The present application relates to the technical field of
lithium metal battery, and especially relates to a negative
electrode interface
protection layer and a preparation method, a
lithium metal negative
electrode and a
lithium metal battery. The preparation method comprises the following steps: under stirring, adding
bismuth ferrite into a PVDF-HFP solution in batches,
ultrasonic dispersion and mixing, obtaining a precursor solution, dropping the precursor solution on a
copper foil, adopting a two-stage
spin coating process to form a wet film,
drying, obtaining a
copper foil loaded with a composite
protection layer BFO / PVDF-HFP, and carrying out high-
voltage corona polarization treatment on the
copper foil loaded with the composite
protection layer BFO / PVDF-HFP, thereby obtaining the negative
electrode interface protection layer. The negative
electrode interface protection layer is more sensitive to the stress response of the
lithium metal negative electrode volume strain and
lithium dendrite, and generates a stronger piezoelectric field more quickly. Under the action of the
electric field, the lithium
ion flux is larger and more uniform, the lithium deposition is more uniform and dense, the growth of lithium dendrites is effectively inhibited, and the
lithium metal is protected while the lithium deposition / peeling behavior is more effectively regulated.