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769 results about "Polyene" patented technology

Polyenes are poly-unsaturated organic compounds that contain at least three alternating double and single carbon–carbon bonds. These carbon–carbon double bonds interact in a process known as conjugation resulting in some unusual optical properties. Related to polyenes are dienes, where there are only two alternating double and single bonds.

Crosslinkable rubber compositions and uses thereof

InactiveUS20030013818A1High crosslinking rateImprove adhesionPolymer scienceCrazing
The crosslinkable rubber composition is crosslinkable at room temperature, has a gelation time at room temperature of 30 days or less, and can prepare a crosslinked rubber sheet by crosslinking the composition at room temperature, wherein the crosslinked rubber sheet has a tensile elongation of 20% or more, and is free of cracks after treatment at 40° C. in a 50 pphm ozone concentration for 96 hr. Specifically, it comprises an ethylene/alpha-olefin/non-conjugated polyene random copolymer rubber comprising a norbornene compound having a specific vinyl end group, an SiH group-containing compound, which has at least two SiH groups in one molecule, and optionally a platinum catalyst, a reaction inhibitor and/or a silane-coupling agent. The sealing, potting and coating materials and adhesives of the present invention comprise the above rubber composition. The rubber composition has a high crosslinking rate at room temperature and excellent productivity, and can prepare crosslinked rubber molded products (including foamed products) having excellent weathering resistance, ozone resistance, heat aging resistance and compression set at low cost. Further, it is suitable for use of electric and electronic parts, transportation machines, civil engineering and construction materials, medical appliances and goods for leisure activities.
Owner:MITSUI CHEM INC

Copolymer, rubber composition, cross-linked rubber, cross-linked foam, and uses thereof

The present invention provides a rubber composition having adequate foamability, uses thereof, a copolymer contained in the rubber composition, a rubber composition capable of providing a cross-linked foam, which has a low specific gravity and an excellent shape-retaining property even when the usage of a nonconjugated polyene is reduced, and a cross-linked rubber and a cross-linked foam, which are produced from the rubber composition. A copolymer (A) according to the present invention is a copolymer including structural units derived from ethylene [A], an α-olefin [B], a nonconjugated polyene [C-1], in which one carbon-carbon double bond (C═C) polymerizable with a metallocene catalyst is present in one molecule, and a nonconjugated polyene [C-2], in which two bonds of C═C polymerizable with the metallocene catalyst are present in one molecule, and being synthesized with the metallocene catalyst, wherein (1) the units derived from the component [B] constitute 10 to 50 percent by mole, (2) the total of the units derived from the component [C-1] and the units derived from the component [C-2] is 1.0 to 6.0 percent by mole, (3) the molar ratio of the units derived from the component [C-1] to the units derived from the component [C-2] is 75 / 25 to 99.5 / 0.5, (4) [ML (1+4) 100° C.] is 10 to 200, and (5) 50>activation energy of fluidization (kJ / mol)>35 is satisfied.
Owner:MITSUI CHEM INC

Preparation method of continuous high-melt-strength polypropylene based on grafting reaction

The invention relates to a preparation method of a continuous high-melt-strength polypropylene based on a grafting reaction. The continuous high-melt-strength polypropylene comprises the following components: 100 parts by weight of polypropylene, 0.01-1 part by weight of initiator, 0.1-5 parts by weight of a first grafting monomer and 0.1-5 parts by weight of a second grafting monomer. The first grafting monomer is a vinyl silicone oil compound, and the second grafting monomer is a C5-C10 monoolefin or polyene compound. The preparation method comprises the following steps: weighing the polypropylene, the initiator, the first grafting monomer and the second grafting monomer, adequately mixing the mixture, and then, adding the mixture to a twin-screw extruder, milling, extruding and granulating the mixture at 140-250 DEG C. The invention provides a method for preparing the high-melt-strength polypropylene which has no gelatin, has favorable color and luster and contains a long branch chain through a one-step silane method which has a simple process, flexibility in operation and an industrial implementation foreground, and a high-melt-strength polypropylene material obtained by the preparation method is applicable to the application fields of foaming, thermal forming, film blow molding, extrusion coating and the like.
Owner:EAST CHINA UNIV OF SCI & TECH

Titanium-silicon molecular sieve compound catalyst and preparation method thereof

The invention discloses a titanium-silicon molecular sieve compound catalyst and a preparation method thereof. The method comprises the following steps of: fully mixing a titanium-silicon molecular sieve, an acid molecular sieve, a polymeric monomer polyene-based compound and a pore forming agent; undergoing a polymerization reaction in the presence of an initiator; smashing an obtained lump solid catalyst; adding into a halogenated hydrocarbon for swelling; and extracting and activating with a solvent to obtain a molded titanium-silicon molecular sieve compound catalyst. Due to the adoption of the catalyst obtained in the invention, a corresponding process for preparing a corresponding diol compound by performing alkene epoxidation and undergoing a one-step hydration reaction can be realized, the problem of difficulty in separating titanium-silicon catalyst powder from a reaction solution can be solved simultaneously, and the reaction efficiency is increased. The catalyst is particularly suitable for catalytic reaction processes for preparation of ethylene glycol from ethylene, preparation of 1,2-propylene glycol from ethylene, alkene epoxidation, preparation of alcohol ether by etherification, and the like with a fixed bed process.
Owner:CHINA PETROLEUM & CHEM CORP +1
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