The invention discloses a novel electromagnetic shielding nanocarbon conductive fibrous material and a preparation method thereof, and belongs to the field of a nano-material technology. The material comprises the following components: graphite, a nanometer carbon fiber, a conductive polymer, a polymer adhesive, a dispersant, alkali metal fluoride, a metal catalyst, a conductive metal and a surface conditioning agent. The preparation method comprises the following steps: the graphite is subjected to pretreatment with alkali metal fluoride; the nanometer carbon fiber is oxidized by an acid mixture, the surface conditioning agent and the conductive metal are added separately, and a heating treatment is carried out; after the pretreated graphite and the pretreated nanometer carbon fiber are dissolved, the dispersant, the conductive polymer and the polymer adhesive are added for blending, and ultrasonic dispersion, ozonization treatment and grinding are carried out to form a homogeneous solution; a chemical blend is blended with the obtained solution, and the nanocarbon conductive fibrous material is prepared by a electrostatic spinning method. The novel electromagnetic shielding nanocarbon conductive fibrous material prepared by the invention has good electromagnetic shielding performance, and does not have toxicity and any carcinogenic substances; the novel electromagnetic shielding nanocarbon conductive fibrous material can be used for manufacturing radiation-proof clothes and the like.