The application discloses a
graphene sliding ferroelectric regulation method and device based on defect
engineering and belongs to the technical field of two-dimensional ferroelectric materials. In the application, structural defects are introduced into specified monolayers of double-layer
graphene, the lattice spatial symmetry is destroyed, and a defect double-layer
graphene system with intrinsic polarity is constructed. Then, the
system is polarized and regulated by using out-of-plane interlayer sliding, the out-of-plane ferroelectric polarization is reversibly flipped, and a non-typical sliding ferroelectric response is formed. Meanwhile, a three-layer graphene structure is constructed, defects are introduced into specific layer positions, and a defect three-layer graphene
system with high polarization intensity is prepared. The system is subjected to double-mode sliding regulation, small-amplitude polarization is quickly switched by using low-barrier in-plane interlayer sliding, and super-high out-of-plane polarization is obtained by using out-of-plane interlayer sliding, and the polarization is reversibly flipped. The application breaks through the limitation of traditional two-dimensional sliding ferroelectric regulation, provides a new design idea for the research and development of high-performance van der Waals ferroelectric devices, and can be applied to the fields of high-density
information storage, intelligent sensing and preparation of new microelectronic devices.