The invention provides a method and a
system for accurately controlling the pH value of single-tank outlet light salt brine in multiple groups of electrolytic tanks, comprising multiple groups of electrolytic tanks, a tank inlet brine
branch pipe is connected with a diluted
hydrochloric acid branch pipe, the diluted
hydrochloric acid branch pipe is provided with a diluted
hydrochloric acid flowmeter and a diluted hydrochloric acid regulating valve, and the tank outlet light salt brine branch pipe is connected with a light salt brine sampling branch pipe. Each light salt brine sampling branch pipe is provided with a light salt brine sampling
program control valve and a
simulation assignment module, the light salt brine sampling branch pipes are connected with a light salt brine sampling header pipe, and the light salt brine sampling header pipe is provided with a sampling adjusting valve, a sampling flow meter and a
pH meter; the diluted hydrochloric acid flow meter, the diluted hydrochloric acid adjusting valve, the light salt brine sampling
program control valve, the sampling adjusting valve, the sampling flow meter and the
pH meter are all connected into a DCS
system, and the diluted hydrochloric acid adjusting valve adjusts the opening degree according to the detection value of the
pH meter. Precise adjustment and control of pH of light salt brine discharged from each single
cell in multiple groups of electrolytic cells are realized through a pH meter and a control loop thereof, the
anode efficiency and the quality of a liquid caustic soda product are improved, and the production stability is improved.