The invention discloses a magnetic response type high-efficiency oil-water separation fiber membrane and a preparation method thereof, and belongs to the field of functional micro-nano fiber materials. The magnetic response type high-efficiency oil-water separation fiber membrane disclosed by the invention is prepared by the following steps: dissolving hydrophobic polymers, such as polyvinylidene fluoride, polyurethane or polycaprolactone, as main raw materials into an organic solvent to form a polymer solution; preparing a non-woven fiber membrane material prepared from micro-nano structure fibers by adopting an electrospinning method; forming a sticky polydopamine membrane through polymerization of polydopamine in an alkaline solution, and firmly attaching magnetic nanoparticles onto the surface of an electrospinning fiber membrane by adopting the sticky polydopamine membrane, so as to prepare the magnetic response type high-efficiency oil-water separation fiber membrane. The fiber membrane disclosed by the invention has a super-hydrophobic/super-oleophilic property in air, and has an excellent adsorptive property on a plurality of common oils; the preparation method of the high-efficiency oil-water separation fiber membrane, disclosed by the invention, is simple, low in energy consumption, and high in efficiency,and can be widely applied to the fields such as remote controllable efficient separation of oily wastewater, and the magnetic responsiveness is realized.