The invention provides a process for preparing inorganic highly performance combustion inhibitor crystallization II type ammonium polyphosphate, which comprises selecting equal mol of phosphorus pentoxide and ammonium monohydric phosphate, under 150-350 deg. C, charging ammonium sulfate, melamine or ammonium hydrogen carbonate polycondensation agent, mixing, liquating, crystallizing, and disintegrating at the presence of ammonia gas atmosphere, thus obtaining crystallization II type polyphosphoric acid (APP-II). The method for detecting crystallization II type ammonium polyphosphate consists of measuring crystallization form of the APP-II through X-ray diffraction analysis, measuring polymerization degree of the APP-II through nuclear magnetic resonance method, measuring the decomposition temperature of the APP-II through heat weight / differential heat synchronization analytic method.