The invention discloses a real-time monitoring sensor for durability of concrete structures. The real-time monitoring sensor comprises a sensor shell, and further comprises a reference electrode, a rebar electrode, an auxiliary electrode, a chlorion probe, a pH probe and a concrete resistivity probe. The auxiliary electrode is laid on the upper surface of the shell, at least parts of the reference electrode, the rebar electrode, the chlorion probe, the pH probe and the concrete resistivity monitoring probe are exposed out of the upper surface of the sensor shell to serve as detecting ends, and the other ends are connected with copper cables which penetrate through the sensor shell from top to bottom and stretch out of the shell. According to the real-time monitoring sensor, not only corrosion rate, chlorion concentration and pH of rebar, but also concrete resistivity can be monitored in real time; further, system resistance can be compensated during the monitoring of rebar corrosion current density, and corrosion rate of rebar can be monitored more accurately by the monitoring of concrete resistance.