1172 results about "Acid catalyzed" patented technology

The invention discloses a deep eutectic solvent / bimetal organic framework co-catalyzed straw polyol as well as a preparation method and application thereof, the straw polyol is prepared by the following method: uniformly mixing straw powder, small molecular alcohol, an acid catalyst and a deep eutectic solvent in a nitrogen atmosphere, and reacting to obtain a reaction product; and adding a bimetal organic framework catalyst into the reaction product, and reacting to obtain the straw polyol. A green, natural and pollution-free eutectic solvent catalytic liquefaction technology is adopted, lignin and hemicellulose can be dissolved, the cross-linking effect between lignin and hemicellulose and cellulose is reduced, the crystalline structure of cellulose can be destroyed, the available surface area is increased, the contact with a liquefying agent is enhanced, the conversion efficiency is improved, and the residue rate is reduced; the bimetallic organic framework catalyst is added in the middle and later periods of the reaction, aldehydes, ketones and acid and ester substances can be reduced and upgraded into alcohols, the hydroxyl value of the liquefied polyol is greatly increased, and the film-forming crosslinking degree is improved.

The invention relates to the field of polyurethane coating processing, in particular to a waterproof bio-based polyurethane coating and a preparation technology thereof.The waterproof bio-based polyurethane coating is prepared from, by weight, 25%-40% of castor oil polyester polyol, 15%-25% of isocyanate, 5%-10% of bio-based polybasic acid, 0.2%-0.6% of a catalyst, 0.5%-1% of a chain extender, 15%-20% of modified nanofiller, 3%-5% of a wetting agent and 1%-2% of a curing agent. By adopting the formula, the prepared waterproof bio-based polyurethane coating has good weather resistance, high and low temperature resistance, strength and waterproofness, and can be used in Tibet, Xinjiang, Inner Mongolia, Qinghai and other regions for a long time without aging, and the service life of the waterproof coating is prolonged.

The invention provides a red ginseng processing method capable of increasing the content of rare ginsenoside and reducing pesticide residues, and relates to the technical field of medicinal material processing, the red ginseng processing method comprises the following steps: A, steaming fresh ginseng by using atomized probiotic fermentation liquor; b, drying the steamed fresh ginseng to obtain red ginseng; the pH (Potential of Hydrogen) of the probiotic fermentation liquor is 3.0 to 4.0; the OD600 value of the probiotic fermentation liquor is 1.2-2.5, the probiotic fermentation liquor is obtained through probiotic fermentation, the fermentation liquor with the pH value being 3.0-4.0 is adopted as an acid catalyst to replace purified water, in the ginseng steaming process, steaming is conducted through the atomized probiotic fermentation liquor, conversion of ginsenoside is promoted, and meanwhile organophosphorus pesticide residues in ginseng are degraded. The method is safe, efficient, green and natural, and loss of nutritional ingredients and functional ingredients caused by cooking is avoided. The technical problems that red ginseng processed and prepared in the prior art is low in rare saponin content and poor in effect and pesticide residues exist are solved.

The invention provides a metal organic sulfonic acid-based solid acid catalyst applied to nylon 6 recovery and depolymerization and a preparation method thereof, and realizes upgrading and recovery of waste nylon 6. The main contents are as follows: (1) a structural design and a preparation method of the metal organic framework sulfonic acid-based solid acid catalyst; and (2) the solid acid is used for catalytic depolymerization of nylon 6. The problems that equipment corrosion is aggravated by inorganic acid in the nylon 6 recovery process and a liquid-phase catalyst is difficult to separate and recover are solved, and the application prospect is good.

The invention belongs to the technical field of membrane separation, and aims to provide a preparation method and application of a covalent organic framework bipolar membrane. The method comprises the following steps: combining at least one amine, hydrazide or aldehyde monomer containing ionic groups with a monomer without ionic groups, and respectively synthesizing covalent organic framework COF nanosheets with positive charges and negative charges through a one-pot method under the condition of coexistence of an acid catalyst and an organic solvent; sequentially depositing COF nanosheets with positive and negative charges on the surface of the porous carrier by a hot solvent evaporation method; by constructing two COF separation layers with regular pore channels and opposite electrical properties, the covalent organic framework bipolar membrane with charge asymmetry is finally obtained. The product provided by the invention has high selectivity, can realize efficient separation of protons and metal cations, and significantly improves the extraction and recovery purity of hydrochloric acid; through charge repulsion and pore size screening mechanisms, separation of different anions can be further realized, and selective recovery of acid molecules is enhanced.

The invention provides a hydrolysis method of a waste nylon 6 fishing net. The hydrolysis method comprises the following steps: step 1, screening the waste nylon 6 fishing net, cleaning, removing impurities, disinfecting and crushing; step 2, pretreating diatomite; step 3, adding pretreated diatomite, solid acid and deionized water into a reaction kettle, stirring at 50 DEG C for 5 hours, and removing moisture to obtain a solid acid catalyst; 4, adding the solid acid catalyst, the cleaned waste nylon 6 fishing net and deionized water into a reaction kettle, controlling the temperature and time for reaction, and filtering while hot to obtain a liquid-phase product; 5, neutralizing, decolorizing and extracting the liquid-phase product to obtain a caprolactam monomer; and 6, carrying out polymerization reaction on the obtained caprolactam monomer to generate regenerated polyamide for chinlon spinning. According to the method provided by the invention, the solid acid catalyst is easily separated from reactants, the catalytic efficiency is high, the corrosion to equipment can be reduced, and the method is more environment-friendly.

The invention relates to a preparation method and application of thermal-insulation flame-retardant silicon-based composite aerogel, and the preparation method comprises the following steps: mixing a silane coupling agent, an acid catalyst, a surfactant, a cosolvent and water, adjusting the pH value to 2-5, stirring, and hydrolyzing to obtain a silica sol solution; adding an alkali catalyst into the obtained silica sol solution, stirring, adjusting the pH value to 9-11, adding the cellulose nanofibril / graphene oxide co-grinding liquid, stirring, and carrying out ultrasonic treatment to obtain a cellulose nanofibril / graphene oxide-silane mixed solution; transferring the obtained cellulose nanofibril / graphene oxide-silane mixed solution into a closed container, reacting at 25-95 DEG C for 15-75 hours, and then carrying out solvent replacement washing and normal-temperature and normal-pressure drying to obtain cellulose nanofibril / graphene oxide-silicon-based composite aerogel; the cellulose nanofibril / graphene oxide is used for modification, so that the aerogel has more ideal heat-insulating property and flame-retardant property.

The invention relates to the technical field of catalysts, and provides a supported sulfonated phenolic resin solid acid catalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: carrying out hydrophobic modification on the surface of a carrier by adopting a silane coupling agent to obtain a modified carrier; then carrying out polymerization in-situ growth on soluble phenolic resin and a curing agent on the modified carrier to obtain a phenolic resin-loaded modified carrier; the preparation method of the supported sulfonated phenolic resin solid acid catalyst provided by the invention has the advantages that the process is simple, the cost is low, and the utilization rate of phenolic resin is high; the prepared catalyst is uniform in size, high in mechanical strength, not easy to crush, small in resistance and good in stability during liquid-phase flow catalytic continuous reaction, has good catalytic activity and high isosorbide yield when being used for catalyzing dehydration of sorbitol to prepare isosorbide, and can be recycled.

The invention discloses coal tar mixed phenol novolac epoxy resin as well as a preparation method and application thereof. The preparation method of the coal tar mixed phenol novolac epoxy resin comprises the following steps: S1, in an inert atmosphere, mixing and stirring refined coal tar mixed phenol, a solvent and an acid catalyst, then adding an aldehyde solution, and reacting to obtain phenolic resin; s2, in an inert atmosphere, mixing and stirring phenolic resin, a phase transfer catalyst and epoxy chloropropane, preheating to 70-100 DEG C, reacting for 1-4 hours, cooling to 65-70 DEG C, dropwise adding a basic catalyst, heating to 80-85 DEG C, continuously reacting for 2-3 hours, and naturally cooling; and carrying out post-treatment. According to the preparation method and application of the coal tar mixed phenol novolac epoxy resin, operation is easy and convenient, control is easy, and batch production can be achieved conveniently; in addition, the refined coal tar mixed phenol is low in price, the production cost of the anticorrosive paint is greatly reduced, the performance of the paint is improved, and the economic benefits of enterprises are improved.

The present application relates to the technical field of fine chemical synthesis, and in particular to an efficient preparation process of octanoyl hydroxamic acid, which comprises the following preparation steps: S1, preparation of ethyl n-octanoate: 90-110 parts by weight of n-octanoic acid and 35-40 parts by weight of ethanol are mixed, and then a solid acid catalyst is added, and the mixture is heated to reflux for reaction for 2.5-3 hours, filtered to obtain a precipitate and a filtrate, and the filtrate is decompressed and distilled to obtain ethyl n-octanoate; S2, preparation of octanoyl hydroxamic acid: 0.4-0.6 parts by weight of sodium acetate and 0.2-0.4 parts by weight of sodium carbonate are added to water, stirred until dissolved, ethanol is added, and after stirring, 24-32 parts by weight of hydroxylamine and ethyl n-octanoate prepared in S1 are added to react to obtain octanoyl hydroxamic acid; the process has the advantage of improving the reusability of the solid acid catalyst.

The invention belongs to the technical field of release film preparation, and particularly relates to an organosilicon release film and a preparation method thereof.The epoxy-terminated fluorine-containing polysiloxane serves as a main agent of a release agent and is blended with a curing agent and an acid catalyst to form the release agent, and the mass ratio of the epoxy-terminated fluorine-containing polysiloxane to the curing agent to the acid catalyst is 8: (1.5-1.8): (0.8-1); and coating a PE substrate with the diluted release agent by using a film coating rod, baking at 80 DEG C for 2 minutes, then curing at 60 DEG C for 36 hours, and curing the release agent on the PE film to obtain the release film. The epoxy group in the epoxy-terminated fluorine-containing polysiloxane reacts with the curing agent to generate a cured product with a three-dimensional cross-linked structure, a layer of thin film is formed on the surface of the PE film, and the adhesive force with a release film is better.

The invention provides a synergistic accelerant suitable for SNCR (selective non-catalytic reduction) denitration and application of the synergistic accelerant. The synergistic accelerant comprises the following components in parts by weight: 2-80 parts of an activating agent, the activating agent is selected from at least one of sodium glycinate, sodium glutamate, sodium iminodiacetate, sodium aspartate, sodium aminopropionate, sodium aspartate and potassium aspartate; 3-12 parts of a catalyst, wherein the catalyst is selected from soluble heteropolyacid; 1-10 parts of a catalytic promoter; the catalytic promoter is selected from at least one of soluble tungstate and molybdate. A trace amount of synergistic accelerant is added into a common SNCR denitration solution, so that the reaction speed of NOx and reducing agents such as ammonia or urea can be increased, a temperature window of SNCR reaction moves downwards, the application range of the traditional SNCR technology is expanded, the removal efficiency of NOx is improved, and a low-cost and high-efficiency method is provided for pollution abatement of nitric oxide in waste gas.

The invention relates to a method for efficiently hydrolyzing nylon 6 by acid catalysis, and relates to the technical field of hydrolysis of nylon 6, the method comprises the following steps: carrying out hydrolysis reaction on nylon 6, water and an acid catalyst in a closed state to obtain a hydrolysis product; and carrying out purification post-treatment on the hydrolysis product to obtain caprolactam, the reaction pressure of the hydrolysis reaction is controlled in a self-boosting manner; the specific process of the self-boosting mode comprises the step of changing the pressure of the hydrolysis reaction system by adjusting the adding mode of the water. The nylon 6 hydrolysis process provided by the invention is simple, hydrolysis reaction pressure is controlled mainly by a self-boosting control method of a reaction system by controlling a water adding mode, other raw materials do not need to be added, efficient hydrolysis of nylon 6 is realized, and the nylon 6 hydrolysis process has the characteristics of short hydrolysis reaction time, high depolymerization rate and the like, and is suitable for industrial production. The method effectively solves the technical problems of long hydrolysis reaction time and low depolymerization rate in the existing process for catalyzing and hydrolyzing nylon 6 by using an acid method.

The invention relates to the technical field of crystalline porous materials, in particular to a covalent organic framework material and a preparation method and application thereof.The preparation method includes the steps that a tridentate organic ligand monomer, a bidentate organic ligand monomer and a solid acid catalyst are evenly mixed to obtain a mixture, the rotating speed of a double-screw extruder is set to be 5-35 r / min, the temperature is set to be 80-140 DEG C, and the mixture is extruded to obtain a covalent organic framework material; and adding the mixture into a double-screw extruder, heating, kneading, mixing, washing and drying to obtain the COF material. Shear force and heat are provided through a double-screw extruder, a molten reaction monomer is used as a reaction medium, a toxic solvent is not needed, the preparation method is simple, rapid, green and environmentally friendly, the obtained COFs material is high in crystallinity, the COF material is expected to be further processed and formed through a specific extrusion head, continuous large-scale production is achieved, and the method is suitable for industrial production. And the COFs material synthesized by the method disclosed by the invention has good flame retardant property.

Provided herein are processes for preparing Compound A or a salt thereof, comprising admixing Compound B or a salt thereof and crotonaldehyde in the presence of an acid catalyst and a solvent to form Compound A

Provided herein are processes for preparing Compound A or a salt thereof, comprising admixing Compound B or a salt thereof and crotonaldehyde in the presence of an acid catalyst and a solvent to form Compound A

The invention provides a BVPE preparation method based on solid acid catalysis and continuous flow reaction, and relates to the technical field of disubstituted ethane preparation, and the method comprises the following steps: mixing a compound 1, a polymerization inhibitor, a solid acid catalyst and a solvent to form a reaction liquid; enabling the reaction liquid to pass through a fixed bed continuous flow reactor, and reacting at 20-180 DEG C for 1-45 minutes to obtain a compound 2; post-treating, separating and purifying a product; wherein the solid acid catalyst is an HZSM-5 type molecular sieve or acidic resin, the product purity and yield are high, the HZSM-5 type molecular sieve or acidic resin is adopted as the solid acid catalyst, residual pollution of traditional protonic acid (such as p-toluenesulfonic acid) is avoided, in embodiments 1-3, the product GC purity reaches 98.6%-99.1%, the yield reaches 88.8%-93.8%, and the product GC purity and the yield are remarkably higher than those of a contrast (the purity is 96.1%, and the yield is 74.2%).

The invention discloses a high-activity graphene quantum dot and a preparation method thereof, and relates to the technical field of oilfield chemistry, and the preparation method comprises the following steps: uniformly ground carbon source and nitrogen source are mixed, heated, fully reacted and cooled, uniformly dispersed in deionized water by ultrasonic waves, and then subjected to suction filtration, dialysis and freeze drying to obtain the nitrogen-containing graphene quantum dot. The preparation method comprises the following steps: dispersing nitrogen-containing graphene quantum dots, fatty alcohol-polyoxyethylene ether carboxylic acid and a catalyst in absolute ethyl alcohol, carrying out ultrasonic oscillation for 30 minutes, carrying out reflux reaction, and carrying out reduced-pressure rotary evaporation, thereby obtaining the nitrogen-containing graphene quantum dots. The prepared high-activity graphene quantum dots are small in particle size, high in activity and capable of entering small pores to peel crude oil, so that the recovery efficiency can be remarkably improved, the point injection allocation process is simple, the high-activity graphene quantum dots can be rapidly dispersed into injected water, an additional injection allocation device is not needed, and the construction cost is low.

The invention belongs to the technical field of recycling of waste blended textiles, and particularly discloses a method for oxidative depolymerization of waste blended textiles into alpha-hydroxy acid and terephthalic acid, which comprises the following steps: adding waste blended textiles, a solid acid catalyst and a reaction solution into a catalytic reaction kettle, filling a certain amount of air and / or oxygen, and reacting for 2-4 hours; the method comprises the following steps: adding alpha-hydroxy acid into a reaction kettle, heating to a specified temperature, stirring, carrying out selective oxidative depolymerization, after the reaction is finished, filtering, concentrating, separating and purifying the product to obtain terephthalic acid, glycollic acid and lactic acid, and taking terephthalic acid and alpha-hydroxy acid as depolymerization products of blended textiles and also as catalysts to participate in depolymerization of blended textiles. According to the method, the autocatalysis process of depolymerization conversion of the waste blended textiles is achieved, the product composition is simple and easy to recycle, carbon atoms in the raw materials are fully utilized, the requirement of green chemistry is met, depolymerization conversion of multiple components in the waste blended textiles is achieved through a one-pot method, the process steps are few, economic benefits are high, and actual operation is simple.

The invention relates to the technical field of epoxy resin, in particular to self-repairing epoxy resin and a preparation method thereof. The self-repairing epoxy resin is prepared from the following raw materials in parts by mass: 80 to 120 parts of bisphenol A type epoxy resin, 20 to 40 parts of bisphenol F type epoxy resin, 5 to 15 parts of 1, 6-hexanediol diglycidyl ether, 1 to 3 parts of 3, 5-dimethylphenylboronic acid, 1 to 5 parts of furyl maleimide, 10 to 20 parts of dodecanedioic acid, 5 to 15 parts of butanetetracarboxylic acid, 1 to 3 parts of catalyst, 10 to 15 parts of nano silicon dioxide, 1 to 2 parts of boron nitride nanosheet and 1 to 2 parts of hyperbranched polyamidoamine. The curing agent is prepared from the following components in parts by weight: 20-30 parts of epoxy resin, 1-2 parts of sulfydryl-terminated polysiloxane, 20-30 parts of amine curing agent, 5-15 parts of reinforcing filler and 0.5 According to the invention, the balance among self-repairing capability, mechanical property and heat resistance is successfully realized; in the microcrack propagation process, fracture and recombination mechanisms of dynamic covalent bonds effectively prevent further propagation of cracks.

The invention provides a preparation method of a block poly (biphenyl-trifluoroacetophenone-piperidone) bicontinuous hollow fiber loose nanofiltration membrane, which comprises the following steps: adding acid into biphenyl and N-methyl-4-piperidone to react to obtain a first product; adding acid into biphenyl and 2, 2, 2-trifluoroacetophenone to react, so as to obtain a second product; adding the second product into the first product, and carrying out condensation polymerization to obtain a PBTbBP block polymer; dissolving the PBTbBP block polymer in a solvent, and defoaming to obtain a membrane casting solution; spinning the membrane casting solution and the core solution to obtain membrane filaments; and immersing the membrane filaments in a coagulating bath, and carrying out phase separation. According to the preparation method, biphenyl, a hydrophobic trifluoroacetophenone monomer and a hydrophilic N-methyl piperidone monomer are subjected to superacid catalysis Friedel-Crafts reaction and are subjected to step-by-step copolymerization to obtain the amphiphilic block polymer PBTbBP. The membrane has efficient mass transfer channels and excellent membrane surface hydrophilicity, and the separation capacity of dye molecules and salt ions and the water permeability are improved.

The invention belongs to the technical field of high polymer material synthesis, and particularly relates to an artificial antioxidant enzyme material with an interlayer structure and a preparation method of the artificial antioxidant enzyme material. The preparation method of the artificial antioxidant enzyme material comprises the following steps: dissolving an aldehyde monomer and an amine monomer in a reaction solvent, performing thermal polymerization under the action of an acid catalyst, and then loading interlayer coordination metal, and further defining an aldehyde monomer and an amine monomer as well as an interlayer coordination metal. According to the present invention, the treatment-level oxidation resistance can be achieved through the space-optimized catalysis center and the fully-conjugated frame structure, and the innovative strategy is provided for solving the inflammation-driven tissue damage through the precise oxidation-reduction regulation and the immune microenvironment engineering.

Provided is method for producing a glycoside in which a phenolic compound is bonded to an anomeric position of a sugar, the method including: a step (1) of reacting a peracetylated sugar with the phenolic compound in the presence of an acid catalyst; and a step (2) of directly adding a deacetylating agent and a deacetylating solvent selected from the group consisting of water and an alcohol to a reaction mixture obtained in the step (1) to perform a deacetylation reaction.

The invention relates to the technical field of heat energy storage materials, and particularly provides a silicon dioxide aerogel composite phase change heat storage material and a preparation method thereof. The method comprises the following steps: mixing an organic silicon source, absolute ethyl alcohol and deionized water according to a specific ratio, fully stirring to obtain a mixed solution, and dropwise adding an acid catalyst into the mixed solution at room temperature for hydrolysis reaction to obtain a hydrolysate; sequentially adding a drying control agent and an alkali catalyst, and standing for gelation reaction to obtain gel; adding an organic solvent to carry out aging reaction, and then adopting the organic solvent to carry out replacement for multiple times to obtain alcogel; replacing the alcohol gel with an organic solvent for multiple times to obtain wet gel, soaking the wet gel in an excessive molten phase change material, and carrying out normal-pressure solvent replacement and drying at 40 DEG C to obtain the phase change material, the loading capacity of octadecane in the obtained CPCM is about 83%, the phase change enthalpy reaches up to 192J / g, the heat conductivity is as low as 0.0812 W / m.K, and no obvious leakage occurs after 200 times of circulation.

The invention discloses a method for catalytically synthesizing 1, 4-butanediol diacrylate. The preparation method comprises the following steps: firstly, polymerizing paraformaldehyde and p-toluenesulfonic acid under the catalytic action of concentrated sulfuric acid to form a solid paraformaldehyde sulfonic acid catalyst; then, acrylic acid, 1, 3-butadiene, a paraformaldehyde sulfonic acid catalyst and a polymerization inhibitor are added into a reactor, a stirring reaction is performed at the reaction temperature of 30-60 DEG C, acrylic acid and 1, 3-butadiene are catalyzed to be subjected to an acid addition esterification reaction, 1, 4-butanediol diacrylate is synthesized, and the product yield is higher than 98%. The preparation process of the solid paraformaldehyde sulfonic acid catalyst is simple, the reaction of catalyzing the esterification reaction of acrylic acid and 1, 3-butadiene is carried out in a solvent-free system, the reaction conditions are mild and easy to control, the product yield is high, the product and the catalyst are easy to separate, and industrial conversion application is facilitated.

According to the palladium adsorbent with the fluorescence indication function and the preparation method and application of the palladium adsorbent, an aldehyde compound is dispersed in a mixed solution of acid and water, a turbid liquid of a hydrazide compound and water is dropwise added into the obtained aldehyde compound turbid liquid, stirring reaction is conducted at the room temperature, and the palladium adsorbent with the fluorescence indication function is obtained. Different from a conventional two-step method in which an organic polymer needs to be synthesized firstly, the preparation method disclosed by the invention adopts a strategy of pre-activating an aldehyde monomer by using an acid catalyst, so that the nucleophilicity of an amino monomer is prevented from being reduced, the generation of a semi-amine aldehyde intermediate is accelerated, and the reaction efficiency is improved, so that Schiff base condensation can be rapidly synthesized in a water phase at room temperature, and precious metal catalysis is not needed; and batch production can be realized more easily. And the material has an optical indication performance while having an adsorption capacity on palladium, and can be recycled and reused after elution.

The invention belongs to the technical field of production, separation and purification of hydroxyl carbazole, and provides a continuous flow production process of hydroxyl carbazole, which specifically comprises the following steps: (1) mixing raw materials of o-halogenated aniline, benzenediol, an organic solvent and an acid catalyst, and pumping into a first reactor for reaction; (2) sequentially performing extraction, reduced pressure distillation, recrystallization and drying treatment on the reaction liquid at the outlet of the first-stage reactor to obtain a reaction product photoreaction intermediate; (3) continuously pumping a mixed solution of the photoreaction intermediate prepared in the step (2), a photoreaction catalyst and a second solvent into a second-stage photoreactor, and carrying out photochemical reaction under the irradiation of a UV-LED light source; and (4) sequentially carrying out neutralization, reduced pressure distillation and recrystallization on the reaction liquid at the outlet of the second-stage photoreactor to obtain a hydroxyl carbazole product. By adopting the technical scheme provided by the invention, various hydroxycarbazole with high yield and high purity can be prepared, and the production period is shortened.

Disclosed are a preparation method for a SiO2 aerogel and a SiO2 aerogel, and belongs to the technical field of chemical coatings. The preparation method for the SiO2 aerogel comprises the following steps: S100: uniformly mixing an inorganic silicon source, water, a surfactant and an acid catalyst, and gelating the mixture to obtain a wet gel; S200: uniformly mixing a surfactant, a cosolvent and a low-surface-tension solvent to obtain a reverse micelle extraction solution; S300: mixing the wet gel obtained in the step S100 with the reverse micelle extraction solution obtained in the step S200, and soaking the mixture to obtain a gel; and S400: drying the gel obtained in the step S300 to obtain the SiO2 aerogel.

The invention discloses a low-cost high-first-effect micron silicon negative electrode material and a preparation method and application thereof. The preparation method comprises the following steps: treating the surface of micron silicon by adopting an oxidant solution to form a silicon dioxide passivation layer, and then carrying out surface modification by using a silane coupling agent; the method comprises the following steps: performing acid-base alternate soaking treatment on a biomass carbon source to reduce the content of metal impurities; mixing the delimed biomass carbon source, the composite carbon source and the pretreated micron silicon, firstly adding a weak acid catalyst for hydrothermal reaction to form a hard carbon inner layer, then adding a weak base catalyst for regulating the pH value of the system to alkalescence in batches, and continuing hydrothermal reaction to form a soft carbon outer layer; and washing and drying the product, and carrying out carbonization treatment in an inert atmosphere to obtain the composite coated micron silicon material. The first efficiency of the material is greater than or equal to 92%, the 1C 1000-time circulation capacity retention ratio is greater than or equal to 82%, the raw material cost is low, the process is simple, and the material is suitable for lithium ion batteries in the fields of power, energy storage and consumer electronics.

The invention relates to the technical field of adhesives, and provides a high-thermal-conductivity modified silane polyether adhesive and a preparation method thereof.The silane-terminated polyether sealant is prepared from silane modified polyether resin, modified filler, a flame retardant, a silane coupling agent, a catalyst, an antioxidant and a water removal agent; the modified filler is obtained by grafting a hydroxylated AlN filler or a hydroxylated BN filler or a hydroxylated AlN and hydroxylated BN compound filler with silane under the catalysis of a weak acid to form a Si-O-Al or / and Si-O-B covalent bond network, and then mixing the Si-O-Al or / and Si-O-B covalent bond network with nano silicon dioxide particles of which the surfaces are coated with polydopamine. Through a multi-dimensional filler modification technology and reasonable matching of other auxiliaries, the problem of synergism of heat conduction, flame retardance and mechanical properties of the MS adhesive under a high filling system is solved, and the material is suitable for a new energy power battery module.