Novel multi-element structure composite conductive filling material
A technology of composite conductive and conductive materials, applied in other chemical processes, chemical instruments and methods, etc., can solve the problems of reduced conductivity, poor shielding effect, poor high temperature characteristics, etc.
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Embodiment 1
[0014] A layer of ferric oxide is plated on the surface of hollow glass microspheres by co-precipitation method, and then a layer of silver is plated on the surface by electroless plating to prepare a multi-component composite conductor filler-hollow glass microspheres / ferric oxide / silver , wherein the mass percentages of hollow glass microspheres, ferroferric oxide and silver are 35%, 35% and 30% respectively, and each raw material is calculated and weighed according to the ratio of the corresponding mass ratios. Mix ferric nitrate and ferrous chloride solutions of the same concentration in a ratio of 3:2, add the washed and roughened hollow glass microspheres, add the precipitant NaOH solution dropwise, react for 15 minutes, and then filter , washing and drying to obtain hollow glass microsphere / ferric oxide composite powder. Prepare a silver ammonia solution with a concentration of 0.05mol / L, add hollow glass microspheres / ferric oxide composite powder, stir, heat to 45°C, a...
Embodiment 2
[0016] A layer of ferric oxide is plated on the surface of carbon fiber by hydrothermal method, and then a layer of silver is plated on the surface by chemical plating to prepare a multi-component composite conductor filler-carbon fiber / ferric oxide / silver, wherein carbon fiber, ferric oxide The mass percentages of the three irons and the silver are respectively 40%, 35% and 25%, and each raw material is calculated and weighed according to the ratio of the corresponding mass ratios. Mix ferric nitrate and ferrous chloride solutions of the same concentration in a ratio of 5:3, add urea, and stir to obtain a transparent solution, then place the solution in a high-pressure reactor, add carbon fiber, and add an appropriate amount of Water, make the filling degree 0.65, seal the reaction kettle, pass in nitrogen gas (as a protective gas), stir at high speed, heat the solution in the reaction kettle to 140°C, maintain the atmospheric pressure at 6-7 atmospheric pressure, react for 2 ...
Embodiment 3
[0018] A layer of barium ferrite (BaFe) was coated on the surface of glass fiber by sol-gel method 12 o 19 ), and then adopt electroless plating to plate a layer of silver on its surface to prepare multiple structure composite conductor filler-glass fiber / barium ferrite / silver, wherein the mass percentages of glass fiber, barium ferrite and silver are respectively 40%, 40% and 20%, calculate and weigh each raw material according to the ratio of the corresponding mass ratio. Mix barium nitrate, ferric nitrate and citric acid in a molar ratio of 1:12:13, add distilled water and stir for 20 minutes to dissolve completely, add ammonia water dropwise to adjust the pH value to 7, make the solution into a transparent sol, and heat at 75°C Put the water bath at constant temperature for 2 hours, then place the cleaned and roughened glass fibers in the sol solution, and under stirring, make the sol coat the surface of the glass fibers; then place them in an oven and dry at 120°C for 20...
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