16333 results about "Water baths" patented technology

The invention discloses a fluid-solid-heat coupling triaxial servo percolation device for gas-contained coal, comprising a lifting stand, a hydraulic servo control system, an axial loading device mounted at the top of the lifting stand and a triaxial pressure chamber connected with the lower end of the axial loading device. A thermostatic water tank is arranged below the triaxial pressure chamber; a movable worktable is arranged above the thermostatic water tank; the lower end of the triaxial pressure chamber is arranged on the movable worktable; heating tubes are arranged in the thermostatic water tank; and a water inlet valve, a water drain valve and a water-bath circulating water pump are arranged outside the thermostatic water tank and are communicated with the thermostatic water tank. In the hydraulic servo control system, an axial compression loading oil pump is communicated with an oil inlet and an oil outlet by a pipeline, and a peripheral compression loading oil pump is communicated with an oil intake/drain hole by a pipeline. The fluid-solid-heat coupling triaxial servo percolation device for gas-contained coal can carry out the research of gas-contained coal percolation tests in states, such as different terrestrial stresses, different gas pressures, different temperatures, and the like and the distortion and failure characteristics of the gas-contained coal in a percolation process.

The invention relates to a method for recovering and preparing lithium cobalt oxide by using a disused lithium battery, belonging to the technical field of recovery and recycle of electrode materials.The method comprises the steps of: discharging, disassembling, smashing, NMP processing and burning a disused lithium battery sequentially, to obtain a disused LiCoO2 material; ball-milling the disused LiCoO2 material and adding natural organic acid and hydrogen peroxide to obtain a solution of Li<+> and Co<2+>; adding lithium salt or cobalt salt after filtering, and then heating by water bath; dropwise adding ammonia water in the solution to prepare a xerogel; and performing secondary burning to obtain an electrode material of lithium cobalt oxide. The method has the advantages that the electrochemical properties of the electrode material of the disused lithium battery can be recycled with obvious effect as well as simple and easy operation; the natural organic acid used in the process of acid dipping has small damage to apparatus; and the method is environment friendly and efficient, and has low cost, simple technique, high recovery rate and industrialized promotion.

The invention discloses a method for preparing nano ceramic fibers, which is implemented by the following steps: 1, preparing 3 to 15 volume percent of 10 to 30 nanometer ceramic nanoparticles, 5 to 30 volume percent of spinnable high polymer, 0.5 to 5 volume percent of dispersant and the balance of solvent, wherein the total volume of the raw materials is 100 volume percent; 2, adding the spinnable high polymer into the solvent, heating the mixture in a water bath with magnetic stirring to obtain solution of spinnable high polymer; 3, adding the ceramic nanoparticles and the dispersant into the solution of spinnable high polymer obtained by the step 2, keeping the temperature of the mixture constant in a water bath, performing dispersion and ultrasonic dispersion, and performing swelling at a constant temperature to obtain ceramic nanoparticle/spinnable high polymer/solvent spinning solution; 4, controlling the electrostatic spinning process parameters of the spinning solution obtained by the step 3 to obtain nano fibers; and 5, sintering the nano fibers at 400 to 1,200 DEG C to obtain nano ceramic fibers.

The invention discloses an electrostatic spinning preparation method of ceramic nanometer composite fibers, comprising the following concrete steps of: firstly, according to volume percentage, weighing 3-10 percent of ceramic nanometer particles with the partilce size of 10-300 nm, 3-20 percent of ceramic precursor, 5-30 percent of spinnable polymer and 40-89 percent of solvent with the total volume of 100 percent; secondly, adding the spinnable polymer into the solvent, heating in water bath and magnetically stirring; thirdly, adding the ceramic precursor into the spinnable polymer solution obtained in the second step, heating in water bath, magnetically stirring and ageing; fourthly, adding the ceramic nanometer particles into the ceramic precursor spinnable solution obtained in the third step, heating at constant temperature in the water bath and forming a spinning solution by carrying out ultrasonic dispersion and constant temperature swelling; fifthly, preparing composite nanometer fibers by the spinning solution according to an electrostatic spinning technology; and sixthly, obtaining the ceramic nanometer composite fibers by sintering the composite nanometer fibers. In the method, raw materials have wide selection conditions and wide optional range.

The present invention is coated aluminum powder pigment and its preparation process. The coated aluminum powder pigment is prepared through the following steps: mixing aluminum powder pigment with alcohol solvent; adding organosiloxane, water and acid catalyst, and heating in water bath to react to obtain organosiloxane coated aluminum powder pigment; heating the reaction system to 65-120 deg.c, adding polymer monomer and initiator to react to obtain organosiloxane and polymer coated aluminum powder pigment; and cooling, filtering, washing and drying to obtain the coated aluminum powder pigment product. The coated aluminum powder pigment with two coating layers has excellent metal luster and high acid and alkali resistance, and is suitable for water paint.

The invention belongs to the technical field of molecular sieve preparation, and particularly relates to an in-situ preparation method for a microporous-mesoporous molecular sieve containing noble metal. The in-situ preparation method comprises the steps as follows: adding a coupling pore-forming agent, a silicon source, an aluminum source or a titanium source, and an alkali source into a water solution of noble metal nano particles in sequence under the water bath condition; and ageing, drying, crystallizing, drying and carrying out high-temperature calcination to obtain the microporous-mesoporous molecular sieve containing the noble metal. The prepared microporous-mesoporous molecular sieve is provided with a hierarchical pore structure; the noble metal nano particles with high dispersity are covered in situ while a mesoporous structure is generated; and a synthetic method is convenient and simple, saves energy and reduces emission. A multifunctional catalyst prepared with the method integrates the advantages of the microporous channels of the molecular sieve, the transgranular meso pores and the intergranular meso pores of the molecular sieve and the noble metal nano particles, and is more suitable for catalytic reactions of sulfur-containing large molecules such as hydrogen desulfurization and the like.

The invention provides a method for screening stereoselective alpha-hydroxy acid dehydrogenase, comprising the following steps: (1) dissolving a sample to be detected containing alpha-hydroxy acid dehydrogenase in a buffer with pH of 6-9, adding an alpha-hydroxy acid chiral monomer as a substrate, and carrying out conversion reaction in water-bath at 20-50 DEG C; and (2) after the conversion reaction, adding the conversion solution in an FeCl3 developer solution to conduct color development reaction for 5-30 min, when the color development reaction finishes, judging the result according to the color appeared in the reaction solution. The method has no need to carry out derivatization on the substrate which is intend to screen, can rapidly identify the dehydrogenase activity and optical selectivity of the selected microbe by using simple colourimetry, has the advantages of simple screening flow, fast speed, low request for devices, strong versatility and the like, and offers great conveniences to the obtainment of optically pure products by using racemic mandelic acid and related derivatives as substrates to carry out resolution through biological enzymatic method.

Relating to the technical field of resource recovery and recycling, the invention discloses a resource-based and harmless treatment method for kitchen waste. The method is directed at the problems of high salt content in fertilizer products, easy cause of soil salinization, and large equipment investment for anaerobic fermentation of total waste in existing kitchen waste treatment methods. The method comprises the steps of: (a) kitchen waste sorting; (b) water bath desalting: adding water, and conducting heating and stirring to dilute salt; (c) solid-liquid separation: dehydrating the waste; (d) solid material aerobic fermentation: crushing the dehydrated solid material into small particles, and conducting aerobic fermentation and drying treatment to obtain an organic fertilizer; and (e) waste liquid anaerobic fermentation: conducting oil-water separation on the waste liquid, recovering grease, subjecting sewage to anaerobic fermentation, making the produced biogas residue and biogas slurry into a liquid fertilizer, and taking the produced biogas as the fuel of a biogas boiler. The method provided by the invention is particularly suitable for resource-based and harmless treatment of kitchen waste.

The invention relates a kind of preparation method of bio-diesel oil under the condition of solid ac and alk catalyzing. The character is that under the condition of solid ac and alk catalyzing, gain the bio-diesel oil using the craft of exchange reaction of soja oil with carbinol. Afer the reaction, apart catalyser from reaction liquor by centrifugal machine till delimination in quiet placing, the above is rough output, the below is admixture of glycerol and carbinol. Distil the of above to gain bio-diesel oil and to gain the pure glycerin in the same way. The distilled carbinol can be used again and again. The invention has many advantages, for example, its raw material can be rebirth, its craft is easy and only need normal equipment. Even treat the used oil, the whole process is easier compared with the method in solid ac and alk catalyzing, besides, the process will not produce foul water so it is environmental. Every plant of the bio-diesel accords with standards compared with foreign similar competitive grade and the main plants are close to its of 0# (GB252-1994, superior product)diesel of China.

The invention discloses a preparation method of a fiber/ZrO2 aerogel composite material. The method comprises the following steps of: 1) carrying out surface pretreatment on a reinforcement fiber; 2) uniformly stirring an inorganic zirconium salt, an alcohol water solvent, the surface pretreated fiber, a chelating agent, a drying control chemical additive and epoxide; 3) carrying out water bath on a composite system of an obtained sol and the fiber; 4) after aging the wet gel after the water bath is carried out, washing the wet gel by using absolute ethyl alcohol; dipping the wet gel by usinga surface modifying agent solution; and finally, dipping the wet gel by using a low surface tension solvent; 5) drying the obtained gel; and 6) carrying out heat treatment on the obtained article after being dried in the step 5) at 400-700 DEG C for 3-8 h so as to obtain the fiber/ZrO2 aerogel composite material. By using the fiber/ZrO2 aerogel composite material prepared by using the method disclosed by the invention, the excellent performance of the ZrO2 aerogel can be kept and the mechanical performance of the ZrO2 aerogel can be improved.

A process for three-dimensional modeling in which water soluble thermoplastic material is used in an additive deposition process to form a soluble support structure for a three-dimensional model formed via layer-by-layer deposition of the model's geometry. The water-soluble thermoplastic material includes a base of vinyl alcohol. Following the completion of the model, the model is placed in a cold water bath to dissolve the support structure. The water-soluble material can also be used to form soluble model directly.

A heat insulating container having its outer surface formed of a synthetic resin such as a vacuum bottle, a cooler box, an ice box, a heat insulating cup, a heat retaining lunch box, and a heat insulating and retaining storage container capable of preventing problems such as a small available volume compared with a relatively large outer size so as to provide an increased insulating effect, corrosion of metallic containers, and inefficient washing of synthetic resin containers because the containers float in a water bath when washing; the heat insulating container having a metallic inner wall member 2 and a metallic outer wall member 3 disposed with a space portion 4 between them, the opening end portions 2a, 3a of these wall bodies being formed integrally with each other, and at least one of the inner and outer surfaces of a heat insulating layer body 1 formed by evacuating the space part 4 being covered by a synthetic resin inside container part 11 or an outside container part 12 and formed integrally with the heat insulating layer body so as to increase the specific gravity of the heat insulating container.

The invention discloses a modified silica sol and application thereof in preparation of aqueous painting. The inventive modified silica sol is prepared from aqueous silica sol by regulate pH value of raw material to 3-6; charging organosilane with a mass ratio with SiO2 in silica sol of 1:1 - 5:1, water bathing at temperature of 50-80 DEG C., waiting for 0.5-5 hours, vaporizing by-products generated in hydrolysis to obtain transparent sol, which is final product. The modified silica sol has cheap raw material, simple preparation. When used as matrix in preparation of paint, the sol uses only water as solvent, without need of adding any organism such as alcohol. The preparation is simple, economic, environmental protecting. The prepared aqueous paint not only has high decorative, great adhesion and toughness of organic paint, but also has high rigidity, chemical resistance of inorganic paint, which can be used on surface of substrates of metal, glass, wood, plastic and in construction industry.

Ar anaerobic-aerobic reactor for preparing composit is composed of fermentor, ventilation system, stirring system, and heating system. The said fermentor has a sieve plate to divided it into thepartsand a stirring axle driven by motor. Its fermenting chamber is a sealed unit with circulating water both jacket for heating it and liquid inlet and outlet, and features that the anaerobic digestion and aerobic reaction are conduted in a single equipment.

Disclosed is a container warmer that utilizes the same compartment for heating and cooling. In optional embodiments, the unit may include a programmable timer operably connected to the heating and cooling units such that the timer may regulate activity of the units. In other embodiments, the invention may include a baby bottle warmer in which the baby bottle is placed in a water bath in a compartment, the water bath being heated or cooled by heating or cooling units, and optionally operably connected to a programmable timer.

The invention relates to a preparation method for graphene, especially to a method for preparing high-quality graphene through electrochemical high-efficiency exfoliation. The method mainly overcomes the technical problems that the honeycomb lattice structure of graphene is severely destroyed in the process of oxidation, an obtained membrane resistance is 1 K to 70 K omega/square (wherein light transmittance is less than 80%), the resistance is too high and much higher than requirements of ITO, etc. The method comprises the following steps: with graphite as a positive electrode and a platinum filament as a negative electrode, repeatedly applying high offset voltage and negative offset voltage on the graphite electrode, which enables graphite to be rapidly disassociated and decomposed into double-layer graphene floating on the surface of an electrolyte; collecting graphene and then filtering and drying graphene; dispersing obtained powder of a graphene film in a DMF solution; and carrying out water-bath ultrasonic treatment and centrifugation so as to obtain desired 1.5-nm-grade graphene flakes.

The invention discloses an adsorption-desorption-seepage experiment system for loaded coal containing gas under the condition of varying temperatures. The experiment system comprises a tank body used for holding constant-temperature water bath. A triaxial pressure chamber is arranged in the tank body; a coal chamber is arranged in the triaxial pressure chamber; a coal sample is installed in the coal chamber; a foil gauge is adhered onto the coal sample and is connected with a dynamic strain meter; one end of the coal chamber is provided with an opening, and a pressure head is mounted in the opening and connected with a pressure unit; the coal chamber is communicated with a vacuum pipeline and a high pressure gas-transmission pipeline; and a confining pressure pipeline used for conveying hydraulic oil is communicated with a cavity between the coal chamber and the triaxial pressure chamber. The adsorption-desorption-seepage experiment system for loaded coal containing gas under the condition of varying temperatures in the invention has the advantages of a simple structure, convenient operation, reasonable design, high experiment precision and a low price.

The present invention provides a luffa alkalization modification method and an application in the metal ion adsorption, belongs to natural high polymer material modification or wastewater disposal technical field. The method is mixing the natural luffa with m moderate NaOH alcohol solution, alkalization under the temperature 25-80 Celsius degree, or alkalization by microwave interval radiation 1-10 min, then obtaining alkalization luffa by reflowing, washing, filtering, drying in the thermostatic waterbath. The luffa comes from variety of natural resources, and biodegradation, and treating process is relatively simple, partly substituting high molecular synthetic material in aspect of the sewage treatment, and having advantages such as friendly to the environment.

The invention relates to a layered lithium-rich anode material clad by metal fluoride, and a preparation method thereof. According to the invention, a layered lithium-rich material Li[Li(1-2x)/3MxMn(2-x)/3]O2 is prepared with a combined technology of a oxalate precipitation method and a hydro-thermal method, wherein M is Ni, Co, Cr or any two of them which coexist, and x=0 to 0.33. The lithium-rich material is impregnated in a solution of soluble salts of metals such as yttrium, magnesium and iron; a soluble fluoride solution is added to the mixture, wherein n(Me):n(F)=1:y; the solution is continuously stirred for 3-8h in a water bath with a temperature of 60-90 DEG C; the solution is subject to centrifugal washing, and is dried under a temperature of 60 DEG C in a vacuum thermostat; a material obtained after drying is roasted for 4-8h under a temperature of 400 DEG C and under the protection of argon gas, such that Li[Li(1-2x)/3NixMn(2-x)/3]O2 clad by a fluoride MeFy is prepared. The electrode material provided by the invention is advantaged in high electrochemical capacity, good cyclical stability, excellent rate performance, and the like. The preparation process is simple, the cost is low, and the reproducibility is good.

The invention provides a preparation method of a super-hydrophobic membrane. The preparation method comprises steps as follows: hydrophobic organic polymer materials and nano granules are dissolved in an organic solvent, the mixture is stirred and left to stand, and an electrostatic spinning solution is prepared; high-pressure electrostatic spinning parameters are set, electrostatic spinning membrane preparation is performed, and a nanofiber membrane is obtained and subjected to thermal treatment; TiO2 is prepared, the surface of the nanofiber membrane is covered with TiO2, and thermal treatment, water-bath heating, washing and ultraviolet radiation treatment are performed; silane solutions are prepared, the nanofiber membrane surface covered with TiO2 is covered with the silane solutions, thermal treatment, washing and airing are performed, and the super-hydrophobic membrane is obtained. The invention further provides an application of the super-hydrophobic membrane in the membrane distillation process. By means of the method, the super-hydrophobic nanofiber membrane is prepared. The membrane simultaneously has super-hydrophobicity and high throughput performance, the wet resistance of the membrane is effectively improved, and the service life of the membrane is prolonged.

The invention discloses a method for preparing a cathode material of a sodium-ion battery, namely sodium vanadium fluorophosphates. The method comprises the following steps: using a vanadium source, a phosphorus source and a carbon source as main synthetic raw materials; dissolving into deionized water according to the molar ratio 1:1:1.2 of vanadium: phosphorus: carbon, heating in water bath, and continuously stirring to obtain light green pulp; after vacuum drying, grinding, then transferring into a tube furnace, preburning in an inert atmosphere at a certain temperature rise rate, cooling and then taking out to obtain black VPO4/C precursor powder; mixing the VPO4/C with NaF according to a stoichiometric ratio, ball-milling for 3 hours, sending into the tube furnace, then roasting in the inert atmosphere at the certain temperature rise rate, and cooling along with the furnace to obtain a positive active material NaVPO4F/C. According to the invention, cheap and easily-obtained pentavalent vanadium oxide or trivalent vanadium oxide is used as the main raw materials to prepare the sodium vanadium fluorophosphates cathode material through a sol gel activated auxiliary two-step high-temperature solid phase method, and the sodium vanadium fluorophosphates cathode material has the advantages of good stability, uniform particle size and good electrochemical performance. Meanwhile, the method has the advantages of simple synthesis process, short period and low cost and is convenient for large-scale production.

The invention relates to a method for preparing a nano-cellulose antibacterial composite material through on-line culture. The method comprises the following steps of: (1) inoculating an activated bacterial cellulose producing strain into a liquid culture medium, performing amplification culture, transferring the liquid culture medium into a bioreactor, culturing, adding an antibacterial material into the liquid culture medium, and continuing to culture to obtain an unpurified antibacterial bacterial cellulose composite material; and (2) peeling a bacterial cellulose membrane from a framework or directly soaking the composite material in a NaOH solution, treating in water bath, and washing until an obtained product is neutral to obtain the nano-cellulose antibacterial composite material. The preparation efficiency is high, and the method is simple, convenient, feasible and low in cost; and the surface of the bacterial cellulose composite material has a nanoscale three-dimensional fibrous mesh-shaped structure, the tensile strength of the material is greatly improved compared with that of a pure bacterial cellulose membrane, and the material can be widely applied to products such as facial masks, wound dressings, plasters, artificial skins and the like.

The invention discloses a water-gas two-phase adsorption-desorption-seepage experimental system and method for loaded coal containing methane. The water-gas two-phase adsorption-desorption-seepage experimental system for loaded coal containing methane comprises a pressure loading part, wherein the pressure loading part comprises a tank body for containing a constant-temperature water bath, a reference pot and a coal sample holder are arranged in the tank body, the gas inlet of the reference pot is connected with a high-pressure methane delivery pipeline, the gas outlet of the reference pot is connected with the gas inlet of the coal sample holder through a connecting pipeline, and the gas outlet of the coal sample holder is connected with a water-gas separation device. The water-gas two-phase seepage experimental method for loaded coal containing methane is carried out on the basis of the experimental system. By changing different loading conditions, loading paths and experimental temperatures, adsorption-desorption experiments and methane seepage experiments for the loaded coal containing methane under the conditions of different solid-gas thermal coupling can be realized, and water-gas two-phase seepage experiments and methane adsorption-desorption experiments under the condition of different moisture contents also can be realized.

The invention discloses a method for testing accelerating and loading of main drive wheel type pavement materials and a device thereof. The device comprises a control console, a PLC control box, an electronic box, a hydraulic device, a motor, a brake, a driving chain and chain wheel, a drive wheel, a driven wheel, a water bath tank, a circulated air inlet duct, a thermostatic chamber, a test cabinet and a circulated air outlet duct; the control console is positioned on the outside of the test cabinet; the hydraulic device is connected with the driven wheel; the motor is connected with the drive wheel via the driving chain and chain wheel; the drive wheel is fixed on a bracket; the driven wheel is positioned in a guide slot; the water bath tank is arranged right below the driven wheel; a ranging laser is positioned on one side of the driven wheel; one end of the drive wheel is provided with a microphone and the bottom thereof is provided with a torque sensor; the contact surface of the drive wheel and a test piece is provided with a pressure sensor; two tachometers are fixed on the bracket and are respectively positioned on the outsides of the drive wheel and the driven wheel. The device has simple structure, low prices, flexible use and good reliability.

The invention belongs to the new field of chemical engineering, and particularly relates to a nano material with clay as a carrier and perovskite type compound nano particles as active components and a preparation method and application thereof to the field of optical coupling-SCR denitration. Lanthanum nitrate, nickel nitrate, ferric nitrate, citric acid and the clay are added to deionized water to be stirred, then the mixture is transferred into a water bath kettle to evaporate to obtain wet gel, and the nano material can be obtained through drying, calcining and drying. The composite is adopted as a catalyst for photocatalytic denitration, and compared with traditional SCR denitration, the amount of adopted NH3 is reduced, and the conversion efficiency on NO at low temperature is improved.

The invention relates to a preparation method and application method of a titanium dioxide nanosheet supported MIL-100 (Fe) composite photocatalysis material, belongs to the field of titanium dioxide photocatalysis, and especially relates to the field of titanium dioxide nanosheet supported porous metal organic skeleton (MOFs) composite materials. The preparation method comprises the following steps: 1, uniformly stirring tetrabutyl titanate and hydrofluoric acid at normal temperature, putting the obtained mixture in a hydrothermal reaction kettle, carrying out a reaction, separating the obtained material, washing the separated material, and drying the washed material to obtain titanium dioxide nanosheets; and 2, uniformly dispersing the titanium dioxide nanosheets in an anhydrous ethanol solution of iron trichloride, carrying out magnetic stirring at normal temperature for 15 min, carrying out suction filtration separation to obtain a product, dispersing the product in an anhydrous ethanol solution of trimesic acid, carrying out a 50-80 DEG C water bath reaction for 20-50 min, carrying out suction filtration separation to obtain a product, and repeating above processes in step 2 2-50 times to obtain the titanium dioxide nanosheet supported MIL-100 (Fe) composite photocatalysis material. The catalyst prepared through the method is especially suitable for catalytic degradation of high-concentration organic dyes (such as methylene blue) under visible light irritation) to reach a very high degradation rate.