Nickel-base high-temperature alloy with low density and high melting point and preparation process thereof

A nickel-based superalloy and a preparation process technology, applied in the field of superalloys, can solve the problems of low initial melting temperature, poor plasticity and oxidation resistance of nickel-based superalloys, and achieve good casting performance, good oxidation resistance, and cold and heat fatigue good performance

Inactive Publication Date: 2009-09-23
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to provide a high initial melting temperature, good high temperature strength, low specific gravity and low cost, good castability and excellent comprehensive performance equiaxed casting nickel-based superalloy and its preparation process, to solve the problem of nickel-based superalloy primary Low melting temperature, and poor plasticity and oxidation resistance

Method used

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  • Nickel-base high-temperature alloy with low density and high melting point and preparation process thereof
  • Nickel-base high-temperature alloy with low density and high melting point and preparation process thereof
  • Nickel-base high-temperature alloy with low density and high melting point and preparation process thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] The composition of this embodiment is shown in Table 1:

[0044] Table 1 Alloy composition table of the present invention (wt.%)

[0045] C

Cr

co

Al

W

Mo

Nb

Y

B

Ni

Example 1

0.045

9.0

5.0

5.9

3.5

3.0

2.3

0.013

0.023

Remain

[0046] The preparation process of the alloy is as follows: the experimental master alloy is smelted by a vacuum induction furnace, the smelting crucible is a CaO crucible, the temperature measurement system is W-Re galvanic couple and JH-5 infrared photoconductive temperature / vacuum degree tester, and the temperature measurement protection sleeve for Mo-Al 2 o 3Metal-ceramic tubes. Based on the smelting of 300kg master alloy, the operation process is as follows: put carbon, chromium, cobalt, tungsten, molybdenum, niobium alloy elements and nickel plate into the crucible; vacuumize the low-power 130kw furnace to remov...

Embodiment 2

[0059] The difference from Example 1 is that the alloy composition of this example is shown in Table 6:

[0060] Table 6 Test alloy composition table (wt.%)

[0061] C

Cr

co

Al

W

Mo

Nb

Y

B

Ni

Example 2

0.05

9.0

5.0

5.9

3.4

3.0

2.2

0.015

0.021

Remain

[0062] The preparation process of the alloy is as follows: the experimental master alloy is smelted by a vacuum induction furnace, the smelting crucible is a CaO crucible, the temperature measurement system is a W-Re galvanic couple and a JH-5 infrared photoconductive temperature / vacuum tester, and a temperature measurement protection sleeve for Mo-Al 2 o 3 Metal-ceramic tubes. The operation process of smelting 200kg master alloy meter is as follows: put carbon, chromium, cobalt, tungsten, molybdenum, niobium alloy elements and nickel plate into the crucible; vacuumize the furnace with a power of ...

Embodiment 3

[0074] The alloy composition of embodiment is as follows:

[0075] Table 10 Test Alloy Composition Table (wt.%)

[0076] C

Cr

co

Al

W

Mo

Nb

Y

B

Ni

Example 3

0.055

9.0

5.0

5.9

5.9

3.0

2.3

0.017

0.021

Remain

[0077] The preparation process of the alloy is as follows: the experimental master alloy is smelted by a vacuum induction furnace, the smelting crucible is a CaO crucible, the temperature measurement system is a W-Re galvanic couple and a JH-5 infrared photoconductive temperature / vacuum tester, and a temperature measurement protection sleeve for Mo-Al 2 o 3 Metal-ceramic tubes. The quantity of smelted master alloy is 20kg. The operation process is as follows: put carbon, chromium, cobalt, tungsten, molybdenum, niobium alloy elements and nickel plate into the crucible; vacuumize the low-power 30kw furnace to remove the attached gas, when the...

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Abstract

The invention relates to high-temperature alloy technology, and in particular provides an isometrical cast nickel-base high-temperature alloy with low density, high incipient melting temperature and good casting property and a preparation process thereof, which can be used for floating tile materials of a combustion chamber. The alloy comprises the following compositions by mass percentage: 0.03 to 0.06 percent of C, 5 to 12 percent of Cr, 5.5 to 6.5 percent of Al, 3 to 8 percent of Co, 3 to 7 percent of W, 2 to 4 percent of Mo, 1.6 to 3.2 percent of Nb, 0.01 to 0.03 percent of B, 0.008 to 0.025 percent of Y and the balance of Ni. A vacuum induction furnace is adopted to smelt a master alloy, and a smelting crucible is a CaO crucible or a MgO crucible; and the operation process comprises the following steps: putting alloying elements such as carbon, chromium, cobalt, tungsten, molybdenum and niobium in proportion and a nickel plate into the crucible; melting the alloy when the vacuum degree reaches between 50 and 0.1 Pa; and after completion of the melting, refining for 30 to 300 seconds at a temperature of between 1,550 and 1,600 DEG C, cutting off electricity, forming a film, breaking the film to add Al and Al-Y and Ni-B interalloy for uniform stirring, and casting a master alloy pig at a temperature of between 1,450 and 1,500 DEG C. The invention solves the problems of low incipient melting temperature, poor plasticity and inoxidability and the like of the nickel-base high-temperature alloy.

Description

technical field [0001] The invention relates to superalloy technology, and in particular provides an equiaxed casting nickel-based superalloy with low density, high initial melting temperature and excellent casting performance and its preparation process, which can be used as a floating tile material for a combustion chamber. Background technique [0002] Superalloys refer to a class of metal materials based on iron, nickel, and cobalt that can work for a long time at high temperatures above 600°C and under certain stresses. For half a century, the temperature before the turbine of the aero-engine has increased from 730°C in the 1940s to 1677°C. The increase in service temperature puts forward more and more stringent requirements on the materials of aero-engines. Nickel-based superalloys are by far the most superior performance and the most widely used aero-engine materials. At present, the upper limit temperature of the alloy's service temperature has reached about 1200 °...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C19/05C22C1/03C22F1/10
Inventor 孙晓峰周鹏杰于金江侯贵臣连占卫王志辉管恒荣胡壮麒
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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