1431results about How to "High pore volume" patented technology

Basic magnesium carbonate comprising a tubular aggregated particle of flaky fine crystals.

The present invention provides porous mineral oxide beads which have large pore volumes and enhanced stability. The beads are based on a tetravalent metal oxide, such as zirconia, titania or hafnia. These highly porous beads are produced from a mixture of tetravalent mineral oxides, mineral pore inducing agents which are oxides or salts of trivalent metals, and optional binders. The porous mineral beads can be filled with a polymer gel and used for adsorption and chromatography applications.

A sponge-like pad used for cleaning and other wiping and polishing applications is disclosed. The sponge-like pad is made from a plurality of textured paper webs attached together at selected locations. The paper web can be, for instance, a highly textured throughdried paper web containing high-yield fibers and a wet strength agent. In one embodiment, the stacked plies can be contained within a cover material that is liquid pervious. The sponge-like product of the present invention can be used alone or it can be incorporated into a cleaning tool, such as a mop.

The invention discloses a solid-phase synthetic method of a highly ordered mesoporous carbon material. The solid-phase synthetic method comprises the following steps: 1) mixing a structure-directing agent with a high molecular monomer used as a carbon source, and grinding for 5-180 min at 10-100 DEG C; 2), heating for 0.5-120 h at 40-380 DEG C; 3) under the protection of inert gases, rising the temperature to 500-2,100 DEG C at the temperature rising speed of 1-40 DEG C/min, and roasting for 2-10 h at high temperature. The functionalization mesoporous carbon material is synthetized through the organic-organic self-assembly between the high molecular monomer and the structure-directing agent and between the low polymer of the high molecular monomer and the structure-directing agent, and the mechanical grinding. The solid-phase synthetic method is simple to operate, efficient, and low in cost, and the prepared mesoporous carbon material has a highly ordered mesoporous channel, high specific surface area (500-2,500 m<2>/g and large pore volume (pore diameter of 2.5-20 nm and pore volume of 0.1-2.5 cm <3>/g).

The invention discloses property-transformation alumina carrier which contains titanium and silica agent and its relative preparing method. Said silica agent is added in the sol process of aluminum hydroxide to improve the specific surface, pore diameter and pore capacity of alumina; after the sol process, individually using acid agent and alkali agent to adjust the pH value of mixed paste solution for several times to make the attained alumina with more centralized pore distribution; the titanium agent is added after the sol process and before the aging process, to improve the surface acid property, surface acid amount and B acid amount of carrier. In addition, the surface of alumina is modified by titanium to decrease the interactive condition between active metal and carrier, which can apply the diffusion of active metal components in the catalyst. The property transformation of said invention can be used as catalysis material when processing oil, especially as the catalyst carrier of hydrogenation treatment and hydrogenation transformation.

The invention relates to a dechlorinating agent used for removing HCl from a gas by using a dry method and a preparation method thereof. The dechlorinating agent is prepared from Na2CO3, CaCO3, CaO and MaO as active constituents, crosslinked bentonite as a porous auxiliary agent, and methyl cellulose as a foaming agent and an auxiliary extrusion agent through extrusion forming, drying and roasting. The cross-linked bentonite is prepared by exchanging large-size poly aluminum cation with small-size simple cation, so that the crosslinked bentonite has great porosity factor and large specific surface. The specific surface and the pore volume of the crosslinked bentonite are larger than those of non-crosslinked bentonite. By using the crosslinked bentonite as the porous auxiliary agent, the specific surface of the dechlorinating agent is enlarged, and the dechlorinating activity and the chlorosity of the dechlorinating agent are increased. The dechlorinating agent prepared by using the crosslinked bentonite has a pore volume of 0.3-0.4 mL/g, a specific surface of 70-90 m<2>/g and a crushing strength of 60-80 N/cm, not only has lower price than pseudo-boehmite and a molecular sieve, but also has simple preparation process, high dechlorinating activity and great low-temperature penetration chlorosity.

An O2-bearing low-Ce RE material with high performance and multiple purposes is a composite oxide consisting of cerium oxide, zirconium oxide and assistant chosen from lanthanum oxide, strontium oxide and yttrium oxide. It is prepared through codeposition and calcining at 500-600 deg.C. It can be used as the carrier and assistant of the catalyst for cleaning the tail gas of car.

The invention discloses high-silicon amorphous silica alumina and a preparation method thereof. The amorphous silica alumina product has the properties of a specific surface area of 400 to 650m/g, a pore volume of 1.0 to 2.0cm/g, a silicon oxide content of 20 to 80wt percent, a infrared acid content of 0.3 to 0.8 mmol/g and evenly distributed acidic centers. Moreover, the amorphous silica alumina is prepared by a method comprising first coprecipitation of silicon oxide and alumina and then modification of organic silicon. Compared with the prior art, the amorphous silica alumina has larger pore volume and specific surface area, evenly distributed acidic centers and excellent service performance; moreover, the preparation method is simple, free from special environmental protection problem and low in production cost.

A multilayer composite sheet for use in a lead-acid battery includes

• • a) a base layer including paper or a glass fiber mat;
  • b) a layer of polymeric nanofibers bonded with discrete adhesive particles to a first surface of the base layer; and
  • c) a scrim layer bonded with discrete adhesive particles to a surface of the layer of nanofibers opposite the base layer.

A plate assembly for a lead-acid battery includes one or more multilayer composite sheets located adjacent or partially enclosing a lead plate.

The invention provides a preparation method of an S/TiO2 composite material for an anode of a sodium-sulfur battery. The preparation method comprises the following steps: dissolving butyl titanate, a template agent and a hydrolysis inhibitor into absolute ethyl alcohol; adding a mixed solution of de-ionized water and the absolute ethyl alcohol to form semi-transparent sol; transferring the sol into a high-pressure reaction kettle to react; calcining a solid product in air to remove the template agent to obtain meso-porous titanium dioxide; dispersing the meso-porous titanium dioxide into a sodium thiosulfate solution dissolved with a surfactant; adding hydrochloric acid to react; washing the solid product by a lot of the de-ionized water and drying; and eating under the protection of an inert atmosphere to obtain the S/TiO2 composite material. The meso-porous titanium dioxide prepared by the preparation method is large in specific surface area, high in porosity and strong in adsorption capability; the electrical conductivity of sulfur can be improved and a lot of nano sulfur and polysulfide can be contained; the polysulfide can be effectively prevented from being dissolved and diffused in electrolyte, and the utilization rate of the sulfur is improved; meanwhile, the structure of the meso-porous titanium dioxide is stable and a pore channel cannot be easily damaged, so as to have buffering effects on volume expansion and retraction in a charging/discharging process of a sulfur electrode.

The invention provides a phosphorus modification method of a high-alkali-metal-ion-content ZSM-5 molecular sieve. The method is characterized by comprising mixing a phosphorus-containing compound selected from one or more of phosphoric acid, diammonium phosphate, ammonium biphosphate and ammonium phosphate with a high-alkali-metal-ion-content ZSM-5 molecular sieve to obtain a mixture with at least 0.1 wt% of phosphorus-loading content, wherein phosphorus is counted in terms of P2O5, drying and calcinating the mixture, carrying out an ammonium exchange process and a washing process to make the alkali metal ion content no more than 0.10 wt%, performing drying, and carrying out hydrothermal aging at the temperature of 400-1000 DEG C in a 100% of vapor condition. The obtained phosphorus-containing ZSM-5 molecular sieve is high in total acid amount, is excellent in cracking conversion rate and propylene selectivity, and is good in hydro-thermal and active stability.

The invention discloses a preparation method of a nitrogen-doped porous carbon nano sheet composite material. The preparation method comprises the steps of performing high-temperature carbonization treatment on a mixture which consists of melamine and adjacent phenanthroline iron and serves as a precursor in a tubular furnace under an inert gas environment, and then removing dissolved iron compounds from an acidic solution to obtain a porous carbon nano sheet layer with carbon-coated iron carbide nano particles. The preparation method has the advantages that the technology is simple, the raw materials are cheap, and operation is easy to implement; in the prepared composite material, iron carbide is uniformly dispersed in the carbon nano sheet layer, so that the composite material is high in specific surface area and pore volume; iron carbide nano particles are completely coated by graphitized carbon, so that oxidization and corrosion are hardly caused; the composite material is stable in acidic electrolyte, and the battery activity can be effectively improved; when used as an electrocatalyst, the composite material is relatively high in electrocatalysis efficiency; the preparation method has an important value and significance in the field of preparation of doped carbon nano composite materials and electrocatalysis of proton membrane fuel batteries.

The present invention relates to the field of catalyst molding, and particularly provides a titanium-silicon molecular sieve molding method, which comprises: mixing a titanium-silicon molecular sieve and a water-containing mixture, carrying out hydrothermal treatment under a sealed condition, molding the slurry obtained from the hydrothermal treatment to obtain a molding body, and calcining the molding body, wherein the water-containing mixture contains a silicon element, a titanium element and a nitrogen element, and is at least partially derived from the crystallization mother liquor of the titanium silicon molecular sieve. The present invention provides a molding catalyst prepared according to the preparation method, and applications thereof. The invention further provides a cyclohexanone oxidation method. According to the present invention, with the titanium-silicon molecular sieve molding method, the industrial waste liquid is effectively utilized, and the problems of complex process, corrosion on equipment, harmful emission and the like of the traditional process are overcome; and the molding catalyst has characteristics of high titanium-silicon molecular sieve content, high pore volume, high crushing resistance, and high selectivity to the target product.

A fluid catalytic cracking catalyst is provided with a high porosity by in-situ crystallizing an aluminosilicate zeolite from a reactive microsphere comprising metakaolin and hydrous kaolin. Any calcination of the reactive microsphere before reaction with a zeolite-forming solution is done at low temperatures so as to ensure the hydrous kaolin is not converted to metakaolin.

The invention provides an anode material for lithium ion secondary battery using a coated graphite powder as a raw material. The coated graphite powder is coated with carbonized material of thermoplastic resin of a carbonization yield of not more than 20 wt % in a proportion of not more than 10 parts by weight the carbonized material per 100 parts by weight graphite powder. The graphite powder as coated with thermoplastic resin increases 5% or more in accumulative pore volume of the graphite powder having a pore size of 0.012 μm to 40 μm as measured by a mercury porosimeter method, as compared with the graphite powder before coated with the thermoplastic resin. The coated graphite powder has a mesopore volume defined by IUPAC of 0.01 cc/g or less as calculated with the BJH method as viewed from desorption isotherm, which is also equal to 60% or less of the pore volume of the graphite powder before coated with the thermoplastic resin, an average particle size ranging from 10 μm to 50 μm, as measured by a laser-scattering-particle-size-distribution measuring device, and a ratio of standard deviation to the average particle size (σ/D) of 0.02 or less.

A process for preparing the hydrophobic SiO2 aero-gel from rice husk ash includes such steps as burning rice husk to obtain its ash, extracting its hydro-gel in inorganic strong-alkaline aqueous solution, neutralizing by inorganic strong acid, laying aside to generate SiO2 hydro-gel, filter, acid treating, ageing, water washing, displacing the water from the hydro-gel by organic solvent, supercritical drying and modifying surface. Its advantages are high specific surface area and pore volume, and low apparent density.

The invention discloses a microspherical ethylene oxychlorination catalyst preparation method, which comprises the following six steps: solution preparation; precipitation and reaction; peptization; active component and assistant component homogenization; spray forming; and post-treatment. Solution of an active component and solution of an assistant component are dissolved in peptized pulp; a proper amount of dispersant and pore-expanding agent are added into the pulped sol solution to ensure the active component and the assistant component are uniformly distributed in the sol solution; the dispersant can prevent active and assistant component deposition caused by the prolongation of spray time; and the added proper amount of pore expanding agent can expand formed pore passage with a microspherical structure in a spraying process of the sol solution so as to improve the volume of the pore passage of a catalyst carrier and improve the pore volume and specific area of the catalyst.

The invention discloses a preparation method of porous geological polymer microspheres. The porous geological polymer microspheres are prepared by a dispersion suspension solidification method. Compared with the prior art, low-temperature curing and one-shot molding granulation are realized without requirements of high-temperature calcination and curing and addition of other auxiliaries; and at the same time, large-scale use of solid wastes is realized, and raw materials are widely available, cost is low, process is simple, and the whole process is non-toxic and pollution-free; in addition, the preparation efficiency is high with a ball-forming degree exceeding 90%; the size of the particles can be adjusted, and the pore size distribution is uniform; the pore volume is large, and can be regulated, and a specific surface area of the microspheres reaches 110m2/g, thus, the porous geological polymer microspheres can be directly used for packed columns for column separation. Experiments show that the porous geological polymer microspheres have a good adsorption effect on heavy metals, and can be used as adsorbents for heavy metals, and have a broad application prospect in the aspect ofremoving heavy metals and radioactive elements in water.

The invention discloses a preparation method of ordered mesoporous silica microspheres with hollow structures. The preparation method comprises the following steps: firstly, dissolving a cationic surface active agent in mixed solution of ethanol and water, sequentially adding ammonia water and a silicon source in the mixed solution under the conditions of heating and mixing, and reacting for a period of time to obtain solid silica microspheres; washing the obtained silica, transferring the silica into water for etching, and reacting for a period of time to obtain hollow silica microspheres; and finally, collecting the hollow silica, and obtaining products of ordered mesoporous silica microspheres with hollow structures by drying and roasting. In the preparation method, a sacrificial hard template or an emulsion template does not need to be prepared in advance. The preparation method has the characteristics of simple technological process, mild reaction conditions, low cost, and environmental friendliness; and the prepared hollow mesoporous silica microspheres have great application potential in ultrasonic imaging, drug delivery and other biomedical fields.

The invention provides a preparation method of silica, relating to a preparation method of silica materials. In the preparation method, sodium silicate aqueous solution is pumped into a carbonization agitated reactor, supercritical carbon dioxide or subcritical carbon dioxide is added into the carbonization agitated reactor for reaction, so that a reaction product silicide is obtained; after washing and filtering, filtrate enters an evaporator, and carbonate is recycled; a filter cake is pulped by solvent and then forms supercritical fluid which enters a supercritical drying kettle; and after drying, the solvent and the supercritical fluid are separated under reduced pressure in a separation tank, the pressure of the supercritical drying kettle is released, and the product of silica is obtained.

The invention belongs to the technical field of advanced nanocomposites, and particularly discloses a magnetic mesoporous silica microsphere material with a yolk structure and a preparing method thereof. The macromolecule sol-gel chemical synthesis method is adopted first, magnetic nanoparticles are coated with a polymer resin macromolecule shell, then a mesoporous silica shell is grown on the surface of the polymer resin shell in a non-contact mode by means of the water-oil two-phase method, a surface active agent and an organic solvent are removed through solvent washing and extraction, and finally the magnetic mesoporous silica composite microsphere material provided with ordered mesopore ducts, a large cavity and the yolk structure is obtained. The obtained composite microsphere has the large adjustable cavity, a high specific surface area, the mesoporous shell with a uniform and vertical interface, stable and high magnetic responsiveness, a quite uniform size and high dispersity and has broad application prospects in nanoreactors, catalysis, drug sustained release, large-volume bioseparation and adsorption. The method is simple, raw materials are easy to obtain, and enlarged production is facilitated.