384 results about "Vinyl chloride" patented technology

The invention provides an acetylacetone-based composite thermal stabilizer which is a mixture obtained by mixing zinc acetylacetonate, calcium acetylacetonate or magnesium acetylacetonate and hydrotalcite pro rata. The composite thermal stabilizer is suitable for chloride-containing high polymer, such as polyvinyl chloride, chlorinated polyethylene, chlorinated polyvinyl chloride, copolymer of vinyl chloride-ethylene or copolymer of vinyl chloride-vinyl acetate, has better thermal stability, prolongs the thermal aging time of the chloride-containing high polymer, and overcomes the shortcomings of poor long-term performance of single stabilizer of zinc acetylacetonate, poor transparency of stabilizer of calcium acetylacetonate, and poor initial colorability of stabilizer of hydrotalcite. The composite thermal stabilizer has low cost, good initial colorability, excellent long-term performance and good transparency, and is an efficient composite thermal stabilizer.

The invention belongs to the technical field of new materials, and discloses a polyolefin dissolving agent as well as a preparation method and application thereof. The cleaning agent is composed of modified long-carbon-chain imidazole dinitrile amine salt, modified long-carbon-chain imidazole long-carbon-chain anion salt, betaine salt, imidazole acetate, imidazole long-carbon-chain anion salt, quaternary ammonium long-carbon-chain anion salt, imidazole bis (fluorosulfonyl) imide salt, imidazole hexafluorophosphate and long-carbon-chain anion and cation liquid. Under the condition of 180-210 DEG C, polyolefin (PP or PE) with the molecular weight of 50-8 million can be dissolved by adopting the polyolefin dissolving agent disclosed by the invention, and effective extrusion can be realized by adopting a twin-screw extruder after dissolution. After PP / PE powder is dissolved by adopting the polyolefin dissolving agent disclosed by the invention, sheet casting or spinning is carried out, casting sheets or PP / PE fibers are washed by using ethanol / dichloromethane / hydrocarbon / tetrachloroethylene to remove ionic liquid, and a polyolefin diaphragm or polyolefin fibers can be prepared.

Natural renewable resources are used as raw materials, efficient and environment-friendly catalytic performance is achieved through multi-stage optimization, coconut shells, fruit shells, reeds and wood chips are used as base materials in the process, a channel template is introduced after fine crushing, a graded pore structure is constructed, and the mercury-free catalyst is prepared. Dynamic extrusion forming and program temperature control carbonization-activation technologies are adopted to form an active carbon skeleton with a high specific surface area, a pulsating pressure impregnation system is innovatively designed, ultrasonic vibration is combined to strengthen copper chloride solution permeation, deep and uniform loading of active components is realized, and a mixed pickling process is developed in a matched manner. Metal impurities are efficiently removed through the synergistic effect of hydrochloric acid and citric acid, and the obtained catalyst has three-dimensional through pore channels and high-activity component dispersity, can replace a traditional mercury-containing catalyst to be applied to the fields of vinyl chloride synthesis and the like, remarkably reduces the risk of environmental pollution, improves the reaction selectivity and prolongs the service life of the catalyst, and is suitable for industrial production. And a technical support is provided for green transformation of the chemical industry.

The invention discloses a preparation method of FeS-coated Fe / BC, the FeS-coated Fe / BC prepared by adopting the preparation method, and an application of the FeS-coated Fe / BC in groundwater pollution remediation. The method comprises the following steps: adding 0.5-2g / L of vulcanized nano zero-valent iron biochar functional material (FeS and Fe / BC) into to-be-repaired underground water with the pH value of 6-8, the Cr (VI) concentration of 0.5 mg / L, the Pb < 2 + > concentration of 0.5 mg / L, the Cd < 2 + > concentration of 0.05 mg / L, the carbon tetrachloride concentration of 250.0 mu g / L and the trichloroethylene concentration of 1050 mu g / L, and oscillating for 24 hours under the conditions of 25 DEG C and 110 r / min, so that the highest removal rates of Cr (VI), Pb < 2 + >, Cd < 2 + >, carbon tetrachloride and trichloroethylene are 99.5%, 99.1%, 98.7%, 99.8% and 99.7% respectively. According to the prepared FeS-coated Fe / BC, the TCE removal efficiency is improved by 18.9% compared with that of zero-valent iron biochar (BC-coated Fe) under the condition that the pH is 6. The FeS-coated Fe / BC has the characteristics of economy, greenness and high adaptability, and can be widely applied to groundwater pollution remediation.

The invention relates to the technical field of plastic sheet extrusion, in particular to packaging rigid polyvinyl chloride sheet extrusion equipment which comprises a support and further comprises two sets of forming rollers which are symmetrically distributed on the support and used for extrusion forming, and each forming roller comprises a roller and an inner cylinder assembly which is arranged on the support in a sliding mode and located in the roller. The roller is rotationally connected with the inner cylinder assembly, and guide columns are arranged at the two ends of the roller. The inner cylinder assembly comprises an inflator pump and an air storage cylinder which are communicated with each other, the air storage cylinder is provided with an air blowing piece for guiding air to flow to the inner wall of the roller, a piston assembly slidably connected with the roller is arranged in the inflator pump, and the piston assembly is connected with the guide column in a matched mode; the guide column is used for driving the piston assembly to move in a reciprocating mode to supplement air into the air storage cylinder when rotating along with the roller, and an exhaust groove for guiding out air in the roller is formed in the inflator pump. According to the cooling device, extruded sheets can be cooled during shaping, the sheets can be cooled more uniformly and stably, and the complexity and the technical difficulty of production operation are reduced.

The embodiment of the invention provides a polymer binder, a preparation method thereof and an all-solid-state sulfide lithium battery. The polymer binder is a modified polyvinylidene fluoride-trifluorochlor oethylene copolymer, and chlorine in the modified polyvinylidene fluoride-trifluorochlor oethylene copolymer is partially or completely substituted by bromine and / or iodine; in the modified polyvinylidene fluoride-trifluorochlor oethylene copolymer, the molar ratio of a corresponding repeating unit of polyvinylidene fluoride to a corresponding repeating unit of trifluorochlor oethylene is (1-9): (9-1); in the modified polyvinylidene fluoride-trifluorochlor oethylene copolymer, the weight of chlorine is a, the weight of bromine and / or iodine is b, and b / (a + b) * 100% is equal to 1%-100%. The technical effect of improving the cycling stability and safety of the battery is achieved, and then the technical problems that when a traditional binder is applied to the all-solid-state sulfide lithium battery, the interface is unstable, the binding power is insufficient, and the traditional binder reacts with electrolyte are solved.

The invention belongs to the technical field of RAP recycled asphalt mixtures, and particularly relates to a high-dosage RAP recycled asphalt mixture for alpine regions and a preparation method of the high-dosage RAP recycled asphalt mixture. The high-dosage RAP recycled asphalt mixture for the alpine region is characterized by comprising the following components in percentage by mass: 50-60% of RAP, 3-6% of mineral powder, 1-3% of new asphalt, 1-2% of a composite regenerant, 1-2% of a modifier and the balance of a new aggregate, the composite regenerant is composed of pine tar, plant-based epoxy ester oil, cashew nut shell oil and a penetrant. The modifier is prepared from regenerated low-density polyvinyl chloride, hyperbranched epoxy resin and liquid polybutadiene rubber coated waste rubber powder. According to the technical scheme provided by the invention, the technical problems of poor low-temperature performance, water stability and freeze-thaw cycle stability when a high-dosage RAP recycled asphalt mixture is used in an alpine region are solved.

The invention discloses a mineral-based easily-recyclable compostable water-based barrier coating and a preparation method thereof, and belongs to the technical field of paper-based packaging materials. The coating takes water as a carrier, and is composed of a biodegradable film forming system and a designed graded lamellar mineral system composed of three minerals with different sizes and morphologies. The mineral system comprises flaky kaolin with specific morphology and size, non-asbestos grade flaky talc and fully stripped sodium montmorillonite. A mineral sheet layer forms a compact parallel spreading barrier path in a coating through a specific coating and drying curing process, and excellent water vapor and oxygen barrier, water resistance and oil resistance are realized under the low dry weight of 8-15g / m by combining with a pH value response type reversible cross-linking system. The coating system does not contain polyvinylidene chloride and perfluoroalkyl and polyfluoroalkyl substances. The paper-based material coated with the coating is easy to defibrillate and recover under the standard alkaline warm water condition, the fiber recovery rate is high, and meanwhile, the whole material meets the industrial composting requirement.

The invention discloses a moisture-conducting cool-feeling fabric for sportswear and a preparation method of the moisture-conducting cool-feeling fabric, and relates to the field of fabrics. When the moisture-conducting cool-feeling fabric for sportswear is prepared, zinc ions are loaded on porous nanometer aluminum oxide, then chloromethyl trimethoxy silane is grafted, and modified zinc-loaded nanometer aluminum oxide is obtained through a reaction with 2, 6-pyridine dimethyl carbinol and 3, 6-dichloro-4-vinylpyridazine; reacting dimethyl terephthalate, a modified monomer and ethylene glycol to obtain a modified polyester chip; uniformly mixing the modified polyester chips, the modified zinc-loaded nano aluminum oxide and polyethylene glycol 2000, and spinning to obtain spinning fibers; the preparation method comprises the following steps: reacting spinning fibers with hydrogen-containing silicone oil, weaving to obtain a precursor fabric, and reacting with 3-bromopropyl trimethyl ammonium bromide to obtain the moisture-conducting cool-feeling fabric for sportswear. The moisture-conducting cool fabric for sportswear prepared by the invention has excellent moisture-conducting cool, flame-retardant, antibacterial and mechanical properties.

The invention discloses a high-performance anti-interference low-voltage cable, which relates to the technical field of power transmission equipment, and is technically characterized by comprising a conductor core, an insulating layer, a shielding layer, a buffer layer and an outer sheath which are sequentially and coaxially arranged from inside to outside, the conductor core is made of a plurality of strands of tinned copper wires through a double stranding process of bunch stranding and compound stranding; the insulating layer coats the outer side of the conductor core; the shielding layer is of a double-layer structure and comprises an inner-layer aluminum-plastic composite belt and an outer-layer tinned copper wire braid layer, and an aluminum layer of the aluminum-plastic composite belt faces the inner side and is in equipotential connection with the conductor core. A layer of conductive carbon fiber cloth is wrapped on the outer side of the braid layer; the buffer layer is filled between the shielding layer and the outer sheath, and a plurality of aramid fiber reinforcing ribs are uniformly embedded in the buffer layer along the axial direction of the cable; the thickness of the outer sheath is made of a weather-resistant polyvinyl chloride material added with an ultraviolet light absorber and an anti-aging agent, and the inner surface of the outer sheath is provided with an anti-skid groove. And a nano montmorillonite filler is uniformly dispersed in the outer sheath.

A method and system for contamination remediation comprising the steps of forming recirculating electrolysis remediation system. The system includes a vessel configured to receive a volume of contaminated fluid and / or soil containing an initial concentration of a perfluoroalkyl and / or polyfluoroalkyl substances (PFAS) and / or a perchloroethylene (PCE) contaminant. The vessel in fluid communication with an electrolysis chamber including electrodes therein. A recirculation pump is configured to recirculate the contaminated fluid, soil, semi-aqueous biosolids and / or sludges between the vessel and the electrolysis chamber. A treatment media comprising biochar is introduced to the vessel and the pump and electrodes are activated resulting in concentrating the contaminant at the surface of the biochar to generate a final concentration of the contaminant in the fluid, soil, semi-aqueous biosolids and / or sludges that is less than the initial concentration.

The utility model discloses a windproof butter candle lamp which comprises a base, the upper end of the base is fixedly sleeved with a high-temperature-resistant transparent cover, a cavity for containing a butter candle is formed between the high-temperature-resistant transparent cover and the base, the butter candle is fixedly arranged in the cavity, and a lamp wick is fixedly arranged in the butter candle. The high-temperature-resistant transparent cover comprises a transparent outer layer located outside and a high-temperature-resistant layer fixedly arranged inside the transparent outer layer, and the transparent outer layer and the high-temperature-resistant layer are bonded and fixed through glue. Stable combustion can still be ensured in an outdoor or ventilation environment, and extinguishment is not prone to occurring; the high-temperature-resistant layer in the high-temperature-resistant transparent cover is made of a biaxially oriented polyester material and has excellent flame retardance, the high-temperature-resistant layer is not prone to being ignited or damaged in the burning process of the candle, and flame spreading and cover body burning loss are effectively prevented.

The invention discloses an electrolyte interference resistant solid heavy metal cation electrode and a preparation and use method thereof, and belongs to the technical field of electrode preparation. The electrode sequentially comprises a heavy metal wire, a nano heavy metal coating, a heavy metal / selenide sensitive film or a heavy metal / sulfide sensitive film and a nano microporous polyvinyl chloride film from inside to outside. Firstly, a nanometer heavy metal coating is formed on the surface of a to-be-plated heavy metal wire through an electroplating method; placing in a sodium selenide solution or a sodium sulfide solution for chemical deposition reaction to generate a heavy metal / selenide sensitive film or a heavy metal / sulfide sensitive film to obtain a heavy metal ion selective electrode blank; vertically dipping in a film-forming agent, and standing vertically with the detection end facing upwards, so that a nano-microporous polyvinyl chloride film is generated on the surface; and finally, washing to remove the residual film-forming agent, and drying to obtain the electrolyte interference resistant solid heavy metal ion electrode. The electrode is firm in structure and small in size, is matched with a reference electrode for use, and is sensitive in response to metal ions in a solution to be detected.

A multilayer hose includes a liner layer and an outer sleeve circumferentially surrounding the liner layer. The liner layer has an inner circumferential surface defining a tubular flowthrough passage extending in an axial direction through the multilayer hose. The liner layer comprises ethylene chlorotrifluoroethylene. The inner circumferential surface of the liner layer may be electrically conductive and may have a surface resistivity of less than or equal to about 1×106 Ohms per square at 20 degrees Celsius, or the inner circumferential surface of the liner layer may be electrically insulating and may have a surface resistivity of greater than 1×106 Ohms per square at 20 degrees Celsius. The outer sleeve defines an outer circumferential surface of the multilayer hose and comprises a reinforcing material.

The invention discloses a method for producing hydrogen by gasifying plastic biomass, which comprises the following steps of: physically grading waste plastics according to different types (such as polyethylene, polypropylene, polyvinyl chloride and the like), sorting and treating the waste plastics by adopting an infrared component analyzer, a pyrolysis experiment, laser cutting and other technical means, adjusting the particle size of the waste plastics to be 1-3cm, and carrying out extrusion molding on the waste plastics. And a proper treatment mode is adopted according to pyrolysis characteristics of different plastics, so that the gasification reaction efficiency is improved. Therefore, through fine temperature and atmosphere regulation and control, the hydrogen generation efficiency is improved, the emission of byproducts is reduced, the catalytic efficiency is improved by introducing the composite catalyst, the service life of the catalyst is prolonged, the hydrogen purification process adopts the combination of membrane separation and a temperature swing adsorption method, so that the hydrogen purity reaches 99.99% or above, and the production cost is reduced. According to the technology, the hydrogen yield and purity are remarkably improved, the service life of the catalyst is prolonged, meanwhile, emission of greenhouse gas and harmful by-products is effectively reduced, and remarkable economic and environmental benefits are achieved.

The purpose of the present invention is to improve the life of a battery using a negative electrode comprising a metal by reducing the amount of gas generation, reducing the resistance, and reducing the amount of metal elements such as Mn and Ni deposited in a positive electrode in the negative electrode. A secondary battery having a liquid electrolyte and a negative electrode in which a fluoropolymer is laminated on a layer containing a metal, the secondary battery being characterized in that: the metal is at least one type selected from the group consisting of lithium, sodium, magnesium and zinc; the fluoropolymer is a copolymer having a vinylidene fluoride unit (A) and a structural unit (B) of at least one monomer selected from the group consisting of tetrafluoroethylene, trifluoroethylene, chlorotrifluoroethylene, a monomer represented by general formula (1), a monomer represented by general formula (2), and a monomer represented by general formula (3), and the liquid electrolyte contains a fluorinated ether. [chemical formula 1] # imgabs0 # [chemical formula 2] # imgabs1 # [chemical formula 3] # imgabs2 #

The invention belongs to the technical field of anticorrosive coatings, and particularly relates to a novolac epoxy resin anticorrosive coating modified by a chlorine-containing polymer and a preparation method of the novolac epoxy resin anticorrosive coating. Comprising a component A and a component B. The component A comprises the following raw materials by weight: 20-50 parts of novolac epoxy resin; 10-30 parts of a solvent (1: 10); 10 to 20 parts of a trichloroethylene by-product; 10 to 35 parts of pigment; 5-20 parts of an antirust material; 5 to 30 parts of filler; 3-5 parts of an auxiliary agent; the component B is prepared from the following raw materials in parts by weight: 60 to 80 parts of alicyclic amine curing agent; 10-30 parts of a solvent 2; and 1-5 parts of a curing accelerator. According to the chlorine-containing polymer modified novolac epoxy resin anticorrosive paint, a novolac epoxy resin anticorrosive coating material is modified by using a trichloro ethylene byproduct, so that the cost is reduced, the brittleness of a paint film is reduced, and meanwhile, the toughness, compactness and stability of the paint film are remarkably improved.

The invention discloses continuous synthesis equipment for high-purity tetrachloroethylene. The continuous synthesis equipment comprises a chlorination synthesis device, an energy-saving device, a cooling and washing device, a carbon tetrachloride refining device and a tetrachloroethylene refining device. The invention further discloses a continuous synthesis process of the high-purity tetrachloroethylene. The continuous synthesis process comprises the steps of chlorination synthesis, cooling and washing, carbon tetrachloride refining and tetrachloroethylene refining. The reaction in the tube nest of the chlorination reaction kettle generates carbon tetrachloride, the carbon tetrachloride in the shell pass reacts to generate tetrachloroethylene, and the heat released by the first-step reaction promotes the forward proceeding of the second-step reaction. The heat-conducting oil is used for removing heat after reaction and supplying the heat to the rectification system, so that the energy consumption of the system is reduced. According to the invention, the carbon tetrachloride crude product is refined and then returns to the system, the tetrachloroethylene yield is high, and the conversion rate of tetrachloroethylene in the synthesis kettle is not influenced. The heat transfer oil is used for heating the rectification system and a tetrachloroethylene high-low pressure rectification mode, and the energy of the system is saved by more than 50%.

The invention provides a method for preparing anti-permeation anti-corrosion filler by using waste rubber and anti-corrosion paint, and belongs to the technical field of paints.The method comprises the steps that the waste rubber is smashed and sieved to obtain rubber particles, then the rubber particles are sequentially subjected to acid pickling, alkali washing and water washing and dried, then the rubber particles are added into tetrachloroethylene to be chlorinated, flocculent products are removed through an air blowing rotary furnace, and the anti-permeation anti-corrosion filler is obtained; and adding the rubber particles into tetrachloroethylene again for chlorination, carrying out bubbling operation, and draining to obtain the anti-permeation and anti-corrosion filler. The chlorine content of the impermeable anticorrosive filler prepared by the method is increased, the corrosion resistance is enhanced, and an anticorrosive coating prepared from the filler can effectively solve the problem of diffusion of water molecules, also can effectively inhibit permeation and migration of corrosive medium chloride ions, and can greatly improve the impermeability.

The invention discloses an intelligent safety monitoring and dynamic risk management and control system and method for a polyvinyl chloride polymerization section. The system comprises a sensing and execution layer, a reliable transmission and safety network layer, a digital twinning and intelligent center layer, an algorithm and service center and a business application layer, and an intelligent digital twinborn body which deeply interacts and is fused with a physical working section is constructed, so that fundamental transformation from passive response to active early warning, from experience driving to data and model driving, and from single-point monitoring to global collaboration is realized. According to the invention, an autonomous intelligent closed loop of perception-mapping-diagnosis-decision-control is realized, so that the safety production level of the workshop section is comprehensively improved.

The present invention provides a sound insulation coating, a preparation method thereof and a sound insulation coating. The sound insulation coating of the present invention comprises a styrene-acrylic emulsion, an inorganic filler, an organic sound insulation filler, a porous drying accelerating filler and a drainage drying accelerating fiber, and the organic sound insulation filler comprises at least one of acrylonitrile-butadiene rubber powder, ethylene-propylene rubber powder, polyurethane powder, acrylonitrile foamed microspheres, polyvinylidene chloride foamed microspheres and acrylate foamed microspheres. The present invention also provides a preparation method of the sound insulation coating and a sound insulation coating.

The invention relates to the technical field of gas adsorption materials, in particular to a plasma modified UiO-66-NH2 / activated carbon composite filter material as well as a preparation method and application thereof. The preparation method comprises the following steps: adding activated carbon into a UiO-66-NH2 precursor solution, vacuumizing in a vacuum drying oven for 1-3 hours, then transferring into a reaction kettle, heating to 80-120 DEG C, reacting for 20-25 hours, cooling to room temperature, washing and drying to obtain a UiO-66-NH2 / activated carbon composite material; and placing the UiO-66-NH2 / activated carbon composite material in a plasma reactor, and carrying out plasma treatment by taking H2 / Ar as a working gas to obtain the plasma-modified UiO-66-NH2 / activated carbon composite material. According to the invention, UiO-66-NH2 is loaded in the activated carbon, so that the effects of increasing the specific surface area of the activated carbon and developing a microporous structure are achieved, the adsorption capacity of low-concentration trichloro ethylene reaches 281 mg / g, and the UiO-66-NH2 loaded activated carbon is a filter material for effectively adsorbing trichloro ethylene (TCE).

The invention discloses a composite material for a cable shielding layer film and a preparation method of the composite material. A resin matrix of the composite material comprises 30-60 parts by mass of metallocene linear low density polyethylene, 3-10 parts by mass of an ethylene-octylene copolymer, 3-20 parts by mass of polytrifluorochloroethylene, 3-10 parts by mass of an ethylene trifluorochloroethylene copolymer and 15-40 parts by mass of an ethylene tetrafluoroethylene copolymer, and the total parts by mass of the resin matrix is 100. The tensile strength of the composite material for the cable shielding layer film is larger than 40 MPA, and the composite material is not prone to stripping from a metal belt; the yield strength is greater than 10MPA, and the steel is not easy to be stretched and deformed in the compounding process of the steel and a metal belt; the water vapor transmission rate is smaller than 6, the water vapor barrier effect is good, hydrolysis is not prone to occurring, aging resistance is good, the metal belt can be well protected within the quality guarantee period, and in addition, the flame retardant property is excellent.

The invention discloses an application and a method for preventing and controlling longhorn beetles by using a disotropic agent, and belongs to the technical field of prevention and control of agricultural pest longhorn beetles. The component of the lysimachia christinae disruption agent is trans-9-tetradecene-2, 2-difluoroacetate, and the disruption effect of the lysimachia christinae disruption agent is superior to that of a lysimachia christinae disruption pheromone disruption substance under the same dosage. According to the isotropic agent, 100-200 mg of trans-9-tetradecene-2, 2-difluoroacetate is dissolved in liquid chlorinated paraffin and added into a polyvinyl chloride (PVC) capillary tube to be prepared into isotropic filaments, 30-60 isotropic filaments are arranged per mu in the using process, and the result shows that the field lasting period of the isotropic filaments is longer than 3 months, and the isotropic rate is larger than 80%. The isotropic agent disclosed by the invention can be used for remarkably interfering the mating of male and female jettilonghorn beetles, is safe to the environment and natural enemies, is simple to operate, can be used for preventing and treating the pests in a large area, and has important significance on comprehensive treatment of the jettilonghorn beetles.

The invention discloses a method for treating a metal surface through ethylene glycol butyl ether after a fire disaster. The treatment method comprises the following steps that modified ethylene glycol butyl ether is prepared; sequentially adding modified ethylene glycol butyl ether serving as a main chemical solution into the reaction kettle according to the quantitative percentage, and carrying out mixed reaction; standing the mixed chemical solution in the step S2 for 10-20 minutes, and adding water to dilute the mixed solution according to the remaining percentage of the volume of the reaction kettle; the ethylene glycol butyl ether is modified and serves as a main component of the cleaning solution, the sodium phosphate, the epichlorohydrin, the sodium pyrophosphate and the trichloroethylene are mixed according to a proper proportion, a proper amount of water is added for dilution, and the cleaning solution is obtained. Dirt formed by fire disasters on the metal surface can be effectively removed, and metal objects cannot be damaged.

The invention belongs to the technical field of sewage treatment, and provides a method for relieving inhibition of polyvinyl chloride micro-plastics on an anaerobic digestion process by using sludge and coal gangue based biochar, which comprises the following steps: adding pretreated sludge and simulated wastewater into an SBR (Sequencing Batch Reactor); soaking PVC-MPs in alcohol for 48 hours, washing the PVC-MPs with distilled water for 3-5 times to remove impurities in the PVC-MPs, and drying the PVC-MPs at 105 DEG C for 24 hours for later use; pVC-MPs is added into a reaction device according to the proportion of 0.1 g. (g. VS)-1 and placed in a constant-temperature shaking table at the temperature of 35.0 + / -0.1 DEG C in a dark place; sCBC is added into the reaction device according to the adding amount of 1.0 g.L <-1 >, other conditions are kept the same, and sampling and analysis are conducted at 0, 1, 2, 3, 5, 7, 9 and 12 h respectively. The invention proves that the SCBC can effectively relieve the inhibition of PVC-MPs on anaerobic digestion, promote the enrichment of dominant methanogens, and provide a feasible technical path for the resource utilization of coal gangue and sludge at the same time.

The invention discloses an ion selective electrode for detecting perchlorate and a preparation method thereof. The invention first synthesizes a perchlorate ion carrier, specifically dichlorophosphorus tetraphenylporphyrin, using a pyridine solution of tetraphenylporphyrin, POCl3, and PCl5 as raw materials; then dichlorophosphorus tetraphenylporphyrin, an ion exchanger, specifically tetraoctylammonium chloride, polyvinyl chloride, polytetrafluoroethylene, and a plasticizer, specifically dibutyl phthalate, as raw materials, after a mixed reaction, the resulting reaction product is coated on the surface of an Mxene modified electrode to obtain an Mxene / ISE membrane electrode; finally, an Mxene / ISE membrane / Mxene‑py electrode is prepared. The results show that the composite electrode assembled with the electrode as an ion selective electrode has extremely strong selectivity for perchlorate, and at the same time, the response time is extremely fast, and sensitive and rapid detection of perchlorate under complex water conditions can be achieved. The ion selective electrode prepared by the present invention has the characteristics of low detection limit, strong anti-interference ability, and low cost in detecting perchlorate.

The invention relates to a pretreatment method for chemical recovery of waste plastics. The pretreatment method comprises the following steps: determining the production quantity of the waste plastics to be pretreated; measuring the weight part ratio of polyvinyl chloride in the waste plastics to be pretreated; the weight of polyvinyl chloride in the to-be-pretreated waste plastic is obtained, and the weight of polyvinyl chloride in the to-be-pretreated waste plastic is the product of the production amount of the to-be-pretreated waste plastic and the weight part ratio of polyvinyl chloride; preparing a treatment agent with a set weight, wherein the set weight is equal to the weight of the obtained polyvinyl chloride; and putting the determined production quantity of the waste plastics and the prepared treatment agent into a screw extrusion device, and carrying out extrusion molding under the condition of 180-350 DEG C to complete the pretreatment of chemical recovery of the waste plastics. The waste plastic is subjected to high-temperature extrusion pretreatment, so that PVC is decomposed at high temperature, generated chlorine is removed by using calcium oxide or calcium carbonate, the chlorine removal rate can reach 99.999%, and the removal rate is high.

The application discloses resin-coated urea slow-release fertilizer, a preparation method and application thereof, and first prepares resin-coated urea slow-release fertilizer, adopts polystyrene, polyethylene, talcum powder and starch mixture to be dispersed and heated in tetrachloroethylene to prepare coating liquid, then sprays the coating liquid on the surface of dried urea after pretreatment, and with evaporation of the solvent, a resin layer is formed on the particle, and the resin-coated urea slow-release fertilizer is obtained. The resin-coated urea can simulate atmospheric nitrogen deposition, and can more truly simulate the nitrogen deposition mode.

The invention discloses a solid mercury ion electrode resistant to electrolyte interference, a preparation method and a use method, and belongs to the technical field of electrode preparation. The electrode sequentially comprises a gold wire serving as a base material, a gold amalgam transition conducting layer, a mercury / mercury selenide sensitive film or a mercury / mercuric sulfide sensitive film and a nano microporous polyvinyl chloride film from inside to outside. Firstly, a gold amalgam transition conducting layer is formed on the surface of a gold wire through an electroplating method or a soaking method; immersing in a sodium selenide or sodium sulfide solution to form a mercury / mercury selenide sensitive film or a mercury / mercury sulfide sensitive film on the surface to obtain a mercury ion electrode blank; vertically dipping the mercury ion electrode blank into the film-forming agent, and standing vertically with the detection end facing upwards, so that a nano-microporous polyvinyl chloride film is generated on the surface of the mercury ion electrode blank; and finally, washing to remove the residual film-forming agent, and drying to obtain the electrolyte interference resistant solid mercury ion electrode. The electrode is firm in structure and small in size, is matched with a reference electrode for use, and is sensitive in response to mercury ions in a solution to be detected.