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308results about How to "Improves stain resistance" patented technology

Hydrophilic modification method for polytetrafluoroethylene membrane

The inveniton provides a hydrophilic modification method for a polytetrafluoroethylene membrane. The method comprises the following steps: step 1, subjecting the polytetrafluoroethylene membrane to plasma treatment under a nitrogen atmosphere, and allowing the surface of the polytetrafluoroethylene membrane to generate relatively-stable free radicals and active sites; step 2, placing the polytetrafluoroethylene membrane into an acylic acid solution and carrying out static impregnation for a period of time, then taking the polytetrafluoroethylene membrane out of the solution and then placing the polytetrafluoroethylene membrane between two glase plates, and carrying out thermochemical polymerization in a vacuum drying oven so as to obtain the polytetrafluoroethylene membrane with the surface grafted with polyacrylic acid; and step 3, subjecting the polytetrafluoroethylene membrane to static impregnation in a titanium dioxide sol for a period of time, and allowing titanium dioxide to be assembled onto the surface of the polytetrafluoroethylene membrane through the coordination effect of metal titanium-ion Ti4+ and a carboxyl group on the polyacrylic acid so as to obtain a hydrophilic modified polytetrafluoroethylene membrane. The hydrophilic modified polytetrafluoroethylene membrane prepared by using the method in the invention retains excellent properties of a conventional polytetrafluoroethylene membrane and greatly improves filter performance, hydrophilic property, pollution resistant property and photocatalytic property of the polytetrafluoroethylene membrane.
Owner:深圳市新纳捷科技有限公司

Hydrophilic oleophobic polymer and preparation method thereof, and application thereof in humidity response oil and water separating membrane

The invention discloses a hydrophilic oleophobic polymer and preparation method thereof, and application thereof in humidity response oil and water separating membrane. The preparation of the hydrophilic oleophobic polymer comprises the following steps: carrying out an esterification reaction of polyvinyl alcohol and perfluorocarboxylic acid or firstly carrying out a carboxylation of polyvinyl alcohol and then a neutralization reaction of the intermediate product and perfluorotertiary amine. When the product is used, a fabric silk screen is cleaned with ultrasonic sound; 10-50 parts of hydrophilic oleophobic polymer, 50-500 parts of nanometer sol, 1-5 parts of cross-linking agents and 1-5 parts of catalysts are dispersed uniformly; the mixed liquor is dip-coated or spray-coated on the surface of the membrane, and after drying and crosslinking, the humidity response super-hydrophilic and super-oleophobic oil and water separating net membrane. According to the invention, hydrophilic groups are distributed surrounding the hydrophobic chain segment on the surface of the net membrane with humidity responsiveness, and contact angle in the air of the product to water is reduced to 0 degree from more than 90 degrees, and the contact angle in air and water of the product to oil is above 150 degrees, so the product has a low adherence characteristic of droplet. The net membrane is used for separating oil and water mixture and processing oil-containing sewage.
Owner:SOUTH CHINA UNIV OF TECH

Normal-temperature multiple curing organic-inorganic hybridized aqueous nano polyurethane woodware coating and preparation method thereof

The invention discloses a normal-temperature multiple curing organic-inorganic hybridized aqueous polyurethane woodware coating and a preparation method thereof. The coating mainly contains organic-inorganic hybridized aqueous nano polyurethane latex, a film-forming assistant, a defoaming and foam inhibitor, a flatting agent, a base material wetting agent, a stable dispersing agent, a thickening agent and an aqueous photo initiator, wherein the organic-inorganic hybridized aqueous nano polyurethane latex is prepared by firstly obtaining a polyurethane prepolymer by pre-polymerizing, and then adding an inorganic nano material in an organic-inorganic hybridization way by an in-situ polymerization technology, and finally grafting a photo-curing end-capping agent containing active functional groups and C-C double bonds. The normal-temperature multiple curing organic-inorganic hybridized aqueous polyurethane woodware coating is obtained by adding and dispersing pigment fillings and an assistant evenly in the organic-inorganic hybridized aqueous nano polyurethane latex. The invention not only solves the pollution problem of a solvent-type VOC (Volatile Organic Compound) coating, but also solves the problem of aqueous coatings which have the defects of poor toughness and poor performances in weather resistance, aging resistance, acid resistance, alkaline resistance and solvent resistance.
Owner:SICHUAN UNIV +1

Preparation method of hollow fiber pipe in overlay film

The invention discloses a preparation method of a hollow fiber pipe in an overlay film, which comprises the following steps 1) preparing a high-molecular polymer, an organic solvent, an additive and a pore forming agent to a plurality of homogeneous casting solutions according to different proportions; 2) removing the PET fiber braiding tube surface spot objects; 3) using a modifier for modifying the PET fiber braiding pipe, fixing a circular pipe at high temperature; 4) using a multi-immersing multi-rolling (several primary immersing-technology in series) technology for cladding various homogeneous casting solutions to the internal and external walls of the PET fiber braiding pipe in order, carrying out a process of circular pipe heat fixing after each time of immersing and rolling, placing the obtained the composite braiding pipe in a gel bath for splitting the phase after the multi-immersing multi-rolling process is finished to obtain the hollow fiber pipe. According to the invention, the PET fiber braiding pipe is taken as a main body, the multi-immersing multi-rolling technology is used, the micro casting solution is coated to the internal and external walls of the braiding pipe, the anti-pollution capability of the braiding pipe can be improved, and a polymer coat layer is formed on the braiding tube surface which can ensure the effective porosity amount and interception effect of the hollow fiber tube.
Owner:SUZHOU CNPT SOURCETECH ENVIRONMENTAL TECH

Nano-fiber composite ultrafiltration membrane preparation method based on electrostatic spinning technology

The invention relates to a nano-fiber composite ultrafiltration membrane preparation method based on an electrostatic spinning technology. According to the invention, a high-molecular polymer used for spinning is dissolved in a solvent, such that a spinning solution A with a concentration of 10-30wt% is obtained; a PVA spinning solution with a mass percentage of 7-10% is prepared; a PVA water solution with a mass concentration of 1-6% is prepared; through crosslinking treatment, a PVA coating liquid is obtained; the spinning solution A and the PVA spinning solution is subjected to composite electrostatic spinning, such that a nano-fiber composite membrane is obtained; the membrane is processed under water vapor, and is soaked with a crosslinking bath; the PVA coating liquid is used for coating by using a spin coater; a sealed reaction is carried out under room temperature; the membrane is soaked by using deionized water, and is suspended and air-dried, such that the ultrafiltration membrane is obtained. The surface of the prepared nano-fiber composite ultrafiltration membrane comprises large amounts of hydrophilic groups and active groups. The membrane has good mechanical performances and anti-pollution performances, and is especially suitable for ultrafiltration under ultra-low pressure or even no power. The membrane has high flux and retention rate under low pressure.
Owner:BEIJING INSTITUTE OF CLOTHING TECHNOLOGY

Waterborne fluorocarbon texture coating and preparation method and application thereof

The invention discloses a waterborne fluorocarbon texture coating and a preparation method and application thereof. The coating comprises the following components in part by weight: 141 to 180 parts of fluorocarbon emulsion, 5 to 12 parts of film-forming aid, 5 to 6 parts of cosolvent, 80 to 100 parts of water, 1 to 2 parts of antifoaming agent, 3 to 6 parts of disinfectant, 1 to 3 parts of mildew preventive, 2 to 3 parts of pH regulator, 5 to 10 parts of thickening agent, 600 to 1,000 parts of color sand, and 0 to 89 parts of sheet. The preparation method comprises the following steps of: under the stirring at a high speed, adding the film-forming aid, the cosolvent, the antifoaming agent, the disinfectant, and the mildew preventive in turn, stirring at the high speed and reducing the stirring speed; adding the fluorocarbon emulsion, regulating the pH value, and regulating the viscosity by using the thickening agent to obtain pulp; stirring the pulp at a low speed, adding the color sand and sheet, and mixing to obtain the waterborne fluorocarbon texture coating. The waterborne fluorocarbon texture coating applied to a coated outer wall surface has good protection functions of water resistance, weather resistance, smudge resistance, and the like, and makes the wall surface have elegant, harmonious and serious aesthetic feeling.
Owner:SHANGHAI HENGFENG FLUOROCARBON MATERIAL

Method for forming amphoteric ion structure on surface of separation membrane and separation membrane

The invention discloses a method for forming an amphoteric ion structure on the surface of a separation membrane. The method comprises the following steps: (1) immersing the separation membrane in a solution containing positively charged substances, wherein the positively charged substances react with active groups on the surface of the separation membrane to realize the grafting of the positively charged substances onto the surface of the separation membrane; and (2) washing the separation membrane with the surface being grafted with the positively charged substances, and immersing the separation membrane in a solution containing negatively charged substances, wherein the negatively charged substances have Michael addition reaction with the positively charged substances on the surface of the separation membrane so as to be grafted to the surface of the separation membrane to obtain an ampphoteric ion modified separation membrane. The invention also discloses a modified membrane prepared by the method. The method for forming the amphoteric ion structure on the surface of the separation membrane is carried out under the normal temperature and normal pressure, only the separation membrane needs to be immersed in the positively charged substance solution and the negatively changed substance solution, the reaction conditions are moderate, the preparation steps are simple, and therefore industrialization can be achieved easily.
Owner:ZHEJIANG UNIV

Novel inorganic artificial quartzite and preparation method thereof

InactiveCN102503345AAdvantages of preparation methodNo room temperature maintenanceHardnessMaterials science
The invention discloses a novel inorganic artificial quartzite and a preparation method thereof and belongs to the field of building decorative materials. The novel inorganic artificial quartzite provided by the invention comprises the following raw materials by weight parts: 2-20 parts of inorganic polymer A components, 4-20 parts of inorganic polymer B components, 50-90 parts of aggregates and 0.1-1.0 part of additives. The preparation method provided by the invention comprises the following steps: uniformly stirring the components, such as inorganic polymers, pigments, aggregates, and additives, according to a certain technology, and then performing the processes of distributing materials, vacuumizing, vibrating, pressing and forming, fixing thickness, curing, polishing, cutting, protecting and the like, thereby obtaining the inorganic artificial quartzite. The production technology for the inorganic artificial quartzite is simple; during the production process, a plate surface is free from being cracked and warped; the mechanical property is excellent, the glossiness is high and the hardness is high; and the novel inorganic artificial quartzite belongs to a novel environment-friendly product which can be widely applied to various indoor and outdoor decorative and fitting-out projects.
Owner:GUANGZHOU INSTITUTE OF BUILDING SCIENCE CO LTD
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