4796 results about "Biodegradation" patented technology

The present invention discloses a water-based emulsion of PHA, PBAT and PVOH and its application in paper-based barrier coatings. This emulsion is prepared by first melt-blending PHA and PBAT at 150-170 °C and then dispersing them into an aqueous PVOH solution at 80-95 °C. Plasticizers, cross-linking agents and surfactants can be added to improve the performance. After coating on paper and drying at 80-150 °C, a barrier film with a Cobb value of 10-15 g / m² and a Kit ≥ 10 grade is formed. Compared with traditional PE film laminating or fluorine-containing coatings, this system is more environmentally friendly and recyclable; PVOH dissolves in pulping water, PHA and PBAT are easily separated, and fibers can be efficiently recovered; in composting, soil and marine environments, PHA and PBAT have extensive biodegradability and are superior to PLA which is difficult to recycle and requires industrial composting. It is applicable to food, industrial, special packaging and agricultural paper products.

The invention discloses a PHA / PVA nano-scale paper-based barrier emulsion as well as a preparation method and application thereof. The water-based emulsion comprises PHA particles with the average particle size ranging from 100 nanometers to 300 nanometers and PVA, the PHA and the PVA are blended according to a specific proportion, and the PVA serves as a main film forming component and a barrier property contribution component and is blended with the PHA to form the nano-emulsion. The preparation method comprises the following steps: mixing PHA particles with an initial average particle size of 1-100 microns with a PVA aqueous solution, and carrying out high-pressure homogenization and other nanocrystallization means to obtain the nano-emulsion. The emulsion can be coated on the surfaces of paper-based materials such as paper and paperboards, and a barrier coating is formed after the emulsion is dried. The obtained emulsion is small in particle size, good in stability and good in leveling property, a uniform and compact barrier film is easily formed on a paper base, the film has excellent water vapor, oxygen and grease barrier performance, and the material is bio-based, biodegradable and environmentally friendly.

The invention discloses a multi-layer controllable degradation coating composition as well as a preparation method and application thereof, and belongs to the field of biodegradable high polymer materials and coating compositions. The coating composition comprises an outer protective layer and an inner functional layer, and the inner functional layer is arranged between a substrate and the outer protective layer and comprises a plurality of microcapsules. The key innovation lies in that the microcapsule encapsulates an enzyme capable of catalytically degrading the outer protective layer and is configured to be released after a predetermined delay time. The pH buffer system is integrated in the inner functional layer, and an optimal catalytic microenvironment is created for released enzyme, so that the outer protective layer is actively and quickly degraded, and programmable time-controlled removal is realized. The problem that the degradation rate of an existing biodegradable material is passive and uncontrollable is solved, and the coating has a remarkable application value in the field of seed coating or fertilizer controlled release by endowing the coating with a unique two-stage degradation characteristic.

The invention relates to the technical field of plastic packaging preparation, in particular to an anti-aging plastic packaging material and a preparation method thereof.The anti-aging plastic packaging material is prepared from, by mass, 100-140 parts of polylactic acid, 60-80 parts of PBAT, 2-5 parts of a composite anti-aging agent, 1-2 parts of a lubricant, 2-4 parts of a flame retardant and 3-6 parts of a compatilizer; the composite anti-aging agent comprises a modified anti-aging agent obtained by compounding functionalized montmorillonite and modified silicon dioxide, the functionalized montmorillonite is carnosic acid grafted rare earth ion modified montmorillonite, and the modified silicon dioxide is epoxy methyl oleate grafted silicon dioxide. According to the anti-aging plastic packaging material provided by the invention, a plastic material system with multiple protection mechanisms is constructed through the synergistic effect of all the components, and the prepared plastic packaging material not only keeps good biodegradability, but also has excellent ultraviolet light resistance and oxidation resistance.

The present invention discloses a PHA / PVA nanoscale paper-based barrier emulsion, and its preparation method and application. The aqueous emulsion comprises PHA particles with an average particle size of 100 nanometers to 300 nanometers and PVA, wherein PHA and PVA are blended in a specific ratio, and PVA is blended with PHA as the main film-forming component and barrier performance contributing component to form the nanoemulsion. The preparation method comprises mixing PHA particles with an initial average particle size of 1 micron to 100 microns with a PVA aqueous solution, and processing the nanoemulsion by nano-processing means such as high-pressure homogenization. The emulsion can be applied to paper-based materials, such as paper and cardboard surfaces, and forms a barrier coating after drying. The emulsion obtained by the present invention has small particle size, good stability, good leveling properties, and is easy to form a uniform and dense barrier film on the paper base. The film has excellent water vapor, oxygen and grease barrier properties, and the material is bio-based, biodegradable, and environmentally friendly.

The invention discloses a bamboo powder-containing biodegradable plastic for food contact and a preparation method thereof, and relates to the technical field of bio-based materials. The bamboo powder-containing biodegradable plastic for food contact comprises chitosan starch and modified bamboo powder, the chitosan starch is prepared by adding composite chitosan and amino-terminated polyethylene glycol into oxidized corn starch, and the composite chitosan is prepared by grafting chlorogenic acid on the surface of chitosan and then coating succinic anhydride derivatives. The succinic anhydride derivative is prepared from dodecenyl succinic anhydride and 1, 4-butanediamine through a reaction, so that the plastic has the antibacterial property, and meanwhile, the mechanical property is enhanced; the modified bamboo powder is prepared by reacting bamboo powder with a carboxyl-terminated composition, and the carboxyl-terminated composition comprises carboxyl-terminated polylactic acid and carboxyl-terminated polyamide. The toughness of the plastic is enhanced, and the mechanical property of the plastic is further enhanced.

The invention relates to the technical field of biodegradable materials, and discloses a full-biodegradable bamboo fiber film material and a preparation method thereof, the full-biodegradable bamboo fiber film material comprises the following raw materials by weight: 30-50 parts of modified bamboo fiber, 20-40 parts of a biodegradable polymer, 3-8 parts of a plasticizer, and 1-5 parts of a cross-linking agent. Acrylic acid grafted hydroxyethyl methylacrylate is grafted to epoxy resin containing azobenzene side chains to form a grafting product of a latticed structure, and the grafting product and hydroxyl groups on bamboo fibers form ether bonds to modify the bamboo fibers. The latticed structure can effectively improve the mechanical property of the film, and azobenzene is grafted to the side chain of bisphenol A epoxy resin, so that the epoxy resin has better degradability.

The invention discloses a titanium alloy feeding implant and a preparation method thereof, and the preparation method comprises the following steps: carrying out activating treatment on a biodegradable bonding system in an inert gas environment to form an expansion-state binder precursor, and then mixing titanium alloy powder and the precursor which are proportioned in stages in a multi-stage mixing device in stages to obtain the titanium alloy feeding implant. Sequentially executing low-temperature activation, melting and dispersing operations to prepare uniform feed; carrying out vibration-assisted injection molding on the feed to generate a green body with a multi-stage pore structure; removing the binder step by step and reserving pores by adopting a synergistic degreasing process of supercritical fluid extraction, microwave decomposition and gas phase cleaning; densification sintering molding of the titanium alloy implant is realized through pre-sintering and plasma activating treatment, so that an implant finished product is formed; according to the process, through the coupling design of innovation of a biodegradable binder system and an intelligent degreasing process, on the premise that the biological safety of the titanium alloy implant is ensured, precise forming and sintering densification control of a complex pore structure are synchronously achieved.

The invention discloses a hydrogel wound dressing for promoting healing of infectious wounds. The hydrogel wound dressing is prepared from the following raw materials: oxidized methacrylic acid hyaluronic acid, waterborne polyurethane, polylysine, cannabidiol, neomycin sulfate and 2-roots alcohol. The invention also provides a preparation method of the hydrogel wound dressing and application of the hydrogel wound dressing in preparation of products for repairing infectious wounds. The wound dressing provided by the invention has a microporous structure, good biocompatibility and biodegradability, and can be used for stopping bleeding, reducing wound infection and promoting cell proliferation and wound healing.

The invention discloses a PHA nano aqueous suspension as well as a preparation method and application thereof, and belongs to the field of high polymer materials and processing and application thereof. The suspension takes PHA resin as a dispersion phase and water as a continuous phase, the total solid content is 23-65wt%, the PHA resin accounts for 80-98.5 wt% of the total solid, and the assistant accounts for 1.5-20wt% of the total solid. The average particle size of PHA particles is 30-140 nm, D90 is smaller than or equal to 150 nm, the polydispersity index PDI is smaller than 0.3, and when the pH is 6.5-7.5, the absolute value of Zeta potential is larger than 30 mV. The preparation method comprises the following steps: pretreating the PHA raw material, preliminarily dispersing in a water phase under the action of the dispersion stabilizing aid, and carrying out high-energy homogenization treatment. The obtained suspension is stable in storage, has excellent barrier property and mechanical property after film formation, and is suitable for preparing biodegradable food packaging barrier coatings, water-based environment-friendly coatings and water-based adhesives.

The invention relates to a biodegradable composition as well as a preparation method and application thereof, and belongs to the technical field of compositions of high-molecular compounds. The biodegradable composition disclosed by the invention is prepared from the following components in parts by weight: 44 to 90 parts of PBAT resin, 5 to 15 parts of amorphous resin and 5 to 40 parts of inorganic filler, based on the total molar weight of a terephthalic acid monomer unit and an adipic acid monomer unit in the PBAT resin, the molar ratio of the terephthalic acid monomer unit is 47-49%; the amorphous resin is at least one of PPC-P, PMMA (Polymethyl Methacrylate), PETG (Polyethylene Terephthalate Glycol) and PCTG; the inorganic filler comprises at least one of calcium carbonate and talcum powder; the particle size D50 of the calcium carbonate is less than 5 [mu] m, and / or the particle size D50 of the talcum powder is less than 8 [mu] m. The biodegradable film produced by adopting the biodegradable composition under a low blow-up ratio process has excellent dart falling performance, and can meet the requirement of ultra-long shelf life.

The invention discloses a biodegradable plastic and a preparation method thereof, belongs to the field of bioplastic preparation, and aims to solve the problem that the existing plastic is slow in degradation rate in a marine environment. The biodegradable plastic is prepared from the following components in percentage by weight: 50-80% of a biomass-based high polymer material; 10 to 35% of a degradable toughening agent; 1-5% of a photosensitizer; 2-10% of a microbial inducer; 1-5% of a processing aid; after the biomass degradable plastic is subjected to ultraviolet radiation for 7-15 days in a marine environment, initial cracks with the density being larger than or equal to 20 pieces / cm < 2 > appear on the surface, the initial cracks are broken into degradation units with the particle size being 5-20 mm after being subjected to mechanical impact of sea waves for 30-60 days, and the biological decomposition rate of the degradation units is larger than or equal to 90% within 6-12 months under the action of marine microorganisms; and no micro-plastic particles with the particle size of less than or equal to 1mm exist in the residual product. Through the synergistic effect of the photosensitizer and the microbial inducer, the degradation period in the marine environment is shortened, the degradation efficiency is improved, and the method is remarkably superior to the prior art.

The invention discloses a biological environment-friendly clothing material with a self-cleaning function and a preparation method of the biological environment-friendly clothing material. According to the invention, the environmental friendliness is obviously improved, and natural components which can be completely biodegraded are adopted and can be quickly decomposed in the natural environment, so that the micro-plastic pollution is reduced; the self-cleaning function is enhanced, and through the synergistic effect of the bionic hydrophobic surface and photocatalytic decomposition, automatic falling and decomposition of stains are achieved; the durability is enhanced, a dynamic self-repairing network can automatically repair daily wear, the service life is prolonged, and the bio-based raw materials are natural, skin-friendly and excellent in air permeability. The supercritical fluid processing and microwave shaping technology replaces a high-energy-consumption process; emission of toxic substances is eliminated, and organic solvents and fluorine-containing compounds are forbidden in the whole process; raw material loss is reduced, and the using amount of functional materials is reduced through an accurate structure regulation and control technology; the maintenance cost is simplified, and the washing frequency and the use of chemical cleaning agents are reduced due to the self-cleaning characteristic; waste is compressed, and resource utilization of by-products is achieved through a closed-loop production system.

The invention relates to the technical field of sewage treatment, and discloses an integrated sewage treatment method based on intelligent sensing. According to the method, sewage flow, PH value, temperature, turbidity and suspended matter concentration are collected in real time through an intelligent sensor, in each treatment link, the intelligent sensor can monitor the concentration of organic matter, nitrogen, phosphorus and other pollutants, the pollutant removal rate and the biological reaction rate are calculated, timely adjustment of a sewage treatment strategy is achieved, and the sewage treatment efficiency is improved. Through real-time monitoring of dissolved oxygen, temperature and mixed liquid reflux ratio in the bioreactor, reaction conditions are optimized, biodegradation efficiency and sludge yield are improved, and through monitoring of the dosage and reaction time in the reaction process, the dosage adding proportion is optimized, so that the removal effect of chemical reaction is improved; finally, the flow, the PH value, the chemical oxygen demand and the biological oxygen demand of the treated effluent are comprehensively monitored, so that the sewage treatment efficiency and reliability are remarkably improved.

The invention discloses a degradable PHA / PU composite water-based barrier coating and a coated paper product, and belongs to the field of biodegradable polymer coatings. The coating composition comprises a high proportion of polyhydroxyalkanoates as a barrier phase and a bio-based polyurethane as a toughening and heat sealing phase. The key innovation lies in that the cooperation of rigid barrier and flexible functions is realized by accurately regulating and controlling the ratio of two phases and adopting bio-based crosslinking, and the problem that the barrier property, the heat sealability and the flexibility of a traditional single material are difficult to consider at the same time is solved under the condition of low coating amount. The invention provides a full-life-cycle green packaging solution, aims to replace a polyethylene spraying film and a fluorine-containing coating, and has a remarkable application value in the field of food packaging.

The invention relates to the technical field of high-barrier environment-friendly packaging films, and discloses a high-barrier environment-friendly packaging film with an antibacterial function, the high-barrier environment-friendly packaging film comprises a base layer, a nano composite barrier layer, a bio-based functional layer and an outer protective layer from bottom to top in sequence, and the layers are tightly attached through a coated starch-based adhesive. According to the high-barrier environment-friendly packaging film with the antibacterial function, good biodegradability of polyhydroxyalkanoate adopted in the base layer film, polycaprolactone which is adopted in the nano-composite barrier layer film and has a biodegradable function and konjac glucomannan in the biological functional layer film are utilized; the composite packaging film can be decomposed into carbon dioxide and water by microorganisms in various environments, has excellent flexibility and processability, can adapt to different packaging requirements, provides basic flexibility, structural support and green and environment-friendly effects for the whole packaging film, and has a wide application prospect. The procyanidine arranged in the outer protective layer film provides stronger antibacterial property and water solubility for the whole packaging film.

The invention belongs to the technical field of sewage treatment, and discloses a biodegradable-photocatalytic composite material as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing a photocatalyst, sodium alginate and water to obtain gel containing the photocatalyst, then adding a photosynthetic bacteria concentrated solution, then adsorbing photosynthetic bacteria and the photocatalyst by using a carrier, and finally immobilizing in a calcium chloride solution to obtain the composite material. Photosynthetic bacteria are selected as microorganisms, and the method has the advantages of being flexible in metabolism mode, high in antibiotic tolerance, high in breeding speed, free of sludge treatment and the like. The photocatalyst and the photosynthetic bacteria are loaded on the polyurethane sponge, so that the photosynthetic bacteria are easily separated from water while being protected. The photocatalyst outside the carrier generates high-activity substances, and refractory antibiotics are converted into biodegradable intermediates. And a generated intermediate product is decomposed by microorganisms in the carrier, so that efficient degradation and mineralization of antibiotics in the sewage are realized.

To provide a medical tissue reconstruction material, which is involved in tissue reconstruction and exhibits superior tissue affinity, tissue conductivity, and mechanical properties, and a method for producing the same.SOLUTION: The present invention provides a composite comprising a biodegradable polymer and calcium phosphate exhibiting one of scaly, acicular, grooved, or linear recessed structures, and / or calcium carbonate containing vaterite, the composite meeting specific conditions.SELECTED DRAWING: Figure 3

The invention discloses a vascular endothelial growth factor (VEGF) and antibacterial peptide (AMP) loaded chitosan methacrylic acid (CSMA) hydrogel microneedle patch as well as a preparation method and application thereof, the microneedle patch takes CSMA hydrogel as a main body material, the CSMA hydrogel is crosslinked and cured through ultraviolet light, and the microneedle patch has the characteristics of simplicity and convenience in preparation and stable material performance. The microneedle patch can continuously and stably release VEGF and AMP, promote wound healing and inhibit bacterial infection. Experiments show that the hydrogel microneedle is non-toxic to cells, has good biocompatibility and biodegradability, and also has excellent antibacterial performance. The invention provides an efficient and safe novel treatment tool for repairing infectious wounds.

The invention relates to the field of plastic bags, and discloses a biodegradable plastic bag and a preparation method thereof, the biodegradable plastic bag comprises polylactic acid, poly (butylene adipate-co-terephthalate), a functional additive, modified starch, a lubricant and an antioxidant; the functional additive is prepared by grafting hydroxylated modified castor oil and isocyanated montmorillonite loaded titanium dioxide; the hydroxylation modified castor oil is prepared by modifying castor oil with chloroethyl isocyanate, then reacting with N-allylimidazole, and then reacting with 6-mercaptohexyl-1-alcohol; the isocyanated montmorillonite loaded titanium dioxide is prepared by reacting montmorillonite loaded titanium dioxide obtained by a sol-gel method with isophorone diisocyanate; the modified starch is prepared by reacting octadecanoyl chloride and acryloyl chloride with starch, then carrying out graft copolymerization with ethyl acrylate and further introducing glycidyl methacrylate, so that the plastic bag is endowed with excellent mechanical properties, biodegradability and antibacterial property.

The invention relates to the technical field of 3D printing, and discloses an environment-friendly packaging box rapid forming method and system based on biodegradable materials, and the method comprises the steps that a thermal-structure coupling finite element model is established; based on the thermal-structural coupling model, a multi-objective optimization model is constructed, and structural design parameters and initial printing path configuration are obtained; training a printing control strategy by utilizing a strategy optimization algorithm; according to the structural design parameters, the printing path configuration and the printing control strategy, a layer-by-layer printing path and a supporting structure configuration scheme matched with the printing object are generated; and the 3D printing process is executed, and closed-loop adjustment is conducted according to the control strategy. According to the method, the thermal-structural coupling finite element model based on the biodegradable material is constructed, and changes of a temperature field, a stress field and a thermal strain field in the printing process are accurately simulated, so that a printing path and supporting structure configuration are optimized, the printing precision is improved, structural instability caused by thermal deformation and interlayer stress is avoided, and the strength and stability of an object are ensured.

The application discloses degradable PHA / PU composite water-based barrier coating and coated paper products, and belongs to the field of biodegradable polymer coating. The coating composition contains a high proportion of polyhydroxyalkanoate as a barrier phase and a bio-based polyurethane as a toughening and heat-sealing phase. The key innovation is that by precisely controlling the ratio of the two phases and using bio-based cross-linking, the synergy of rigid barrier and flexible function is achieved, and the problem that the barrier property, heat-sealing property and flexibility of traditional single material are difficult to balance is solved at low coating amount. The application provides a full life cycle green packaging solution, which aims to replace polyethylene shower film and fluorine-containing coating, and has significant application value in the field of food packaging.

The invention discloses a biodegradable polylactic acid composite material and a preparation method thereof, and relates to the technical field of polylactic acid materials. The method comprises the steps that firstly, chitosan activated through hydrochloric acid is subjected to graft modification through a KH550 silane coupling agent, meanwhile, nano-zinc oxide is subjected to surface modification through stearic acid, the chitosan and the nano-zinc oxide are mixed, spray drying is conducted, and antibacterial composite powder is prepared; the preparation method comprises the following steps: performing hydrochloric acid activation and KH570 silane coupling agent modification on nano silicon dioxide, performing hydroxypropylation modification on alkali lignin, and performing reflux crosslinking reaction on the modified alkali lignin, KH570 modified nano silicon dioxide, polycaprolactone, methyl methacrylate and azodiisobutyronitrile to prepare a heat-resistant reinforcer; uniformly mixing polylactic acid, poly (butylene succinate), the antibacterial composite powder, the heat-resistant reinforcer, tributyl citrate, polyethylene glycol and talcum powder, and extruding and granulating by using a twin-screw extruder to obtain the heat-resistant antibacterial material. The composite material prepared by the invention has excellent antibacterial property, heat resistance and biodegradability.

The invention discloses a preparation method of a completely biodegradable dustproof net based on modified bamboo powder, and belongs to the technical field of biodegradable new materials. The formula comprises the following components in parts by weight: 50-70 parts of poly (butylene adipate-co-terephthalate), 10-40 parts of bamboo powder, 0.1-2 parts of a silane coupling agent, 0.1-1 part of a surfactant, 0.1-1 part of an anti-blocking agent, 0.1-1 part of an antioxidant and 0.1-1 part of an ultraviolet light absorber. The dust screen prepared by the invention not only has biodegradability, but also has the characteristics of being green and environment-friendly by adopting the bio-based material bamboo powder. Meanwhile, in order to realize good combination of the bamboo powder and matrix plastic poly (butylene adipate-co-terephthalate), a silane coupling agent capable of combining the bamboo powder and the matrix plastic poly (butylene adipate-co-terephthalate) through a chemical reaction and a surfactant capable of combining the bamboo powder and the matrix plastic poly (butylene adipate-co-terephthalate) through a physical effect are sequentially adopted for composite modification of the bamboo powder; the dispersity of the bamboo powder and the compatibility of the bamboo powder and poly (butylene adipate-co-terephthalate) are effectively improved, and the prepared dustproof net has good mechanical properties.

In accordance with the purpose(s) of the present disclosure, as embodied and broadly described herein, the disclosure, in one aspect, relates to lipid nanoparticles for use as drug delivery agents. The lipid nanoparticles are composed of lipopeptide conjugates, where a peptide is bonded to a lipid. The lipid nanoparticles described herein represent a new approach in drug delivery, addressing critical challenges in balancing biodegradability, biocompatibility, and organspecific targeting. The lipid nanoparticles can selectively target and deliver bioactive agents to specific tissues in a subject by modifying specific amino acids and ratios thereof in the peptide of the lipopeptide conjugate.

The invention discloses a starch-based full-biodegradable mulching film capable of being rapidly degraded and a preparation method of the starch-based full-biodegradable mulching film, and belongs to the technical field of degradable materials.The preparation method comprises the steps of tea polyphenol calcium salt preparation, filler preparation, thermal plasticization and film preparation. The preparation of the filler comprises the following steps: adding silicon dioxide into a polyacrylic acid aqueous solution, stirring and centrifuging at room temperature, taking a precipitate, adding the precipitate into a polyvinylpyrrolidone aqueous solution, adjusting the pH value to 3-3.5, stirring and centrifuging at room temperature, taking the precipitate, adding the precipitate into the polyacrylic acid aqueous solution, adjusting the pH value to 3-3.5, stirring and centrifuging at room temperature, taking the precipitate, and freeze-drying to obtain the filler. The starch-based full-biodegradable mulching film prepared by the preparation method disclosed by the invention is good in processability, waterproofness and heat resistance and high in mechanical strength, the problem of phase separation does not occur in preparation, the problem of plasticizer precipitation does not easily occur in long-term use, and rapid degradation can be realized.

The invention relates to the technical field of degradable PE (polyethylene) packaging materials, and discloses a PE film, a preparation process and application in tissue packaging, and the PE film is prepared by the following steps: by taking 7-(diethylamino) coumarin-3-carboxylic acid, 2-naphthyl methanol and epoxy chloropropane as raw materials, carrying out esterification reaction and quaternization reaction to prepare an epoxidized biodegradable organic photosensitizer; based on an epoxy-hydroxyl ring-opening reaction mechanism, hydroxylated titanium dioxide nanoparticles and polyvinyl alcohol resin are respectively modified by using an epoxidized biodegradable organic photosensitizer, and compounding is performed based on a pi-pi accumulation effect between aromatic rings to prepare the ultraviolet light dependent photo-biodegradable component. According to the present invention, the ultraviolet light dependent light-biological degradation component, the compatible component and the composite auxiliary agent are added to the polyethylene matrix, and blow molding is performed to obtain the PE film, and the film product shows excellent light-biological dual degradation performance, has actual use value, and can be used in the tissue packaging field.

The invention discloses flame-retardant recyclable compressible biodegradable cellulose aerogel and a preparation method and application thereof.The preparation method comprises the following steps that 1, phosphorus / nitrogen-containing bridged organosiloxane and tetraethyl orthosilicate are added into bacterial cellulose dispersion liquid and stirred to be uniform, and a milk white dispersion solution is prepared; (2) heating, curing, pre-freezing and freeze-drying the milky white dispersion solution to obtain the flame-retardant recyclable compressible biodegradable cellulose aerogel, and the phosphorus / nitrogen-containing bridged organosiloxane is prepared by carrying out a reaction on phosphonitrilic chloride trimer and 3-aminopropyltriethoxysilane. The prepared cellulose aerogel is excellent in flame retardance, heat insulation and cyclic compression performance, and has a feasible application prospect in the aspect of radiation refrigeration.

The invention discloses an in-situ biomineralizable mineral-PHA water-based seed coating based on microphase separation and soil water potential response and a preparation method and application thereof, and belongs to the technical field of green coatings, the in-situ biomineralizable mineral-PHA water-based seed coating comprises a structural mineral skeleton, a PHA and resin composite matrix and a pore-forming disintegrating agent. According to the invention, a resin enrichment layer and island microphase structure is innovatively constructed, and the contradiction between poor wear resistance and difficult disintegration of a bio-based material is effectively solved. Compared with the prior art, the wear-resistant and dust-reducing coating has the advantages that the wear-resistant and dust-reducing performance far better than that of the traditional PHA coating is realized by utilizing an interface enhancement effect under the condition of equal or even lower polymer dosage; meanwhile, the coating is endowed with a sensitive soil water potential response'switch ', so that dry-state tough seed protection and wet-state rapid disintegration are ensured, and germination is not hindered. Organic components of the composition can be biodegraded in aerobic soil, inorganic components are natural minerals, the environmental compatibility is good, the composition has the advantages of high performance and low cost, and an excellent seed treatment scheme is provided for green agriculture.

The invention provides a microbial slow-release porous composite material for sewage treatment as well as a preparation method and application thereof. The preparation method comprises the following steps: dropwise adding an organic ligand solution into a precursor solution consisting of a nanocellulose solution and a cobalt source solution; mixing the reaction solution with polyvinyl alcohol, injecting the mixture into a mold, and performing directional freezing to obtain an aerogel matrix; carrying out hydrophobic modification on the aerogel matrix to obtain a modified aerogel matrix; mixing the microbial suspension with sodium alginate, and homogenizing at high pressure to obtain a gel precursor emulsion; the preparation method comprises the following steps: dropwise adding a calcium chloride solution to gelatinize to obtain gel particles, and then cross-linking and drying by glutaraldehyde to obtain sustained-release capsule particles; dispersing the sustained-release capsule particles in deionized water to obtain dispersion liquid; and dipping the modified aerogel matrix in the dispersion liquid. An aerogel matrix with a hierarchical porous structure is compounded with a sustained-release capsule with a pH response mechanism, so that physical adsorption, chemical catalysis and biodegradation for sewage treatment are realized.