The invention provides a hollow PtAgS
nanocrystalline material as well as a preparation method and application thereof, and belongs to the technical field of synthesis of nano materials. A simple two-step hydrothermal method is adopted, firstly, a gel precursor is synthesized to serve as a self-sacrifice template, then a
platinum source, a silver source, a
sulfur source and the template are subjected to a
hydrothermal reaction together, and the hollow PtAgS
nanocrystal is obtained. According to the preparation method disclosed by the invention,
platinum and silver atoms are induced to diffuse outwards from a
sulfur-containing core by utilizing twin
crystal defects formed in the initial stage of reaction, so that a hollow structure is formed; the process is simple and efficient, the product is pure, the structure is uniform and controllable, and the prepared hollow PtAgS
nanocrystal is a
ternary alloy nanocrystal with a uniform hollow structure, has twin
crystal defects, shows excellent soft magnetic properties including
high saturation magnetization and low coercive force, is particularly suitable for high-frequency and low-loss magnetic devices, and has wide application prospects. Such as miniaturized electronic components and magnetic sensors, and has a wide industrial application prospect.