The invention relates to a 
calcium silicate hydrate and a preparation method thereof and concrete antifreezing agent containing the 
calcium silicate hydrate, which pertains to the field of construction materials and manufacturing method thereof. The invention solves the problems of antifreezing agent in existing market of poor durability of concrete, steel-bar 
corrosion, alkaline aggregate reaction, etc., caused by large quantity of 
salt content in the concrete antifreezing agent. The 
calcium silicate hydrate is made from 
calcareous material, siliceous material and water. The preparation method comprises the steps that: the 
calcareous material and the siliceous material are evenly mixed and grinded and added with water to prepare pasty material, which goes through heat reaction at 1 to 3atm for 2 to 5h. The concrete antifreezing agent containing the 
calcium silicate hydrate is made of the 
calcium silicate hydrate, antifreezing components, water reducing components, air entraining components and 
fly ash. The 
calcium silicate hydrate uses 
seed crystal hydration to improve the hydration of the concrete, which leads set 
cement to be more 
impact and the long-term property of the concrete not to be reduced. The antifreezing agent of the invention does not contain 
chloride salts, reduces the damage effect of the steel-bar 
corrosion caused by mixing the 
chloride salts with the concrete when in construction during winter period and greatly reduces the 
salt content in the concrete.