-super-oleophobic oil-water separation mesh membrane, and a preparation method and an application thereof. According to the method, fabric mesh with a specification of 100-300 meshes is subjected to ultrasonic cleaning, and is air-dried under normal temperature; a hydrophilic polymer water-sensitive agent and a cross-linking agent are dissolved in water according to a ratio of 1:9-9:1; the mixture is well mixed by magnetic stirring, such that a solution with a concentration of 1-99% is prepared; nano-sol is prepared with a sol-gel method; the solution and the nano-sol are prepared into a mixed solution with a concentration of 1-99%, and the solution is well dispersed through ultrasonic dispersion; the mesh is soaked in the mixed solution and is vertically lifted, or the mesh is directly sprayed by using a high-pressure spraying gun; and the mesh is bake-dried, such that the super-hydrophilic and underwater-super-oleophobic oil-water separation mesh membrane is obtained. Contact angles of the super-hydrophilic and underwater-super-oleophobic oil-water separation mesh membrane with water and oil in air are both 0 DEG, and the membrane is super-hydrophilic. Under water, the contact angle of the membrane with oil drops is larger than 150 DEG, and the membrane has an oil drop low adhesion characteristic. The mesh membrane provided by the invention can be used in oil-water mixture separation and oil-containing sewage processing.

A description is given of a gas separation device for a physiological fluid, comprising a containing body (6) having at least a first inlet aperture (7) for a physiological fluid, positioned with a tangential direction of access, at least one outlet aperture (9) for the said fluid, spaced apart from the said inlet aperture, and a guide element (17) housed within the said body. The guide element (17) has a continuous active surface (15) designed to contact and guide the said fluid and delimits, together with the containing body (6), a first annular chamber (20) into which the first inlet aperture (7) opens directly.

An electrical current generating system is disclosed that includes a fuel cell operating at a temperature of at least about 250° C. (for example, a molten carbonate fuel cell or a solid oxide fuel cell), a hydrogen gas separation system or oxygen gas delivery system that includes a compressor or pump, and a drive system for the compressor or pump that includes means for recovering energy from at least one of the hydrogen gas separation system, oxygen gas delivery system, or heat of the fuel cell. The drive system could be a gas turbine system. The hydrogen gas separation system or the oxygen gas delivery system may include a pressure swing adsorption module.

In a dual-source organic Rankine cycle (DORC), the condensed and slightly sub-cooled working fluid at near ambient temperature (˜300 K) and at low-side pressure (0.1 to 0.7 MPa) is (1) pumped to high-side pressure (0.5-5 MPa), (2) pre-heated in a low-temperature (LT) recuperator, (3) boiled using a low-grade heat source, (4) super-heated in a high-temperature (HT) recuperator to a temperature close to the expander turbine exhaust temperature using this exhaust vapor enthalpy, (5) further super-heated to the turbine inlet temperature (TIT) using a mid-grade heat source, (6) expanded through a turbine expander to the low-side pressure, (7) cooled through the HT recuperator, (8) cooled through the LT recuperator, (9) mostly liquefied and slightly subcooled in a condenser, and (10) the condensed portion is returned to the pump to repeat this cycle.

A modular and compact adsorbent bed structure is disclosed for use in an adsorption-based gas separation plant. The conventional adsorbent bed in a gas separation plant is replaced with a plurality of modular adsorbent bed units connected to make the adsorbent bed structure. The modular design requires lower fabrication and maintenance costs; is easier to transport; and is easier to load with adsorbent material.

The present invention is an in-situ apparatus for generating carbon dioxide gas at an oil site for use in enhanced oil recovery (EOR). The apparatus includes a steam generator adapted to boil and superheat water to generate a source of superheated steam, as well as a source of essentially pure oxygen. The apparatus also includes a steam reformer adapted to react a carbonaceous material with the superheated steam and the pure oxygen, in an absence of air, to generate a driver gas comprising primarily carbon dioxide gas and hydrogen gas. A separator is adapted to separate at least a portion of the carbon dioxide gas from the rest of the driver gas to generate a carbon dioxide-rich driver gas and a hydrogen-rich fuel gas. A compressor is used for compressing the carbon dioxide-rich driver gas for use in enhanced oil recovery, and the compressed carbon dioxide-rich driver gas, with substantially no oxygen, is injected to a predetermined depth in order to enhance oil recovery at the oil site. Unlike traditional CO2-EOR, which requires large power plants stationed near metropolitan areas and expensive pipeline networks, the in-situ apparatus can be placed or constructed at the site of the oil field, while a portion of the carbonaceous material may be obtained from a site outside the oil field.

The invention discloses a preparation method and an application of an anti-pollution hydrophilic separating membrane. The preparation method is characterized in that a pyrocatechol derivative is used as an accelerant and a curing agent between a separating membrane material and a hydrophilic material, when blending casting film liquid of the separating membrane is prepared, the pyrocatechol derivative is added to blending liquid of the separating membrane material and the hydrophilic material, and the pyrocatechol derivative is subjected to polymerization cross-linking in a phase conversion process of the membrane preparation, so that the effect of fixing the hydrophilic material is achieved. The preparation method of the anti-pollution hydrophilic separating membrane has strong universality and is suitable for the blending of multiple hydrophilic materials and multiple membrane materials. The preparation method is simple, easy to operate, mild in conditions, economic, high-efficiency, environmentally-friendly, easy for industrialization and suitable for the preparation of multi-functional hydrophilic micro-filtration membranes, ultra-filtration membranes, nano-filtration membranes, reverse-osmosis membranes, positive-osmosis membranes, pressure-delay osmosis membranes, pervaporation membranes and the like which are used for liquid and gas separation and membrane reactors.

In a dual-source organic Rankine cycle (DORC), the condensed and slightly sub-cooled working fluid at near ambient temperature (˜300 K) and at low-side pressure (0.1 to 0.7 MPa) is (1) pumped to high-side pressure (0.5-5 MPa), (2) pre-heated in a low-temperature (LT) recuperator, (3) boiled using a low-grade heat source, (4) super-heated in a high-temperature (HT) recuperator to a temperature close to the expander turbine exhaust temperature using this exhaust vapor enthalpy, (5) further super-heated to the turbine inlet temperature (TIT) using a mid-grade heat source, (6) expanded through a turbine expander to the low-side pressure, (7) cooled through the HT recuperator, (8) cooled through the LT recuperator, (9) mostly liquefied and slightly subcooled in a condenser, and (10) the condensed portion is returned to the pump to repeat this cycle.

Various systems, method and apparatuses are disclosed that include a pressure swing adsorption apparatus coupled to a fuel cell, wherein the fuel cell receives at least a portion of a product gas from the pressure swing adsorption and powers the pressure swing adsorption apparatus. Also disclosed is a portable gas separator that include a housing that houses a rotary pressure swing adsorption apparatus.

The invention comprises a PSA process and apparatus wherein the fixed adsorbent bed comprises an equilibrium zone and a mass transfer zone. Further, the equilibrium and mass transfer zones each comprise at least one adsorbent material, selective for the adsorption of a more selectively adsorbable component, that is selected on the basis of the performance of that adsorbent material under the process conditions applicable to either the equilibrium or mass transfer zones.

Provided herein composition and methods for nanoporous membranes comprising single walled, double walled, or multi-walled carbon nanotubes embedded in a matrix material. Average pore size of the carbon nanotube can be 6 nm or less. These membranes are a robust platform for the study of confined molecular transport, with applications in liquid and gas separations and chemical sensing including desalination, dialysis, and fabric formation.