The invention discloses a biosynthetic
bacterial cellulose-based
solid electrolyte as well as a preparation method and application thereof, and belongs to the technical field of
solid electrolytes. The
solid electrolyte is prepared by taking modified
bacterial cellulose prepared by fermenting
acetobacter xylinum,
rhizobium,
pseudomonas, azospirillum,
alcaligenes and other
bacteria as a substrate, introducing a low-molecular-weight
polymer to regulate and control the arrangement of
cellulose molecular chains to serve as a conductive
ion framework, and then compounding a conductive
ion high-molecular-weight
polymer and a
lithium salt. According to the invention,
cellulose molecular chains are modified by modified glucose, and a
network structure is regulated and controlled by a low-molecular-weight
polymer, so that the problems of small spacing, lack of
ion coordination sites and weak ion transmission capability of pure
cellulose molecular chains are effectively solved, the
ionic conductivity of the prepared solid
electrolyte can reach 10 <-4 > S cm <-1 >, the
electrochemical window width reaches 5V, and the solid electrolyte has a good application prospect. The material can tolerate high
critical current density, is suitable for various positive
electrode materials, and is suitable for high-
voltage and long-cycle-life
energy storage devices.