The invention provides orthogonal-tetragonal multilayer heterostructure antiferroelectric
ceramic and a preparation method thereof. Tetragonal phase antiferroelectric presintering
powder is prepared, orthogonal phase antiferroelectric presintering
powder is prepared, the tetragonal phase antiferroelectric presintering
powder and the orthogonal phase antiferroelectric presintering powder are respectively subjected to secondary ball milling,
drying and sieving and then subjected to
tape casting treatment, and the antiferroelectric
ceramic with the orthogonal-tetragonal multilayer heterostructure is obtained. A single-layer film A and a single-layer film B are obtained; and carrying out heterogeneous lamination temperature isostatic pressing treatment on the single-layer film A and the single-layer film B according to
modes of AAAA, ABBA, BAAB, ABAB and BBBB to obtain the multi-layer heterostructure anti-ferroelectric
ceramic, carrying out glue removal on the multi-layer heterostructure anti-ferroelectric ceramic, and calcining to obtain the orthogonal-tetragonal multi-layer heterostructure anti-ferroelectric ceramic. According to the multilayer heterostructure constructed by the invention, the breakdown
field strength and the macroscopic polarization response of the material are synergistically improved through the interface blocking effect induced by the interlayer interface and the MWS interface polarization effect, so that the
energy storage density is effectively improved.