808 results about "Ferriferrous Oxide" patented technology

The invention discloses a preparation method and application of a vertically-oriented boron nitride / epoxy resin heat-conducting composite material under a magnetic field, and belongs to the field of composite materials. The invention aims to solve the problems of high cost, complex process and narrow application range of the existing filler directional arrangement method. The method comprises the following steps: 1, preparing a mixed solution of boron nitride and ferroferric oxide; 2, preparing a boron nitride nanosheet solution with ferroferric oxide attached to the surface; (3) preparing BNNS coated Fe3O4; and 4, preparing the vertically-oriented boron nitride / epoxy resin heat-conducting composite material under the magnetic field. The invention relates to application of a vertically-oriented boron nitride / epoxy resin heat-conducting composite material in electronic packaging under a magnetic field. The heat conductivity of the epoxy resin can be effectively improved, the process is simple and reliable, the efficiency is high, the cost is low, the heat conductivity coefficient is high, and the method can be applied to electronic packaging.

The invention belongs to the technical field of energy storage materials, and particularly relates to a high-entropy oxide Fe0. 2Co0. 2Ni0. 2Cu0. 2Zn0. 2O and an ultrafast synthesis method and application thereof. According to the preparation method, ferroferric oxide, cobalt oxide, nickel oxide, copper oxide and zinc oxide with equal molar ratio are adopted as direct synthesis raw materials, toxic gases such as chlorine and nitrogen dioxide generated in the synthesis process of a metal salt precursor are avoided, and the uniformly distributed single-phase high-entropy oxide is synthesized in an ultrafast manner within 10 seconds by using a Joule heating technology; the synthesized high-entropy oxide is used as a lithium ion battery negative electrode material, and shows more excellent electrochemical performance and cycling stability compared with other high-entropy oxides prepared from transition metals with different proportions; in the preparation process, extra additives are not needed, operation is easy, the synthesis speed is high, the yield is high, element distribution is uniform, and the method has the advantages of being low in cost, high in efficiency and free of pollution and has the industrialization prospect.

The invention discloses a magnetic biochar-based saline-alkali soil conditioner as well as a preparation method and application thereof, after a biochar material is loaded on ferrous iron, the biochar material is subjected to alkaline oxidation to obtain ferroferric oxide and a porous biochar material in a stable state, and finally activated humic acid, betaine, trehalose and melatonin are combined with magnetic biochar. The magnetic charcoal-based saline-alkali soil conditioner is low in price and easy to obtain and has a good improvement effect on physicochemical properties of saline-alkali soil and promotion of rice growth, and the preparation process is simple and easy to operate.

The invention discloses a CFD (computational fluid dynamics) simulation-based magnetofluid jet shear polishing device and method. The device comprises an industrial five-axis machine tool, a fluid circulation system, a jet polishing module and a CNC (computer numerical control) system. The jet flow polishing module and the machined workpiece 8 are installed on a workbench and a tool installation base of the industrial five-axis machine tool respectively, and five-axis polishing machining can be achieved under the control of a CNC numerical control system. The jet flow polishing module comprises a jet flow tool head and a rotating magnetic field generating device. The rotating magnetic field is applied to the jet flow outlet of the jet flow tool head, ferroferric oxide particles in the polishing solution are driven to be arranged in the magnetic line direction to form a chain structure, the viscosity of the polishing solution is remarkably improved, and the polishing solution is endowed with the high-speed self-rotating motion characteristic. High-speed rotation and enhanced viscosity of the liquid column generate stronger shearing force, so that efficient material removal on the surface of a workpiece is realized.

The invention belongs to the technical field of nano magnetic beads, and relates to a carboxyl nano magnetic bead and application thereof in DNA capture and DNA release. The invention discloses a preparation method of carboxyl nano magnetic beads, which comprises the following steps: dissolving iminodiacetic acid in a sodium hydroxide solution, stirring in an ice bath, dropwise adding a silane coupling agent, carrying out a first heating reaction, cooling in the ice bath, dropwise adding the silane coupling agent again, carrying out a second heating reaction, and cooling in the ice bath to obtain a carboxyl silane coupling agent; and dispersing the ferroferric oxide / silicon dioxide hydroxyl magnetic compound and a carboxyl silane coupling agent in an organic solvent, and stirring for reaction to obtain the carboxyl nano magnetic beads. The carboxyl nano magnetic bead is a nano-scale magnetic bead, is large in specific surface area, good in suspension property and not easy to settle, and has multiple sites for DNA binding; the method can be used for effectively extracting DNA ladders and cfDNA in nucleic acid capture and nucleic acid release.

The invention discloses a preparation method and application of a magnetic enrichment composite SERS (Surface Enhanced Raman Scattering) detection chip, gold nanoparticles are electrostatically adsorbed on the surface of a magnetic ferroferric oxide nanoring, the prepared material is subjected to cyclodextrin modification, nanogaps among the gold nanoparticles form hot spots, a local electromagnetic field enhancement effect is generated, and the magnetic enrichment composite SERS detection chip is obtained. The cyclodextrin molecules adsorb PAHs in the environment through a hydrophobic effect and are fixed in an electromagnetic field enhancement area, amplification of Raman signals is achieved, the magnetic material serves as a carrier, aggregation of gold nanoparticles can be effectively prevented, SERS signals can be further enhanced through a magnetic enrichment effect, and therefore, the method has the advantages that the method is simple, and the application prospect is wide. The high-sensitivity and high-selectivity detection of PAHs in the tail gas of the engineering machinery vehicle is realized by constructing the magnetic composite SERS nano sensing chip.

The invention relates to the field of biological medicine, in particular to IMSFs hydrogel, a ferroptosis induction system, a preparation method and application. The IMSFs hydrogel comprises a hydrogel body, and ferroferric oxide nanoparticles and sorafenib are loaded in the hydrogel body in a wrapping manner. The IMSFs hydrogel can be used as an injectable cascade ferroptosis anti-cancer drug. The preparation method of the IMSFs hydrogel comprises the following steps: firstly, preparing a silk fibroin-hyaluronic acid hydrogel body: dissolving silk hydrogel and hyaluronic acid in a lithium bromide solution; bDDE is added into the dissolved solution, and incubation is carried out; then dialyzing and washing with deionized water to obtain a silk fibroin-hyaluronic acid hydrogel body; and then loading the sorafenib nanoparticles and the ferroferric oxide nanoparticles into the silk fibroin-hyaluronic acid hydrogel body. The IMSFs hydrogel disclosed by the invention integrates magnetic thermal response and drug controlled release, and can be injected to a tumor site, so that the treatment effect on TNBC is remarkably improved.

The invention provides a stationary phase for DNA synthesis and a preparation method and application thereof. The preparation method of the stationary phase for DNA synthesis, provided by the invention, comprises the following steps: S1, preparing nano magnetic ferroferric oxide particles, and coating the surfaces of the nano magnetic ferroferric oxide particles with SiO2 layers to obtain a nano magnetic composite material Fe3O4-SiO2; s2, carrying out azide group modification on the surface of the nano magnetic composite material Fe3O4 (at) SiO2 to form a surface-modified nano magnetic composite material Fe3O4 (at) SiO2 (at) N3; and S3, loading the initiator to the surface of the surface-modified nano magnetic composite material Fe3O4 (at) SiO2 (at) N3 through Click reaction to obtain the stationary phase for DNA synthesis. The stationary phase provided by the invention can be used for DNA synthesis, and has the characteristics of high bonding strength, good stability, difficult shedding of initiators, high DNA synthesis yield and the like.

The invention discloses a preparation method and application of a composite catalyst for preparing aromatic hydrocarbon through hydrogenation of carbon dioxide, the composite catalyst is formed by compounding an iron-based catalyst and an HZSM-5 molecular sieve, the main active components of the iron-based catalyst are Fe3O4 and iron carbide, the preparation method comprises the steps of preparation of modified ferric oxide, preparation of modified ferroferric oxide, preparation of the iron-based catalyst and the like. The preparation method provided by the invention improves the adsorption activation capability of carbon dioxide on the composite catalyst and the anti-poisoning stability of the composite catalyst, and also improves the aromatic hydrocarbon selectivity of the product.

The invention relates to a light / heat / magnetic detachable high-strength polyurethane adhesive as well as a preparation method and application thereof. The light / heat / magnetic detachable high-strength polyurethane adhesive comprises a polyurethane adhesive and a functional filler. According to the light / heat / magnetic detachable high-strength polyurethane adhesive prepared by the preparation method disclosed by the invention, the colloid is black, and the adhesive has excellent light absorption performance and can realize rapid separation of an adhesive interface under infrared irradiation through a heat effect; meanwhile, the ferroferric oxide can be vibrated and heated under the action of an external magnetic field due to the magnetic response characteristic of the ferroferric oxide, so that fracture and separation of the adhesive layer are promoted. By means of the technology, efficient and reversible disassembly of parts bonded through the hot melt adhesive is achieved, possibility is provided for recycling and reusing of bonding materials and devices, and the problem that traditional polyurethane hot melt adhesive cannot be recycled is solved.

The invention provides a wave-absorbing material, and belongs to the technical field of electromagnetic wave absorption. The wave-absorbing material comprises a metal reflection bottom layer, a wave-absorbing middle layer and a scattering upper layer, the wave-absorbing middle layer is made of a ferroferric oxide loaded reduced graphene oxide and epoxy resin (Fe3O4 (at) RGO / EP) composite material and used for absorbing electromagnetic wave energy, and the scattering upper layer is of a patterned metasurface structure made of chopped carbon fiber reinforced epoxy resin (SCF / EP). And a phase-regulated two-dimensional periodic array is formed. By arranging a three-layer structure of the metal reflecting layer, the Fe3O4 (at) RGO / epoxy composite wave-absorbing layer and the chopped carbon fiber scattering layer, broadband absorption and directional scattering control of electromagnetic waves within the range of 2-18 GHz are achieved, a stealth function composite material system with dissipation and deflection dual-mechanism cooperative work is formed, the structure utilizes the patterning design of the scattering layer, and the structure has the advantages that the structure is simple, the structure is compact, and the application range is wide. On the basis of the generalized Snell's law, engineering regulation and control of the radar wave reflection direction are achieved by regulating and controlling the reflection phase difference between pattern units, reflection energy is effectively deviated from the main lobe direction of a radar receiver, and therefore the reflection signal intensity of a target in a radar detection system is reduced.

The invention discloses a heterogeneous nanoflower electrocatalyst and a preparation method thereof. The electrocatalyst is a heterogeneous nanoflower constructed by cross-assembly of ultrathin palladium-based alloy nanosheets and ferroferric oxide nanosheets. The heterogeneous nanoflower contains two physical phases, palladium-based alloy and ferroferric oxide. The palladium-based alloy nanosheets and ferroferric oxide nanosheets cross each other to form a clear interface. The preparation method is simple and feasible, and the process is controllable. The heterogeneous nanoflower electrocatalyst has abundant interface sites, can significantly enhance the electrocatalytic performance, is a new alloy / oxide coupling material system, and is of great significance for improving the electrocatalytic activity and durability.

The invention discloses a magnetic carbon-loaded slow-release microbial agent which comprises an activated carbon carrier containing ferroferric oxide nanoparticles and a compound microbial bacterium composed of bacillus megatherium, bacillus mucilaginosus, white-rot fungi and pseudomonas, and the mass ratio of the compound microbial bacterium to the activated carbon carrier is (3-4): 30. The invention further discloses a preparation method and application of the magnetic carbon-loaded slow-release microbial agent. According to the magnetic carbon-loaded slow-release microbial agent disclosed by the invention, the activated carbon containing the ferroferric oxide nano-particles is used as a carrier to load the compound bacteria, so that the stability of the microbial bacteria is improved, the microbial bacteria can better resist the impact of the environment, the service life of the microbial bacteria is prolonged, and the slow-release effect of the microbial agent in the remediation of vegetable planting soil is achieved; the nutrient absorption of the vegetables is promoted.

The invention belongs to the technical field of seedling raising substrates, and particularly relates to a seedling raising substrate based on straw and cow dung and a preparation method thereof.The seedling raising substrate based on straw and cow dung is prepared from, by weight, 20-40 parts of dry cow dung, 20-40 parts of straw segments, 10-20 parts of ferroferric oxide composite water-absorbent resin, 6-8 parts of EM bacteria and 40-60 parts of field soil. The preparation method comprises the following steps: grafting a silane coupling agent on the surface of ferroferric oxide, then carrying out polymerization reaction on the surface of the ferroferric oxide grafted with the silane coupling agent and acrylic acid to generate ferroferric oxide-sodium polyacrylate particles, and the ferroferric oxide-sodium polyacrylate particles are magnetic particles. And the surfaces of the ferroferric oxide-sodium polyacrylate particles have abundant carboxyl (-COOH) and sodium carboxylate (-COONa) functional groups. The functional groups can form hydrogen bonds or ionic bonds with water molecules, so that the hydrophilicity and water absorption of the surfaces of the particles are improved.

The invention discloses a double-template molecularly imprinted composite magnetic covalent organic framework material and a preparation method and application thereof.A layer-by-layer assembly method is adopted, a covalent organic framework is assembled on the surface of aminated ferroferric oxide nanoparticles at the room temperature, then an imprinted layer is formed on the surface of the covalent organic framework through a surface molecular imprinting method, and the double-template molecularly imprinted composite magnetic covalent organic framework material is obtained. And the double-template molecularly imprinted composite magnetic covalent organic framework material MCOF (at) MIP is prepared. The MCOFF-MIP prepared by the preparation method disclosed by the invention has excellent magnetic responsiveness. Experiments show that the MCOFF-MIP has a good adsorption effect and selectivity on four kinds of bisphenol, and has a good application prospect.

The invention provides a method for producing carboxyl magnetic beads based on industrial solid waste, and relates to the technical field of carboxyl magnetic bead preparation, and the method comprises the following steps: preparing a saturated solution from ferrous sulfate solid waste; removing heavy metal impurities in the saturated solution by using a mixed extraction agent through an extraction method to obtain a ferrous ion crude product; synthesizing the ferrous ion crude product through a hydrothermal method to obtain ferroferric oxide particles; carrying out hydroxyl coating treatment on the ferroferric oxide particles to obtain hydroxyl coated particles; and carrying out carboxyl coating treatment on the hydroxyl coated particles to obtain the carboxyl magnetic bead material. Ferroferric oxide is produced by taking ferrous sulfate solid waste as a raw material through a hydrothermal method, then separation is carried out through a magnetic field, the separated ferroferric oxide is modified with a silicon hydroxyl coupling agent, the required iron oxyhydroxide magnetic beads are directly obtained, waste resources are utilized in an environment-friendly mode, the production cost is reduced, and the method is suitable for industrial production. And the great potential of improving the product quality and functionality is achieved.

The invention relates to the field of water purifying agents, and discloses a polyaluminum chloride water purifying agent for printing and dyeing wastewater and a preparation method thereof.The polyaluminum chloride water purifying agent for printing and dyeing wastewater is prepared from polyaluminum chloride, an adsorption additive, magnetic composite filler and the balance deionized water; the adsorption additive is prepared by ultrasonically compounding a modified ZIF-8 coated iron material and modified nano titanium dioxide; the modified ZIF-8 coated iron material is prepared by coating nano zero-valent iron with ZIF-8 and carrying out high-temperature carbonization. The modified nano titanium dioxide is prepared by doping and modifying cerium; the magnetic composite filler is prepared by the following steps: pretreating sepiolite by using hydrochloric acid, then coating the surface of the pretreated sepiolite with chitosan by adopting a coprecipitation method, and loading ferroferric oxide particles into the chitosan. Therefore, the usage amount of polyaluminum chloride is reduced, and the water purifying agent is endowed with excellent photocatalytic activity and adsorption effect in printing and dyeing wastewater.

The invention discloses a sewage zero discharge treatment device which comprises a sewage treatment tank, a first partition plate, a second partition plate, a third partition plate and a fourth partition plate are arranged in the sewage treatment tank, a closed area between the third partition plate and the fourth partition plate forms a collection pool, and a rotating magnetic field device is arranged on the periphery of an anaerobic pool. The rotating magnetic field device generates a rotating magnetic field, ferroferric oxide nanoparticles with the surfaces modified with sulfonic acid groups exist in the anaerobic tank, the ferroferric oxide nanoparticles have superparamagnetism and are driven by the rotating magnetic field to form a directional vortex flow, and the ferroferric oxide nanoparticles adsorb protons and load anaerobic microorganisms. A magnetic biological membrane is formed, meanwhile, the mixed mass transfer efficiency of microorganisms and sewage is enhanced through the directional vortex flow, an ultrasonic vibrator array is arranged at the bottom of the aerobic tank, and a collecting device is arranged above the sewage treatment tank.

The invention discloses an environment-friendly cooling anti-radiation refrigeration coating and a preparation method thereof, and belongs to the technical field of coating preparation. The raw materials are prepared from core materials, auxiliary materials and ingredients. The core material is prepared from a main raw material, hollow glass beads and environment-friendly resin, the auxiliary material is prepared from a nano additive and mineral pigment, and the ingredients are prepared from ferroferric oxide, nano titanium dioxide, diopside and polyvinylidene fluoride. The main raw materials comprise carbon quantum dots, carbon nanofibers, carbon nanospheres and graphene quantum dots; the environment-friendly resin base material is prepared from waterborne polyurethane resin, rosin resin, shellac resin and polytetrafluoroethylene; the nano additive is composed of silicon carbide, carbon black, carbon fibers, magnesium borate and carbon nanotubes. According to the coating, solar energy can be converted into light energy, the sunlight reflectivity of the coating is improved through the unique optical property of the coating, the sunlight reflectivity of the coating can be correspondingly improved along with increase of the sunlight intensity, and therefore the situation that a building absorbs excessive heat is avoided.

The invention belongs to the technical field of fabric coatings, and particularly relates to a self-cleaning sensing type composite coating for fabric and a preparation method of the self-cleaning sensing type composite coating. The self-cleaning sensing type composite coating comprises a polypyrrole coating, a ferroferric oxide coating and a hydrophobic polyurea modified coating. The self-cleaning sensing type composite coating has good self-cleaning performance, sensing performance, wave absorbing performance and hydrophobic performance.

The invention provides an electrolyte, a preparation method thereof and a lithium ion battery, and relates to the field of lithium ion batteries. According to the electrolyte, carbon-coated ferroferric oxide particles are introduced to serve as a magnetic additive, the carbon-coated ferroferric oxide particles are mainly composed of ferroferric oxide nano-particles and porous carbon coating layers coating the surfaces of the ferroferric oxide nano-particles, and the structure enables the ferroferric oxide nano-particles to have good dispersion stability in the electrolyte; and when the electrolyte is under the action of an external magnetic field, the carbon-coated ferroferric oxide particles can generate specific response and movement, and are orderly arranged in a certain direction within milliseconds to form a chain structure and a linear channel, so that the diffusion of lithium ions in the electrolyte is changed from disordered state to ordered state, the transmission rate of the lithium ions is improved, and meanwhile, the performance of the lithium ion battery is improved. And under the magnetic flux superposition effect of the magnetic particles, Li < + > cuts magnetic induction lines, so that the temperature of the electrolyte is increased, and the fast charging performance is further improved. The invention also provides a lithium ion battery which comprises the electrolyte.

The invention relates to the technical field of biological separation materials, and discloses an amine-functionalized magnetic nano composite material and application thereof in protein separation and purification. The material has a core-shell structure and comprises a magnetic ferroferric oxide nano core, an ordered mesoporous silicon dioxide intermediate layer and a covalent grafted polyethyleneimine functional layer. By controlling the matching relationship between the pore diameter of mesopores and the molecular size of the polymer and adopting a crosslinking strategy, the material has high magnetic responsiveness, rapid mass transfer performance and high-density surface amino groups. The material shows high adsorption capacity, rapid adsorption kinetics and good cycle stability in the protein separation process, and is suitable for enrichment purification and metal chelating affinity separation of protein in a biological sample. According to the invention, the technical problems of low protein adsorption capacity, slow dynamics and poor cycling stability caused by compact shell layer, non-uniform amino distribution and limited mass transfer of the existing amine functionalized magnetic material are solved.

The invention provides a biochar repairing agent for marine sediments and a preparation method of the biochar repairing agent, and belongs to the technical field of repairing agents. The preparation method comprises the following steps: carbonizing straws, modifying by phosphoric acid and concentrated nitric acid, depositing ferroferric oxide-titanium dioxide, loading UiO-66-(COOH) 2 on the surface, coupling cyclodextrin-MOF and chitosan, crosslinking, performing magnet separation, washing and drying to obtain the biochar repairing agent for the marine sediments. The biochar repairing agent for the marine sediments prepared by the invention has a relatively large specific surface area and a plurality of coordination groups, can better fix heavy metal ions in the marine sediments, also has a photocatalytic degradation effect on organic pollutants, and is good in mechanical strength, easy to store and transport, safe, environment-friendly and easy to separate; wide application prospects are realized.

The invention belongs to the technical field of materials and harmful pollutant removal, and particularly relates to a graphite-phase carbon material for adsorbing and removing mycotoxin in food as well as a preparation method and application of the graphite-phase carbon material. The preparation method of the graphite-phase carbon material comprises the following steps: at normal temperature and normal pressure, ball-milling graphite or a mixture of graphite and ferroferric oxide into solid powder, so as to prepare the graphite-phase carbon material for adsorbing and removing mycotoxin in food. The graphite phase carbon material is good in adsorption effect; the composition can be used for preparing aflatoxin, zearalenone, ochratoxin, deoxynivalenol and T-2 toxin in various oils such as peanut oil, soybean oil, corn germ oil, rapeseed oil, sesame oil, walnut oil, linseed oil, rice bran oil, wheat germ oil, edible plant blend oil, sunflower seed oil, olive oil, camellia oleosa seed oil, perilla seed oil and almond oil. And various fungaltoxins such as fumonisins are removed, so that the pollution level of the fungaltoxins in the edible vegetable fat can be effectively reduced.

The invention provides application of Fe3O4 nanoparticles in preparation of a medicine for treating benign prostatic hyperplasia, and relates to the technical field of biological medicines. The invention further discloses application of the Fe3O4 nano-particles in preparation of a medicine for treating benign prostatic hyperplasia. The research result of the invention emphasizes that the ferroferric oxide nanoparticles are a promising candidate drug for targeted therapy of BPH and related prostate diseases, and new possibility is provided for treatment intervention of urinary surgery. The inventor studies the effect of the Fe3O4 nanoparticles in inhibiting benign prostatic hyperplasia. Results of the inventor show that the nanoparticles not only effectively reduce the proliferation rate of prostate cells, but also improve related biochemical indexes. Therefore, the polypeptide has potential application in treatment of prostatic hyperplasia.

The invention belongs to the technical field of preparation, analysis and detection of nano composite materials, and particularly relates to a functional polypeptide modified nano composite magnetic bead, a method for detecting beta-secretase by using the functional polypeptide modified nano composite magnetic bead and application of the functional polypeptide modified nano composite magnetic bead to the detection of beta-secretase. The surface of a shell layer is connected with an ethylenediamine tetraacetic acid modification layer, metal ions Co < 2 + > or Ni < 2 + > are chelated on the modification layer, functional polypeptide marked by fluorescein Cy5 and the metal ions Co < 2 + > or Ni < 2 + > are coupled and loaded on the surface of a nano composite magnetic bead, and the nano composite magnetic bead is used for detecting beta-secretase. The kit has the advantages of high sensitivity, strong anti-interference capability, small background signal and capability of being magnetically separated and repeatedly used, the detection linear range is 2.5 ng / mL-800ng / mL, the detection limit is 0.62 ng / mL, and the kit has important application potential in AD early diagnosis and treatment and drug research and development.

The invention discloses a preparation method of a wear-resistant magnetic composite nano ferroferric oxide material, and belongs to the technical field of nano ferroferric oxide materials.The preparation method comprises the steps that coated modified ferroferric oxide composite powder, silver nitrate and absolute methanol are added into a reaction kettle, stirring and ultrasonic dispersion are conducted, then 2-aminoterephthalic acid is added, stirring and mixing are conducted, and a mixture is obtained; and after the reaction, separating to obtain the wear-resistant magnetic composite nano ferroferric oxide material. The wear-resistant magnetic composite nano ferroferric oxide material prepared by the preparation method disclosed by the invention overcomes the problem that an existing ferrite material is relatively single in electromagnetic loss mechanism in the aspect of nickel-phosphorus plated fabric, and the electromagnetic shielding effectiveness of the fabric is improved; the coated modified ferroferric oxide composite powder has good dispersity, a polydopamine coating layer on the surface of the coated modified ferroferric oxide composite powder improves the anchoring effect on silver MOF particles through a mussel-like adhesion interface, meanwhile, stress is dispersed and crack propagation is reduced through the buffering effect of the polydopamine coating layer, and the mechanical stability of the wear-resistant magnetic composite nano ferroferric oxide material is improved.

The invention discloses an ultraviolet-aging-resistant high-toughness wind power cable and a preparation method thereof, belongs to the technical field of cable preparation, is used for solving the technical problem that the ultraviolet aging resistance and toughness of a wind power cable in the prior art need to be further improved, and specifically comprises a wire layer, a shielding layer and a sheath layer; the preparation method comprises the following steps: coating an organic silicon layer on the outer side of a nano titanium dioxide particle and modifying amino to obtain a modified chain extender, carrying out chain extension on a long-chain polyurethane structure to obtain composite polyurethane, and carrying out hydrolysis by taking activated glass microspheres as a matrix and tetramethyl orthosilicate as a supplement to obtain modified aerogel. The preparation method comprises the following steps: preparing modified aerogel, modifying ferroferric oxide particles on the modified aerogel by using in-situ loading, further modifying perfluoro groups to obtain composite aerogel, finally mixing composite polyurethane, the composite aerogel and auxiliary materials, and performing melt extrusion to obtain a sheath layer of the wind power cable, thereby obtaining the wind power cable.

The invention provides a cerium-zirconium loaded cobalt titanate solid solution nanosphere water treatment catalyst and a preparation method thereof, and relates to the field of water treatment. The cerium-zirconium loaded cobalt titanate solid solution nanosphere water treatment catalyst comprises nano spherical ferroferric oxide, a cerium-zirconium solid solution, cobalt titanate and D-(-)-quinic acid, the nano spherical ferroferric oxide serves as an inner core, the cerium-zirconium solid solution serves as an electron transport middle layer, the cobalt titanate serves as an active component outer layer, and the D-(-)-quinic acid serves as a morphology control agent. On the basis of the mass of the ferroferric oxide inner core, the mass percentage content of the electron transmission middle layer is 60%-80%, and the mass percentage content of the active component outer layer is 20%-40%; wherein the molar ratio of cerium oxide to zirconium oxide in the cerium-zirconium solid solution is 1: (0.33-3). The catalyst provided by the invention is environment-friendly, not only can efficiently catalyze and reduce p-nitrophenol, but also can be repeatedly used, is simple to regenerate, and has higher economic value and wide market application prospect.

The invention belongs to the technical field of lithium battery material recovery, and particularly relates to a method for recovering a waste lithium iron phosphate positive electrode material. The method comprises the following steps: (1) grinding and sieving the positive electrode material of the waste lithium iron phosphate battery, mixing with an alkaline solution, stirring and leaching, and carrying out solid-liquid separation to obtain a lithium-rich solution and leaching residues; (2) introducing a saturated sodium carbonate solution into the obtained lithium-rich solution, carrying out heating reaction, filtering, taking a solid phase, and drying to obtain lithium carbonate; and the obtained leaching residues are dried, and ferroferric oxide is obtained. According to the method, the waste lithium iron phosphate battery positive electrode material is leached through the alkaline liquid phase, it can be guaranteed that lithium and iron in waste lithium iron phosphate are separated through a one-step leaching method, and therefore selective lithium extraction is achieved. The whole technological process is convenient to operate, mild in reaction condition and low in energy consumption, does not need to use any acid or oxidant, avoids generation of a large amount of waste liquid and harmful gas, and is high in selective lithium extraction efficiency.