The invention relates to a substance heat capacity measuring instrument, in particular to an adiabatic calorimeter and a calorimetric system thereof, and comprises a vacuum sealed socket connector, a vacuum system valve, a vacuum conduit, a temperature control ring of conducting wires, a conducting wire beam, an outer heat screen, a middle heat screen, an inner heat screens, a sample container, a differential thermocouple and a vacuum chamber. The substance heat capacity measuring instrument has compact structure, stable performance and convenient operation, realizes the adiabatic calorimetric experiment, which comprises a whole automatically controlled and finished process of electricity energy importing, heat insulation controlling, temperature measuring, heat equilibrium judging, heat capacity data computing and processing, and result displaying and printing and the like. Through the detection with a standard calorimetric substance Alpha-Al2O3 and the comparison with internationally acknowledged data that is published by National Institute of Standards and Technology (NIST), the measuring heat capacity variability of variation with temperature of the instrument is certificated to be plus or minus 0.2mK per minute<-1>, the precision of the instrument is certificated to be plus or minus 0.12 percent and the accuracy of the instrument is certificated to be plus or minus 0.14 percent.