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8874 results about "Oxidation resistant" patented technology

Oxidation Resistance. (resistance to sealing), the ability of metallic materials to resist chemical degradation of the surface caused by the action of air or other gaseous mediums at high temperatures. The oxidation resistance of a metal or alloy in an oxidizing atmosphere is determined by the properties of the oxide layer—scale—that forms on...

Method of forming metal layer using atomic layer deposition and semiconductor device having the metal layer as barrier metal layer or upper or lower electrode of capacitor

A method of forming a metal layer having excellent thermal and oxidation resistant characteristics using atomic layer deposition is provided. The metal layer includes a reactive metal (A), an element (B) for the amorphous combination between the reactive metal (A) and nitrogen (N), and nitrogen (N). The reactive metal (A) may be titanium (Ti), tantalum (Ta), tungsten (W), zirconium (Zr), hafnium (Hf), molybdenum (Mo) or niobium (Nb). The amorphous combination element (B) may be aluminum (Al), silicon (Si) or boron (B). The metal layer is formed by alternately injecting pulsed source gases for the elements (A, B and N) into a chamber according to atomic layer deposition to thereby alternately stack atomic layers. Accordingly, the composition ratio of a nitrogen compound (A-B-N) of the metal layer can be desirably adjusted just by appropriately determining the number of injection pulses of each source gas. According to the composition ratio, a desirable electrical conductivity and resistance of the metal layer can be accurately obtained. The atomic layers are individually deposited, thereby realizing excellent step coverage even in a complex and compact region. A metal layer formed by atomic layer deposition can be employed as a barrier metal layer, a lower electrode or an upper electrode in a semiconductor device.
Owner:SAMSUNG ELECTRONICS CO LTD

High temperature, oxidation-resistant abradable coatings containing microballoons and method for applying same

An abradable coating composition for use on shrouds in gas turbine engines or other hot gas path metal components exposed to high temperatures containing an initial porous coating phase created by adding an amount of inorganic microspheres, preferably alumina-ceramic microballoons, to a base metal alloy containing high Al, Cr or Ti such as β-NiAl or, alternatively, MCrAlY that serves to increase the brittle nature of the metal matrix, thereby increasing the abradability and oxidation resistance of the coating at elevated temperatures. Coatings having a total open and closed porosity of between 20% and 55% by volume due to the presence of ceramic microballoons ranging in size from about 10 microns to about 200 microns have been found to exhibit excellent abradability for applications involving turbine shroud coatings. An abradable coating thickness in the range of between 40 and 60 ml provides improved performance for turbine shrouds exposed to gas temperatures between 1380° F. and 1800° F. Abradable coatings in accordance with the invention can be used for new metal components or to repair existing equipment. The coatings can be applied to the metal shroud using thermal spray, processes that integrate sintering and brazing, or direct write techniques.
Owner:GENERAL ELECTRIC CO

High-wear resistant Ti (C, N)-base ceramet tool bit and preparation thereof

InactiveCN101302595AReliable guarantee of high nitrogen-carbon ratioReliable Guarantee of HardnessLow nitrogenWear resistant
The invention provides a high-abrasion Ti(C, N) based metal ceramic tool and a preparation thereof. The Ti(C, N) based metal ceramic tool uses Ni and Co as a binder phase, is added with at least one carbonitride of Ti(Cx, N1-x) or (TiC)x plus (TiN)1-x as a basic batch, and consists of at least one composition of WC, Mo2C, Co, Ni, ZrC, Cr3C2, VC, TaC and NbC, and the balance being Ti(Cx, N1-x) or (TiC)x plus (TiN)1-x, wherein, an X value for adding the carbonitride of the Ti(C, N) based metal ceramic tool is as follows: X is less than or equal to 0.5 and more than or equal to 0.4, or the X is more than 0.5 and less than or equal to 0.7. The Ti(C, N) based metal ceramic tool is prepared according to the content of nitrogen by nitrogen pressure sintering or vacuum sintering combined with hot isostatic pressing treatment, thereby preventing nitrogen from escaping during the process of sintering high-nitrogen alloy, so that the high-nitrogen-carbon ratio in matrix and material hardness can be reliably guaranteed, and anti-oxidative abrasion property and anti-diffusive abrasion property of the material can be obviously increased through adding slight ZrC, Cr3C2, VC and other carbides into the basic batch; meanwhile, compactability and buckling strength of a low-nitrogen alloy structure can be obviously improved through optimally distributing each composition and content. The Ti(C, N) based metal ceramic tool is widely suitable for high-speed cutting tools of medium-low carbon steel and low alloy steel.
Owner:HUNAN UNIV OF SCI & TECH

Highly purified tocopheryl phosphate, process for producing the same, analytical method therefor and cosmetic

Disclosed herein are a highly purified tocopheryl phosphate and / or a salt thereof (tocopheryl phosphates) wherein a P,P'-bistocopheryl hypophosphate and / or a salt thereof (P,P'-bistocopheryl diphoshates) is contained in a proportion of not higher than 3% by weight; a process for producing a highly purified tocopheryl phosphate and / or a salt thereof, which comprises the steps of reacting a tocopherol with an oxyphosphorus trihalide followed by treating with an acid or basic aqueous solution to thereby form tocopheryl phosphates (i) in which P,P'-bistocopheryl diphoshates (ii) formed as by-products are contained, hydrolyzing the P,P'-bistocopheryl diphoshates (ii) under acid condition, and, optionally, rendering the hydrolyzate neutral or basic under basic condition; and a method of analyzing tocopheryl phosphates, comprising analyzing a sample containing components (i) and (ii) with the use of a high-performance liquid chromatograph column packed with a gel of a polymethacrylate having, bonded thereto, long-chain alkyl groups. None or only an extremely minute amount of P,P'-bistocopheryl diphoshates are contained in the highly purified tocopheryl phosphates, so that the highly purified tocopheryl phosphates exhibit antioxidant and blood circulation promoting effects, have excellent water solubility, are powdery so that the handling thereof is extremely easy, are free from cutaneous irritation and allergenecity and ensure dermal safety. Therefore, the highly purified tocopheryl phosphates are useful as cosmetic ingredients. The amounts of components (i) and (ii) can be simply measured with high accuracy by the above method.
Owner:SHOWA DENKO KK
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