574results about How to "High saturation magnetization" patented technology

The invention relates to a preparation method of a non-rare earth MnAl permanent magnetic alloy. The preparation method comprises the following steps: (1) preparing the compositions of a master alloy sample: preparing master alloy raw materials with Mn60-xAl40+x as a nominal composition according to the atom percentage, wherein x is equal to 0-10; (2) smelting the master alloy: adopting a non-self-consumable electric arc furnace, putting the prepared master alloy raw materials into a water cooling copper crucible, and repeatedly smelting the alloy for 3-5 times to obtain a MnAl alloy ingot with uniform compositions; (3) preparing an MnAl alloy ribbon by the MnAl alloy ingot by adopting a single-roller rapid quenching method; (4) carrying out vacuum heat treatment: carrying out vacuum heat treatment on the MnAl alloy ribbon obtained in the third step to obtain a tau-phase MnAl alloy; and (5) mechanical ball milling: ball milling the tau-phase MnAl alloy obtained in the fourth step to obtain tau-phase MnAl alloy powder, namely the non-rare earth MnAl permanent magnetic alloy with high coercivity. Compared with the prior art, according to the preparation method disclosed by the invention, the cost is low, the preparation process is simple, and the obtained MnAl permanent magnetic alloy is good in permanent magnetic property and high in coercivity.

A composite carbon nanotube/ferromagnetic metal nanowire material is composed of carbon nanotubes and ferromagentic metal nanowires filled in said nanotubes, and is prepared through growing carbon nanotubes while filling said nanowires in the nanotubes, and crystallizing said nanowires. If said material is dispersed in the epoxy resin/alcohol solution and then solidified, a microwave absorption material or an electromagnetic shielding material is obtained.

The invention relates to a preparation method of magnetic fluorescence dual-function silicon oxide hollow microspheres, comprising the steps of: preparing magnetic nanometer particles by a coprecipitation method; diffusing the magnetic nanometer particles in long-chain alkane after the surfaces of the magnetic nanometer particles are modified by oleic acid; mixing the oil phase composed of alkanedispersion consisting of a styrene monomer, a superhydrophobic agent and magnetic nanometer particles, and the orthosilicic acid alkyl ester with water phase in which a surface active agent is dissolved; pre-emulsifying and finely emulsifying the mixture to obtain a fine emulsion drop system; when the drops are in free radical polymerization, adding an alkali catalyst to control the generation ofsilicon oxide and the phase separation of the organic and inorganic components of the system; in the reaction process, adding proper ammonia water and a silane coupling agent which is marked by fluorescein to obtain the hollow compound microspheres which are different in sizes, inorganic shell thicknesses and magnetic particle solid content and have stable fluorescence signals. The preparation method disclosed by the invention is simple, the raw materials are low in cost and easy to obtain; and the obtained fluorescence dual-functional hollow silicon oxide microspheres are narrow in size distribution, high in magnetic substance content and stable in fluorescence performance.

The invention discloses a new compound Fe3O4/Au magnetic compound Nami grain method, which is characterized in that: the invention utilizes supersonic chemical method to restore gold ion on a amino or hydrosulfuryl functional magnetic Nami grain to realize the preparation of the sample. The method doesn't need purifying product, which is quick and directviewing and is a novel compound method with simple and quick operation and high yield.

The invention provides an iron base non-crystalline material and a preparation method thereof. The iron base non-crystalline material has components of Fe100-a-b-cMcBbAa, wherein M is any one or more of Si, Zr, Nb, Cr, P, Al, Co, Ni and Ti, A is N and/or C, a is not less than 0.5 and not more than 2 at%, b is not less than 9 and not more than 14 at%, and c is not less than 0 and not more than 10 at%; the non-crystalline material comprises a non-crystalline basal body layer and a surface layer positioned on the non-crystalline basal body layer; and the surface layer is a FeA enriched layer. The non-crystalline basal body layer in the iron base non-crystalline material is used for providing basic performances of the iron base non-crystalline material; and through auxiliary cooperation of the performances of the surface layer, the performances of the iron base non-crystalline material can be enhanced, the saturation magnetization is improved, the coercive force is reduced, and the overall performances of the iron base non-crystalline material are improved.

The present invention discloses fast microwave crystallizing process for preparing nanometer crystalline iron-base soft magnetic alloy. The technological process includes the following steps: 1. smelting alloy with Fe, Cu, Nb, Si and B in the ratio of Fe73.5Cu1Nb3Si13.5B9 in an induction furnace at vacuum 3-10 Pa in high purity Ar; 2. setting coarsely crushed alloy inside quartz pipe with nozzle in the bottom, setting the quartz pipe inside induction coil in a belt spinning machine, and melting the mother alloy in protecting Ar atmosphere; 3. spraying the alloy liquid under the pressure of Ar to the surface of rotating copper roller to form non-crystalline alloy belt; and 4. sealing the thin belt in quartz tube and crystallizing treatment in a microwave sintering furnace at 400-900 deg.c for 10-180 min to obtain ideal nanometer crystal structure.

The invention relates to a preparation method for a superparamagnetism ferroferric oxide sub-micron hollow microsphere. The preparation method comprises the following steps: 1) taking a reducing agent, an iron source and an alkali source, and dissolving into distilled water; 2) dissolving a surfactant into a solution obtained from step 1); 3) introducing a solution obtained from step 2) into a reaction kettle, reacting in a drying oven, performing natural cooling to room temperature for seasoning, water washing, alcohol washing, and drying in a vacuum drying box, so that the superparamagnetism ferroferric oxide sub-micron hollow microsphere is obtained. The preparation method has the following good effects: 1) according to the invention, the ferroferric oxide sub-micron hollow microsphere is compounded, and has superparamagnetism, high saturation magnetization and excellent oxidation resistance; 2) dispersing agents such as PEG (polyethylene glycol) and PVP (polyvinylpyrrolidone) are adopted to solve the problem of magnetic microsphere agglomeration, so that the ferroferric oxide sub-micron hollow microsphere with uniform particle size is obtained; 3) according to the invention, adopted raw materials is cheap, so that cost is minimized.

A low-loss LiZn ferrite material for a phase shifter relates to the technical field of preparation of ferrite materials. The low-loss LiZn ferrite material consists of main materials, additives and binding agents, calculated by Fe2O3, ZnO, Mn3O4 and Li2CO3, the main materials comprise 64-71 mol percent of Fe2O3, 15-22 mol percent of ZnO, 0.8-1.5 mol percent of Mn3O4 and 9.9-12 mol percent of Li2CO3; relative to the main materials, the additives are calculated by Bi2O3, BST and Nb2O5, and the proportion is 0.5-3.0 wt percent of Bi2O3, 0.1-0.5 wt percent of BST and 0.05-0.4 wt percent of Nb2O5. The invention reduces the coercivity and the dielectric loss, and improves the saturation magnetization, thus realizing the low temperature preparation of the LiZn ferrite material with low coercivity, low dielectric loss and high saturation magnetization.

The invention relates to a high-saturation-magnetization iron-base amorphous nanocrystal soft magnetic alloy and a preparation method thereof. The alloy is expressed as FeaMbCucSixByPz, wherein M is one or more of Al, Cr, Mn, Ti and V; and 68<=a<=90, 0<=b<=6, 0<=c<=2, 3<=x<=20, 4<=y<=20, 0<=z<=10, and a+b+c+x+y+z=100. Compared with the prior art, the product has the advantages of high saturation magnetization and the like.

The invention relates to a method for producing magnetic nanometer particles, with shape aeolotropism and magnetic crystal aeolotropism, or multi aeolotropism. Wherein, it can be used to prepare single-phase stack hexagonal (HCP) cobalt nanometer particles and binary or ternary alloy nanometer particles of iron, cobalt and nickel. The invention processes at 90-200Deg. C and more than one pressure reacts the metal salt or cobalt with water.

The invention provides an amorphous alloy material with Fe as the main component and a preparation method thereof. The amorphous alloy material of the invention comprises the chemical components with the following parts by weight: Fe: 91.0-93.5; Si: 5.2-6.6; B: 2.5-3.3; Cr: 0.05-0.25; Cu: 0.010-0.030; and C: 0.05-0.20. The Fe-based amorphous alloy belt material has simple design in components, and good mechanical property and fine processability of the material; moreover, yield is over 90%. In addition, the manufactured Fe-based amorphous alloy belt material has high comprehensive magnetic property; and coreloss of a transformer manufactured by the amorphous alloy material is greatly reduced. The Fe-based amorphous alloy belt material enjoys wide application and low use cost and serves to save energy and protect the environment.

The invention discloses an inhomogeneous nucleation insulation coating processing method of a metal soft magnetic composite material. The method includes the following steps that (1) particle size distribution is conducted on metal magnetic powder after sieving is conducted; (2) insulation coating is conducted on the distributed metal powder through an inhomogeneous nucleation method, and then the metal powder is dried; (3) the dried magnetic powder and a binding agent are evenly fixed, a release agent is added to conduct dry pressing and forming, and the mixture is pressed to form blank samples; (4) heat preservation is conducted on the blank samples for half an hour to two hours in a protective atmosphere, and air cooling and spray coating are conducted to obtain the target product. The composite powder prepared through the inhomogeneous nucleation method is even and compact in coating and controllable in coating layer thickness, and has high oxidation resistance, high resistivity, high saturation magnetization intensity, the good magnetic property and the good mechanical property; the surface of the metal magnetic powder is evenly coated with an A12O3 insulation layer through the inhomogeneous nucleation method, so that the coating effect is superior to that of an existing method, the operability is high and volume production is facilitated.

The invention provides a method for preparing monodisperse Fe3O4 magnetic nanoparticles. Precursor is Fe2O3 or iron oxide yellow which has the chemical formula of Fe2O3.H2O; stabilizing agent is oleic acid; high temperature organic solvent is 1-octadecylene (b. p. 318DEG C); precipitating agent is prepared by mixing any two of toluene, dimethyl benzene, ethanol, isopropanol and acetone according to the volume ratio of 1:4-2:3; the mol ratio between the precursor and the stabilizing agent is 1:4-1:9; the mol ratio between the precursor and the high temperature organic solvent is 1:10; inert gas protection is not needed, and the Fe3O4 magnetic nanoparticles which have small sizes, monodisperse, narrow distribution, high saturation magnetization intensity and superparamagnetism. The method can be widely applied to biomedicine fields such as magnetic resonance imaging, biological magnetic separation, magnetic target drug carrier, biological magnetic marker and the like, and the high technical fields such as magnetic sealing, aerospace lubrication, magnetic anti-counterfeiting ink material, etc.

The invention discloses Mn element and Zn element-doped super-paramagnetic ferrite nanoparticles and a preparation method thereof. Manganese element is added or manganese element and zinc element are simultaneously added into a face-centered cubic crystal structure of ferriferrous oxide nanoparticles by using a method of decomposing metal precursor compound at a high temperature; the magnetic performance of the prepared super-paramagnetic nanoparticles is improved by changing the doping amount and the distribution of the metal element; and primarily, the saturation magnetization is improved. The preparation method specifically comprises the following steps of: mixing acetylacetones of Fe and Mn as well as Zn with 1,2-hexadecanol; performing high-temperature decomposition in high-boiling-point solvent by taking oleic acid and oleylamine as surfactants; or performing high-temperature decomposition on composite oleate of Fe, Mn and Zn by taking the oleic acid as the surfactant; heating and preserving heat in stages in argon or nitrogen protective atmosphere to guarantee growth of nanoparticle nuclear; and cooling to room temperature after reaction is finished and settling and centrifuging to finally obtain the super-paramagnetic ferrite nanoparticles which are uniformly dispersed in normal hexane solution.

The invention provides a preparation method of a PVP modified prussian blue nanometer material. The method concretely comprises the following steps of (1) dissolving PVP and precursors into water formixing; (2) adding hydrochloric acid for regulating the pH to an acid state; (3) performing reaction under the electromagnetic induction heating; (4) performing ethanol water centrifugal washing, dialysis and freeze drying to obtain a finished product. According to the method, magnetic inner heat is used for replacing an ordinary external heating mode; in a shorter reaction time, the high-qualityprussian blue nanometer material can be obtained. The PVP modified prussian blue nanometer material prepared by the method has the advantages of small polydispersity coefficient, uniform particle dimension distribution, higher magnetism and higher nanometer enzymatic activity.

The invention discloses a high-bonding-strength insulated coating treatment method of a metal soft magnetic composite material. The method comprises the following steps: (1) sieving metal magnetic powder, and performing particle size distribution; (2) performing insulated coating on the distributed metal magnetic powder by using a sol-gel method, and then drying the metal magnetic powder; (3) uniformly mixing the dried magnetic powder and an adhesive, adding a release agent, and performing dry pressing to obtain a magnetic ring; (4) performing heat preservation, air cooling and spraying on the magnetic ring in protective atmosphere to obtain a target product. The bonding strength of composite powder prepared by using the sol-gel method and magnetic powder particles is high, the powder is coated uniformly and densely, and a coating layer is controllable in thickness, good, oxidation resistance and high saturation magnetization intensity are achieved, excellent in magnetic property and mechanical property, high in bonding strength, and not prone to disengagement; the coating effect is superior to that of an existing method; the method is high in operability and facilitates batch production; the resistivity of soft magnetic metal particles is effectively improved, and the magnetic core loss of the soft magnetic composite material is greatly reduced.

The invention discloses a preparation method of a magnetic nano ferroferric oxide modified hollow glass microsphere. The method comprises the steps of removing oil of a hollow glass microsphere; soaking the hollow glass microsphere with oil removed in a coarsening solution to react, filtering and subsequently washing, and drying; dipping the hollow glass microsphere in a coupling agent solution to react, filtering and subsequently washing, drying and baking; dipping the hollow glass microsphere in a chitosan solution, stirring and filtering, subsequently prebaking and baking; soaking the dried hollow glass microsphere in a sodium hydroxide solution, filtering and then washing; and finally dipping the hollow glass microsphere in a ferrous chloride mixture solution, transferring to a high-pressure reaction kettle, sealing and then carrying out insulation treatment, and filtering the hollow glass microsphere after finishing reacting; and washing respectively by using absolute ethyl alcohol and deionized water and drying. The preparation method saves the raw material and is easy and simple to operate; through the modification on the surface of the hollow glass microsphere, the problems of no magnetism, poor coating fastness, weak magnetism and the like of the hollow glass microsphere are solved.